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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 487 records · Page 27
All sourcesNASA NTRSDOE OSTI
NASA NTRS1996

Modeling of Sound Transmission through Shell Structures with Turbulent Boundary Layer Excitation

The turbulent boundary layer (TBL) pressure field is an important source of cabin noise during cruise of high subsonic and supersonic commercial aircraft. The broadband character of this excitation field results in an interior noise spectrum that dominates the overall sound pressure level (SPL) and speech interference metrics in the forward and midcabins of many aircraft. In the authors' previous study, sound transmission through an aircraft fuselage, modeled by two concentric cylindrical sandwich shells and excited by a TBL statistical model was investigated analytically. An assessment of point and global structural vibration levels and resulting interior noise levels was obtained for different TBL models, flight conditions and fuselage structural designs. However, due to the complication of the shell structure, the important noise transmission mechanisms were difficult to discern. Previous experience has demonstrated that a fundamental understanding of the range of modes (or wavenumbers) generated by the TBL source both in the structure and the acoustic cavity is key to the development of both active and passive control technologies. In an initial effort to provide this insight, the objective of this paper is to develop an analytical model of sound transmission through a simple unstiffened cylindrical aluminum shell excited by a TBL pressure field. The description of the turbulent pressure field is based on the Corcos formulation for the cross-spectral density (CSD) of the pressure fluctuations. The coupled shell and interior and exterior acoustic equations are solved for the structural displacement and the interior acoustic response using a Galerkin approach to obtain analytical solutions. Specifically, this study compares the real part of the normalized CSD of the TBL excitation field, the structural displacement and the interior acoustic field. Further the modal compositions of the structural and cavity response are examined and some inference of the dominant mechanism of noise transmission is made.

Tang, Yvette Y.↗
NASA NTRS2000

A semiempirical study for the ground and excited states of free-base and zinc porphyrin-fullerene dyads

The ground and excited states of a covalently linked porphyrin-fullerene dyad in both its free-base and zinc forms (D. Kuciauskas et al., J. Phys. Chem. 100 (1996) 15926) have been investigated by semiempirical methods. The excited-state properties are discussed by investigation of the character of the molecular orbitals. All frontier MOs are mainly localized on either the donor or the acceptor subunit. Thus, the absorption spectra of both systems are best described as the sum of the spectra of the single components. The experimentally observed spectra are well reproduced by the theoretical computations. Both molecules undergo efficient electron transfer in polar but not in apolar solvents. This experimental finding is explained theoretically by explicitly considering solvent effects. The tenth excited state in the gas phase is of charge-separated character where an electron is transferred from the porphyrin donor to the fullerene acceptor subunit. This state is stabilized in energy in polar solvents due to its large formal dipole moment. The stabilization energy for an apolar environment such as benzene is not sufficient to lower this state to become the first excited singlet state. Thus, no electron transfer is observed, in agreement with experiment. In a polar environment such as acetonitrile, the charge-separated state becomes the S, state and electron transfer takes place, as observed experimentally. The flexible single bond connecting both the donor and acceptor subunits allows free rotation by ca. +/- 30 degrees about the optimized ground-state conformation. For the charge-separated state this optimized geometry has a maximum dipole moment. The geometry of the charge-separated state thus does not change relatively to the ground-state conformation. The electron-donating properties of porphyrin are enhanced in the zinc derivative due to a reduced porphyrin HOMO-LUMO energy gap. This yields a lower energy for the charge-separated state compared to the free-base dyad.

Bridged Compounds/chemistry↗
NASA NTRS2005

Excitation of Earth Rotation Variations "Observed" by Time-Variable Gravity

Time variable gravity measurements have been made over the past two decades using the space geodetic technique of satellite laser ranging, and more recently by the GRACE satellite mission with improved spatial resolutions. The degree-2 harmonic components of the time-variable gravity contain important information about the Earth s length-of-day and polar motion excitation functions, in a way independent to the traditional "direct" Earth rotation measurements made by, for example, the very-long-baseline interferometry and GPS. In particular, the (degree=2, order= 1) components give the mass term of the polar motion excitation; the (2,O) component, under certain mass conservation conditions, gives the mass term of the length-of-day excitation. Combining these with yet another independent source of angular momentum estimation calculated from global geophysical fluid models (for example the atmospheric angular momentum, in both mass and motion terms), in principle can lead to new insights into the dynamics, particularly the role or the lack thereof of the cores, in the excitation processes of the Earth rotation variations.

Chao, Ben F.↗
NASA NTRS2005

Acoustics of Excited Jets: A Historical Perspective

The idea that a jet may be excited by external forcing is not new. The first published demonstration of a jet responding to external pressure waves occurred in the mid-1800's. It was not, however, until the 1950's, with the advent of commercial jet aircraft, that interest in the subject greatly increased. Researchers first used excited jets to study the structure of the jet and attempt to determine the nature of the noise sources. The jet actuators of the time limited the range (Reynolds and Mach numbers) of jets that could be excited. As the actuators improved, more realistic jets could be studied. This has led to a better understanding of how jet excitation may be used not only as a research tool to understand the flow properties and noise generation process, but also as a method to control jet noise.

Brown, Cliffard A.↗
NASA NTRS2007

Tailored Excitation for Frequency Response Measurement Applied to the X-43A Flight Vehicle

An important aspect of any flight research project is assessing aircraft stability and flight control performance. In some programs this assessment is accomplished through the estimation of the in-flight vehicle frequency response. This estimation has traditionally been a lengthy task requiring separate swept sine inputs for each control axis at a constant flight condition. Hypersonic vehicles spend little time at any specific flight condition while they are decelerating. Accordingly, it is difficult to use traditional methods to calculate the vehicle frequency response and stability margins for this class of vehicle. A technique has been previously developed to significantly reduce the duration of the excitation input by tailoring the input to excite only the frequency range of interest. Reductions in test time were achieved by simultaneously applying tailored excitation signals to multiple control loops, allowing a quick estimate of the frequency response of a particular aircraft. This report discusses the flight results obtained from applying a tailored excitation input to the X-43A longitudinal and lateral-directional control loops during the second and third flights. The frequency responses and stability margins obtained from flight data are compared with preflight predictions.

Baumann, Ethan↗
NASA NTRS2009

Investigating Response from Attached and Separated Flow Excitations on a Real Launch Vehicle using SEA

Statistical Energy Analysis (SEA) response has been fairly well anchored to test observations for Diffuse Acoustic Field (DAF) loading by others. Meanwhile, not many examples can be found in the literature anchoring the SEA vehicle panel response results to Turbulent Boundary Layer (TBL) fluctuating pressure excitations. This deficiency is especially true for supersonic trajectories such as those required by this nation s launch vehicles. Response and excitation data from vehicle flight measurements gathered during the development flight era of the Space Shuttle have been used in a trial to assess the sensitivity of response analysis to certain known and unknown parameters of the flight. This assessment compares vibration response predictions for TBL excitations produced by the SEA tool to flight measurements. A secondary, but perhaps more important objective, is to provide more clarity concerning the accuracy and conservatism that can be expected from response estimates to TBL-excited vehicle models in SEA. What range of parameters must be included in such an analysis in order to land on the conservative side in response predictions? What is the variability produced in the results with changes in these parameters? The TBL fluid structure loading model used for this study is provided from the SEA module of the commercial code VA One.

Harrison, Phil↗
NASA NTRS2011

LES of a Jet Excited by the Localized Arc Filament Plasma Actuators

The fluid dynamics of a high-speed jet are governed by the instability waves that form in the free-shear boundary layer of the jet. Jet excitation manipulates the growth and saturation of particular instability waves to control the unsteady flow structures that characterize the energy cascade in the jet.The results may include jet noise mitigation or a reduction in the infrared signature of the jet. The Localized Arc Filament Plasma Actuators (LAFPA) have demonstrated the ability to excite a high-speed jets in laboratory experiments. Extending and optimizing this excitation technology, however, is a complex process that will require many tests and trials. Computational simulations can play an important role in understanding and optimizing this actuator technology for real-world applications. Previous research has focused on developing a suitable actuator model and coupling it with the appropriate computational fluid dynamics (CFD) methods using two-dimensional spatial flow approximations. This work is now extended to three-dimensions (3-D) in space. The actuator model is adapted to a series of discrete actuators and a 3-D LES simulation of an excited jet is run. The results are used to study the fluid dynamics near the actuator and in the jet plume.

Brown, Clifford A.↗
NASA NTRS2017

Decadal Polar Motion of the Earth Excited by the Convective Outer Core From Geodynamo Simulations

Long time geodetic observation records show that the orientation of the Earth's rotation axis with respect to the terrestrial reference frame, or polar motion, changes on a broad range of timescales. Apart from external torques from the luni-solar tides, these changes are excited by interactions among different components of the Earth system. The convective fluid outer core has long been conjectured a likely contributor to the observed polar motion on timescales upward of decades, such as the 30 year Markowitz wobble. We investigated the electromagnetic coupling scenario across the core-mantle boundary via numerical geodynamo simulation for different geodynamo parameters (Rayleigh numbers and magnetic Rossby numbers). Our simulated polar motion varies strongly with the dynamo parameters, while its excitation on decadal timescales appear to converge asymptotically within the adopted range of numerical Rossby numbers. Three strongest asymptotic modes emerge from numerical results, with periods around 30, 40, and 60 years for the prograde excitation and around 24, 30, and 60 years for the retrograde excitation. Their amplitudes are all larger than 5 times 10 (sup minus 8), or approximately 10 milliseconds of arc.The results suggest that the electromagnetic core-mantle coupling could explain a substantial portion, if not all, of the observed decadal polar motion. In particular, the predicted 60 year polar motion deserves special attention for future observations and studies.

Kuang, W.↗
NASA NTRS2018

The Exoplanet Climate Infrared TElescope (EXCITE)

Although there are a large number of known exoplanets, there is little data on their global atmospheric properties.Phase-resolved spectroscopy of transiting planets - continuous spectroscopic observation of planets during their full orbits - probes varied depths and longitudes in the atmospheres thus measuring their three-dimensional thermal and chemical structure and contributing to our understanding of their global circulation. Planets with characteristics suitable for atmospheric characterization have orbits of several days, so phase curve observations are highly resource intensive, especially for shared use facilities. The Exoplanet Climate Infrared TElescope (EXCITE) is a balloon-borne near-infrared spectrometer designed to observe from 1 to 5 meters to perform phase-resolved spectroscopy of hot Jupiters. Flying from a long duration balloon (LDB) platform, EXCITE will have the stability to continuously stare at targets for days at a time and the sensitivity to produce data of the quality and quantity needed to signicantly advance our understanding of exoplanet atmospheres. We describe the EXCITE design and show results of analytic and numerical calculations of the instrument sensitivity. We show that an instrument like EXCITE will produce a wealth of quality data, both complementing and serving as a critical bridge between current and future space-based near infrared spectroscopic instruments.

Spectroscopy↗
NASA NTRSDate not supplied

Intense High-Energy ESP Events and Self-Excited Waves at Inner Heliospheric Distances

Energetic Storm Particle (ESP) events are particle intensity increases associated with the passage of interplanetary (IP) shocks. Although ESP events at 1 AU are usually a low-energy phenomenon (i.e., at proton energies <10 MeV), occasionally they may reach energies of >100 MeV. An analysis of the ESP events observed at proton energies >40 MeV over the last four solar cycles shows that these high-energy particle intensity increases tend to occur when unrelated IP structures such as intervening coronal mass ejections and other unlinked shocks are present in the solar wind through which the IP shock generating the ESP event propagates. The acceleration of particles by IP shocks becomes more efficient when particles repeatedly interact with the traveling shocks. These multiple interactions may be favored by either the effects that these unrelated IP structures produce in the particle transport, or by amplified magnetic field fluctuations excited by the accelerated particles. However, the search for these self-excited waves at IP shocks at 1 AU has been often unsuccessful, with just a handful of events showing enhanced field fluctuations that can resonate with the energetic particles. Modeling results indicate that particle acceleration to the highest energies by the shocks occurs close to the Sun, resulting in large intensities of self-excited waves. We have initiated a search for ESP events in the inner heliosphere with evidence for self-excited waves and few cases observed by Parker Solar Probe will be shown.

David Lario↗
NASA NTRSDate not supplied

Ab Initio Electronic Structure Calculations of CNN for CN Excitation Studies

The CN molecule is an important contributor to radiative heat flux in shock layers around vehicles entering Titan’s atmosphere. Current data for heavy particle (de)excitation rate coefficients of CN leads to uncertainties in the population of CN in its first and second excited states. This in turn leads to uncertainties in the radiative heat flux predicted by Computational Fluid Dynamics (CFD) simulations of Titan atmospheric entry. This work performs ab initio electronic structure calculations of the CNN complex to create Potential Energy Surfaces (PESs) that correlate to the ground and first and second excited states of CN. Specifically, the state combinations of CN(X,A,B) + N(4S𝑜) correlate to six states of CNN (three Quintet A” and three Triplet A”). Initial calculations of these states suggest that heavy particle (de)excitation of CN by N atoms is likely to proceed through collinear geometries on triplet surfaces. Complete PESs will show all of the reaction pathways in detail, and will be used in nonadiabatic dynamics calculations to evaluate improved rate coefficients and reduce uncertainty in the radiative heat flux during Titan entry.

Eric C Geistfeld↗
NASA NTRSDate not supplied

Ab Initio Electronic Structure Calculations of CNN for CN Excitation Studies

The CN molecule is an important contributor to radiative heat flux in shock layers around vehicles entering Titan’s atmosphere. Current data for heavy particle (de)excitation rate coefficients of CN leads to uncertainties in the population of CN in its first and second excited states. This in turn leads to uncertainties in the radiative heat flux predicted by Computational Fluid Dynamics (CFD) simulations of Titan atmospheric entry. This work performs ab initio electronic structure calculations of the CNN complex to create Potential Energy Surfaces (PESs) that correlate to the ground and first and second excited states of CN. Specifically, the state combinations of CN(X,A,B) + N(4S𝑜) correlate to six states of CNN (three Quintet A” and three Triplet A”). Initial calculations of these states suggest that heavy particle (de)excitation of CN by N atoms is likely to proceed through collinear geometries on triplet surfaces. Complete PESs will show all of the reaction pathways in detail, and will be used in nonadiabatic dynamics calculations to evaluate improved rate coefficients and reduce uncertainty in the radiative heat flux during Titan entry.

Eric Geistfeld↗
DOE OSTI2026

Brushless Excitation for Wound-field Synchronous Machines using Multi-harmonic Windings

Wound-field synchronous machines (WFSM) are promising alternatives to electric machines with permanent magnets (PM). The ability to control the rotor field in these machines makes them well-suited to safety critical applications, while the absence of rare-earth permanent magnets makes these machines sustainable. The WFSM rotor excitation schemes have traditionally used carbon brushes, which significantly reduces the reliability of these machines, limiting their widespread adoption. To overcome this limitation and improve the reliability of WFSMs, several brushless rotor excitation schemes have been developed. However, most of these systems require additional windings or dedicated power electronics, making them expensive and limiting achievable power-density. In this paper a new brushless excitation scheme is proposed. In this scheme, a multiphase, multi-harmonic stator winding is designed. This winding can independently control two spatial harmonics in the airgap of the machine; the first to create torque and the second to wirelessly transfer power to the rotor to excite it.

Gadiyar, Nishanth [ORNL] (ORCID:0000000348267524)↗
DOE OSTI2020

Excitations of Intercalated Metal Monolayers in Transition Metal Dichalcogenides

We combine Raman scattering spectroscopy and lattice dynamics calculations to reveal the fundamental excitations of the intercalated metal monolayers in the Fe x TaS 2 (x = 1/4, 1/3) family of materials. Both in- and out-of-plane modes are identified, each of which has trends that depend upon the metal–metal distance, the size of the van der Waals gap, and the metal-to-chalcogenide slab mass ratio. We test these trends against the response of similar systems, including Cr-intercalated NbS 2 and RbFe(SO 4 ) 2 , and demonstrate that the metal monolayer excitations are both coherent and tunable. Here, we discuss the consequences of intercalated metal monolayer excitations for material properties and developing applications.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2022

Plasmon-induced excitation energy transfer in silver nanoparticle dimers: A real-time TDDFTB investigation

Here, using real-time quantum dynamics calculations, we perform theoretical investigations of light-induced interactions and electronic excitation transfer in a silver nanoparticle dimer. Real-time time-dependent density functional tight-binding (RT-TDDFTB) calculations provide details of the quantum dynamical processes at an electronic/atomistic level with attosecond resolution. The computational efficiency of RT-TDDFTB allows us to examine electronic dynamics up to picosecond time scales. With time scales varying over six orders of magnitude, we provide insight into interactions between the nanoparticle and laser and between nanoparticles. Our results show that the coupling between nanoparticle monomers is dependent on the separation distance between the nanoparticles in the dimer. As the interparticle distance is varied, the dipole–dipole interactions and electronic excitation transfer mechanisms are markedly different. At large distances (from 50 to 20 Å), the energy transfer from NP1 to NP2 becomes more efficient as the interparticle distance decreases. The total dipole moment of the Ag 14 nanoparticle dimer increases linearly at an interparticle distance of 20 Å and reaches its maximum after 1.2 ps. The electronic excitation transfer is also the most efficient at 20 Å. At short distances, back-transfer effects reduce the ability of the dimer and NP1 to accept energy from the incident electric field. We attribute the distance-dependent features of the nanoparticle dimer to the beating between the laser acting on NP1 and the back transfer from NP2 to NP1.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Kinetics of the luminescence decay of Fe{sup 2+} impurity centres in polycrystalline ZnSe upon excitation by an electron beam

The kinetics of the decay of the luminescence of Fe{sup 2+} ions is measured at nitrogen temperature in polycrystalline ZnSe excited by a short pulse of accelerated electrons. The time dependence of the luminescence intensity differs from the exponential one, observed upon excitation of luminescence by a short light pulse. The obtained nonexponential dependence is theoretically described. The explanation is based on the quenching effect of the excited state of the Fe{sup 2+} ion by free electrons of the volume charge of the current of accelerated electrons in the sample (Auger effect). It was shown that the relaxation of the volume charge after the electron-accelerating voltage is removed makes a significant contribution to the decay kinetics of the impurity luminescence. (paper)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2022

libwfa: Wavefunction analysis tools for excited and open‐shell electronic states

Abstract An open‐source software library for wavefunction analysis, libwfa, provides a comprehensive and flexible toolbox for post‐processing excited‐state calculations, featuring a hierarchy of interconnected visual and quantitative analysis methods. These tools afford compact graphical representations of various excited‐state processes, provide detailed insight into electronic structure, and are suitable for automated processing of large data sets. The analysis is based on reduced quantities, such as state and transition density matrices (DMs), and allows one to distill simple molecular orbital pictures of physical phenomena from intricate correlated wavefunctions. The implemented descriptors provide a rigorous link between many‐body wavefunctions and intuitive physical and chemical models, for example, exciton binding, double excitations, orbital relaxation, and polyradical character. A broad range of quantum‐chemical methods is interfaced with libwfa via a uniform interface layer in the form of DMs. This contribution reviews the structure of libwfa and highlights its capabilities by several representative use cases. This article is categorized under: Software > Quantum Chemistry Theoretical and Physical Chemistry > Spectroscopy

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Vibrationally resolved ionization cross sections for the ground state and electronically excited states of the hydrogen molecule and its isotopomeres

An existing set of vibrationally resolved ionization cross section for the ground state and the first excited states of the hydrogen molecule, based on the Gryzinski method, is extended by cross sections for the isotopomeres of H{sub 2} (i.e. D{sub 2}, T{sub 2}, HD, HT, and DT), both for non-dissociative and dissociative ionizations. The comparison of cross sections for non-dissociative ionization of H{sub 2} with results obtained by the Molecular Convergent Close-Coupling method gives a very good agreement. The compiled tables give non-dissociative and dissociative cross sections for the ground state and the five energetically lowest electronically excited states of H{sub 2} and its isotopomeres, in each case for the first 9 vibrational levels. Data for all vibrational levels of the excited states is available online.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗