Search NASA⌕ Search

SEARCH · Search NASA

Results for “hydrogen analysis”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 487 records · Page 27

Analytical and experimental investigation of rubbing interaction in labyrinth seals for a liquid hydrogen fuel pump

Cracking of the titanium knife edges on the labyrinth seals of the liquid hydrogen fuel pump in the Space Shuttle main engine is considered. Finite element analysis of the thermal response of the knife edge in sliding contact with the wear ring surface shows that interfacial temperatures can be quite high and they are significantly influenced by the thermal conductivity of the surfaces in rubbing contact. Thermal shock experiments on a test specimen similar to the knife edge geometry demonstrate that cracking of the titanium alloy is possible in a situation involving repeated thermal cycles over a wide temperature range, as might be realized during a rub in the liquid hydrogen fuel pump. High-speed rub interaction tests were conducted using a representative knife edge and seal geometry over a broad range of interaction rates and alternate materials were experimentally evaluated. Plasma-sprayed aluminum-graphite was found to be significantly better than presently used aluminum alloy seals from the standpoint of rub performance. Ion nitriding the titanium alloy knife-edges also improved rub performance compared to the untreated baseline.

Dolan, F. X.↗

Control System Development for A Zero Boil-Off Hydrogen Storage Demonstration With Two-Stage Active Cooling

A NASA team is designing and building a test article to demonstrate the long duration storage of liquid hydrogen via active cooling (cryocoolers) while implementing a two-stage cooling approach. This activity is one of a large portfolio of NASA’s Space Technology Mission Directorate funded activities which focuses on the technology maturation needed for long duration storage of cryogenic liquid in-space. The current state-of-the-art for liquid hydrogen storage on-orbit is on the order of hours while NASA’s planned missions require storage for months, or even years. To enable such a long duration, Zero Boil-Off conditions must be achieved which requires passive technologies to minimize environmental heat loads, but also active cooling to intercept and reject the remaining heat to deep space. The implementation of active cooling results in a significant amount of dry mass added to the vehicle. Utilizing a Two-Stage Cooling approach, analysis and testing to date indicates the Zero Boil-Off of liquid hydrogen can be achieved with less mass and electrical power relative to a single-stage cooling approach where only one cryocooler is used. This activity will demonstrate the fully integrated suite of technologies needed to enable the Two-Stage Cooling approach which includes Multi-Layer Insulation blankets, Low Conductivity Structures, a Tube-On-Tank Heat Exchanger, Tube-On-Shield Heat Exchanger and a Two-Stage Cryogenerator (both 90 Kelvin and 20 Kelvin) with each stage having an independently controlled circulation loop. The bulk of the heat load is intercepted by the 90 Kelvin loop via a thin foil heat exchanger internal to the insulation blankets (also known as a Broad Area Cooling Shield), with the remainder removed at cryofluid temperature (20 Kelvin) by tubes directly welded to the outer tank surface. In this paper, we examine the challenges of controlling the system, and describe the development of control algorithms and software for future testing with liquid hydrogen. The interactions between the cryofans which control circulation loop mass flow rates, electrical heaters which vary the cryocooler lift to simulate the operation of variable-lift flight units, tank heaters which can vary the overall heat load, and the effects of changes in circulation loop pressure as temperatures change, can be complex and must be well understood to maintain steady-state propellant conditions and achieve Zero Boil-Off. Parallel PID loops and watchdog programs implemented on the user interface system will help bring the systems to steady state operation and keep them at selected operating points within acceptable error, while avoiding runaway feedback loops.

cryogenics↗

Photospheres of hot stars. IV - Spectral type O4

The basic stellar parameters of a supergiant (Zeta Pup) and two main-sequence stars, 9 Sgr and HD 46223, at spectral class O4 are determined using line profile analysis. The stellar parameters are determined by comparing high signal-to-noise hydrogen and helium line profiles with those from stellar atmosphere models which include the effect of radiation scattered back onto the photosphere from an overlying stellar wind, an effect referred to as wind blanketing. At spectral class O4, the inclusion of wind-blanketing in the model atmosphere reduces the effective temperature by an average of 10 percent. This shift in effective temperature is also reflected by shifts in several other stellar parameters relative to previous O4 spectral-type calibrations. It is also shown through the analysis of the two O4 V stars that scatter in spectral type calibrations is introduced by assuming that the observed line profile reflects the photospheric stellar parameters.

Bohannan, Bruce↗

Resources Available for Hazards Analysis of Aerospace Fluids

In recent years, the legislative and executive branches of the federal government have pushed to make government more efficient and responsive to the needs of the marketplace. One of these initiatives, Public Law 104-113, also known as the National Technology Transfer and Advancement Act of 1995 (NTTAA), is designed to accelerate technology transfer to industry and promote government-industry partnership. Summarized, NTTAA states that '... all Federal agencies and departments shall use technical standards that are developed or adopted by voluntary consensus standards bodies, using such technical standards as a means to carry out policy objectives or activities determined by the agencies and departments. Government agencies must now determine if their in-house requirement-setting activities are sufficiently unique that no public interest is served by having them adopted by a voluntary consensus organization (VCO), or if not, to use or develop voluntary consensus standards. The Office of Management and Budget (OMB) is chartered by the law to monitor federal agency progress and report the results to Congress. In response to NTTAA, agency-wide oxygen and hydrogen safety standards sponsored by the NASA Headquarters (HQ) Office of Safety and Mission Assurance (OSMA) were obvious choices for early adoption by VCOs. In 1996, HQ sought assistance from the Johnson Space Center (JSC) White Sands Test Facility (WSTF), the technical lead for development of these safety standards, to evaluate their adoption by VCOs. At that time, WSTF-developed propellant hazards manuals were likewise identified for possible VCO adoption. Subsequently, WSTF was asked to represent NASA for development of an international ISO safety standard for hydrogen use. Concurrent with these WSTF standards activities are related efforts to develop and publish propellant hazards analysis protocols and safety courses for the industrial, propellant use of oxygen, hydrogen, and hypergols. This paper reports on these efforts and describes WSTF's overall voluntary consensus standards program to coordinate the interchange of NASA's propellant hazards and safety information with industry.

Woods, S. S.↗

Stirling engine supporting research and technology

The supporting research and technology effort is intended to provide technical support to the current engine program and also to investigate advanced concepts for the next generation of Stirling engines. Technical areas represented are: seals, materials, engine experiments, combustion, system analysis, cseramics, and tribology. A collage of more recent work in each area is presented. Under seals, analysis and some experimental data on the effect of wear on rod seal performance is presented. The material work described concerns the effect of water content on hydrogen permeation. Results of experiments with the Philips' Advenco engine are presented. A comparison is made of two combustor nozzles, an air atomizing and an ultrasonic atomizing nozzle. A new venture in systems analysis to provide more rigorous Stirling engine simulation is discussed. The results of hydrogen corrosion tests on silicon carbide are presented. Friction and wear tests on candidate materials for engine hot ring tests are discussed.

Tomazic, W. A.↗

Weight savings in aerospace vehicles through propellant scavenging

Vehicle payload benefits of scavenging hydrogen and oxygen propellants are addressed. The approach used is to select a vehicle and a mission and then select a scavenging system for detailed weight analysis. The Shuttle 2 vehicle on a Space Station rendezvous mission was chosen for study. The propellant scavenging system scavenges liquid hydrogen and liquid oxygen from the launch propulsion tankage during orbital maneuvers and stores them in well insulated liquid accumulators for use in a cryogenic auxiliary propulsion system. The fraction of auxiliary propulsion propellant which may be scavenged for propulsive purposes is estimated to be 45.1 percent. The auxiliary propulsion subsystem dry mass, including the proposed scavenging system, an additional 20 percent for secondary structure, an additional 5 percent for electrical service, a 10 percent weight growth margin, and 15.4 percent propellant reserves and residuals is estimated to be 6331 kg. This study shows that the fraction of the on-orbit vehicle mass required by the auxiliary propulsion system of this Shuttle 2 vehicle using this technology is estimated to be 12.0 percent compared to 19.9 percent for a vehicle with an earth-storable bipropellant system. This results in a vehicle with the capability of delivering an additional 7820 kg to the Space Station.

Schneider, Steven J.↗

Weight savings in aerospace vehicles through propellant scavenging

Vehicle payload benefits of scavenging hydrogen and oxygen propellants are addressed. The approach used is to select a vehicle and a mission and then select a scavenging system for detailed weight analysis. The Shuttle 2 vehicle on a Space Station rendezvous mission was chosen for study. The propellant scavenging system scavenges liquid hydrogen and liquid oxygen from the launch propulsion tankage during orbital maneuvers and stores them in well insulated liquid accumulators for use in a cryogenic auxiliary propulsion system. The fraction of auxiliary propulsion propellant which may be scavenged for propulsive purposes is estimated to be 45.1 percent. The auxiliary propulsion subsystem dry mass, including the proposed scavenging system, an additional 20 percent for secondary structure, an additional 5 percent for electrical service, a 10 percent weight growth margin, and 15.4 percent propellant reserves and residuals is estimated to be 6331 kg. This study shows that the fraction of the on-orbit vehicle mass required by the auxiliary propulsion system of this Shuttle 2 vehicle using this technology is estimated to be 12.0 percent compared to 19.9 percent for a vehicle with an earth-storable bipropellant system. This results in a vehicle with the capability of delivering an additional 7820 kg to the Space Station.

Schneider, Steven J.↗

Hazardous Gas Leak Analysis in the Space Shuttle

Helium tests of the main propulsion system in the Space Shuttle and on hydrogen leaks are examined. The hazardous gas detection system (HGDS) in the mobile launch pad uses mass spectrometers (MS) to monitor the shuttle environment for leaks. The mass spectrometers are fed by long tubes to sample gas from the payload bay, mid-body, aft engine compartment, and external tank. The purpose is to improve the HGDS, especially in its potential for locating cryogen leaks. Pre-existing leak data was analyzed for transient information to determine if the leak location could be pinpointed from test data. A rapid response leak detection experiment was designed, built, and tested. Large eddies and vortices were visually seen with Schlieren imaging, and they were detected in the time plots of the various instruments. The response time of the MS was found in the range of 0.05 to 0.1 sec. Pulsed concentration waves were clearly detected at 25 cycles per sec by spectral analysis of MS data. One conclusion is that the backup HGDS sampling frequency should be increased above the present rate of 1 sample per second.

Barile, Ronald G.↗

Systems Analysis Initiated for All-Electric Aircraft Propulsion

A multidisciplinary effort is underway at the NASA Glenn Research Center to develop concepts for revolutionary, nontraditional fuel cell power and propulsion systems for aircraft applications. There is a growing interest in the use of fuel cells as a power source for electric propulsion as well as an auxiliary power unit to substantially reduce or eliminate environmentally harmful emissions. A systems analysis effort was initiated to assess potential concepts in an effort to identify those configurations with the highest payoff potential. Among the technologies under consideration are advanced proton exchange membrane (PEM) and solid oxide fuel cells, alternative fuels and fuel processing, and fuel storage. Prior to this effort, the majority of fuel cell analysis done at Glenn was done for space applications. Because of this, a new suite of models was developed. These models include the hydrogen-air PEM fuel cell; internal reforming solid oxide fuel cell; balance-of-plant components (compressor, humidifier, separator, and heat exchangers); compressed gas, cryogenic, and liquid fuel storage tanks; and gas turbine/generator models for hybrid system applications. Initial mass, volume, and performance estimates of a variety of PEM systems operating on hydrogen and reformate have been completed for a baseline general aviation aircraft. Solid oxide/turbine hybrid systems are being analyzed. In conjunction with the analysis efforts, a joint effort has been initiated with Glenn s Computer Services Division to integrate fuel cell stack and component models with the visualization environment that supports the GRUVE lab, Glenn s virtual reality facility. The objective of this work is to provide an environment to assist engineers in the integration of fuel cell propulsion systems into aircraft and provide a better understanding of the interaction between system components and the resulting effect on the overall design and performance of the aircraft. Initially, three-dimensional computer-aided design (CAD) models of representative PEM fuel cell stack and components were developed and integrated into the virtual reality environment along with an Excel-based model used to calculate fuel cell electrical performance on the basis of cell dimensions (see the figure). CAD models of a representative general aviation aircraft were also developed and added to the environment. With the use of special headgear, users will be able to virtually manipulate the fuel cell s physical characteristics and its placement within the aircraft while receiving information on the resultant fuel cell output power and performance. As the systems analysis effort progresses, we will add more component models to the GRUVE environment to help us more fully understand the effect of various system configurations on the aircraft.

Kohout, Lisa L.↗

Model for the formation of silicon carbide from the pyrolysis of dichlorodimethylsilane in hydrogen. I - Silicon formation from chlorosilanes. II - Silicon carbide formation from silicon and methane

In the first part of this work, a model is developed for the deposition of silicon from the reduction of silicon tetrachloride with hydrogen in a tubular reactor at 700-1100 C, at atmospheric pressure. The model is based on gas chromatography of the volatile products of the reaction, followed by gravimetric analysis of total Si deposition on the tube. In the second part of this work, a model is developed for the case of SiC deposition from the pyrolysis of dichlorodimethylsilane in hydrogen under the same reactor conditions. The rate constants derived from a nonlinear regression analysis are reported.

Cagliostro, Domenick E.↗

Coal gasification systems engineering and analysis. Appendix C: Alternate product facility designs

The study of the production of methane, methanol, gasoline, and hydrogen by an add-on facility to a Koppers-Totzek based MBG plant is presented. Applications to a Texaco facility are inferred by evaluation of delta effects from the K-T cases. The production of methane from an add-on facility to a Lurgi based MBG plant and the co-production of methane and methanol from a Lurgi based system is studied. Studies are included of the production of methane from up to 50 percent of the MBG produced in an integrated K-T based plant and the production of methane from up to 50 percent of the MBG produced from an integrated plant in which module 1 is based on K-T technology and modules 2, 3, and 4 are based on Texaco technology.

Source record↗

Polycyclic aromatic hydrocarbons and the unidentified infrared emission bands - Auto exhaust along the Milky Way

The unidentified infrared emission features (UIR bands) are attributed to a collection of partially hydrogenated, positively charged polycyclic aromatic hydrocarbons (PAHs). This assignment is based on a spectroscopic analysis of the UIR bands. Comparison of the observed interstellar 6.2 and 7.7-micron bands with the laboratory measured Raman spectrum of a collection of carbon-based particulates (auto exhaust) shows a very good agreement, supporting this identification. The infrared emission is due to relaxation from highly vibrationally and electronically excited states. The excitation is probably caused by UV photon absorption. The infrared fluorescence of one particular, highly vibrationally excited PAH (chrysene) is modeled. In this analysis the species is treated as a molecule rather than bulk material and the non-thermodynamic equilibrium nature of the emission is fully taken into account. From a comparison of the observed ratio of the 3.3 to 11.3-micron UIR bands with the model calculations, the average number of carbon atoms per molecule is estimated to be about 20. The abundance of interstellar PAHs is calculated to be about 2 x 10 to the -7th with respect to hydrogen.

Allamandola, L. J.↗

Soft X-ray and H I surveys of the low N(sub H) region in Ursa Major

A region of almost 300 deg squared in Ursa Major around the direction of the lowest neutral hydrogen column density in the sky has been surveyed in the 1/4 keV X-ray band (approximately 0.12 to 0.284 keV at 10% of the peak response) using the ROSAT position sensitive proportional counter (PSPC) and has been fully mapped in the 21 cm line of neutral hydrogen with an angular resolution of 21' or better. We present maps of these two data sets and an analysis of the spatial correlation between them. Over the entire field, the 1/4 keV band X-ray count rate shows a strong negative correlation with the column density of Galactic neutral hydrogen. We discuss the local, extragalactic, and halo contributions to the observed diffuse X-ray intensity and derive an upper limit to the Galactic X-ray emission originating beyond this H I distribution that is more than a factor of 7 smaller than the inferred flux beyond the Draco nebula, an apparent halo object located approximately 41 degs away. This implies that while there may be significant amounts of hot gas in the Galactic halo, its properties must vary strongly across the sky.

Snowden, S. L.↗

Extended atmospheres of outer planet satellites and comets

The new cometary hydrogen particle-trajectory model, completed last year, has been used successfully to analyze observations of Comet P/Giacobini-Zinner. The Pioneer Venus Orbiter Ultraviolet Spectrometer observed the comet at 1216 A (hydrogen Lyman-a) on 11 September 1985 when the comet was 1.03 AU from the Sun and 1.09 AU from Venus. The analysis implies a production rate at 1.03 AU 2.3 x 10 to the 28th power/sec of the water molecules which photodissociate to produce the observed hydrogen. An upper limit for the H2O production rate of Comet P/Halley of 5 x 10 to the 28th power/sec at 2.60 AU was also obtained from the Pioneer Venus instrument.

Smyth, W. H.↗

Electromagnetic pulse from supernovae

Upper and lower limits to the radiated electromagnetic pulse from a supernova are calculated assuming that the mass fraction of the matter expanding inside the dipole magnetic field shares energy and maintains the pressure balance in the process. A supernova model is described in which the explosion occurs in old low-mass stars containing less than 10% hydrogen in their ejecta and a remnant neutron star is produced. The analysis indicates that although the surface layer of a star of 1 g/cu thickness may be shock-accelerated to an energy factor of about 100 and may expand into the vacuum with an energy factor approaching 10,000, the equatorial magnetic field will retard this expansion so that the inner, more massive ejecta layers will effectively accelerate the presumed canonical dipole magnetic field to greater velocities than would the surface layer alone. A pulse of 10 to the 46th power ergs in a width of about 150 cm will result which will not be affected by circumstellar matter or electron self-radiation effects. It is shown that interstellar matter will attenuate the pulse, but that charge separation may reduce the attenuation and allow a larger pulse to escape.

Colgate, S. A.↗

Composition and thermal profiles of the Jovian upper atmosphere determined by the Voyager ultraviolet stellar occultation experiment

During the occultation of the star Regulus (B7 type) by Jupiter as seen from the Voyager 2 spacecraft on July 9, 1979, two absorbing regions were detected. Between 911 and 1200 A, H2 was absorbing over a 600 km altitude range. Above 1300 A, the rapid increase of the absorption by the hydrocarbons was observed over an altitude interval of approximately 100 km with a height resolution of 3 km. The analysis of these absorption features has provided the height profiles of molecular hydrogen, methane, ethane, and acetylene, as well as the thermal profile in the upper atmosphere of Jupiter. Combining the Voyager ultraviolet spectrometer results with other data, such as those obtained by the Voyager infrared and radioscience instruments, has yielded a comprehensive model of the composition and structure of the atmosphere of Jupiter.

Festou, M. C.↗