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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 487 records · Page 27

An approach to urban waterway assessment using holistic values and reciprocity

Current aquatic ecosystem assessment methods and tools often focus on physical, chemical, and biological indicators of ecosystem health. This approach to ecosystem assessment is not always straightforward to execute in urban environments and ignores potential connectivity between social and environmental outcomes. During a workshop at the Symposium on Urbanization and Stream Ecology in Brisbane, Australia in 2023 (SUSE6), we developed an approach to urban aquatic ecosystem assessment that incorporates a holistic perspective. Specifically, our approach considers both environmental (biological, chemical, and physical integrity) and social (community connection, human safety, resource use) values of urban waterways. This approach is inclusive of Indigenous perspectives, such as the concept of reciprocity, whereby consideration of both the environment and society leads to a healthy ecosystem. Here, to highlight how this holistic assessment approach could be used, we present real-world examples that included assessing both environmental and societal values informed by reciprocity or balanced perspectives. This approach can be broadly applied and adapted to specific aquatic ecosystem conditions and projects, providing an inclusive, community-centered approach for assessing the health of waterways in urban environments.

Indigenous knowledge↗

Tidal energy extraction modifies tidal asymmetry and transport in a shallow, well-mixed estuary

Tidal energy extraction is increasingly being studied as a potential renewable energy resource in estuaries worldwide. Although it is understood that energy extraction via tidal stream turbines can modify currents and transport within estuaries, it is not clear how the underlying nonlinear physical mechanisms dictating tidal hydrodynamics are modulated. This research investigates the influence of a hypothetical tidal stream turbine array on barotropic tidal processes in a shallow, well-mixed system: the Piscataqua River – Great Bay (PRGB) estuary, using a numerical model. The modeled turbine farm includes 180 turbines which would extract an estimated 44.7 GWh of energy, annually. The tidal hydrodynamic model for the existing condition is validated with in-situ observations of currents and water level before analyzing tidal asymmetry and transport with and without tidal turbines. Results indicate that the tidal turbine array will decrease tidal elevation and current magnitudes system-wide, but generally reduce ebb currents and transport more than flood over most of the estuary footprint, thereby diminishing tidal asymmetry. The smaller asymmetric distortion compared to the no-turbine case is attributed to reductions in the storage volume of water over the estuary’s extensive tidal flat regions between low and high waters which decreases the associated nonlinear intertidal storage mechanism up to 25%. This leads to weakened ebb dominance over estuary sections from the mouth to mid-reaches, where depths are deep enough to keep the combined nonlinear shallow water and frictional effects from asserting control over the storage mechanism. Even in upstream shallow regions where depth-dependent friction controls asymmetry in both cases, the frictional mechanism is reduced only by 10% with turbines. Some environmental considerations of this work are discussed, with focus on sediment transport, water quality, and ecology.

16 TIDAL AND WAVE POWER↗

Rice Bran Stabilisation and Oil Extraction Using the Microwave-Assisted Method and Its Effects on GABA and Gamma-Oryzanol Compounds

Rice bran oil (RBO) is a valuable ingredient extracted from rice bran (RB), a side stream of polishing rice grain in the milling process. RBO is rich in bioactive ingredients with potential health benefits, such as gamma-oryzanol (GO) and gamma-aminobutyric acid (GABA). Despite its benefits, the quality of RBO depends on the degree of stabilisation of the RB, which is easily affected by lipase enzymes, and thus needs an effective treatment prior to RBO production. To assess the potential of the microwave-assisted method for RB stabilisation and RBO extraction, three Carolino rice varieties (Ariete, Teti, Luna) were tested. The effect of RB stabilisation was evaluated via acid value, water absorption, and GO and GABA levels. The RBO yield was optimised by solvent, temperature, and solvent-to-sample ratio, and the GO and fatty acid levels were determined. The RB stabilisation for the Luna variety did not affect the GO and GABA; for the Ariete and Teti varieties, the GO decreased by 34.4% and 24.2%, and the GABA increased by 26.5% and 47.0%, respectively. The GO levels in RBO samples were not affected by RB stabilisation. The RBO nutritional value was confirmed by the suitable ratio (>2) between polyunsaturated (PUFA) and saturated fatty acids (SFA), with the Teti variety presenting the highest ratio.

Reis, Núria (ORCID:0000000194339109)↗

The Role of Remotely Sensed and Relayed Data in the Delaware River Basin

The planned integration of the existing water quality monitoring and data processing systems in the Delaware River Basin with a data relay experiment proposed for the ERTS-1 is discussed. The experiment is designed to use ERTS-1 as a data relay link for a maximum of 20 hydrologic stations in the basin, including stream gaging, reservoir level, ground water level, and water quality monitoring stations. This experiment has the potential for reducing the time lag between data collection and dissemination to less than 12 hours. The experiment will also provide impetus to develop an operational system of real time data processing and dissemination to handle the large quantity of data that will be obtained from the stations in the basin. The results of this experiment will demonstrate the relative merits of satellite relay of data versus conventional means of data telemetry and will provide a basis for the development of operational satellite relay of hydrologic data.

Paulson, R. W.↗

Field-aligned current sources in the high-latitude ionosphere

The paper determines the electric potential in a plane which is fed current from a pair of field-aligned current sheets. The ionospheric conductivity is modelled as a constant with an enhanced conductivity annular ring. It is shown that field-aligned current distributions are arbitrary functions of azimuth angle (MLT) and thus allow for asymmetric potential configurations over the pole cap. In addition, ionospheric surface currents are computed by means of stream functions. Finally, the discussion relates these methods to the electrical characteristics of the magnetosphere.

Barbosa, D. D.↗

Curvature effects and turbulent boundary layers

Results are examined from an experiment conducted to determine quantitatively the secondary factors which affect the response of a turbulent boundary layer to convex curvature and to examine the recovery process after curvature ended. The variation of Stanton number with streamwise distance and with enthalpy thickness Reynolds number for the baseline case is shown. The effect of delta sub .99/R on the velocity of the potential core would have if we extended to the wall with no viscous effects, of free stream acceleration, of an unheated starting length, and of boundary layer maturity are discussed. Mixing length and turbulent Prandtl number models are reviewed.

Moffat, R. J.↗

On transonic flow past a wave-shaped wall

This report is an extension of a previous investigation (described in NACA rep. 1069) concerned with the solution of the nonlinear differential equation for transonic flow past a wavy wall. In the present work several new notions are introduced which permit the solution of the recursion formulas arising from the method of integration in series. In addition, a novel numerical tests of convergence, applied to the power series (in transonic similarity parameter) representing the local Mach number distribution at the boundary, indicates that smooth symmetrical potential flow past the wavy wall is no longer possible once the critical value of the stream Mach number has been exceeded.

Kaplan, Carl↗

The Effects of the Uncertainty of Departures on Multi-Center Traffic Management Advisor (TMA) Scheduling

The Multi-center Traffic Management Advisor (McTMA) provides a platform for regional or national traffic flow management, by allowing long-range cooperative time-based metering to constrained resources, such as airports or air traffic control center boundaries. Part of the demand for resources is made up of proposed departures, whose actual departure time is difficult to predict. For this reason, McTMA does not schedule the departures in advance, but rather relies on traffic managers to input their requested departure time. Because this happens only a short while before the aircraft's actual departure, McTMA is unable to accurately predict the amount of delay airborne aircraft will need to take in order to accommodate the departures. The proportion of demand which is made up by such proposed departures increases as the horizon over which metering occurs gets larger. This study provides an initial analysis of the severity of this problem in a 400-500 nautical mile metering horizon and discusses potential solutions to accommodate these departures. The challenge is to smoothly incorporate departures with the airborne stream while not excessively delaying the departures.' In particular, three solutions are reviewed: (1) scheduling the departures at their proposed departure time; (2) not scheduling the departures in advance; and (3) scheduling the departures at some time in the future based on an estimated error in their proposed time. The first solution is to have McTMA to automatically schedule the departures at their proposed departure times. Since the proposed departure times are indicated in their flight times in advance, this method is the simplest, but studies have shown that these proposed times are often incorrect2 The second option is the current practice, which avoids these inaccuracies by only scheduling aircraft when a confirmed prediction of departure time is obtained from the tower of the departure airport. Lastly, McTMA can schedule the departures at a predicted departure time based on statistical data of past departure time performance. It has been found that departures usually have a wheels-up time after their indicated proposed departure time, as shown in Figure 1. Hence, the departures were scheduled at a time in the future based on the mean error in proposed departure times for their airport.

Thipphavong, Jane↗

Evaluating NMME Seasonal Forecast Skill for use in NASA SERVIR Hub Regions

The U.S. National Multi-Model Ensemble seasonal forecasting system is providing hindcast and real-time data streams to be used in assessing and improving seasonal predictive capacity. The coupled forecasts have numerous potential applications, both national and international in scope. The NASA / USAID SERVIR project, which leverages satellite and modeling-based resources for environmental decision making in developing nations, is focusing on the evaluation of NMME forecasts specifically for use in driving applications models in hub regions including East Africa, the Hindu Kush- Himalayan (HKH) region and Mesoamerica. A prerequisite for seasonal forecast use in application modeling (e.g. hydrology, agriculture) is bias correction and skill assessment. Efforts to address systematic biases and multi-model combination in support of NASA SERVIR impact modeling requirements will be highlighted. Specifically, quantilequantile mapping for bias correction has been implemented for all archived NMME hindcasts. Both deterministic and probabilistic skill estimates for raw, bias-corrected, and multi-model ensemble forecasts as a function of forecast lead will be presented for temperature and precipitation. Complementing this statistical assessment will be case studies of significant events, for example, the ability of the NMME forecasts suite to anticipate the 2010/2011 drought in the Horn of Africa and its relationship to evolving SST patterns.

Roberts, J. Brent↗

Process Intensification for Recovery of Uranium from Spent Fuel Using DEHiBA

Two approaches are being pursued to intensify the DEHiBA process for recovery of U from used nuclear fuel. For the traditional solvent extraction approach in which the fuel is first dissolved in hot nitric acid, the DEHiBA concentration was adjusted to 1.5 M. This allows for increased loading in the organic phase, but the organic phase U concentration should remain below 100 g/L to avoid unfavorable physicochemical properties that would upset the hydrodynamics in contacting equipment such as centrifugal contactors. Direct extraction of U into the 1.5 M DHEiBA solvent is another intriguing approach to intensifying the process. In this case, the hot nitric acid dissolution step is avoided, a potential significant simplification of the process. Strategies for routing Tc, Np, and Pu to the HLW stream will likely need to be developed to avoid contamination of the U product with these undesirable species.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Xe Recovery from Nuclear Power Plants Off-Gas Streams: Molecular Simulations of Gas Permeation through DD3R Zeolite Membrane

Recent experimental work has shown zeolite membrane-based separation as a promising potential technology for Kr/Xe gas mixtures due to its much lower energy requirements in comparison to cryogenic distillation, the conventional separation method for such mixtures. Such a separation is also economically rewarding because Xe is in high demand, as a valuable product for many applications/processes. In this work, we have used Molecular Dynamics (MD) simulations to study the effects of different conditions, i.e., temperature, pressure, and gas feed composition, on Kr/Xe separation performance via DD3R zeolite membranes. We provide a comprehensive study of the permeation of the different gas species, density profiles, and diffusion coefficients. Molecular simulations show that if the feed is changed from pure Kr/Xe to an equimolar mixture, the Kr/Xe separation factor increases, which agrees with experiments. In addition, when Ar is introduced as a sweep gas, the adsorption of both Kr and Xe increases, while the permeation of pure Kr increases. A similar behavior is observed with equimolar mixtures of Kr/Xe with Ar as the sweep gas. High-separation Kr/Xe selectivity is observed at 50 atm and 425 K but with low total permeation rates. Changing pressure and temperature are found to have profound effects on optimizing the separation selectivity and the permeation throughput.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Hydrological controls of a riparian wetland based on stable isotope data and model simulations

Isotopic evidence of groundwater and stream water is frequently used to investigate water exchanges with groundwater. Monthly sampling of rain, stream water, and groundwater was conducted at Tims Branch watershed in South Carolina for the oxygen and hydrogen stable isotope (δ 2 H and δ 18 O) measurement, as well as pH and oxidation–reduction potential (ORP). Together with a mass balance perspective, it was determined that it takes a few weeks to one month for groundwater in the hyporheic zone to fully exchange with stream water. From hydrodynamic modelling, we show that substantial (up to 70 %) groundwater exchange occurs at gaining and losing sites. Groundwater exfiltration, i.e. inflow into stream water, contributes up to 4 % to stream water, with the remainder from upstream exfiltration. A 2–4 % per day renewal rate of adjacent groundwater would indirectly indicate a groundwater residence time in the order of half a month to a full month (assuming either a well-mixed case or large dispersion rate in pulse flow case), in agreement with a greatly reduced variability of δ 2 H and δ 18 O of groundwater compared to stream water and rain. This reduced variability of stable isotope signal from groundwater confirms our hypothesis that riparian groundwater mixing at Tims Branch is more of a mixed type rather than a pulse flow type. As a result, a monthly time scale is sufficient for groundwater to become anoxic at exit points into stream water resulting in the episodic production of natural organic matter- and iron-rich flocs upon oxidation.

54 ENVIRONMENTAL SCIENCES↗

System Configuration Evaluation for Process Settling of Hanford Waste Solid Particles

Direct Feed High-Level Waste (DFHLW) is a potential flowsheet operations approach to initiating high-level waste (HLW) vitrification prior to completion of the Hanford Waste Treatment and Immobilization Plant (WTP) Pretreatment Facility. A settle/decant process has been proposed to concentrate solids prior to delivery to the WTP HLW Facility during DFHLW operations, wherein the solids in a settled layer would be remixed with the supernatant liquid remaining after decanting operations to provide the feed at required solids concentrations. Settling would be used in lieu of purpose-built filtration or other solids separation equipment. Pacific Northwest National Laboratory (PNNL) is providing baseline technical support to the Washington River Protection Solutions (WRPS) Flowsheet Integration group. To support planning for DFHLW, WRPS previously requested that PNNL evaluate the current data set available to predict the time needed for HLW solids to settle and the solids concentration and strength of that settled layer, to identify gaps in the understanding and predictive capability of HLW solids waste settling times, and to provide scoping estimates of the potential settling times. Eight technical gaps were identified for predicting settling times and characteristics of the formed sediment layers. In addition to the data gaps, an overarching observation was made that there is significant variation in behavior of settling rate and settled layer data. The settling time required to concentrate solids via a settle/decant process was determined from the limited data to have a difference of potentially more than a factor of 5,000 in the estimated settling times, varying from 0.2 to 1,060 days for example depending on process vessel depth and final sediment solids concentration. In contrast, successful processes of liquid-forward output streams resulting from in-tank settling and decanting forward liquid have been reported for operations conducted at the Hanford Site. The purpose of this current report is to further support DFHLW planning by evaluating double-shell tank (DST) and alternate vessel equipment and operational configurations to enable optimization of the settle/decant process to concentrate solids. Hanford waste processing behavior specific to liquid feed availability following a slurry transfer in a DST is summarized, including process stream characteristics and process equipment configurations. The performance of DST process equipment configurations is evaluated for possible improvements using computational fluid dynamics (CFD) and simple analytical models. Potential new vessel design(s) specific to enabling effective settle/decant processes, and cursory summary of other separate and inline solids separations processes, are also provided. The CFD results indicated that improvement in outflow solids concentration was promoted by a reduction in the slurry flow rate, angling the distributor nozzles downward, and lifting the transfer pump. The solid-liquid analysis evaluating particle trajectory confirmed that the potential for particle ingestion (in the transfer pump) was decreased with increased radial separation between the inlet and outlet (transfer pump inlet), decreased inlet flow, and decreased liquid density and viscosity for a neutrally buoyant inlet flow. An assessment was also made of the potential for inflow configuration changes to result in the discrete mounding or piling of solids within the tank. Based on the characterization of the settled waste to date, HLW sediments will be unlikely to sustain a substantial angle of repose to facilitate significant variations in the elevation of the settled solids.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Mercury methylation potential and bioavailability in the sediments of two distinct aquatic systems

Here, this study explored mercury (Hg) methylation potential in two distinct aquatic systems. Fourmile Creek (FMC) was historically polluted with Hg effluents from groundwater as it is a typical gaining stream, where organic matter and microorganisms in streambed are continuously winnowed. The H02 constructed wetland only receives atmospheric Hg and is rich in organic matter and microorganisms. Both systems receive Hg from atmospheric deposition now. Surface sediments were collected from FMC and H02, spiked with inorganic Hg, and cultivated in an anaerobic chamber to stimulate microbial Hg methylation reactions. Total mercury (THg) and methylmercury (MeHg) concentrations were measured at each spiking stage. Mercury methylation potential (MMP, %MeHg in THg) and Hg bioavailability were assessed with the deployment of diffusive gradients in thin films (DGTs). During the methylation process and at the same incubation stage, FMC sediment showed faster increasing rates of %MeHg and higher MeHg concentrations than H02, demonstrating a stronger MMP in the FMC sediment. Similarly, higher Hg bioavailability was observed in FMC sediment compared to the H02 as indicated by DGT-Hg concentrations. In conclusion, the H02 wetland with high levels of organic matter and microorganisms presented low MMP. But the Fourmile Creek as a gaining stream and a historical site of Hg pollution showed strong MMP and high Hg bioavailability. A related study on microbial community activities characterized the microorganisms between FMC and H02, which is attributed to be the main reason for their different methylation capabilities. Our study further brought up the considerations on remediated sites from Hg contamination: Hg bioaccumulation and biomagnification can still be elevated and higher than the surrounding environment due to lagged changes in microbial community structures. This study supported the sustainable ecological modifications of legacy Hg contamination and raised the necessity of long-term monitoring actions even after executing a remediation plan.

54 ENVIRONMENTAL SCIENCES↗

Genomewide and Enzymatic Analysis Reveals Efficient D-Galacturonic Acid Metabolism in the Basidiomycete Yeast Rhodosporidium toruloides

Biorefining of renewable feedstocks is one of the most promising routes to replace fossil-based products. Since many common fermentation hosts, such as Saccharomyces cerevisiae , are naturally unable to convert many component plant cell wall polysaccharides, the identification of organisms with broad catabolism capabilities represents an opportunity to expand the range of substrates used in fermentation biorefinery approaches. The red basidiomycete yeast Rhodosporidium toruloides is a promising and robust host for lipid- and terpene-derived chemicals. Previous studies demonstrated assimilation of a range of substrates, from C 5 /C 6 sugars to aromatic molecules similar to lignin monomers. In the current study, we analyzed the potential of R. toruloides to assimilate d -galacturonic acid, a major sugar in many pectin-rich agricultural waste streams, including sugar beet pulp and citrus peels. d -Galacturonic acid is not a preferred substrate for many fungi, but its metabolism was found to be on par with those of d -glucose and d -xylose in R. toruloides . A genomewide analysis by combined transcriptome sequencing (RNA-seq) and RB-TDNA-seq revealed those genes with high relevance for fitness on d -galacturonic acid. While R. toruloides was found to utilize the nonphosphorylative catabolic pathway known from ascomycetes, the maximal velocities of several enzymes exceeded those previously reported. In addition, an efficient downstream glycerol catabolism and a novel transcription factor were found to be important for d -galacturonic acid utilization. These results set the basis for use of R. toruloides as a potential host for pectin-rich waste conversions and demonstrate its suitability as a model for metabolic studies with basidiomycetes. The switch from the traditional fossil-based industry to a green and sustainable bioeconomy demands the complete utilization of renewable feedstocks. Many currently used bioconversion hosts are unable to utilize major components of plant biomass, warranting the identification of microorganisms with broader catabolic capacity and characterization of their unique biochemical pathways. d -Galacturonic acid is a plant component of bioconversion interest and is the major backbone sugar of pectin, a plant cell wall polysaccharide abundant in soft and young plant tissues. The red basidiomycete and oleaginous yeast Rhodosporidium toruloides has been previously shown to utilize a range of sugars and aromatic molecules. Using state-of-the-art functional genomic methods and physiological and biochemical assays, we elucidated the molecular basis underlying the efficient metabolism of d -galacturonic acid. This study identified an efficient pathway for uronic acid conversion to guide future engineering efforts and represents the first detailed metabolic analysis of pectin metabolism in a basidiomycete fungus.

59 BASIC BIOLOGICAL SCIENCES↗

Combined VHF Dopplar radar and airborne (CV-990) measurements of atmospheric winds on the mesoscale

Hourly measurements of wind speed and direction obtained using two wind profiling Doppler radars during two prolonged jet stream occurrences over western Pennsylvania were analyzed. In particular, the time-variant characteristics of derived shear profiles were examined. To prevent a potential loss of structural detail and retain statistical significance, data from both radars were stratified into categories based on the location data from the Penn State radar were also compared to data from Pittsburgh radiosondes. Profiler data dropouts were studied in an attempt to determine possible reasons for the apparently reduced performance of profiling radars operating beneath a jet stream. Temperature profiles for the radar site were obtained using an interpolated temperature and dewpoint temperature sounding procedure developed at Penn State. The combination of measured wind and interpolated temperature profiles allowed Richardson number profiles to be generated for the profiler sounding volume. Both Richardson number and wind shear statistics were then examined along with pilot reports of turbulence in the vicinity of the profiler.

Fairall, Christopher W.↗

EdgeAI: Machine learning via direct attached accelerator for streaming data processing at high shot rate x-ray free-electron lasers

We present a case for low batch-size inference with the potential for adaptive training of a lean encoder model. We do so in the context of a paradigmatic example of machine learning as applied in data acquisition at high data velocity scientific user facilities such as the Linac Coherent Light Source-II x-ray Free-Electron Laser. We discuss how a low-latency inference model operating at the data acquisition edge can capitalize on the naturally stochastic nature of such sources. We simulate the method of attosecond angular streaking to produce representative results whereby simulated input data reproduce high-resolution ground truth probability distributions. By minimizing the mean-squared error between the decoded output of the latent representation and the ground truth distributions, we ensure that the encoding layers and resulting latent representation maintains full fidelity for any downstream task, be it classification or regression. We present throughput results for data-parallel inference of various batch sizes, some with throughput exceeding 100 k images per second. We also show in situ training below 10 s per epoch for the full encoder–decoder model as would be relevant for streaming and adaptive real-time data production at our nation’s scientific light sources.

97 MATHEMATICS AND COMPUTING↗

Panel Session 90: US DOE Mixed Waste: Proposals for Dealing with Problematic Waste Streams and Policy Changes

This panel focused on generation and management of low level and mixed low-level radioactive wastes, challenges for disposition, innovative solutions applied at DOE sites, and collaboration among sites to ensure that waste disposition pathways are understood. In addition, potential policy initiatives were discussed including depleted uranium, elemental mercury, and treatment of legacy mixed waste components. As part of the introduction, Theresa Kliczewski provided an overview of why this panel is relevant: problematic mixed waste streams still exist across the DOE cleanup complex. Theresa noted that the DOE EM Headquarters Office of Waste and Materials Management (EM-4.2), for which she is employed with, continues to work with the DOE cleanup sites on a path forward for these problematic mixed waste streams. As part of this effort, EM-4.2 requested that the Energy Facility Contractors Group (EFCOG) perform a review of all the DOE sites problematic mixed waste streams. Panelists with presentations: Challenging Waste Streams: Disposition of Depleted Uranium Oxide Conversion Product (Douglas Tonkay); EFCOG WMWG Challenging Waste Subgroup (Tammy Monday); Mercury Waste Challenges (John Wrapp); Legacy Large Mixed Waste Components (Kalli Shupe)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗