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At least 487 records · Page 27

Seasonal Evolution of Rossby and Gravity Wave Induced Laminae in Ozonesonde Data Obtained from Wallops Island, Virginia

A method for evaluating the seasonal evolution of ozone laminae using ozonesonde data is discussed. The method uses the correlation between small-scale ozone and potential temperature variations to distinguish between laminae generated by quasi-isentropic filamentation by Rossby waves and by vertical displacements of material surfaces by gravity waves. Data from Wallops Island, Virginia show that Rossby wave induced ozone laminae are most frequently encountered at Wallops during the winter months near 15 km while statistically significant gravity wave induced laminae occur above 15 km during the early winter and at the tropopause from late winter through early spring.

Pierce, R. Bradley↗

Homogenization of the Observatoire de Haute Provence electrochemical concentration cell (ECC) ozonesonde data record: comparison with lidar and satellite observations

The Observatoire de Haute Provence (OHP) weekly Electrochemical Concentration Cell (ECC) ozonesonde data have been homogenized for the period 1991-2021 according to the recommendations of the Ozonesonde Data Quality Assessment (O3S-DQA) panel. The assessment of the ECC homogenization benefit has been carried out using comparisons with other ozone measuring ground based instruments at the same station (lidar, surface measurements) and with collocated satellite observations of the O3vertical profile by Microwave Limb Sounder (MLS). The major differences between uncorrected and5homogenized ECC data are related to a change of ozonesonde type in 1997, removal of the pressure dependency of the ECC background current and correction of internal pump temperature. The original 3-4 ppbv positive bias between ECC and Lidar in the troposphere is corrected with the homogenization. The ECC 30-years trends of the seasonally adjusted ozone concentrations are also significantly improved in both the troposphere and the stratosphere after the ECC homogenization, as shown by the ECC/lidar or ECC/surface ozone trend comparisons. A -0.19% per year negative trend of the normalization factor (NT)10calculated using independent measurements of the total ozone column (TOC) at OHP disappears after homogenization of the ECC data. There is however a remaining -3.7% negative bias in the TOC which is likely related to an underestimate of the ECC concentrations in the stratosphere above 50 hPa. Differences between TOC measured by homogenized ECC and satellite observations show a smaller bias of -1%. Comparisons between homogenized ECC and OHP stratospheric lidar and MLS observations below 26 km are slightly negative (-2%) or positive (+2%), respectively. Both the comparisons with lidar and15satellite observations suggest that homogenization increases the negative bias of the ECC to values lower than -6% above 28km. The reason for this bias is still unclear, but a possible explanation might be related to freezing or evaporation of the sonde solution in the stratosphere.

Ozonesondes↗

The Atmospheric Infrared Sounder- An Overview

The Atmospheric Infrared Sounder (AIRS) was launched in May 2002. Along with two companion microwave sensors, it forms the AIRS Sounding Suite. This system is the most advanced atmospheric sounding system to date, with measurement accuracies far surpassing those available on current weather satellites. The data products are calibrated radiances from all three sensors and a number of derived geophysical parameters, including vertical temperature and humidity profiles, surface temperature, cloud fraction, cIoud top pressure, and profiles of ozone. These products are generated under cloudy as well as clear conditions. An ongoing calibration validation effort has confirmed that the system is very accurate and stable, and many of the geophysical parameters have been validated. AIRS is in some cases more accurate than any other source and can therefore be difficult to validate, but this offers interesting new research opportunities. The applications for the AIRS products range from numerical weather prediction to atmospheric research - where the AIRS water vapor products near the surface and in the mid to upper troposphere will make it possible to characterize and model phenomena that are key for short-term atmospheric processes, such as weather patterns, to long-term processes, such as interannual cycles (e.g., El Nino) and climate change.

microwave↗

The Critical Influence of Spin–Dry Technique on the Surface Passivation Quality of Crystalline Silicon Solar Cell Structures

This study examines the effects of spin-dry (SD) and N 2 blow-dry (ND) techniques on the quality and surface passivation performance of silicon oxide grown in ozone-dissolved deionized water. The SD method achieves greater oxide thickness uniformity, averaging 1.39 nm ± 4.17% across 49 points, compared to 1.68 nm ± 21.67% for the ND wafers. However, persistently poor passivation of ozonated oxide-grown wafers following the SD process is exhibited, with carrier lifetime, τ eff < 0.3 ms and saturation current density, J 0 (per side) ranging from 26 to 45 fA cm 2 . These findings are analyzed in the context of the fundamental phenomena involved in the drying processes of both techniques. Following this, an optimized spin-drying process is developed, resulting in improved τ eff and J 0 values of 1.4 ms and 5.6 fA cm –2 , respectively. Scanning electron microscopy further confirms that the oxide films dried with the enhanced SD technique are free of pinholes.

14 SOLAR ENERGY↗

Radiative transfer in real atmospheres

The problem of multiple radiation scattering in an atmosphere characterized by various amounts of aerosol absorption and different particle size distributions was investigated. The visible part of the spectrum was emphasized, including the effect of ozone absorption. An atmosphere bounded by a nonhomogenous, Lambertian surface was also studied, along with the effect of background radiation on target in terms of various atmopheric and geometric conditions. Results of the investigation indicate that comtaminated atmospheres can change the radiation field by a considerable amount, and that the effect of non-uniform surface significantly alters the intrinsic radiation from a target element. The implications of these results for the recognition processing of multispectral remote sensing data is discussed.

Turner, R. E.↗

Error in Dasibi flight measurements of atmospheric ozone due to instrument wall-loss

Theory suggests that in laminar flow the percent loss of a trace constituent to the walls of a measuring instrument varies as P to the -2/3, where P is the total gas pressure. Preliminary laboratory ozone wall-loss measurements confirm this P to the -2/3 dependence. Accurate assessment of wall-loss is thus of particular importance for those balloon-borne instruments utilizing laminar flow at ambient pressure, since the ambient pressure decreases by a factor of 350 during ascent to 40 km. Measurements and extrapolations made for a Dasibi ozone monitor modified for balloon flight indicate that the wall-loss error at 40 km was between 6 and 30 percent and that the wall-loss error in the derived total ozone column-content for the region from the surface to 40 km altitude was between 2 and 10 percent. At 1000 mb, turbulence caused an order of magnitude increase in the Dasibi wall-loss.

Ainsworth, J. E.↗

Indicators of transport and vertical motion from correlations between in situ measurements in the Airborne Antarctic Ozone Experiment

Analysis of small-scale structure in the in situ measurements made from the ER-2 during the Airborne Antarctic Ozone Experiment shows the existence of a region at the boundary of the chemiclly perturbed region where the mixing ratios and small-scale structure of trace gases are influenced by transport across the boundary. This transition region is characterized by horizontal interchange and vertical layering of air parcels from within and outside of the chemically perturbed region and negative small-scale correlations between ClO and ozone. The horizontal transport in this region creates large surface areas between dissimilar air masses, providing the potential for substantial mixing. Correlations between ClO and O3 show that the transition region extends to 2-4 deg of latitude to either side of the boundary of the chemically perturbed region. A + or - 4-deg-wide transition region would contain nearly as much air as the chemically perturbed region proper. Analysis of water vapor and nitrous oxide data suggests that diabatic descent is associated with dehydration. This could be caused by strong radiative cooling of those polar stratospheric clouds in which enough water condenses for the particles to fall and dehydrate the air.

Murphy, D. M.↗

Chemistry and dynamics of the lower troposphere over North America and the North Atlantic Ocean in fall 1997 observed using an airborne UV DIAL system

The NASA Langley Research Center's airborne UV Differential Absorption Lidar (DIAL) system participated in the Subsonic Assessment, Ozone and Nitrogen Oxide Experiment (SONEX) mission from October 13 to November 12, 1997. The purpose of the mission was to study the upper troposphere/lower stratosphere in and near the North Atlantic flight corridor to better understand this region of the atmosphere and how civilian air travel in the corridor might be affecting the atmospheric chemistry. Bases of operations included NASA Ames, California (37.4 deg N, 122.1 deg W); Bangor, Maine (44.8 deg N, 68.8 deg W); Shannon, Ireland (52.7 deg N, 8.9 deg W); and Lajes, Terceira Island, Azores (38.8 deg N, 27.1 deg W). Since the UV DIAL system observes in the nadir as well as the zenith, aerosol and ozone data were obtained from near the Earth's surface to the lower stratosphere. A number of interesting features were noted relating to both chemistry and dynamics of the troposphere, which are reported here.

Grant, William B.↗

AIRS Level 2 Data Products

The Atmospheric InfraRed Sounder (AIRS) Standard Retrieval Product consists of retrieved cloud and surface properties; profiles of retrieved temperature, water vapor, and ozone; and a flag indicating the presence of cloud ice or water. They contain quality assessment flags in addition to retrieved quantities and are generated for all locations where atmospheric soundings are taken. An AIRS granule consists of 6 minutes of data. This corresponds to approximately 1/15 of an orbit but exactly 45 scan lines of AMSU-A data or 135 scan lines of AIRS and HSB data.

Vicente, Gilberto↗

Sensitivity of Stratospheric Geoengineering with Black Carbon to Aerosol Size and Altitude of Injection

Simulations of stratospheric geoengineering with black carbon (BC) aerosols using a general circulation model with fixed sea surface temperatures show that the climate effects strongly depend on aerosol size and altitude of injection. 1 Tg BC/a injected into the lower stratosphere would cause little surface cooling for large radii but a large amount of surface cooling for small radii and stratospheric warming of over 60 C. With the exception of small particles, increasing the altitude of injection increases surface cooling and stratospheric warming. Stratospheric warming causes global ozone loss by up to 50% in the small radius case. The Antarctic shows less ozone loss due to reduction of polar stratospheric clouds, but strong circumpolar winds would enhance the Arctic ozone hole. Using diesel fuel to produce the aerosols is likely prohibitively expensive and infeasible. Although studying an absorbing aerosol is a useful counterpart to previous studies involving sulfate aerosols, black carbon geoengineering likely carries too many risks to make it a viable option for deployment.

Kravitz, Ben↗

Diagnosing Changes In Earth's Top-Of-Atmosphere Radiation Budget Since 2000

Earth’s radiation budget (ERB) is a key indicator of the climate system as it describes the delicate balance between how much of the sun’s energy reaching Earth is absorbed and how much thermal infrared radiation is emitted back to space. It is now well established that there is a positive net imbalance in ERB of 0.5-1 Wm-2. This imbalance, referred to as Earth’s Energy Imbalance (EEI), is shaped by natural and anthropogenic climate forcings and the climate system’s response to the forcing.When averaged over a long period, a positive EEI leads to an increase in surface temperature, sea levelrise, ocean heat content, melting of snow and sea-ice, and an acceleration of the hydrological cycle.EEI is also influenced by internal climate variability at interannual (e.g., El Niño/Southern Oscillation(ENSO)) and longer timescales (e.g., Pacific Decadal Oscillation (PDO)). Here we use CERES data toshow that since 2000, EEI has been increasing at a rate of 0.04+-0.03 Wm-2 per yr, corresponding to 0.8 Wm-1 over the 20-year CERES record. To understand the underlying causes for this increase, we analyze the CERES data in the context of internal climate variability indices and regional pattern changes. We also perform a partial radiative perturbation analysis that decomposes the TOA SW and LW radiation variations in terms of contributions by clouds, aerosols, surface albedo, temperature,water vapor and other gases (e.g., ozone, carbon dioxide, methane, etc.).

Norman G Loeb↗

Data Fusion for Urban Air Quality Assessment & Forecasting

This presentation provides an overview for our funded project with NASA's Health and Air Quality Applied Sciences Program. The project will expand an existing air quality data fusion tool implemented in Google Earth Engine (GEE) by our project team members at Sonoma Technology, Inc. (STI), a private air quality data company. We will expand the capabilities of this tool using new methods developed by the NASA GMAO which will give it the capability of providing sub-city scale resolution and hourly frequency estimates and forecasts of three key air quality indicators: surface-level particulate matter (PM2.5), nitrogen dioxide (NO2), and ozone (O3). We will combine a variety of Earth Observations including satellite data, global air quality forecasts, and local data from regulatory-grade monitors and/or low cost sensors. We will implement the new data fusion capabilities into the existing GEE tool in consultation with our end-users to best address their needs for sub-city scale air quality estimates and forecasts.

K Emma Knowland↗

Causes of Cracking of Ignition Cable

The experiments described here show that the cracking at sharp bends, observed in the insulation of internal combustion engine high tension ignition wires after service, is due to a chemical attack upon the rubber by the ozone produced by the electric discharge that takes place at the surface of the cable. This cracking does not occur if the insulating material is not under tension, or if the cable is surrounded by some medium other than air. But it does occur even if the insulation is not subjected to electric stress, provided that the atmosphere near the cable contains ozone. The extent of this cracking varies greatly with the insulating material used. The cracking can be materially reduced by using braided cable and by avoiding sharp bends.

Silsbee, F B↗

Recent Advances in Ozone Data Assimilation at the GMAO - Towards a New Reanalysis

This presentation summarized ongoing work on improving the representation of ozone in the GEOS Data Assimilation Systems. Data from two EOS Aura sensors was used: the total column ozone from the Ozone Monitoring Instrument (OMI) and high vertical resolution stratospheric profiles from Microwave Limb Sounder (MLS, version 3.3). As several previous studies have demonstrated, assimilation of this data can constrain the stratospheric and tropospheric ozone columns with relatively good accuracy. However, the representation of the vertical structures in the troposphere and near tropopause region is often deficient. Since both these layers of the atmosphere are critical to the understanding of the radiative forcing as well as the ozone budget in the troposphere, current work will focus on improving the assimilated product between the surface and the 50 hPa pressure level. The discussion included recent steps that have been taken towards refining the treatment of ozone in GEOS-5. Impacts of improved tropospheric chemistry model were discussed including the introduction of efficiency factors ("averaging kernels") for OMI total ozone, and direct assimilation of radiances from the MLS instrument. In particular, advantages and challenges involved in assimilating limb radiances rather than retrieved product were discussed. This work is, in part, a preparation for a planned reanalysis of the EOS Aura data from 2005 to present.

Krzysztof, Wargan↗

Feasibility study for a microwave-powered ozone sniffer aircraft, volume 2

Using 3-D design techniques and the Advanced Surface Design Software on the Computervision Designer V-X Interactive Graphics System, the aircraft configuration was created. The canard, tail, vertical tail, and main wing were created on the system using Wing Generator, a Computervision based program introduced in Appendix A.2. The individual components of the plane were created separately and were later individually imported to the master database. An isometric view of the final configuration is presented.

Source record↗

Response of the global climate to changes in atmospheric chemical composition due to fossil fuel burning

Tropospheric ozone and methane might increase in the future as the result of increasing anthropogenic emissions of CO, NOx and CH4 due to fossil fuel burning. Since O3 and CH4 are both greenhouse gases, increases in their concentrations could augment global warming due to larger future amounts of atmospheric CO2. To test this possible climatic impact, a zonal energy-balance climate model has been combined with a vertically-averaged tropospheric chemical model. The latter model includes all relevant chemical reactions which affect species derived from H2O, O2, CH4 and NOx. The climate model correspondingly incorporates changes in the infrared heating of the surface-troposphere system resulting from chemically induced changes in tropospheric ozone and methane. This coupled climate-chemical model indicates that global climate is sensitive to changes in emissions of CO, NOx and CH4, and that future increases in these emissions could enhance global warming due to increasing atmospheric CO2.

Cess, R. D.↗

Dobson spectrophotometer ozone measurements during international ozone rocketsonde intercomparison

Measurements of the total ozone content of the atmosphere, made with seven ground based instruments at a site near Wallops Island, Virginia, are discussed in terms for serving as control values with which the rocketborne sensor data products can be compared. These products are profiles of O3 concentration with altitude. By integrating over the range of altitudes from the surface to the rocket apogee and by appropriately estimating the residual ozone amount from apogee to the top of the atmosphere, a total ozone amount can be computed from the profiles that can be directly compared with the ground based instrumentation results. Dobson spectrophotometers were used for two of the ground-based instruments. Preliminary data collected during the IORI from Dobson spectrophotometers 72 and 38 are presented. The agreement between the two and the variability of total ozone overburden through the experiment period are discussed.

Parsons, C. L.↗

Response of the global climate to changes in atmospheric chemical composition due to fossil fuel burning

Recent modeling of atmospheric chemical processes (Logan et al, 1978; Hameed et al, 1979) suggests that tropospheric ozone and methane might significantly increase in the future as the result of increasing anthropogenic emissions of CO, NO(x), and CH4 due to fossil fuel burning. Since O3 and CH4 are both greenhouse gases, increases in their concentrations could augment global warming due to larger future amounts of atmospheric CO2. To test the possible climatic impact of changes in tropospheric chemical composition, a zonal energy-balance climate model has been combined with a vertically averaged tropospheric chemical model. The latter model includes all relevant chemical reactions which affect species derived from H2O, O2, CH4, and NO(x). The climate model correspondingly incorporates changes in the infrared heating of the surface-troposphere system resulting from chemically induced changes in tropospheric ozone and methane. This coupled climate-chemical model indicates that global climate is sensitive to changes in emissions of CO, NO(x) and CH4, and that future increases in these emissions could augment global warming due to increasing atmospheric CO2.

Hameed, S.↗