Accurate frequency and intensity measurements of the infrared spectra of atmospheric molecules
Various problems encountered and solutions found in infrared laboratory measurements on atmospheric molecules are discussed. The advantages and limitations of various measurement techniques and equipment are discussed, with emphasis placed on calibration techniques and measurement accuracy and precision. Frequency calibration aids are presented, including the current and planned tables of absorption frequency standards being developed by the Bureau of Standards for the calibration of high-resolution devices with an accuracy of + or - 3 MHz. It is noted that intensity measurements are highly susceptible to systematic errors and that great care must be taken to obtain accuracies better than + or - 10%. What is even more difficult is knowing the accuracy of a particular measurement. Recent work done on providing accurate intensity data are described.