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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 505 records · Page 28

Signal-Induced Noise Effects in a Photon Counting System for Stratospheric Ozone Measurement

A significant source of error in making atmospheric differential absorption lidar ozone measurements is the saturation of the photomultiplier tube by the strong, near field light return. Some time after the near field light signal is gone, the photomultiplier tube gate is opened and a noise signal, called signal-induced noise, is observed. Research reported here gives experimental results from measurement of photomultiplier signal-induced noise. Results show that signal-induced noise has several decaying exponential signals, suggesting that electrons are slowly emitted from different surfaces internal to the photomultiplier tube.

Harper, David B.↗

Differential Absorption Lidar (DIAL) Measurements of Atmospheric Water Vapor Utilizing Robotic Aircraft

A new unpiloted air vehicle (UAV) based water vapor DIAL system will be described. This system is expected to offer lower operating costs, longer test duration and severe weather capabilities. A new high-efficiency, compact, light weight, diode-pumped, tunable Cr:LiSAF laser will be developed to meet the UAV payload weight and size limitations and its constraints in cooling capacity, physical size and payload. Similarly, a new receiver system using a single mirror telescope and an avalanche photo diode (APD) will be developed. Projected UAV parameters are expected to allow operation at altitudes up to 20 km, endurance of 24 hrs and speed of 400 km/hr. At these conditions measurements of water vapor at an uncertainty of 2-10% with a vertical resolution of 200 m and horizontal resolution of 10 km will be possible.

Hoang, Ngoc↗

Microreactor System Design for a NASA In Situ Propellant Production Plant on Mars

The NASA In Situ Resource Utilization (ISRU) program is planning near-term missions to Mars that will include chemical processes for converting the carbon dioxide (CO2) and possibly water from the Martian environment to propellants, oxygen, and other useful chemicals. The use of indigenous resources reduces the size and weight of the payloads from Earth significantly, representing enormous cost savings that make human exploration of Mars affordable. Extraterrestrial chemical processing plants will need to be compact, lightweight, highly efficient under reduced gravity, and extraordinarily reliable for long periods. Microchemical and thermal systems represent capability for dramatic reduction in size and weight, while offering high reliability through massive parallelization. In situ propellant production (ISPP), one aspect of the ISRU program, involves collecting and pressurizing atmospheric CO2, conversion reactions, chemical separations, heat exchangers, and cryogenic storage. A preliminary system design of an ISPP plant based on microtechnology has demonstrated significant size, weight, and energy efficiency gains over the current NASA baseline. Energy management is a strong driver for Mars-based processes, not only because energy is a scarce resource, but because heat rejection is problematic; the low pressure environment makes convective heat transfer ineffective. Energy efficiency gains are largely achieved in the microchemical plant through extensive heat recuperation and energy cascading, which has a small size and weight penalty because the added micro heat exchangers are small. This leads to additional size and weight gains by reducing the required area of waste heat radiators. The microtechnology-based ISPP plant is described in detail, including aspects of pinch analysis for optimizing the heat exchanger network. Three options for thermochemical compression Of CO2 from the Martian atmosphere, adsorption, absorption, and cryogenic freezing, are presented, as well as three options for water decomposition, low temperature electrolysis, high temperature electrolysis, and thermochemical decomposition. Other elements of the plant include Sabatier and reverse water gas shift reactors, water recovery, chemical separations, and cryogenic storage. Data are presented supporting preliminary sizing of components, and results of the system design are compared to the existing NASA baseline that is based on conventional technologies.

TeGrotenhuis, W. E.↗

Seasonal Evolution and Interannual Variability of the Local Solar Energy Absorbed by the Arctic Sea Ice-Ocean System

The melt season of the Arctic sea ice cover is greatly affected by the partitioning of the incident solar radiation between reflection to the atmosphere and absorption in the ice and ocean. This partitioning exhibits a strong seasonal cycle and significant interannual variability. Data in the period 1998, 2000-2004 were analyzed in this study. Observations made during the 1997-1998 SHEBA (Surface HEat Budget of the Arctic Ocean) field experiment showed a strong seasonal dependence of the partitioning, dominated by a five-phase albedo evolution. QuikSCAT scatterometer data from the SHEBA region in 1999-2004 were used to further investigate solar partitioning in summer. The time series of scatterometer data were used to determine the onset of melt and the beginning of freezeup. This information was combined with SSM/I-derived ice concentration, TOVS-based estimates of incident solar irradiance, and SHEBA results to estimate the amount of solar energy absorbed in the ice-ocean system for these years. The average total solar energy absorbed in the ice-ocean system from April through September was 900 MJ m(sup -2). There was considerable interannual variability, with a range of 826 to 1044 MJ m(sup -2). The total amount of solar energy absorbed by the ice and ocean was strongly related to the date of melt onset, but only weakly related to the total duration of the melt season or the onset of freezeup. The timing of melt onset is significant because the incident solar energy is large and a change at this time propagates through the entire melt season, affecting the albedo every day throughout melt and freezeup.

Perovich, Donald K.↗

Spectral line discriminator for passive detection of fluorescence

A method and apparatus for detecting fluorescence from sunlit plants is based on spectral line discrimination using the A-band and B-band absorption of atmospheric oxygen. Light from a plant including scattered sunlight and the fluorescence from chlorophyll is passed through a chopper into a cell containing low-pressure, high-purity oxygen. A-band or B-band wavelengths present in the light are absorbed by the oxygen in the cell. When the chopper is closed, the absorbed light is remitted as fluorescence into a detector. The intensity of the fluorescence from the oxygen is proportional to the intensity of fluorescence from the plant.

Kebabian, Paul L.↗

Chlorophyll Fluorescence Emissions of Vegetation Canopies From High Resolution Field Reflectance Spectra

A two-year experiment was performed on corn (Zea mays L.) crops under nitrogen (N) fertilization regimes to examine the use of hyperspectral canopy reflectance information for estimating chlorophyll fluorescence (ChlF) and vegetation production. Fluorescence of foliage in the laboratory has proven more rigorous than reflectance for correlation to plant physiology. Especially useful are emissions produced from two stable red and far-red chlorophyll ChlF peaks centered at 685V10 nm and 735V5 nm. Methods have been developed elsewhere to extract steady state solar induced fluorescence (SF) from apparent reflectance of vegetation canopies/landscapes using the Fraunhofer Line Depth (FLD) principal. Our study utilized these methods in conjunction with field-acquired high spectral resolution canopy reflectance spectra obtained in 2004 and 2005 over corn crops, as part of an ongoing multi-year experiment at the USDA/Agriculture Research Service in Beltsville, MD. A spectroradiometer (ASD-FR Fieldspec Pro, Analytical Spectral Devices, Inc., Boulder, CO) was used to measure canopy radiances 1 m above plant canopies with a 22deg field of view and a 0deg nadir view zenith angle. Canopy and plant measurements were made at the R3 grain fill reproductive stage on 3-4 replicate N application plots provided seasonal inputs of 280, 140, 70, and 28 kg N/ha. Leaf level measurements were also made which included ChlF, photosynthesis, and leaf constituents (photosynthetic pigment, carbon (C), and N contents). Crop yields were determined at harvest. SIF intensities for ChlF were derived directly from canopy reflectance spectra in specific narrowband regions associated with atmospheric oxygen absorption features centered at 688 and 760 nm. The red/far-red S F ratio derived from these field reflectance spectra successfully discriminated foliar pigment levels (e.g., total chlorophyll, Chl) associated with N application rates in both corn crops. This canopy-level spectral ratio was also positively correlated to the foliar C/N ratio (r = 0.89, n = go), as was a leaf-level steady state fluorescence ratio (Fs/Chl, r = 0.92). The latter ratio was inversely correlated with crop grain yield (Kg 1 ha) (r = 0.9). This study has relevance to future passive satellite remote sensing approaches to monitoring C dynamics from space.

Middleton, E. M.↗

Mid-Infrared Reflectance Imaging of Thermal-Barrier Coatings

An apparatus for mid-infrared reflectance imaging has been developed as means of inspecting for subsurface damage in thermal-barrier coatings (TBCs). The apparatus is designed, more specifically, for imaging the progression of buried delamination cracks in plasma-sprayed yttria-stabilized zirconia coatings on turbine-engine components. Progression of TBC delamination occurs by the formation of buried cracks that grow and then link together to produce eventual TBC spallation. The mid-infrared reflectance imaging system described here makes it possible to see delamination progression that is invisible to the unaided eye, and therefore give sufficiently advanced warning before delamination progression adversely affects engine performance and safety. The apparatus (see figure) includes a commercial mid-infrared camera that contains a liquid-nitrogen-cooled focal plane indium antimonide photodetector array, and imaging is restricted by a narrow bandpass centered at wavelength of 4 microns. This narrow wavelength range centered at 4 microns was chosen because (1) it enables avoidance of interfering absorptions by atmospheric OH and CO2 at 3 and 4.25 microns, respectively; and (2) the coating material exhibits maximum transparency in this wavelength range. Delamination contrast is produced in the midinfrared reflectance images because the introduction of cracks into the TBC creates an internal TBC/air-gap interface with a high diffuse reflectivity of 0.81, resulting in substantially higher reflectance of mid-infrared radiation in regions that contain buried delamination cracks. The camera is positioned a short distance (.12 cm) from the specimen. The mid-infrared illumination is generated by a 50-watt silicon carbide source positioned to the side of the mid-infrared camera, and the illumination is collimated and reflected onto the specimen by a 6.35-cm-diameter off-axis paraboloidal mirror. Because the collected images are of a steady-state reflected intensity (in contrast to the transient thermal response observed in infrared thermography), collection times can be lengthened to whatever extent needed to achieve desired signal-to-noise ratios. Each image is digitized, and the resulting data are processed in several steps to obtain a true mid-infrared reflectance image. The raw image includes thermal radiation emitted by the specimen in addition to the desired reflected radiation. The thermal-radiation contribution is eliminated by subtracting the image obtained with the illumination off from the image obtained with the illumination on. A flat-field correction is then made to remove the effects of non-uniformities in the illumination level and pixel-to-pixel variations in sensitivity. This correction is performed by normalizing to an image of a standard object that has a known reflectance at a wavelength of 4 microns. After correction, each pixel value is proportional to the reflectance (at a wavelength of 4-microns) at the corresponding location on the specimen. Mid-infrared reflectance imaging of specimens that were thermally cyc led for different numbers of cycles was performed and demonstrated t hat mid-infrared reflectance imaging was able to monitor the gradual delamination progression that occurs with continued thermal cycling . Reproducible values were obtained for the reflectance associated w ith an attached and fully delaminated TBC, so that intermediate refle ctance values could be interpreted to successfully predict the numbe r of thermal cycles to failure.

Edlridge, Jeffrey I.↗

Diurnal and Directional Responses of Chlorophyll Fluorescence and the PRI in a Cornfield

Determining the health and vigor of vegetation using high spectral resolution remote sensing is an important goal which has application to monitoring agriculture and ecosystem productivity and carbon exchange. Two spectral indices used to assess whether vegetation is performing near-optimally or exhibiting symptoms of environmental stress (e.g., drought or nutrient deficiency, non-optimal temperatures, etc.) are the Photochemical Reflectance Index (PRI) and solar-induced red and far-red Chlorophyll Fluorescence (Fs). Both the PRI and Fs capture the dynamics of photoprotection mechanisms within green foliage: the PRI is based on the association of the reflected radiation in the green spectrum with the xanthophyll cycle, whereas Fs measures the emitted radiation in the red and far-red spectrum. Fs was determined from retrievals in the atmospheric oxygen absorption features centered at 688 and 760 nm using a modified Fraunhofer Line Depth (FLD) method. We previously demonstrated diurnal and seasonal PRI differences for sunlit vs. shaded foliage in a conifer forest canopy, as expressed in the hotspot and darkspot of the Bidirectional Reflectance Function (BRF). In a USDA-ARS experimental field site located in Beltsville, MD, USA, measurements were acquired over a corn crop from a nadir view in 2008 with an ASD FieldSpec Pro (Analytical Spectral Devices, Inc., Boulder, CO, USA) to study the behavior of the PRI for sunlit and shaded foliage as captured in reflectance variations associated with the BRF, in a I m tall canopy in the vegetative growth stage. Those observations were compared to simulations obtained from two radiative transfer models. Measurements were then acquired to examine whether the PRI and Fs were influenced by view zenith and azimuth geometries at different times of day. Those measurements were made in 2010 with the Ocean Optics USB4000 Miniature Fiber Optic Spectrometer (Ocean Optics Inc., Dunedin, Florida, USA) at several times during the day on multiple days throughout the growing season. We found that the PRI consistently had higher values, indicating lower stress, in the BRF darkspot associated with shaded foliage than in the hotspot associated with sunlit foliage. We also found that Fs exhibited differences associated with sunlit and shaded canopy sectors, which were most pronounced for the red/far-red Fs ratio. Values indicated greater physiological stress in afternoons compared to mornings, and in the early senescent canopy as compared to the vegetative growth stage, BRFs for both the PRI and the red/far-red Fs ratio were bowl-shaped for the full azimuth sweep of the canopy. These two spectral indices (PRI, Fs ratio) provided complementary information on the photosynthetic function of the corn canopy.

Middleton, Elizabeth↗

Saturn's Equatorial Oscillation: Evidence of Descending Thermal Structure from Cassini Radio Occultations

A series of near-equatorial radio occultations of Cassini by Saturn occurred in 2005 and again in 2009-2010. Comparison of the temperature-pressure profiles obtained from the two sets of occultations shows evidence of a descending pattern in the stratosphere that is similar to those associated with equatorial oscillations in Earth's middle atmosphere. This is the first time that this descent has been observed in another planetary atmosphere. If absorption of upwardly propagating waves drives the descent, the implied absorbed flux is 0.05 square meters per square second at least as large if not greater than on Earth.

Schinder, P. J.↗

A Combined Observational and Modeling Approach to Study Modern Dust Transport from the Patagonia Desert to East Antarctica

The understanding of present atmospheric transport processes from Southern Hemisphere (SH) landmasses to Antarctica can improve the interpretation of stratigraphic data in Antarctic ice cores. In addition, long range transport can deliver key nutrients normally not available to marine ecosystems in the Southern Ocean and may trigger or enhance primary productivity. However, there is a dearth of observational based studies of dust transport in the SH. This work aims to improve current understanding of dust transport in the SH by showing a characterization of two dust events originating in the Patagonia desert (south end of South America). The approach is based on a combined and complementary use of satellite retrievals (detectors MISR, MODIS, GLAS ,POLDER, OMI,), transport model simulation (HYSPLIT) and surface observations near the sources and aerosol measurements in Antarctica (Neumayer and Concordia sites). Satellite imagery and visibility observations confirm dust emission in a stretch of dry lakes along the coast of the Tierra del Fuego (TdF) island (approx.54deg S) and from the shores of the Colihue Huapi lake in Central Patagonia (approx.46deg S) in February 2005. Model simulations initialized by these observations reproduce the timing of an observed increase in dust concentration at the Concordia Station and some of the observed increases in atmospheric aerosol absorption (here used as a dust proxy) in the Neumayer station. The TdF sources were the largest contributors of dust at both sites. The transit times from TdF to the Neumayer and Concordia sites are 6-7 and 9-10 days respectively. Lidar observations and model outputs coincide in placing most of the dust cloud in the boundary layer and suggest significant de- position over the ocean immediately downwind. Boundary layer dust was detected as far as 1800 km from the source and approx.800 km north of the South Georgia Island over the central sub-Antarctic Atlantic Ocean. Although the analysis suggests the presence of dust at approx.1500 km SW of South Africa five days after, the limited capabilities of existing satellite platforms to differentiate between aerosol types do not permit a definitive conclusion. In addition, the model simulations show dust lifting to the free troposphere as it travels south but it could not be confirmed by the satellite observations due to cloudiness. This work demonstrates that complementary information from existing transport models, satellite and surface data can yield a consistent picture of the dust transport from the Patagonia desert to Antarctica. It also illustrates the limitation of using any of these approaches individually to characterize the transport of dust in a heavily cloudy area.

Gasso, S.↗

Integrating Solar Induced Fluorescence and the Photochemical Reflectance Index for Estimating Gross Primary Production in a Cornfield

The utilization of remotely sensed observations for light use efficiency (LUE) and tower-based gross primary production (GPP) estimates was studied in a USDA cornfield. Nadir hyperspectral reflectance measurements were acquired at canopy level during a collaborative field campaign conducted in four growing seasons. The Photochemical Reflectance Index (PRI) and solar induced chlorophyll fluorescence (SIF), were derived. SIF retrievals were accomplished in the two telluric atmospheric oxygen absorption features centered at 688 nm (O2-B) and 760 nm (O2-A). The PRI and SIF were examined in conjunction with GPP and LUE determined by flux tower-based measurements. All of these fluxes, environmental variables, and the PRI and SIF exhibited diurnal as well as day-to-day dynamics across the four growing seasons. Consistent with previous studies, the PRI was shown to be related to LUE (r2 = 0.54 with a logarithm fit), but the relationship varied each year. By combining the PRI and SIF in a linear regression model, stronger performances for GPP estimation were obtained. The strongest relationship (r2 = 0.80, RMSE = 0.186 mg CO2/m2/s) was achieved when using the PRI and SIF retrievals at 688 nm. Cross-validation approaches were utilized to demonstrate the robustness and consistency of the performance. This study highlights a GPP retrieval method based entirely on hyperspectral remote sensing observations.

cornfield↗

The Salinity Retrieval Algorithms for the NASA Aquarius Version 5 and SMAP Version 3 Releases

The Aquarius end-of-mission (Version 5) salinity data set was released in December 2017. This article gives a comprehensive overview of the main steps of the Level 2 salinity retrieval algorithm. In particular, we will discuss the corrections for wind induced surface roughness, atmospheric oxygen absorption, reflected galactic radiation and side-lobe intrusion from land surfaces. Most of these corrections have undergone major updates from previous versions, which has helped mitigating temporal and zonal biases. Our article also discusses the ocean target calibration for Aquarius Version 5. We show how formal error estimates for the Aquarius retrievals can be obtained by perturbing the input to the algorithm. The performance of the Aquarius Version 5 salinity retrievals is evaluated against salinity measurements from the ARGO network and the HYCOM model. When stratified as function of sea surface temperature or sea surface wind speed, the difference between Aquarius Version 5 and ARGO is within +/-0.1 psu. The estimated global RMS uncertainty for monthly 100 km averages is 0.128 psu for the Aquarius Version 5 retrievals. Finally, we show how the Aquarius Version 5 salinity retrieval algorithm is adapted to retrieve salinity from the Soil-Moisture Active Passion (SMAP) mission.

retrieval algorithm↗

The Salinity Retrieval Algorithms for the NASA Aquarius Version 5 and SMAP Version 3 Releases

The Aquarius end-of-mission (Version 5) salinity data set was released in December 2017. This article gives a comprehensive overview of the main steps of the Level 2 salinity retrieval algorithm. In particular, we will discuss the corrections for wind induced surface roughness, atmospheric oxygen absorption, reflected galactic radiation and side-lobe intrusion from land surfaces. Most of these corrections have undergone major updates from previous versions, which has helped mitigating temporal and zonal biases. Our article also discusses the ocean target calibration for Aquarius Version 5. We show how formal error estimates for the Aquarius retrievals can be obtained by perturbing the input to the algorithm. The performance of the Aquarius Version 5 salinity retrievals is evaluated against salinity measurements from the ARGO network and the HYCOM model. When stratified as function of sea surface temperature or sea surface wind speed, the difference between Aquarius Version 5 and ARGO is within +-0.1 psu. The estimated global RMS uncertainty for monthly 100 km averages is 0.128 psu for the Aquarius Version 5 retrievals. Finally, we show how the Aquarius Version 5 salinity retrieval algorithm is adapted to retrieve salinity from the Soil-Moisture Active Passion (SMAP) mission.

calibration↗

Remote Sensing of the Ocean Surface Refractive Index via Short-Wave Infrared Polarimetry

The linear polarization of sunlight reflected by ocean surfaces in the shortwave infrared (SWIR), at geometries where specular reflection dominates the signal, is a direct function of the refractive index of the surface microlayer(SML). This simple physical concept is at the base of a novel technique presented in this study. We invert observations obtained by the airborne Research Scanning Polarimeter (RSP) in the sun glint region, where each pixel's radiance is dominated by the signal originating from the wave slopes oriented precisely to cause specular reflection. The SWIR wavelength ensures minimization of aerosol interference when radiance travels through the atmosphere; strong absorption by the water body then limits the penetration depth to the first micrometer or so, effectively probing the SML. The resulting Degree of Linear Polarization (DoLP) is then governed by the refractive index via the Fresnel law for the specfic pixel geometry, independently of the wind speed. The selected dataset concerns several field deployments from both low- and high-altitude aircraft, including total reflectance measurements with the sole purpose of accounting for the residual aerosol effect.Stable retrievals from transects above pure seawater yielded values of refractive index that match the values published in the literature within an accuracy of 5 x 10 [superscript 4]. Flying over the oil spill caused by the explosion of the Deepwater Horizon platform, detected variations were found compatible with the presence of an oil slick. The robustness of the results, guaranteedby the high RSP polarimetric accuracy (less than or equal to 0:2%), opens the possibility for remote-sensing detection of other entities that similarly affect the refractive index including whitecaps, microplastics, biological gels, seaweed and grass mats.

Surface Microlayer↗

Cloud Habitability From Earth To Venus: Science & Technology Considerations

Early Venus and early Earth are believed to have shared many aspects associated with the emergence of an Earth-like biochemistry: surface geochemistry, rock/water interfacing, and geothermal activity. There is significant interest in whether such life – based on water and carbon – could have persisted to the present day in Venus’s sulfuric acid cloud and haze layers, where some liquid water remains. Investigations of this possibility have been connected to understanding observations such as disequilibria in atmospheric sulfur chemistry, strong atmospheric UV absorption, and the controversial recent claim of phosphine detection.

Cloud↗