Heat sterilizable impact resistant cell development Quarterly report, 1 Apr. - 30 Jun. 1969
Electrochemical studies of impact resistance, cycle life, and embrittlement of silver zinc batteries
SEARCH · Search NASA
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Electrochemical studies of impact resistance, cycle life, and embrittlement of silver zinc batteries
Electrochemical studies of silver grid embrittlement, life cycle testing, and tear down inspection of failed silver zinc batteries
Ablation, transmission transparency and embrittlement of heat shield materials for Voyager tested under simulated Mars entry conditions
Materials technology for reuse capability of space shuttle, discussing normal and stress corrosion, hydrogen embrittlement and flammability
Titanium hydride deformation assisted nucleation in alpha-beta titanium alloy, showing low strain rate embrittlement and stress corrosion crack propagation in aqueous environments
Nuclear irradiation effect on embrittlement of Ti and Ti alloys at cryogenic temperature, determining radiation damage threshold as function of tensile properties changes
Hydrogen embrittlement during hot salt, stress corrosion of titanium alloys
Hydrogen embrittlement of titanium as related to stress corrosion cracking
Electroplating and vacuum evaporation of yttrium oxide-chromium oxide coating of chromium alloys for nitrogen embrittlement protection
Gaseous hydrogen embrittlement in Inconel 718, Inconel 625, AISI 321 stainless steel, Ti-5Al-25Sn ELI, and OFHC copper
Rare earth and thorium alloying of chromium and mechanism for controlling nitrogen embrittlement
Hydrogen embrittlement of titanium alloy surface in hot salt corrosion cracking
Effectivness of yttrium, lanthanum, and hafnium coatings for preventing nitridation embrittlement of chromium alloys at high temperatures
Hydrogen embrittlement in hot salt stress corrosion of Ti alloy
Advanced alloy design technique was developed for treating alloys that will have extended life in service at high temperature and intermediate temperatures. Process stabilizes microstructure of the alloy by designing it so that compound identified with embrittlement is eliminated or minimized. Design process is being used to develop both nickel and cobalt-base superalloys.
Additional support is presented for the previously proposed role of hydrogen as an embrittling agent in hot-salt stress corrosion cracking of titanium-aluminum alloys. The main source of hydrogen formed during the reactions of titanium alloys with hot salt was identified as water associated with the salt. Hydrogen is produced by the reaction of an intermediate (hydrogen halide) with the alloy rather than from metal-water reactions. The fracture mode of precracked tensile specimens was ductile when the specimens were tested in air, and brittle when tests were made in high-pressure hydrogen. Stressed titanium-aluminum alloys also were cracked by bombardment with hydrogen ions produced in a proton accelerator. The approximate concentrations of the hydrogen ions in the alloys were calculated.
The Ti-8Al-1Mo-1V alloy was tested in four conditions: mill annealed (70 ppM H), duplex annealed (70 ppM H), vacuum annealed to an intermediate (36 ppM) and a low (9 ppM H) hydrogen level. Material annealed at 650 C (duplex condition) exhibited resistance to hot-salt stress corrosion superior to that exhibited by material in the mill-annealed condition. Reduction of the alloy hydrogen content from 70 to as low as 9 ppM did not influence resistance to hot-salt stress corrosion embrittlement or cracking.
Susceptibility of titanium alloys to hot-salt stress-corrosion cracking increased as follows: Ti-2Al-11Sn-5Zr-0.2Si(679), Ti-6Al-2Sn-4Zr-2Mo(6242), Ti-6Al-4V(64), Ti-6Al-4V-3Co(643), Ti-8Al-1Mo-1V(811), and Ti-13V-11Cr-3A1(13-11-3). The Ti-5Al-6Sn-2Zr-1Mo-0.25Si(5621S) alloy was both the least and most susceptible depending on heat treatment. Such rankings can be drastically altered by heat-to-heat and processing variations. Residual compressive stresses and cyclic exposures also reduce susceptibility to stress-corrosion. Simulated turbine-engine compressor environmental variables such as air velocity, pressure, dewpoint, salt concentration, and salt deposition temperature have only minor effects. Detection of substantial concentrations of hydrogen in all corroded alloys confirmed the existence of a hydrogen embrittlement mechanism.