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At least 505 records · Page 28

Carbonated Brine Injection for a Pilot Site as a Low-Risk Geologic Carbon Storage Strategy: A Simulation Study

This technical report presents a preliminary study for CBI implementation in the Pena Creek pilot site in Dimmit County, Texas, targeting the Edwards Limestone Formation for SWD, in collaboration with NGL Energy Partners. The objective of this study is to find the conservative CO 2 molality for safe storage and potential risks for CBI at this pilot site. Geomodel was performed to get site-specific reservoir geology information. Reservoir modeling was performed to investigate dissolved CO 2 molality and pressure changes at relevant injection conditions. Wellbore corrosion and compatibility was discussed with corrosion modeling. Dissolved CO 2 long-term fate in the reservoir was examined with reactive transport modeling. This plan would set the scientific foundation as the initial step for future implementation in the field.

58 GEOSCIENCES↗

Genetic implications of the shapes of Martian and lunar craters.

Discussion of the problem of lunar crater genesis in the light of some considerations prompted by lunar and Martian crater similarities. By analogy with the moon, Martian craters seem both to vary in initial shape according to the energy of the impact that formed them and to have been modified subsequently by endogenic and surface processes. A proposed model for the geologic development of large Martian and lunar craters outlines a time-dependent sequence of events. Craters which have undergone rapid isostatic adjustment on the moon have distinctive morphologies and occur preferentially along mare basin-upland margins.

Pike, R. J.↗

Some aspects of core formation in Mercury

An evaluation of existing theories on the existence of the planet's metallic core is presented. Topics considered are: (1) magnetic fields; (2) surface geology; (3) cosmochemical models.

Solomon, S. C.↗

Earth resources-regional transfer activity contracts review

A regional transfer activity contracts review held by the Earth Resources Office was summarized. Contracts in the earth resources field primarily directed toward applications of satellite data and technology in solution of state and regional problems were reviewed. A summary of the progress of each contract was given in order to share experiences of researchers across a seven state region. The region included Missouri, Kentucky, Tennessee, Mississippi, Alabama, Georgia, and North Carolina. Research in several earth science disciplines included forestry, limnology, water resources, land use, geology, and mathematical modeling. The use of computers for establishment of information retrieval systems was also emphasized.

Bensko, J., Jr.↗

Geophysical interpretation of satellite laser ranging measurements of crustal movement in California

As determined by satellite laser ranging the rate of contraction of a 900 kilometer baseline between sites located near Quincy in northern California and San Diego in southern California is about 61 to 65 mm/yr with a formal uncertainty of about 10 mm/yr. The measured changes in baseline length are a manifestation of the relative motion between the North America and Pacific tectonic plates. This long baseline result is compared to measurements made by more conventional means on shorter baselines. Additional information based on seismicity, geology, and theoretical modelling is also analyzed. Deformation lying within a few tens of kilometers about the major faults in southern California accounts for most, but not all of the observed motion. Further motion is attributable to a broader scale deformation in southern California. Data suggesting crustal movements north of the Garlock fault, in and near the southern Sierra Nevada and local motion at an observatory are also critically reviewed. The best estimates of overall motion indicated by ground observations lie between 40 and 60 mm/yr. This lies within one or two standard deviations of that deduced by satellite ranging but the possibility of some unresolved deficit cannot be dismissed. The long time scale RM2 plate tectonic model of Minster and Jordan predicts a contraction between 47 and 53 mm/yr depending on the extension rate of the Basin and Range. Thus the ground based observations, satellite laser ranging (SLR) results, and RM2 rates differ at about the 10 mm/yr level and are consistent with one another within the data and model uncertainties.

Cohen, S. C.↗

The earth as a planet - Paradigms and paradoxes

The independent growth of the various branches of the earth sciences in the past two decades has led to a divergence of geophysical, geochemical, geological, and planetological models for the composition and evolution of a terrestrial planet. Evidence for differentiation and volcanism on small planets and a magma ocean on the moon contrasts with hypotheses for a mostly primitive, still undifferentiated, and homogeneous terrestrial mantle. In comparison with the moon, the earth has an extraordinarily thin crust. The geoid, which should reflect convection in the mantle, is apparently unrelated to the current distribution of continents and oceanic ridges. If the earth is deformable, the whole mantle should wander relative to the axis of rotation, but the implications of this are seldom discussed. The proposal of a mantle rich in olivine violates expectations based on evidence from extraterrestrial sources. These and other paradoxes force a reexamination of some long-held assumptions.

Anderson, D. L.↗

Reconstruction of the dynamics of the 1800-1801 Hualalai eruption: Implications for planetary lava flows

The 1800-1801 eruption of alkalic basalt from the Hualalai volcano, Hawaii provides a unique opportunity for investigating the dynamics of lava flow emplacement with eruption rates and compositions comparable to those that have been suggested for planetary eruptions. Field observations suggest new considerations must be used to reconstruct the emplacement of these lava flows. These observations are: (1) the flow traversed the 15 km from the vent to the sea so rapidly that no significant crust formed and an observation of the eruption reported that the flow reach the sea from the vent in approximately 1 hour; (2) the drainage of beds of xenolith nodules indicates a highly fluid, low viscosity lava; (3) overspills and other morphologic evidence for a very low viscosity host fluid; (4) no significant longitudinal increase in flow thickness that might be associated with an increase in the rheological properties of the lava; and (5) the relatively large size of channels associated with the flow, up to 80 meters across and several km long. Models for many geologic mass movements and fast moving fluids with various loadings and suspensions are discussed.

Baloga, Stephen↗

Detection and Characterization of Martian Volatile-Rich Reservoirs: The Netlander Approach

Geological and theoretical modeling do indicate that, most probably, a significant part of the volatiles present in the past is presently stocked within the Martian subsurface as ground ice, and as clay minerals (water constitution). The detection of liquid water is of prime interest and should have deep implications in the understanding of the Martian hydrological cycle and also in exobiology. In the frame of the 2005 joint CNES-NASA mission to Mars, a set of 4 NETLANDERs developed by an European consortium is expected to be launched between 2005 and 2007. The geophysical package of each lander will include a geo-radar (GPR experiment), a magnetometer (MAGNET experiment), a seismometer (SEIS experiment) and a meteorological package (ATMIS experiment). The NETLANDER mission offers a unique opportunity to explore simultaneously the subsurface as well as deeper layers of the planetary interior on 4 different landing sites. The complementary contributions of all these geophysical soundings onboard the NETLANDER stations are presented.

Banerdt, B.↗

A New Measurement of the Absolute Spectral Reflectance of the Moon

The spectral reflectance of the Moon is an important property for studies of lunar geology, quantitative physical modeling of the moon, and in-flight calibration of spacecraft sensors. Previous studies have claimed that telescopic absolute reflectance values for the Moon are greater than laboratory reflectance measurements by a factor of two. In order to confirm these results, we performed ground-based observations of the lunar surface using a visible/near-infrared spectroradiometer and compared the measured lunar surface radiance to solar radiance corrected for atmospheric scattering and absorption. These data were compared to previously obtained laboratory reflectance measurements from Apollo soil samples.

Lawrence, S. J.↗

Large-Scale Features of Pliocene Climate: Results from the Pliocene Model Intercomparison Project

Climate and environments of the mid-Pliocene warm period (3.264 to 3.025 Ma) have been extensively studied.Whilst numerical models have shed light on the nature of climate at the time, uncertainties in their predictions have not been systematically examined. The Pliocene Model Intercomparison Project quantifies uncertainties in model outputs through a coordinated multi-model and multi-mode data intercomparison. Whilst commonalities in model outputs for the Pliocene are clearly evident, we show substantial variation in the sensitivity of models to the implementation of Pliocene boundary conditions. Models appear able to reproduce many regional changes in temperature reconstructed from geological proxies. However, data model comparison highlights that models potentially underestimate polar amplification. To assert this conclusion with greater confidence, limitations in the time-averaged proxy data currently available must be addressed. Furthermore, sensitivity tests exploring the known unknowns in modelling Pliocene climate specifically relevant to the high latitudes are essential (e.g. palaeogeography, gateways, orbital forcing and trace gasses). Estimates of longer-term sensitivity to CO2 (also known as Earth System Sensitivity; ESS), support previous work suggesting that ESS is greater than Climate Sensitivity (CS), and suggest that the ratio of ESS to CS is between 1 and 2, with a "best" estimate of 1.5.

mathematical models↗

FIELD IMPLEMENTATION PLAN FOR A WILLISTON BASIN BRINE EXTRACTION AND STORAGE TEST

The Energy & Environmental Research Center (EERC) successfully completed all technical work of Phase I, including development of a field implementation plan (FIP) for a brine extraction and storage test (BEST) in the North Dakota portion of the Williston Basin. This implementation plan was commissioned by the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) as a proxy for managing formation pressure plumes and measuring/monitoring the movement of differential pressure and CO2 plumes in the subsurface for future saline CO2 storage projects. BEST comprises the demonstration and validation of active reservoir management (ARM) strategies and extracted brine treatment technologies. Two prospective commercial brine injection sites were evaluated for BEST to satisfy DOE’s goals. Ultimately, an active saltwater disposal (SWD) site, Johnsons Corner, was selected because it possesses an ideal combination of key factors making it uniquely suited to host BEST. This site is located in western North Dakota and operated by Nuverra Environmental Solutions (Nuverra), a national leader in brine handling, treatment, and injection. An integrated management approach was used to incorporate local and regional geologic characterization activities with geologic and simulation models, inform a monitoring, verification, and accounting (MVA) plan, and to conduct a risk assessment. This approach was used to design a FIP for an ARM schema and an extracted brine treatment technology test bed facility. The FIP leverages an existing pressure plume generated by two commercial SWD wells. These wells, in conjunction with a new brine extraction well, will be used to conduct the ARM schema. Results of these tests will be quantified based on their impact on the performance of the existing SWD wells and the surrounding reservoir system. Extracted brine will be injected into an underlying deep saline formation through a new injection well. The locations of proposed extraction and injection wells were selected during the Phase I efforts. These wells will be permitted as North Dakota Administrative Code Underground Injection Control Class II wells and will yield additional characterization data which will further refine the FIP in Phase II. An array of surface and downhole monitoring techniques will validate ARM performance against predictive simulation results. Infrastructure will be constructed to manage extracted fluids at the surface and provide brine to a treatment test bed facility. Treatment of extracted brine can provide a means of reducing extracted brine disposal volumes, an alternate source of water, and/or salable products for beneficial use. A test bed facility will be constructed to provide a means of demonstrating these technologies on a wide range of brine concentrations. Screening criteria based on a techno-economic and life cycle assessment were developed to select high-salinity brine treatment technologies for extended duration treatment (30–60 days) in Phase II. A detailed cost assessment determined total implementation costs for BEST of $19,901,065 million (DOE share $15,680,505). These costs are inclusive of all necessary equipment, infrastructure construction, operations and project closeout costs required to implement BEST. An ideal combination of key factors makes the Johnsons Corner site uniquely suited to be the BEST demonstration.

10 SYNTHETIC FUELS↗

Challenges and Lessons Learned Performing Subsurface Investigations at a Radiologically Contaminated Site in an Urban Area - 17391

At the Formerly Utilized Sites Remedial Action Program (FUSRAP) Maywood Superfund Site (FMSS) the U.S. Army Corps of Engineers (USACE) has performed minimally intrusive (i.e. non-excavation) sub-surface investigations in soils, underneath roadways, and within buildings to generate information needed to determine whether contaminated material was present and to delineate the nature and extent. Given that thorium-232 (Th-232) contaminated material is present below various surfaces and that the current iteration of the Multi-Agency Radiation survey and Site Investigation Manual (MARSSIM) has only marginal guidance on evaluating and releasing subsurface data, survey design and implementation required detailed up front planning and post investigation analysis and reporting. This paper will discuss the approaches USACE utilized during a recent roadway investigation, some of the challenges encountered, a discussion of techniques used and results obtained, and an overall summary of pitfalls identified and lessons learned for future efforts. In order to evaluate selected areas, direct push technology was utilized in conjunction with plastic tubing to facilitate core capture and sample collection. PVC piping was inserted in each bore hole to prevent borehole collapse and facilitate downhole gamma logging. Soil samples were collected from the surface, from native material or the bottom of the boring, and from the interval or intervals which exhibited elevated downhole gamma readings, and from areas with an identifiable marker of contamination (i.e. soil discoloration) at the judgement of the field staff. Data was collected and evaluated using the approaches laid out in MARSSIM as best possible. As MARSSIM was developed to only address surface contamination, USACE, in agreement with regulators and stakeholders, utilized a 'varying plane' approach, where samples are evaluated as if on a single plane, and only the highest concentration encountered at any point is considered. Because the areas investigated were not easily cast into simple geometric shapes adhering to MARSSIM design criteria, it was important to ensure that Survey Unit design for Class 1 Survey Units were reasonable. All Class 1 SUs were contiguous survey units. Class 2 survey units were allowed to be non-contiguous provided that they are situated in close proximity to one another and share the same geology, conceptual site model, history, and radionuclide concentrations. The information contained in this paper will benefit Projects working with subsurface contamination which may require subsurface investigation and an understanding of the logistical, technological, and regulatory challenges. The ultimate outcome of this effort was the successful delineation of areas of contamination which will facilitate current utility work and guide future remediation. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

From Subsurface to System: Offshore CCS Development for the Northeastern U.S. Atlantic Shelf

This study evaluated offshore carbon sequestration potential and infrastructure design along the mid-north Atlantic outer continental shelf, addressing the limited onshore storage options in the northeastern U.S. The objective was to define viable CCS pathways by integrating geological characterization, reservoir modeling, and system-level engineering for decarbonizing regional industrial sources. The work was conducted under US DOE grant FE0032407 for the Regional Initiatives and builds on a previous prospective resources assessment project by Battelle.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Estimation of grain sizes and mixing ratios of fine powder mixtures of common geologic minerals

Two different approaches for modeling reflectance spectra of intimate mixtures, Hapke's model and the isograin model, are used to estimate grain sizes and mixing ratios of powder mixtures of three geologic minerals: olivine, orthopyroxene, and plagioclase. In Hapke's model, scattering and extinction effiencies are mixed separately, and both models employ semiempirical refractive index spectra for component minerals. Mixing ratios of mixtures of grain size 45-75 micrometers are well estimated by both models assuming a common grain size of 60 micrometers and optimizing the constants for the single-particle scattering. For each model, effective grain size ratios for mineral constituents in mixtures of grain size less than 25 micrometers, are derived successfully that allows mineral abundances to be accurately predicted within approximately 4 wt percent. On the other hand, neither model can accurately predict mineral reflectance spectra for its smaller grain sizes less than 25 and 25-45 micrometers using an absorption coefficient spectrum derived from a larger grain size (45-75 micrometers). The errors in both models are significantly reduced if surface roughness effects of the smaller grain-size fractions are modeled.

Hiroi, Takahiro↗

Informing Geologic CO 2 Storage Site Management Decisions under Uncertainty: Demonstration of NRAP's Integrated Assessment Model (NRAP-IAM-CS) Application

Managing risks at geologic CO 2 storage sites requires making decisions based on the quantitative predictions of long-term performance that not only take into account various subsurface hydrologic, geochemical processes and interactions but also the related uncertainties. The US DOE (United States Department of Energy) funded National Risk Assessment Partnership (NRAP) has developed a quantitative approach and a model to predict the long-term behavior of GCS sites. The approach uses an integrated assessment model (NRAP-IAM-CS) that couples reduced order models (ROMs) for various GCS components (such as storage reservoir, wells, seals, and groundwater aquifer) in a stochastic modeling framework that allows for rapid simulations of entire system behavior over thousands of years while probing uncertainties. We demonstrate application of NRAP-IAM-CS using two examples that focus on CO 2 leakage and resulting impacts. The examples are used to demonstrate how different uncertain parameters affect overall performance objectives.

03 NATURAL GAS↗

Micromagnetic Modeling of a Magnetically Unstable Zone and Its Geological Significances

Abstract Recent micromagnetic simulations have found that particles in the transitional zone between the single domain (SD) and single vortex (SV) zone are prone to thermal and external magnetic field instabilities that could adversely affect the accuracy of interpretations of paleomagnetic recordings. In this study, we attempt to evaluate the internal magnetization characteristics of these magnetically unstable (MU) particles and the influence on paleomagnetic observations by simulating the magnetic behavior of 68–104 nm truncated octahedral magnetite particles using the MERRILL modeling software. We found that: (a) The size region of the “MU zone” for grains of truncated octahedron shape is different from cubic octahedrons and spheres, indicating that the zone may be controlled by the geometry and shape of particles; (b) The MU zone has a range of 79–97 nm region, which is dominated by a hard‐axis aligned single vortex (HSV); and (c) MU particles are unstable as a function of temperature and have low coercive fields. Finally, the numerical fitting of hysteresis parameters for experimental data suggests that the influence of such MU particles in samples should not be ignored, especially for samples with fine‐grained magnetic minerals as the primary magnetic recording carriers. This research has extended our understanding of the behavior of the “MU zone” and its significance on paleomagnetic records.

Wang, Yuqin↗

A coupled thermo-hydro-mechanical model for simulating leakoff-dominated hydraulic fracturing with application to geologic carbon storage

A potential risk of injecting CO2 into storage reservoirs with marginal permeability (≲ 10 mD (1 mD = 10 –15 m 2 )) is that commercial injection rates could induce fracturing of the reservoir and/or the caprock. Such fracturing is essentially fluid-driven fracturing in the leakoff-dominated regime. Recent studies suggested that fracturing, if contained within the lower portion of the caprock complex, could substantially improve the injectivity without compromising the overall seal integrity. Modeling this phenomenon entails complex coupled interactions among the fluids, the fracture, the reservoir, and the caprock. Here, we develop a simple method to capture all these interplays in high fidelity by sequentially coupling a hydraulic fracturing module with a coupled thermal-hydrological-mechanical (THM) model for nonisothermal multiphase flow. The model was made numerically tractable by taking advantage of self-stabilizing features of leakoff-dominated fracturing. The model is validated against the PKN solution in the leakoff-dominated regime. Moreover, we employ the model to study thermo-poromechanical responses of a fluid-driven fracture in a field-scale carbon storage reservoir that is loosely based on the In Salah project's Krechba reservoir. The model reveals complex yet intriguing behaviors of the reservoir-caprock-fluid system with fracturing induced by cold CO 2 injection. We also study the effects of the in situ stress contrast between the reservoir and caprock and thermal contraction on the vertical containment of the fracture. The proposed model proves effective in simulating practical problems on length and time scales relevant to geological carbon storage.

58 GEOSCIENCES↗

Basin and Petroleum System Modeling of Gas Hydrate Deposits in the Walker Ridge Area, Northern Gulf of Mexico - Poster

Poster presented by NETL at ICGH, 06/17 - Abstract:<p><br></p><p>We are currently constructing an Earth model of the Terrebonne Basin for comprehensive 3D modeling. Well data and a high-quality 3D seismic survey underpin the geologic conditions for the model. Additional model constraints include basal heat flow, seafloor temperature, and paleowater depth through time. Our initial investigation comprises the development of a “pseudo” 2D model centered on the deep WR313 #001 well. We are using this test case to establish the workflow for integrating BPSM with gas hydrate analyses; this will eventually be applied to the entire mini-basin. </p><p><br></p><p>A key aspect of investigating the gas hydrate system with BPSM is integrating it with the other active petroleum system(s) in the region, because the methane in hydrate deposits can derive from both biogenic and thermogenic sources. Some of the questions we may consider are: What is the history of these deposits with respect to the gas hydrate stability zone, recognizing that this area is not one characterized by simple continuous sedimentation and subsidence, but instead by periodic uplift, tilting, plate rotation, sea-level change, salt tectonics, and evolution of temperature gradients. </p><p><br></p><p>In conclusion, BPSM has been called the ‘great integrator’ in petroleum exploration. Development of a BPSM model of gas hydrates in the Terrebonne Basin of the northern GoM will provide a vehicle within which to integrate other early exploration and assessment research being conducted on gas hydrates, such as in frontier areas like Japan, as a potential resource likely to provide many decades of energy if proven to be commercially producible</p>

Dafov, Laura↗