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NASA NTRS1991

Prebiotic chemistry in clouds

The chemical evolution hypothesis of Woese (1979), according to which prebiotic reactions occurred rapidly in droplets in giant atmospheric reflux columns was criticized by Scherer (1985). This paper proposes a mechanism for prebiotic chemistry in clouds that answers Scherer's concerns and supports Woese's hypothesis. According to this mechanism, rapid prebiotic chemical evolution was facilitated on the primordial earth by cycles of condensation and evaporation of cloud drops containing clay condensation nuclei and nonvolatile monomers. For example, amino acids supplied by, or synthesized during entry of meteorites, comets, and interplanetary dust, would have been scavenged by cloud drops containing clay condensation nuclei and would be polymerized within cloud systems during cycles of condensation, freezing, melting, and evaporation of cloud drops.

Oberbeck, Verne R.↗
NASA NTRS1991

A collection of diverse micrometeorites recovered from 100 tonnes of Antarctic blue ice

A new type of meteoritic material, intermediate in size between meteorites and interplanetary dust particles (IDPs), is described. Melting and filtering of about 100 tons of blue ice near Cap Prudhomme, Antarctica, yielded 7500 or more irregular, friable particles and about 1500 melted spherules, about 100 microns in size, both showing a 'chondritic' composition suggestive of an extraterrestrial origin. Analyzed irregular particles appear to be unmelted and have similarities with the fine-grained matrix of primitive carbonaceous chondrites, but are extremely diverse in composition. Isotopic analysis of trapped neon confirms an extraterrestrial origin for 16 of 47 irregular particles and 2 of 19 spherules studied and strongly suggests that they were exposed in space as micrometeoroids. These large Antarctic micrometeorites constitute a new family, or at least a new population, of solar system objects, in a mass range corresponding to the bulk of extraterrestrial material accreted by the earth today.

Maurette, M.↗
NASA NTRS1991

Terrestrial production vs. extraterrestrial delivery of prebiotic organics to the early Earth

A comprehensive treatment of comet/asteroid interaction with the atmosphere, ensuring surface impact, and resulting organic pyrolysis is required to determine whether more than a negligible fraction of the organics in incident comets and asteroids actually survived collision with Earth. Results of such an investigation, using a smoothed particle hydrodynamic simulation of cometary and asteroidal impacts into both oceans and rock, demonstrate that organics will not survive impacts at velocities approx. greater than 10 km s(exp -1), and that even comets and asteroids as small as 100m in radius cannot be aerobraked to below this velocity in 1 bar atmospheres. However, for plausible dense (10 bar CO2) early atmospheres, there will be sufficient aerobraking during atmospheric passage for some organics to survive the ensuing impact. Combining these results with analytical fits to the lunar impact record shows that 4.5 Gyr ago Earth was accreting at least approx. 10(exp 6) kg yr(exp 1) of intact cometary organics, a flux which thereafter declined with a approx. 100 Myr half-life. The extent to which this influx was augmented by asteroid impacts, as well as the effect of more careful modelling of a variety of conservative approximations, is currently being quantified. These results may be placed in context by comparison with in situ organic production from a variety of terrestrial energy sources, as well as organic delivery by interplanetary dust. Which source dominated the early terrestrial prebiotic inventory is found to depend on the nature of the early terrestrial atmosphere. However, there is an intriguing symmetry: it is exactly those dense CO2 atmospheres where in situ atmospheric production of organic molecules should be the most difficult, in which intact cometary organics would be delivered in large amounts.

Chyba, C. F.↗
NASA NTRS1991

LDEF post-retrieval evaluation of exobiology interests

Cursory examination of the Long Duration Exposure Facility (LDEF) shows the existence of thousands of impact craters of which less than 1/3 exceed 0.3 mm in diameter; the largest crater is 5.5 mm. Few craters show oblique impact morphology and, surprisingly, only a low number of craters have recognizable impact debris. Study of this debris could be of interest to exobiology in terms of C content and carbonaceous materials. All craters greater that 0.3 mm have been imaged and recorded into a data base by the preliminary examination team. Various portions of the LDEF surfaces are contaminated by outgassed materials from experimenters trays, in addition to the LDEF autocontamination and impact with orbital debris not of extraterrestrial origin. Because interplanetary dust particles (IDP's) nominally impacted the LDEF at velocities greater than 3 km/s, the potential for intact survival of carbonaceous compounds is mostly unknown for hypervelocity impacts. Calculations show that for solid phthalic acid (a test impactor), molecular dissociation would not necessarily occur below 3 km/s, if all of the impact energy was directed at breaking molecular bonds, which is not the case. Hypervelocity impact experiments (LDEF analogs) were performed using the Ames Vertical Gun Facility. Grains of phthalic acid and the Murchison meteorite (grain diameter = 0.2 for both) were fired into an Al plate at 2.1 and 4.1 km/s respectively. The results of the study are presented, and it is concluded that meaningful biogenic elemental and compound information can be obtained from IDP impacts on the LDEF.

Bunch, T. E.↗
NASA NTRS1992

IDE spatio-temporal impact fluxes and high time-resolution studies of multi-impact events and long-lived debris clouds

The purpose of the Interplanetary Dust Experiment (IDE) on the Long Duration Exposure Facility (LDEF) was to sample the cosmic dust environment and to use the spatio-temporal aspect of the experiment to distinguish between the various components of the environment: zodiacal cloud, beta meteoroids, meteor streams, interstellar dust, and orbital debris. It was found that the introduction of precise time and even rudimentary directionality as co-lateral observables in sampling the particulate environment in near-Earth space produces an enormous qualitative improvement in the information content of the impact data. The orbital debris population is extremely clumpy, being dominated by persistent clouds in which the fluxes may rise orders of magnitude above the background. The IDE data suggest a strategy to minimize the damage to sensitive spacecraft components, using the observed characteristics of cloud encounters.

Mulholland, J. Derral↗
NASA NTRS1992

Scanning electron microscope/energy dispersive x ray analysis of impact residues on LDEF tray clamps

To better understand the nature of particulates in low-Earth orbit (LEO), and their effects on spacecraft hardware, we are analyzing residues found in impacts on the Long Duration Exposure Facility (LDEF) tray clamps. LDEF experiment trays were held in place by 6 to 8 chromic-anodized aluminum (6061-T6) clamps that were fastened to the spacecraft frame using three stainless steel hex bolts. Each clamp exposed an area of approximately 58 sq cm (4.8 cm x 12.7 cm x .45 cm, minus the bolt coverage). Some 337 out of 774 LDEF tray clamps were archived at JSC and are available through the Meteoroid & Debris Special Investigation Group (M&D SIG). Optical scanning of clamps, starting with Bay/Row A01 and working toward H25, is being conducted at JSC to locate and document impacts as small as 40 microns. These impacts are then inspected by Scanning Electron Microscopy/Energy Dispersive X-ray Analysis (SEM/EDXA) to select those features which contain appreciable impact residue material. Based upon the composition of projectile remnants, and using criteria developed at JSC, we have made a preliminary discrimination between micrometeoroid and space debris residue-containing impact features. Presently, 13 impacts containing significant amounts of unmelted and semi-melted micrometeoritic residues were forwarded to Centre National d'Etudes Spatiales (CNES) in France. At the CNES facilities, the upgraded impacts were analyzed using a JEOL T330A SEM equipped with a NORAN Instruments, Voyager X-ray Analyzer. All residues were quantitatively characterized by composition (including oxygen and carbon) to help understand interplanetary dust as possibly being derived from comets and asteroids.

Bernhard, Ronald P.↗
NASA NTRS1992

Further analysis of LDEF FRECOPA micrometeroid remnants

Experiments dedicated to the detection of interplanetary dust particles (IDP's) were exposed within the FRECOPA payload, installed on the face of the LDEF directly opposed to the velocity vector (west facing direction, location B3). We were mainly interested in the analysis of hypervelocity impact features of sizes less than or = 10 microns, found in thick Al targets devoted to the research of impact features. In the 15 craters found in the scanned area (approximately 4 sq. cm), the chemical analysis suggests an extraterrestrial origin for the impacting particles. The main elements we identified are usually refered to as chondrite elements: Na, Mg, Si, S, Ca, and Fe are found in various proportions, intrinsic Al being masked by the Al target; we notice a strong depletion in Ni, never observed in our samples. Furthermore, C and O are present in 90 percent of the cases; the C/O peak height ratio varies from 0.1 to 3. Impactor simulations by light gas gun hypervelocity impact experiments have shown that meaningful biogenic element and compound information maybe obtained from IDP residues below impacts of critical velocities, that are less than or = 4 km/sec for particles larger than 100 microns in diameter. Our results obtained for the smaller size fraction IDP's suggest that at such sizes, the critical velocity could be higher by a factor of 2 or 3, as chemical analysis of the remnants were possible in all the identified impact craters, performed on targets possibly hit at velocities greater than or = 7.5 km/s, which is the spacecraft velocity. These samples are now subjected to an imagery and analytical protocol that includes FESEM (field emission scanning electron microscopy) and LIMS (laser ionization mass spectrometry). The LIMS analyses were performed using the LIMA-ZA instrument. Results are presented, clearly indicating that such small events show crater features analogous to what is observed at larger sizes; our first analytical results, obtained for 2 events (P6 and P10) suggest that N is present in the IDP's remnants in which C and O were identified by EDX analysis. In one case (P6), enrichment in K and P is observed. Surface contamination by NaCl is evident on the FRECOPA surfaces.

Borg, J.↗
NASA NTRS1992

Modelling the near-Earth space environment using LDEF data

Near-Earth space is a dynamic environment, that is currently not well understood. In an effort to better characterize the near-Earth space environment, this study compares the results of actual impact crater measurement data and the Space Environment (SPENV) Program developed in-house at POD, to theoretical models established by Kessler (NASA TM-100471, 1987) and Cour-Palais (NASA SP-8013, 1969). With the continuing escalation of debris there will exist a definite hazard to unmanned satellites as well as manned operations. Since the smaller non-trackable debris has the highest impact rate, it is clearly necessary to establish the true debris environment for all particle sizes. Proper comprehension of the near-Earth space environment and its origin will permit improvement in spacecraft design and mission planning, thereby reducing potential disasters and extreme costs. Results of this study directly relate to the survivability of future spacecraft and satellites that are to travel through and/or reside in low Earth orbit (LEO). More specifically, these data are being used to: (1) characterize the effects of the LEO micrometeoroid an debris environment on satellite designs and components; (2) update the current theoretical micrometeoroid and debris models for LEO; (3) help assess the survivability of spacecraft and satellites that must travel through or reside in LEO, and the probability of their collision with already resident debris; and (4) help define and evaluate future debris mitigation and disposal methods. Combined model predictions match relatively well with the LDEF data for impact craters larger than approximately 0.05 cm, diameter; however, for smaller impact craters, the combined predictions diverge and do not reflect the sporadic clouds identified by the Interplanetary Dust Experiment (IDE) aboard LDEF. The divergences cannot currently be explained by the authors or model developers. The mean flux of small craters (approximately 0.05 cm diameter) is overpredicted by Kessler and underpredicted by Cour-Palais. This divergence may be a result of beta-meteoroid fluxes, elliptical orbits or a combination of the two. The results of this study illustrate the definite need for more intensive study of the near-Earth space environment, particularly the small particle regime, as it is the most degrading to spacecraft in LEO.

Atkinson, Dale R.↗
NASA NTRS1992

Endogenous production, exogenous delivery and impact-shock synthesis of organic molecules - An inventory for the origins of life

The contribution of organic-rich comets, carbonaceous asteroids, and interplanetary dust particles and of impact shock-synthesized organics in the atmosphere to the origin of life on earth is studied and quantitatively compared with the principal non-heavy-bombardment sources of prebiotic organics. The results suggest that heavy bombardment before 3.5 Gyr ago either produced or delivered quantities of organics comparable to those produced by other energy sources.

Chyba, Christopher↗
NASA NTRS1992

Solar Probe - System concepts and requirements

The design and related constraints relevant to the development of the Solar Probe are examined with reference to the environmental conditions and mission trajectory. The science-related requirements of the Solar Probe mission include instruments with 360-deg sweep on a platform that spins at 60 rpm and carries a magnetometer on a boom. The mission trajectory of a 4-solar-radii perihelion is designed to eliminate angular velocity about the sun, and the unusual requirements of dense interplanetary dust and enhanced gamma-ray radiation are mentioned. A list of specific functional requirements that directly affect the system configuration is given which includes those for the high-gain antenna and the main shield. These requirements are translated into a full-science-scope spacecraft design, and specific mass and power estimates are given. Reduced-scope and baseline configurations are also presented that allow good scientific return with significantly reduced development costs.

Gronroos, H. G.↗
NASA NTRS1992

Proceedings of Lunar and Planetary Science, Volume 22; Conference, Houston, TX, Mar. 18-22, 1991

Various papers on lunar and planetary science are presented. Individual topics addressed include: analysis of Phobos Mission Gamma ray spectra from Mars, comparison of volcanic and modified landforms from Tharsis Montes on Mars, polygenetic origin of Hrad Vallis region of Mars, new evidence of lacustrine basins on Mars, flood surge through the Lunae Planum Outflow Complex on Mars, interpretation of canyon materials and flood sources on Kasei Valles on Mars, geochemistry of Manson Impact structure rocks, micrometer-sized glass spheres in Apollo 16 soil 61181, isotopic abundances in Pesyanoe of solar-type xenon, mineralogy of 12 large 'chondritic' interplanetary dust particles. Also discussed are: trace elements in chondritic stratospheric particles, evolution of isotopic signatures in lunar regolith nitrogen, pyroclastic deposits on the western limb of the moon, origin of picritic green glass magmas by polybaric fractional fusion, origin of yellow glasses associated with Apollo 15 KREEP basalt fragments, trace elements in 59 mostly highland moon rocks, mineralization on the moon, relation between diogenite cumulates and eucrite magmas.

Ryder, Graham↗
NASA NTRS1992

Olivine in Antarctic micrometeorites - Comparison with other extraterrestrial olivine

The compositions of 5-micron or larger Mg-rich olivines from 26 Antarctic micrometeorite particles were examined and compared with those of other extraterrestrial olivine. The following differences were noted between the Antarctic meteorites and the generally recognized meteorite groups: (1) while refractory-rich (e.g., high Al2O3 or CaO) are common in C2, C3, and UOC meteorites, there are only rare, or possibly no refractory-rich olivines in Antarctic micrometeorites; (2) Mg-rich olivine compositions with FeO less than 1.9 wt pct are underrepresented in the Antarctic micrometeorites, relative to other unequilibrated meteorites; and (3) no Mn-rich, high-Mg olivines were found similar to those described in interplanetary dust, C1, C2, C3, and UOC meteorites.

Steele, Ian M.↗
NASA NTRS1992

Thin-sectioning and analysis of fine-grained meteoritic materials

The overall theme of the work was the identification of the sources and formation/aggregation mechanisms of the various classes of interplanetary dust particles (IDP's) and to clarify the relationship between IDP's and conventional meteorites. IDP's are believed to be derived from a much broader range of parent bodies than conventional meteorites. Some of these parent bodies (e.g., comets) have escaped that post accretional processing that has affected the parent bodies of meteorites. Therefore, IDP's are likely to preserve a record of early solar system and possibly presolar grain forming reactions. Using analytical electron microscopy (AEM) and more recently micro-infrared (IR) microspectroscopy to examine ultramicrotomed thin sections, we have addressed the questions of IDP formation mechanisms, sources, and their relationship to conventional meteorites. The following sections describe specific findings resulting from these studies.

Brooks, Donald A.↗
NASA NTRS1992

Organic material: Asteroids, meteorites, and planetary satellites

Telescopic observations in in situ spacecraft investigations over the last two decades have shown that many planetary satellites, asteroids, and comets have surfaces containing very dark material that is either neutral (black) or red in color. Although comets are not the focus of this paper, the possible relationship of comets to asteroids, meteorites, and interplanetary dust is briefly discussed in the context of their dark-matter component. The following topics are discussed with respect to their organic content: carbonaceous chondrites; asteroids; low-albedo planetary satellites; and Pluto, Charon, and Triton. Laboratory studies and a summary are also presented.

Cruikshank, Dale P.↗
NASA NTRS1992

Asteroids, Comets, Meteors 1991

Papers from the conference are presented and cover the following topics with respect to asteroids, comets, and/or meteors: interplanetary dust, cometary atmospheres, atmospheric composition, comet tails, astronomical photometry, chemical composition, meteoroid showers, cometary nuclei, orbital resonance, orbital mechanics, emission spectra, radio astronomy, astronomical spectroscopy, photodissociation, micrometeoroids, cosmochemistry, and interstellar chemistry.

Harris, Alan W.↗
NASA NTRS1992

A Southern Hemisphere radar meteor orbit survey

A meteor radar system has been operated on a routine basis near Christchurch, New Zealand, to determine the orbits of Earth-impacting interplanetary dust and meteoroids. The system sensitivity is +13 visual magnitude, corresponding to approximately 100 micron sized meteoroids. With an orbital precision of 2 degrees in angular elements and 10 percent in orbital energy (1/a), the operation yields an average of 1500 orbits daily with a total to date in excess of 10(exp 5). The use of pc's and automated data reduction permit the large orbital data sets we collect to be routinely reduced. Some illustrative examples are presented of the signal formats/processing and the results of data reduction, giving the individual orbital elements and hence the overall distributions. Current studies include the distribution of dust in the inner solar system; the influx of meteoroids associated with near-Earth asteroids; and the orbital structure existing in comet-produced streams.

Baggaley, W. Jack↗
NASA NTRS1992

The geocentric particulate distribution: Cometary, asteroidal, or space debris?

Definition of the Low Earth Orbit (LEO) particulate environment has been refined considerably with the analysis of data from NASA's Long Duration Exposure Facility (LDEF). Measurements of the impact rates from particulates ranging from sub-micron to millimetres in dimension and, especially, information on their directionality has permitted new scrunity of the sources of the particulates. Modelling of the dynamics of both bound (Earth orbital) and unbound (hyperbolic interplanetary) particulates intercepting LDEF's faces leads to the conclusion that the source is dominantly interplanetary for particle dimensions of greater than some 5 microns diameter; however the anisotropy below this dimension demands lower velocities and is compatible with an orbital component. Characteristics of the LDEF interplanetary component are compatible with familiar meteoroid sources and deep space measurements. Understanding of the orbital component which exceeds the interplanetary flux by a factor of 4 is less clear; although the very small particulates in orbit have been associated with space debris (Lawrance and Brownlee, 1986) this data conflicts with other measurements (McDonnell, Carey and Dixon, 1984) at the same epoch. By analysis of trajectories approaching the Earth and its atmosphere, we have shown that a significant contribution could be captured by aerocapture, i.e., atmospheric drag, from either asteroidal or cometary sources; such enhancement is unlikely however to provide the temporal and spatial fluctuations observed by the LDEF Interplanetary Dust Experiment (Mullholland et al. 1992). A further new mechanism is also examined, that of aerofragmentation capture, where an atmospheric grazing trajectory, which would not normally lead to capture, leads to fragmentation by thermal or mechanical shock; the microparticulates thus created can be injected in large numbers, but only into short-lifetime orbits. The concentration in one particular orbit plane, could explain the temporal fluctuations seen on LDEF; space debris could also explain the phenomenon.

Mcdonnell, J. A. M.↗
NASA NTRS1993

Inward electrostatic precipitation of interplanetary particles

An inward precipitator collects particles initially dispersed in a gas throughout either a cylindrical or spherical chamber onto a small central planchet. The instrument is effective for particle diameters greater than about 1 micron. One use is the collection of interplanetary dust particles (IDPs) which are stopped in a noble gas (xenon) by drag and ablation after perforating the wall of a thin-walled spacecraft-mounted chamber. First, the particles are positively charged for several seconds by the corona production of positive xenon ions from inward facing needles placed on the chamber wall. Then an electric field causes the particles to migrate toward the center of the instrument and onto the planchet. The collection time (on the order of hours for a 1 m radius spherical chamber) is greatly reduced by the use of optimally located screens which reapportion the electric field. Some of the electric field lines terminate on the wires of the screens so a fraction of the total number of particles in the chamber is lost. The operation of the instrument is demonstrated by experiments which show the migration of carbon soot particles with radius of approximately 1 micron in a 5 cm diameter cylindrical chamber with a single field enhancing screen toward a 3.2 mm central collection rod.

Rulison, Aaron J.↗