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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 505 records · Page 28

Computed Tomography by Combining Transmission and Scatter Radiography Methods

In 2015, approximately 13 billion tons of freight was transported in the US, roughly 40 tons per person. 40% of all freight on a ton-mile basis will be transported by railroads. Class I railroads have approximately 140,000 miles (224,000 km) of railroad track across the country. Approximately 3,200 crossties per mile secure the rails at the proper gauge, transmit loads to the ballast, and prevent lateral and longitudinal shifting. Wood crossties can fail in many ways including rotting, breaking, cracking, and splitting. Developing new technologies to inspect these crossties are necessary to help maintain and ensure safe railroad operations. The Georgetown Railroad Equipment Company partnered with the University of Florida to develop the Aurora Xi X-ray backscatter inspection system. This system generates 2D backscatter images at 25 mph to detect weakness in wood crossties long before the internal degradation is visible on the tie surface. The railroad industry has a need for a high-speed high resolution 3D inspection method to inspect approximately 20 million newly fabricated railroad crossties per year. Currently new ties are not radiographically inspected to reject internal flaws and verify that rot prevention treatments have adequately penetrated into the crosstie. Current spiral scan computed tomography (CT) systems are not designed for the 100 cm/s to 400 cm/s speed of a wood crosstie production line. Building on the technology developed for the 2D Aurora Xi system, a new 3D fan-beam inspection system and CT method is being developed. A previous scatter CT method by Arsenault and Hussein required moving the Xray source to many positions, averaging the X-ray spectra, and ignoring the Compton scatter change of energy. The proposed design and method combines transmission and scatter radiography in all directions without moving or rotating the X-ray sources or detectors. (authors)

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Stress Dependence of Ultrasonic Velocity in Unidirectional Graphite/Epoxy Composites for Longitudinal Waves Propagating Along the Direction of Stress

The first measurements of the stress induced velocity changes for propagation directions along the direction of applied stress in gr/ep composites have been presented. For propagation and stress direction perpendicular to the fiber direction, the data demonstrated a linear relation between normalized velocity shift and stress. After corrections for the delay line were made, the slope or SAC was determined and compared favorably with the expected value calculated from the previously determined nonlinear coefficients of this material. The ratio of the SAC to the elastic compliance for this direction of loading was evaluated and found to have a value similar to numerous other materials which have very different linear elastic properties. Measurements with stress and propagation along the fibers yielded unusual behavior. The curves were very nonlinear and even shifted direction at higher loads. The large scatter in the data due to bond variations made separation of material effects from bond induced artifacts impossible. Thus the SAC, R, and the remaining two unknown TOEC's could not be determined for this direction of propagation. These measurements further expand the basis of determining nonlinear elastic properties of composite materials. These properties may be useful in developing much needed NDE techniques to determine such important parameters as residual stress after cure and residual strength after impact damage. Additional study is needed to measure the nonlinear behavior in other composite materials including angle ply laminates. Also, other techniques to measure elastic nonlinearity such as harmonic generation should be applied to composites to improve the understanding of these properties and their importance.

Prosser, William H.↗

Storing Affordability: Battery Storage as an Asset to Reduce Data Center Cost Shifts

This report examines how battery energy storage systems (BESS) can help utilities accommodate large load growth while protecting affordability for existing ratepayers. Rapid growth in electricity demand from artificial intelligence (AI) data centers is straining the U.S. grid. Furthermore, many new data centers are entering rural markets, which could offer economic benefits but may also pose implementation challenges for smaller utilities. At the same time, retail electricity prices are increasing faster than inflation, elevating customer affordability as a key challenge. While data centers have not been the primary driver of increases in residential prices to date, they have pushed wholesale energy and capacity prices higher in several markets. Fundamental utility cost-allocation principles show that data center growth can be rate-positive for existing customers only if new peak demand grows faster than the costs a utility must incur to serve it. Several factors, including a utility’s degree of wholesale market exposure, forecast uncertainty and stranded-asset risk, and tariff design can determine the outcome of load growth on retail rates. Energy storage can make several affordability contributions in the face of this landscape of uncertainty and market volatility, including deferral of higher-cost grid investments through improved utilization of existing assets and flexibility of new large loads, insulation from volatile wholesale prices through peak shaving, and reliability support to address grid risks stemming from the behavior of AI data center loads. Different potential BESS deployment pathways—utility-scale front-of-the-meter systems, aggregated small-scale storage installations, and data center-sited behind-the-meter storage—are compared against each other and against conventional capacity alternatives. This framework is intended as a conceptual resource to utilities, particularly smaller public utilities with rural service territories, who may be considering the role that energy storage can play in insulating existing ratepayers from data center cost shifts.

25 ENERGY STORAGE↗

Peak Reduction Using Mode Adjustment of Heat Pump Water Heaters in a Residential Neighborhood

Building electrification is putting pressure on distribution grid worldwide. Peak reduction is an important concern that can help reduce the growing stress and allow to defer investments in new capacity. Water heaters represent a convenient way of reducing peak because they are less dependent on weather, and their storage volume allows for asynchronous water heating and hot water use. Previous empirical studies investigated the ability of water heaters to reduce peak through the adjustment of the temperature setpoint. However, not all equipment vendors offer this option. This study aims at understanding the feasibility of peak reduction with an alternative configuration available in the market - by adjusting the device mode rather than temperature setpoint. The peak reduction methodology is tested in an occupied 46-townhome neighborhood located in Atlanta, GA. We find that peak shifting is possible with the adjustable mode approach, with the change in the peak load by 30-60%.

demand response↗

Design Considerations of a Coordinative Demand Charge Mitigation Strategy

This paper presents a coordinative demand charge mitigation (DCM) strategy for reducing electricity consumption during system peak periods. Available DCM resources include batteries, diesel generators, controllable loads, and conservation voltage reduction. All resources are directly controlled by load serving entities. A mixed integer linear programming based energy management algorithm is developed to optimally coordinate of DCM resources considering the load payback effect. To better capture system peak periods, two different kinds of load forecast are used: the day-ahead load forecast and the peak-hour probability forecast. Five DCM strategies are compared for reconciling the discrepancy between the two forecasting results. The DCM strategies are tested using actual utility data. Simulation results show that the proposed algorithm can effectively mitigate the demand charge while preventing the system peak from being shifted to the payback hours. We also identify the diminishing return effect, which can help load serving entities optimize the size of their DCM resources.

Hu, Rongxing↗

Synthesis and characterization of polyethylene/oxidized polyethylene miscible blends and role of OPE as a viscosity control

Polymer blending allows for new materials to be designed with unique properties. Here, blends of linear low density polyethylene (PE) and oxidized polyethylene (OPE) have been prepared. PE/OPE blends are characterized for their molten state properties by thermal analysis and rheology; the solid state properties are studied by scattering, diffraction, and tensile testing. Melt miscibility was confirmed by a negative Flory-Huggins interaction parameter (χ ~ -2.3) from Hoffman-Weeks plots. Additionally, a continuous decrease in melting temperature (from 123 to 119 °C) and thermal stability of blends (25% weight loss from 454 to 416 °C) was observed with increasing OPE loading from 0 to 50 wt %. Time-temperature master curves revealed the shifting of the glassy region to higher frequencies and formation of relaxed polymer chains in the glassy region. A plasticization effect was observed with zero shear viscosity of the blends decreasing with increasing OPE loading. In the end, a decrease in lamellar thickness of PE (from 180 to 140 Å) with increasing OPE resulted in increasing the blends' brittleness.

42 ENGINEERING↗

Location and chemical speciation of Cu in ZSM-5 during the water-gas shift reaction

Here, Cu/ZSM-5 catalysts were found to exhibit activity for the water-gas shift (WGS) reaction at temperatures over 300 °C. Nominal Cu loadings of 1, 5, and 10% on ZSM-5 were synthesized using the wetness impregnation technique and evaluated for WGS activity; with a clear trend favoring increased Cu loading (10% > 5% > 1%). X-ray diffraction (XRD) confirmed high dispersion of small Cu at low loadings while CuO crystallized at higher loadings. In-situ XRD showed an evolving transformation of CuO → Cu metal, with the appearance of a metallic copper phase at the optimum reaction conditions, particularly at the highest copper loading. In-situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) revealed the ability of the surface to activate H2O and adsorb CO, by the presence of HO-Al/Si and transient CO-Cu + surface species in two distinct locations (5 membered rings (2157 cm –1 ) vs channel intersections (2138 cm –1 ) within the ZSM-5 framework, that likely formed during the CuO → Cu transition. The lowest loaded Cu-ZSM-5 (1%) showed only the 5 membered ring occupied Cu + while the higher loadings showed both, with comparable temperature dependent behavior for the channel intersection Cu + . The amounts of Cu + species in each location were observed to be dependent on temperature while the 5-membered ring showed better thermal stability. In-situ ambient-pressure X-ray photoelectron spectroscopy (AP-XPS) was used to further confirm the gradual changes to the chemical state of copper (CuO → Cu 2 O → Cu) under reaction conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Nonsteady Load Responses to Mountain-Generated Turbulence Eddies on the DOE 1.5 MW Wind Turbine at the National Wind Technology Center

Field data collected from the NREL/GE 1.5MW wind turbine and met tower at the NREL Wind Technology Center near Boulder, Colorado from June-October 2018 were analyzed to quantify the impacts of turbulence eddies on the load responses measured from sensors on the main shaft, blade and tower. The passage of individual mountain-generated eddies from the met tower to the wind turbine were critically determined by correlating the optimal time shifts in signal between met tower and nacelle anemometers with mean advection time. Loading responses from mountain eddy passage were compared with atmospheric eddies from the north/south, unimpeded by the mountains, and found to be similar. Whereas time variations in torque were highly correlated with time changes in horizontal eddy velocity, the out-of-plane bending moments on the main shaft (directly forcing the main bearing) were uncorrelated with horizontal eddy velocity. This result is consistent with a previous LES study indicating that the main bearing is forced by asymmetrical interactions between the rotor and turbulence eddies, while power fluctuations respond primarily to advective eddy velocity. Surprisingly, the nacelle anemometer produced statistics very similar to the met tower.

ENGINEERING,WIND ENERGY↗

EV Hosting Capacity Analysis on Distribution Grids: Preprint

Increasing electric vehicle (EV) charging loads can increase the magnitude and duration of conventional peaks in demand profiles and even shift them significantly, causing operational violations in the distribution grid. It is important to develop tools to quantify the impacts of injecting large number of EV charging loads and determine the available capacity of the existing distribution feeder for the safe operation of the grid. Such tools would enable utilities to better prepare for grid operations in the near future while exploring the impact and effectiveness of strategies such as peak pricing and smart charging in managing these loads. This paper evaluates the hosting capacity of some real-world feeders to accommodate EV charging loads, including extreme fast-charging (xFC) options.

47 OTHER INSTRUMENTATION↗

The Demand-Side Grid (dsgrid) Model Documentation

Electrical load is the backdrop for all power systems analysis. As a coequal partner in the supply-demand balance that must be maintained on electrical grids at all times and for all timescales, load is a major source of variability and uncertainty in grid operations. Despite this, utility load forecasting is typically done in a top-down manner that lacks the granularity in time, geography, end use, and technology that is needed to explore the potential impact of technological shifts; and many studies of future grid systems employ relatively simple scaling of historical loads, placing more emphasis on supply-side resources such as generation and transmission that are fewer in number and are better understood in terms of cost and performance. The primary purpose of the demand-side grid model (dsgrid) is to fill these gaps by creating comprehensive load data sets at a sufficient temporal, geographic, sectoral, and end-use resolution to enable detailed analyses of current patterns and future projections of end-use load. Furthermore, the dsgrid platform uses a bottom-up methodology that allows highly resolved analysis of 'what-if' scenarios. dsgrid leverages detailed sectoral energy models to provide hourly time series of load by subsector, end use, and county covering a full year. Although dsgrid currently emphasizes electricity load data, its component sector models for residential buildings, commercial buildings, and industry provide information on other fuel use, including natural gas. The data sets can thus be leveraged to support analysis of numerous demand-side technology-driven changes, such as energy efficiency, electrification, and operational flexibility (i.e., demand response). The electricity use data are time-synchronized with solar and wind data sets so as to be suitable for use in power systems analysis. This report documents dsgrid and its initial data set, which covers electricity demand in the contiguous United States for the historical year of 2012. We start with a historical year to enable model calibration and validation, as well as the development of a mathematical description of our model residuals that can be applied to future-year 'what-if' scenarios to remove known errors between our bottom-up modeling and historical load shapes. This work is part of the Electrification Futures Study (EFS), for which the dsgrid team will be developing future load snapshots that describe projected year 2050 under baseline and a range of electrification assumptions.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Measurement of operator workload in an information processing task

This was an experimental study to develop an improved methodology for measuring workload in an information processing task and to assess the effects of shift length and communication density (rate of information flow) on the ability to process and classify verbal messages. Each of twelve subjects was exposed to combinations of three shift lengths and two communication densities in a counterbalanced, repeated measurements experimental design. Results indicated no systematic variation in task performance measures or in other dependent measures as a function of shift length or communication density. This is attributed to the absence of a secondary loading task, an insufficiently taxing work schedule, and the lack of psychological stress. Subjective magnitude estimates of workload showed fatigue (and to a lesser degree, tension) to be a power function of shift length. Estimates of task difficulty and fatigue were initially lower but increased more sharply over time under low density than under high density conditions. An interpretation of findings and recommedations for furture research are included. This research has major implications to human workload problems in information processing of air traffic control verbal data.

Jenney, L. L.↗

2.1.2.403 - Fatigue and Structural Load Analysis and Control for Variable-Geometry Wave Energy Converters (VGWECs)

The VGWEC project will generate and disseminate the foundational knowledge enabling a paradigm shift in the design of wave energy converters (WECs) by adding a geometry control option on top of power-take-off load control. The variable-geometry modules (VGMs) provide control over a WEC's hydrodynamics that can emphasize power absorption or load shedding. Additional load shedding provided by the VGMs is expected to reduce the device structural mass and extend the sea state operating envelope, by limiting peak loading, both contributing towards reducing levelized cost of energy (LCOE) estimates.

hydrodynamic↗

Examining the Reactions of Ethanolamine’s Thermal Degradation Compounds in Carbon Capture through 1 H NMR and 13 C NMR

In amine scrubbing carbon capture, concerns about amine solvent degradation include whether it can affect the ability of the solvent to capture CO 2 . This study examines the interactions between the three most reported monoethanolamine (MEA) thermal degradation compounds namely, oxazolidine-2-one (OZD), N-(2-hydroxyethyl)-ethylenediamine (HEEDA), and N-(2- hydroxyethyl)-imidazoline-2-one (HEIA) with CO 2 in the presence and absence of MEA. We compared 1 H NMR, 13 C NMR, and heteronuclear single-quantum coherence (HSQC) NMR for neat OZD, HEEDA, and HEIA samples with CO 2 -loaded samples to observe changes in protonation and unique carbamate species formation. We found that OZD and HEIA did not directly react with CO 2 or undergo proton shifting based on our comparison of the neat OZD and HEIA samples with CO 2 -loaded spectra. However, we observed that the OZD can protonate when sparged with CO 2 in the presence of MEA, which suggests that the OZD acts as an intermediate. The NMR spectra for HEEDA indicated that HEEDA directly reacts with CO 2 at both amino groups and can protonate. In the presence of MEA, HEEDA and MEA can act like a solvent blend, resulting in multiple carbamates forming within the solvent. The neat HEIA spectrum, compared with CO 2 -loaded HEIA spectra, revealed similar results as OZD, where it does not react with CO 2 or protonate directly. However, HEIA does not protonate in the presence of MEA. These degradation compound reactions can increase the number of general equilibrium reactions during carbon capture and impact the model MEA solvent. This work helps provide a more complete picture of the reactions as the solvent degrades. Although this study examines CO 2 effects on thermal degradation products for MEA, other amines such as piperazine or 1- amino-3-propanol will degrade, and the degradation may speciate similarly with CO 2 . Furthermore, this study can impact and improve process models by assessing the degradation compounds’ reactions with CO 2 and potentially incorporating them into the model based on a neat solvent.

20 FOSSIL-FUELED POWER PLANTS↗

Some Effects of Horizontal-Tail Position on the Vertical-Tail Pressure Distributions of a Complete Model in Sideslip at High Subsonic Speeds

An investigation has been made in the Langley high-speed 7- by 10-foot tunnel of some effects of horizontal-tail position on the vertical-tail pressure distributions of a complete model in sideslip at high subsonic speeds. The wing of the model was swept back 28.82 deg at the quarter-chord line and had an aspect ratio of 3.50, a taper ratio of 0.067, and NACA 65A004 airfoil sections parallel to the model plane of symmetry. Tests were made with the horizontal tail off, on the wing-chord plane extended, and in T-tail arrangements in forward and rearward locations. The test Mach numbers ranged from 0.60 to 0.92, which corresponds to a Reynolds number range from approximately 2.93 x 10(exp 6) to 3.69 x 10(exp 6), based on the wing mean aerodynamic chord. The sideslip angles varied from -3.9 deg to 12.7 deg at several selected angles of attack. The results indicated that, for a given angle of sideslip, increases in angle of attack caused reductions in the vertical-tail loads in the vicinity of the root chord and increases at the midspan and tip locations, with rearward movements in the local chordwise centers of pressure for the midspan locations and forward movements near the tip of the vertical tail. At the higher angles of attack all configurations investigated experienced outboard and rearward shifts in the center of pressure of the total vertical-tail load. Location of the horizontal tail on the wing- chord plane extended produced only small effects on the vertical-tail loads and centers of pressure. Locating the horizontal tail at the tip of the vertical tail in the forward position caused increases in the vertical-tail loads; this configuration, however, experienced considerable reduction in loads with increasing Mach number. Location of the horizontal tail at the tip of the vertical tail in the rearward position produced the largest increases in vertical-tail loads per degree sideslip angle; this configuration experienced the smallest variations of loads with Mach number of any of the configurations investigated.

Alford, William J., Jr.↗

Effects of Aging-Time Reference on the Long Term Behavior of the IM7/K3B Composite

An analytical study was undertaken to investigate the effects of the time-based shift reference on the long term behavior of the graphite reinforced thermoplastic polyimide composite IM7/K3B at elevated temperature. Creep compliance and the effects of physical aging on the time dependent response was measured for uniaxial loading at several isothermal conditions below the glass transition temperature (T(sub g). Two matrix dominated loading modes, shear and transverse, were investigated in tension and compression. The momentary sequenced creep/aging curves were collapsed through a horizontal (time) shift using the shortest, middle and longest aging time curve as the reference curve. Linear viscoelasticity was used to characterize the creep/recovery behavior and superposition techniques were used to establish the physical aging related material constants. The use of effective time expressions in a laminated plate model allowed for the prediction of long term creep compliance. The effect of using different reference curves with time/aging-time superposition was most sensitive to the physical aging shift rate at lower test temperatures. Depending on the loading mode, the reference curve used can result in a more accurate long term prediction, especially at lower test temperatures.

Veazie, David R.↗

Ultrasonic study of adhesive bond quality at a steel-to-rubber interface by using quadrature phase detection techniques

The quadrature phase detection technique was used to simultaneously monitor the phase and amplitude of a toneburst signal normally reflected from an adhesively bonded steel-to-rubber interface. The measured phase was found to show a positive shift for all bonded samples with respect to the disbonded state - the phase shift being larger for samples with weaker bonds, as manifested by smaller values of applied tensile loads at failure. A model calculation, which incorporates the concept of interfacial strength into the usual problem of wave propagation in multilayered media, was used to deduce a bond-quality parameter from an experimentally measured phase shift. This bond-quality parameter was found to be correlated with the tensile strength of the adhesive bonds at failure loads.

Smith, A. C.↗

Caution on Using Tetrahydrofuran for Processing Crystalline Silica Samples From Engineered Stone for XRD Analysis

Abstract We conducted laboratory experiments to investigate a suspected effect of tetrahydrofuran (THF) on quantifying crystalline silica in samples collected from working with engineered stone when THF is used to process samples prior to the X-ray diffraction (XRD) analysis. Two groups of samples from grinding either engineered stone or granite were simultaneously taken from a laboratory testing system, with one group of samples using THF for processing and another group using muffle furnace for ashing. For each stone type, we also tested four levels of respirable dust loading on the samples by varying the grinding time from 1 to 8 min. Statistical analysis of the experimental results on crystalline silica contents of the two groups of samples showed that the difference between the two methods was not significant (P ≥ 0.05) for the granite at all four levels of respirable dust loading and for the engineered stone at the two levels of respirable dust loading greater than 0.5 mg. However, the crystalline silica content from using THF processing was significantly lower (P = 0.001) than that from using muffle furnace ashing for engineered stone when the respirable dust loading levels were less than 0.5 mg. For the engineered stone dust samples with grinding times of 1 and 2 min, the average respirable dust loading was about 0.19 and 0.34 mg, respectively; while the crystalline silica content from using THF processing was 30.9 and 21.5% lower than that from using muffle furnace ashing, respectively. Since most full-shift samples from field assessments in this industry are expected to have respirable dust loading less than 0.5 mg, muffle furnace or radio frequency plasma ashing should be specified as the preferred sample processing method instead of the THF processing method for quantification of crystalline silica when engineered stone is expected to present to avoid artificially reduced silica content values, which are likely caused by the reactions between THF and the resins in engineered stone.

Public, Environmental & Occupational Health↗

Solar plus: A review of the end-user economics of solar PV integration with storage and load control in residential buildings

Batteries and load control devices can increase the value of distributed solar photovoltaics (PV) from multiple perspectives - end-user, utility, and social. This review paper summarizes the end-user economics of battery and load control technologies that increase the value of PV by controlling and temporally shifting PV output, an approach referred to as 'solar plus.' Solar plus can increase on-site PV use. The literature shows that these values justify the incremental costs of solar plus devices for a wide variety of technologies, geographies, and customer load profiles, especially for customers in three rate structure contexts: where PV is sold to the grid at a lower value than the customer's retail rate, in time-of-use rates where peak periods do not coincide with PV output, and in demand charge rates where load peaks do not coincide with PV output. Rate structure and policy reform may be necessary to ensure that increasing solar plus deployment provides both end-user and system-level benefits.

14 SOLAR ENERGY↗