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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 505 records · Page 28
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Mesocrystallizing Nanograins for Enhanced Li + Storage

Morphology and crystallinity of electrode materials have a major effect on their charge carrier storage properties when applied in rechargeable batteries. While nanosizing electrode particles (with larger surface area) and maintaining electrode integrity are both good for performance enhancement, they seem to contradict each other and can be hardly well-balanced. Herein, we designed electrode particles consisting of numerous nanograins with uniform crystalline orientation to guarantee both high surface area and high structural integrity, allowing the significant improvement of Li + storage kinetics and performance. Applying this “mesocrystallizing” strategy to a NiCo 2 O 4 -based anode, resulting in various degrees of pseudocapacitance response, the long-term cyclability and rate performance of this material have been largely enhanced. Impressively, the mesocrystalline NiCo 2 O 4 electrode exhibits a high reversible capacity of 1403 mAh g -1 after 200 cycles at 1.6 A g -1 (a rate of 1.8 C). The growth mechanism of mesocrystalline materials with different morphologies is identified to be a topotactic strctural transition process featuring a gradual edge-to-core corrasion process. This work presents an important synthetic clue to balance the morpholgy and crystallinity of battery electrode materials for their perforamnce optimization and is expected to inspire future structural design for battery materials beyond the one prototyped here.

25 ENERGY STORAGE↗
NASA NTRS1986

Representation of the vaporization behavior of turbulent polydisperse sprays by equivalent monodisperse sprays

The concept of using an equivalent monodisperse spray to represent the vaporization behavior of polydisperse sprays has been examined by numerically solving two turbulent vaporizing sprays. One involves the injection of Freon-11 in a still environment, whereas the other is a methanol spray in a still but hot environment. The use of three different mean sizes, namely, Sauter mean diameter, volume median diameter, and surface-area mean diameter, has been investigated. Results indicate a good degree of correlation between the polydisperse spray and its equivalent monodisperse sprays represented by the volume median diameter and the Sauter mean diameter, the former giving slightly better results. The surface-area mean diameter does not provide as good a correlation as the other two mean diameters.

Aggarwal, S. K.↗
NASA NTRS1987

Representation of the vaporization behavior of turbulent polydisperse sprays by 'equivalent' monodisperse sprays

The concept of using an equivalent monodisperse spray to represent the vaporization behavior of polydisperse sprays has been examined by numerically solving two turbulent vaporizing sprays. One involves the injection of Freon-11 in a still environment, whereas the other is a methanol spray in a still but hot environment. The use of three different mean sizes, namely, Sauter mean diameter, volume median diameter, and surface-area mean diameter, has been investigated. Results indicate a good degree of correlation between the polydisperse spray and its equivalent monodisperse sprays represented by the volume median diameter and the Sauter mean diameter, the former giving slightly better results. The surface-area mean diameter does not provide as good a correlation as the other two mean diameters.

Aggarwal, S. K.↗
NASA NTRS1993

Evapotranspiration and runoff from large land areas: Land surface hydrology for atmospheric general circulation models

A land surface hydrology parameterization for use in atmospheric GCM's is presented. The parameterization incorporates subgrid scale variability in topography, soils, soil moisture and precipitation. The framework of the model is the statistical distribution of a topography-soils index, which controls the local water balance fluxes, and is therefore taken to represent the large land area. Spatially variable water balance fluxes are integrated with respect to the topography-soils index to yield our large topography-soils distribution, and interval responses are weighted by the probability of occurrence of the interval. Grid square averaged land surface fluxes result. The model functions independently as a macroscale water balance model. Runoff ratio and evapotranspiration efficiency parameterizations are derived and are shown to depend on the spatial variability of the above mentioned properties and processes, as well as the dynamics of land surface-atmosphere interactions.

Famiglietti, J. S.↗
DOE OSTI2021

Impact of sodium vanadium oxide (NaV 3 O 8 , NVO) material synthesis conditions on charge storage mechanism in Zn-ion aqueous batteries

The electrochemical charge storage of sodium vanadate (NaV 3 O 8 or NVO) cathodes in aqueous Zn-ion batteries has been hypothesized to be influenced by the inclusion of structural water for facilitating ion transfer in the material. Materials properties considered important (morphology, crystallite and particle size, surface area) are systematically studied herein through investigation of two NVO materials, NaV 3 O 8 ·0.34H 2 O [NVO(300)] and NaV 3 O 8 ·0.05H 2 O [NVO(500)], with different water content, acicular morphologies with different size and surface area achieved via post-synthesis heat treatment. The electrochemistry of the two materials was evaluated in aqueous Zn-ion cells with 2 M ZnSO 4 electrolyte using cyclic voltammetry, galvanostatic cycling, and rate capability testing. Furthermore, the thinner NVO(300) nanobelts (0.13 μm) demonstrate greater specific capacities and higher effective diffusion coefficients relative to the thicker NVO(500) nanorods. Notably however, while cells containing NVO(500) deliver lower specific capacity, they demonstrate enhanced capacity retention with cycling. The structural changes accompanying oxidation and reduction are elucidated via ex situ X-ray diffraction, transmission electron microscopy, and operando V K-edge X-ray absorption spectroscopy (XAS), where NVO material properties are shown to influence the ion insertion. Operando XAS verified that electron transfer corresponds directly to change in vanadium oxidation state, affirming vanadium redox as the governing electrochemical process.

25 ENERGY STORAGE↗
DOE OSTI2025

Editorial: Functionalization of porous materials for sustainable energy applications

Global energy demands are shifting toward a more sustainable future, with the goal of achieving carbon neutrality by 2050. Emerging technologies are driving this transition. The industry, academia, government, non-profit organizations, and the broader community are collaboratively working to reduce greenhouse gas (GHG) emissions and address climate change to ensure a sustainable future. According to the International Energy Agency, in 2022, the production, transportation, and processing of oil and gas resulted in 5.1 billion tons of CO 2 -equivalent emissions, representing nearly 15% of all energy-related GHG emissions. Moreover, the end-use of oil and gas accounted for an additional 40% of emissions. The IEA’s Net Zero Emissions by 2050 Scenario calls for immediate, collective action from the industry, transportation and other stakeholders to mitigate these emissions. In this effort, the development of energy materials will play a critical role in reducing emissions. Among these, porous materials offer an innovative solution, leveraging their high surface area, adjustable pore sizes, and chemical versatility to address these pressing challenges effectively. By carefully designing their nanostructures, the architecture and properties of these materials can be tailored for specific applications. Key factors such as chemical composition, particle size, pore distribution, and surface area optimization enhance the reactivity and energy conversion efficiency. Additionally, pre- and post-functionalization processes can introduce targeted chemical properties, further improving their performance. This Research Topic explores recent advancements in energy and materials science through four scholarly papers, showcasing innovative solutions for sustainable energy technologies while providing valuable insights into the unique properties and structure of porous materials (Figure 1). Li et al. present their work on highly defective NiFeV layered triple hydroxides, highlighting enhanced electrocatalytic activity and stability for oxygen evolution reactions (OER). Kovalskii et al. contribute a mini-review on hydrogen storage using hexagonal boron nitride (h-BN) and BN-based materials, offering an insightful overview of these promising materials. Chava et al. discuss their recent achievements in ceramic electrolytes used for improvement of performance of solid-state batteries. Lastly, Li et al. review the properties of porous materials with a focus on shrinkage behavior during the drying process, shedding light on key considerations for material design.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Effect of cell compression on the performance and the structure of proton exchange membrane water electrolyzer (PEMWE) assembly

Here, in the field of water electrolysis, the proton exchange membrane water electrolyzer (PEMWE) is currently the most advanced technology for producing hydrogen without emitting CO 2 . Although PEMWE plants are already in operation, further research is needed to improve cell efficiency and reduce the use of rare materials, such as iridium oxide catalysts for the oxygen evolution reaction (OER). One of the main causes of performance loss in PEMWE is the relatively low electric conductivity of the porous transport layer (PTL) and of the anode catalyst layer, which results in ohmic losses and low catalyst utilization during high current density operation. The objective of this study is to investigate how optimization of the PTL and electrode interface can increase the cell performance. To this end, we tested different cell assemblies using fibrous and sintered PTLs, decreasing membrane thickness, reducing iridium loading, and inserting a microporous layer to increase contact surface area. Electrochemical characterization of each cell configuration was systematically performed at various compression levels as the pressure is a crucial parameter influencing the electrode/PTL contact area. In parallel, X-ray microcomputed tomography (micro-CT) was employed to investigate the effects of cell hydration and compression on the structure of PEMWE components. This study combining electrochemistry and micro-CT imaging presents how optimizing the electrode/PTL contact surface area, minimizes ohmic losses, and enables PEMWE operation with low iridium loading at high current densities.

Catalyst - PTL interface↗
NASA NTRS1991

Meteoroid and orbital debris record of the Long Duration Exposure Facility

The Long Duration Exposure Facility (LDEF) was recovered in January 1990 following 5.7 years exposure of approx. 130 square meters of surface area in low-Earth orbit (250-179 miles). Kennedy Space Center acquired data are currently being reduced to yield accurate impact crater depths and diameters. Presented here is a preliminary accounting of the impact record based on the approx. 15.4 square meter surface area of LDEF's 6061-T6 aluminum frame, which was exposed in 26 different directions.

Zolensky, Mike↗
NASA NTRS1991

Monolith catalysts for closed-cycle carbon dioxide lasers

The objective was to explore ways of making a monolithic form of catalyst for CO2 lasers. The approach chosen was to pelletize the catalyst material, Au/MnO2 powder, and epoxy the pellets to stainless steel sheets as structural supports. The CO oxidation reaction over Au/MnO2 powder was found to be first overall, and the reaction rate constant at room temperature was 4.4 +/- 0.3 cc/(g x sec). The activation energy was 5.7 kcal/mol. The BET surface area of the pellets was found to vary from 125 to 140 sq m/g between different batches of catalyst. Pellets epoxied to stainless steel strips showed no sign of fracture or dusting when subjected to thermal tests. Pellets can be dropped onto hard surfaces with chipping of edges but no breakage of the pellets. Mechanical strength tests performed on the pellets showed that the crush strength is roughly one-fourth of the pelletizing force. The apparent activity and activation energy over the pellets were found to be less than over the powdered form of the catalyst. The lower apparent activity and activation energy of the pellets are due to the fact that the internal surface area of a pellet is not exposed to the reactant concentration present in the flowing gas as a result of intrapellet diffusion resistance. Effectiveness factors varied from 0.44, for pellets having thickness of 2 mm and attached with epoxy to a stainless steel strip. The epoxy and the stainless steel strip were found to simply block off one of the circular faces of the pellets. The epoxy did not penetrate the pellets and block the active sites. The values of the effective diffusivities were estimated to be between 2.3 x 10(exp -3) and 4.9 x 10(exp -3) sq cm/s. With measurements performed on one powder sample and one pellet configuration, reasonable accurate predictions can be made of conversions that would be obtained with other pellet thickness and configurations.

Herz, Richard K.↗
NASA NTRS1957

Bodies of Revolution Having Minimum Drag at High Supersonic Airspeeds

Approximate shapes of nonlifting bodies having minimum pressure foredrag at high supersonic airspeeds are calculated. With the aid of Newton's law of resistance, the investigation is carried out for various combinations of the conditions of given body length, base diameter, surface area, and volume. In general, it is found that when body length is fixed, the body has a blunt nose; whereas, when the length is not fixed, the body has a sharp nose. The additional effect of curvature of the flow over the surface is investigated to determine its influence on the shapes for minimum drag. The effect is to increase the bluntness of the shapes in the region of the nose and the curvature in the region downstream of the nose. These shape modifications have, according to calculation, only a slight tendency to reduce drag. Several bodies of revolution of fineness ratios 3 and 5, including the calculated shapes of minimum drag for given length and base diameter and for given base diameter and surface area, were tested at Mach numbers from 2.73 to 6.28. A comparison of theoretical and experimental foredrag coefficients indicates that the calculated minimum-drag bodies are reasonable approximations to the correct shape.

Eggers, A J , Jr↗
NASA NTRS1995

KAO observations of SN1987A

Explosion calculations of SN1987A generate pictures of Rayleigh-Taylor fingers of radioactive Ni-56 (Ni-56 yields Co-56 yields Fe-56) which are boosted to velocities of several thousand km/s. From the KAO observations of the mid-IR iron lines, a picture of the iron in the ejecta emerges which is consistent with the 'frothy iron fingers' having expanded to fill about 50% of the metal-rich volume of the ejecta (nu(sub m) less than or equal to 2500 km/s). The ratio of the nickel line intensities I(sub (Ni I)7.5 micron)/I(sub (Ni II)6.6 microns) yields a high ionization fraction of x(sub Ni) greater than or equal to 0.9 in the volume associated with the iron-group elements at day 415, before dust condenses in the ejecta. From the KAO observations of the dust's thermal emission (2 microns to 100 microns), it is deduced that when the grains condense, their infrared radiation is trapped, their apparent opacity is gray, and they have a surface area filling factor of about 50%. The dust emission from SN1987A is featureless: no 9.7 micron silicate feature, nor PAH features, nor dust emission features of any kind are seen at any time. The total dust opacity increases with time even though the surface area filling factor and the dust/gas ratio remain constant. This suggests that the dust forms along coherent structures which can maintain their radial line-of-sight opacities, i.e., along fat fingers. The coincidence of the filling factor of the dust and the filling factor of the iron strongly suggests that the dust condenses within the iron, and therefore the dust is iron-rich. It only takes approximately 10(exp -4) solar mass of dust for the ejecta to be optically thick out to approximately 100 microns; a lower limit of 4 x 10(exp -4) solar mass of condensed grains exists in the metal-rich volume, but much more dust could be present. The episode of dust formation started at about 539 days and proceeded rapidly, so that by 600 days 45% of the bolometric luminosity was being emitted in the IR; by 775 days, 86% of the bolometric luminosity was being reradiated by the dust. Measurements of the bolometric luminosity of SN1987A from 1000 to 2300 days are based on 10 micron and 20 micron photometry and rely on the suppositions that the IR emission is a graybody (proven to be true by the KAO observations at 615 and 775 days) and that the dust temperature drops to and remainsat 150 K. The late-time bolometric luminosity is stronger than that expected from the radioactive decay of Co-56, Co-57, Ti-44, and Na-22 and the late-time dust temperatures are consistent with the presence of a compact object.

Wooden, Diane H.↗
NASA NTRS1994

Explosion Calculations of SN1087

Explosion calculations of SNT1987A generate pictures of Rayleigh-Taylor fingers of radioactive Ni-56 which are boosted to velocities of several thousand km/s. From the KAO observations of the mid-IR iron lines, a picture of the iron in the ejecta emerges which is consistent with the "frothy iron fingers" having expanded to fill about 50% of the metal-rich volume of the ejecta. The ratio of the nickel line intensities yields a high ionization fraction of greater than or equal to 0.9 in the volume associated with the iron-group elements at day 415, before dust condenses in the ejecta. From the KAO observations of the dust's thermal emission, it is deduced that when the grains condense their infrared radiation is trapped, their apparent opacity is gray, and they have a surface area filling factor of about 50%. The dust emission from SN1987A is featureless: no 9.7 micrometer silicate feature, nor PAH features, nor dust emission features of any kind are seen at any time. The total dust opacity increases with time even though the surface area filling factor and the dust/gas ratio remain constant. This suggests that the dust forms along coherent structures which can maintain their radial line-of-sight opacities, i.e., along fat fingers. The coincidence of the filling factor of the dust and the filling factor of the iron strongly suggests that the dust condenses within the iron, and therefore the dust is iron-rich. It only takes approximately 4 x 10(exp -4) solar mass of dust for the ejecta to be optically thick out to approximately 100 micrometers; a lower limit of 4 x 10(exp -4) solar mass of condensed grains exists in the metal-rich volume, but much more dust could be present. The episode of dust formation started at about 530 days and proceeded rapidly, so that by 600 days 45% of the bolometric luminosity was being emitted in the IR; by 775 days, 86% of the bolometric luminosity was being reradiated by the dust. Measurements of the bolometric luminosity of SN1987A from 1000 - 1800 days are based on 10 micrometers and 20 micrometers photometry and rely on the suppositions that the IR emission is a greybody (proven to be true by the KAO observations at 615 and 775 days) and that the dust temperature drops to and remains at 150 K. The late time bolometric luminosity is stronger than that expected from the radioactive decay of Co-56, Co-57, Ti-44, and Na-22 and the possibility of an embedded compact object will be discussed.

Wooden, Diane H.↗
DOE OSTI2019

Assessing XMT-Measurement Variability of Air-Water Interfacial Areas in Natural Porous Media

This study investigates the accuracy and reproducibility of air-water interfacial areas measured with high-resolution synchrotron X-ray microtomography (XMT). Columns packed with one of two relatively coarse-grained monodisperse granular media, glass beads or a well-sorted quartz sand, were imaged over several years, encompassing changes in acquisition equipment, improved image quality, and enhancements to image acquisition and to processing software. For the glass beads, the specific solid surface area (SSSA-XMT) of 31.6 ± 1 cm -1 determined from direct analysis of the segmented solid-phase image data is statistically identical to the independently calculated geometric smooth-sphere specific solid surface area (GSSA, 32 ± 1 cm -1 ) and to the measured SSSA (28 ± 3 cm -1 ) obtained with the N2-Brunauer, Emmett, and Teller method. The maximum specific air-water interfacial area (Amax) is 27.4 (±2) cm -1 , which compares very well to the SSSA-XMT, GSSA, and SSSA-N2-Brunauer, Emmett, and Teller values. For the sand, the SSSA-XMT (111 ± 2 cm -1 ) and GSSA (113 ± 1 cm -1 ) are similar. The mean Amax is 96 ± 5 cm -1 , which compares well to both the SSSA and the GSSA values. The XMT-SSSA values deviated from the GSSA values by 7–16% for the first four experiments but were essentially identical for the later experiments. This indicates that enhancements in image acquisition and processing improved data accuracy. The Amax values ranged from 74 cm -1 to 101 cm -1 , with a coefficient of variation (COV) of 9%. The maximum capillary interfacial area ranged from 12 cm-1 to 19 cm -1 , for a COV of 10%. The COVs for both decreased to 5–6% for the latter five experiments. These results demonstrate that XMT imaging provides accurate and reproducible measurements of total and capillary interfacial areas.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

The diversity of aluminum-based drinking water treatment residuals for use in environmental remediation

Drinking water treatment residuals (DWTRs) are complex mixtures of organic and inorganic phases generally disposed of as waste materials. However, their strong sorptive properties could be further exploited to immobilize contaminants. To characterize these materials, we applied a range of analytical techniques to a set of aluminum-based DWTRs. Here we determined surface areas, elemental compositions using CHNS analysis and X-ray fluorescence (XRF), performed thermogravimetric analyses paired with mass spectrometry (TGA-MS), and used synchrotron-based methods: X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS). Elemental analyses and specific surface area measurements – that vary between 7.23 ± 0.03 and 197.6 ± 0.9 m 2 g –1 – indicate that non-coagulant additives must play an important role in controlling sorption. High resolution powder XRD reveals the presence of only a few crystalline minerals mostly derived from source waters or additives. Fe was detected by XRF in all samples, whereas Mn was present in significant levels in samples with potassium permanganate as additive. The chemical speciation of these elements was characterized by performing spectral decompositions of XAS spectra. The spectral features of Fe are consistent with iron(III) oxides/hydroxides and structural iron in clays. On the other hand, Mn is predominantly present under its reduced form, Mn(II).

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1987

Oxygen electrodes for rechargeable alkaline fuel cells

Electrocatalysts and supports for the positive electrode of moderate temperature single unit rechargeable alkaline fuel cells were investigated and developed. The electrocatalysts are defined as the material with a higher activity for the oxygen electrode reaction than the support. Advanced development will require that the materials be prepared in high surface area forms, and may also entail integration of various candidate materials. Eight candidate support materials and seven electrocatalysts were investigated. Of the 8 support, 3 materials meet the preliminary requirements in terms of electrical conductivity and stability. Emphasis is now on preparing in high surface area form and testing under more severe corrosion stress conditions. Of the 7 electrocatalysts prepared and evaluated, at least 5 materials remain as potential candidates. The major emphasis remains on preparation, physical characterization and electrochemical performance testing.

Swette, Larry↗
NASA NTRS1985

Changes in the distribution of plastids and endoplasmic reticulum during cellular differentiation in root caps of Zea mays

In calyptrogen cells of Zea mays, proplastids are distributed randomly throughout the cell, and the endoplasmic reticulum (ER) is distributed parallel to the cell walls. The differentiation of calyptrogen cells into columella statocytes is characterized by the following sequential events: (1) formation of ER complexes at the distal and proximal ends of the cell, (2) differentiation of proplastids into amyloplasts, (3) sedimentation of amyloplasts onto the distal ER complex, (4) breakdown of the distal ER complex and sedimentation of amyloplasts to the bottom of the cell, and (5) formation of sheets of ER parallel to the longitudinal cell walls. Columella statocytes located in the centre of the cap each possess 4530 +/- 780 micrometers2 of ER surface area, an increase of 670 per cent over that of calyptrogen cells. The differentiation of peripheral cells correlates positively with (1) the ER becoming arranged in concentric sheets, (2) amyloplasts and ER becoming randomly distributed, and (3) a 280 per cent increase in ER surface area over that of columella statocytes. These results are discussed relative to graviperception and mucilage secretion, which are functions of columella and peripheral cells, respectively.

NASA Discipline Number 40-10↗
NASA NTRS2016

Modeling the Exo-Brake and the Development of Strategies for De-Orbit Drag Modulation

The Exo-Brake is a simple, non-propulsive means of de-orbiting small payloads from orbital platforms such as the International Space Station (ISS). Two de-orbiting experiments with fixed surface area Exo-Brakes have been successfully conducted in the last two years on the TechEdSat-3 and -4 nano-satellite missions. The development of the free molecular flow aerodynamic data-base is presented in terms of angle of attack, projected front surface area variation, and altitude. Altitudes are considered ranging from the 400km ISS jettison altitude to 90km. Trajectory tools are then used to predict de-orbit/entry corridors with the inclusion of the key atmospheric and geomagnetic uncertainties. Control system strategies are discussed which will be applied to the next two planned TechEdSat-5 and -6 nano-satellite missions - thus increasing the targeting accuracy at the Von Karman altitude through the proposed drag modulation technique.

Exo-Brake↗