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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 505 records · Page 28
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Comparison of the Core-collapse Evolution of Two Nearly Equal-mass Progenitors

Abstract We compare the core-collapse evolution of a pair of 15.8 M ☉ stars with significantly different internal structures, a consequence of the bimodal variability exhibited by massive stars during their late evolutionary stages. The 15.78 and 15.79 M ☉ progenitors have core masses (masses interior to an entropy of 4 k B baryon −1 ) of 1.47 and 1.78 M ☉ and compactness parameters ξ 1.75 of 0.302 and 0.604, respectively. The core-collapse simulations are carried out in 2D to nearly 3 s postbounce and show substantial differences in the times of shock revival and explosion energies. The 15.78 M ☉ model begins exploding promptly at 120 ms postbounce when a strong density decrement at the Si–Si/O shell interface, not present in the 15.79 M ☉ progenitor, encounters the stalled shock. The 15.79 M ☉ model takes 100 ms longer to explode but ultimately produces a more powerful explosion. Both the larger mass accretion rate and the more massive core of the 15.79 M ☉ model during the first 0.8 s postbounce time result in larger ν e / ν ¯ e luminosities and RMS energies along with a flatter and higher-density heating region. The more-energetic explosion of the 15.79 M ☉ model resulted in the ejection of twice as much 56 Ni. Most of the ejecta in both models are moderately proton rich, though counterintuitively the highest electron fraction ( Y e = 0.61) ejecta in either model are in the less-energetic 15.78 M ☉ model, while the lowest electron fraction ( Y e = 0.45) ejecta in either model are in the 15.79 M ☉ model.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

The Kangaroo’s First Hop: The Early Fast Cooling Phase of EP250108a/SN 2025kg

Fast X-ray transients are a rare and poorly understood population of events. Previously difficult to detect in real time, the launch of the Einstein Probe with its Wide-field X-ray Telescope has led to a rapid expansionof the sample and allowed the exploration of these transients across the electromagnetic spectrum. EP250108a is a recently detected example linked to an optical counterpart, SN 2025kg, or “the kangaroo.” Together with a companion Letter we present our observing campaign and analysis of this event. In this letter, we focus on the early evolution of the optical counterpart over the first 6 days, including our measurement of the redshift of z = 0.17641. We compare to other supernovae and fast transients showing similar features, finding significant similarities with SN 2006aj and SN 2020bvc, and show that the source is well modelled by a rapidly expanding cooling blackbody. We show the observed X-ray and radio properties are consistent with a collapsar-powered jet that is low energy (≲10 51 erg) and/or fails to break out of the dense material surrounding it. While we examine the possibility that the optical emission emerges from the shock produced as the supernova ejecta expand into a dense shell of circumstellar material, due to our X-ray and radio inferences, we favour a model where it arises from a shocked cocoon resulting from a trapped jet. This makes SN 2025 one of the few examples of this currently observationally rare event.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRSDate not supplied

Supervised Autonomous Assembly to Create and Evolve Persistent Assets

Supervised autonomous assembly (SAA) will create a paradigm shift in the planning and design of future persistent assets (PAs), both in near zero-g environments and on planetary surfaces. SAA refers to an autonomy approach that has the benefits of autonomous assembly as well as the benefits provided by a supervisor (operator) who is available to resolve unexpected situations. SAA provides both increased design freedom as well as reduced programmatic risk. SAA enables evolution of future PAs over decades as in-space operations transition from single purpose missions to creation of PAs, such as laboratories and experimental stations which more closely resembling terrestrial laboratories that can easily adapt and evolve to new missions leveraging repeated visits to the PA. The ability to evolve enables PAs to rapidly respond to changing objectives resulting from new questions as our understanding improves. A recently initiated National Aeronautics and Space Administration (NASA) project in the Space Technology Mission Directorate (STMD) Game Changing Development (GCD) Program called the Precision Assembled Space Structure (PASS), leverages the advantages of SAA to develop technologies that enable efficient creation and evolution of hexagonal topologies; both planar (example: fuel depots) and curved (examples: telescopes and shelters). PASS will be used to provide context for the philosophy and concepts discussed as well as the decision and selections made. PASS objectives are: a) Develop confidence in SAA and on-orbit servicing, assembly and manufacturing (OSAM) technologies by executing a test campaign that uses a path-to-flight autonomous precision assembly process directly applicable to future space telescopes. b) Test autonomous technologies including automated path planning and error recovery, to emphasize a robust approach that relies on generic robots and special purpose tools. c) Validate critical component models using a digital twin that includes the assembled primary mirror support structure and assembly process. A digital twin is a high-fidelity simulation of the asset capable of predicting the on-orbit performance. The paper concludes after identifying the critical need for a modest assembly flight experiment to validate and develop confidence in the SAA paradigm, thus accelerating adoption of the benefits described. SAA is a game changing paradigm that enhances the ability of an organization to infuse new technology through rapid evolution of PAs while leveraging OSAM technologies.

Structural Modeling↗
DOE OSTI2021

Impact of Dark Photon Emission on Massive Star Evolution and Pre-supernova Neutrino Signal

Abstract We study the effects of additional cooling due to the emission of a dark matter candidate particle, the dark photon, on the final phases of the evolution of a 15 M ⊙ star and resulting modifications of the pre-supernova neutrino signal. For a substantial portion of the dark photon parameter space the extra cooling speeds up Si burning, which results in a reduced number of neutrinos emitted during the last day before core collapse. This reduction can be described by a systematic acceleration of the relevant timescales and the results can be estimated semi-analytically in good agreement with the numerical simulations. Outside the semi-analytic regime we find more complicated effects. In a narrow parameter range, low-mass dark photons lead to an increase in the number of emitted neutrinos because of additional shell-burning episodes that delay core collapse. Furthermore, relatively strong couplings produce a thermonuclear runaway during O burning, which could result in a complete disruption of the star but requires more detailed simulations to determine the outcome. Our results show that pre-supernova neutrino signals are a potential probe of the dark photon parameter space.

Astronomy & Astrophysics↗
NASA NTRS2022

Geodetic Investigations of the Mission Concept MAGIC to Reveal Callisto’s Internal Structure

Geodetic and geophysical investigations of the Galilean moon Callisto address fundamental questions regarding the formation and evolution of the Jovian system. Callisto's evolution and internal structure appear to significantly differ from the other Jovian satellites. Similarly-sized Ganymede is a highly evolved ice-rock moon with a differentiated interior, intrinsic magnetic field, and abundant surface evidence of internal activity. In contrast, Callisto's surface is ancient, and Galileo spacecraft data suggest its interior is only incompletely differentiated, despite the presumed presence of a sub-surface ocean. These properties make Callisto uniquely able to constrain the timing and nature of the Jovian system formation. The Magnetics, Altimetry, Gravity, and Imaging of Callisto (MAGIC) mission concept is conceived to fully characterize the properties of this enigmatic moon from its deep interior to the icy shell. Three main instruments are included as a scientific payload. Highly accurate measurements of Callisto's topography, magnetic field, and morphology are obtained by the onboard laser altimeter, magnetometer, and camera, respectively. The telecommunication system supports an additional gravity and radio science investigation. Long- and short-wavelength gravity anomalies afford powerful constraints on internal differentiation and the properties of the hydrosphere (water and ice). Comprehensive numerical simulations and covariance analyses of MAGIC mission scenarios presented in this paper show that the gravitational degree-2 normalized coefficients and the pole obliquity enable the determination of the moment of inertia with an accuracy better than 0.015%. The combination of gravity and altimetry measurements acquired by MAGIC are essential to the characterization of Callisto's interior if – as is likely – the degree-2 gravity includes non-hydrostatic terms. MAGIC's radio science data yield the estimation of Callisto's gravity field with spatial resolutions of <100 km. The combination of gravitational and deformation tides that are retrieved by the radio science and altimetry investigations, respectively, leads to the recovery of the rigid ice shell thickness to within ∼3 km. Together these datasets would resolve ambiguities inherent in Galileo flyby data, revealing Callisto's interior structure as well as the existence and properties of its postulated internal ocean.

Antonio Genova↗
NASA NTRS2001

Flash Mixing on the White-Dwarf Cooling Curve: Understanding Hot Horizontal Branch Anomalies in NGC 2808

We present an ultraviolet color-magnitude diagram (CMD) spanning the hot horizontal branch (HB), blue straggler, and white dwarf populations of the globular cluster NGC 2808. These data, obtained with the Space Telescope Imaging Spectrograph (STIS), demonstrate that NGC 2808 harbors a significant population of hot subluminous HB stars, an anomaly only previously reported for the globular cluster omega Cen. Our theoretical modeling indicates that the location of these subluminous stars in the CMD, as well as the high temperature gap along the HB of NGC 2808, can be explained if these stars underwent a late helium-core flash while descending the white dwarf cooling curve. We show that the convective zone produced by such a late helium flash will penetrate into the hydrogen envelope, thereby mixing hydrogen into the hot helium-burning interior, where it is rapidly consumed. This phenomenon is analogous to the "born again" scenario for producing hydrogen-deficient stars following a late helium-shell flash. The flash mixing of the envelope greatly enhances the envelope helium and carbon abundances that, in turn, leads to a discontinuous increase in the HB effective temperatures. We argue that the hot HB gap is associated with this theoretically predicted dichotomy in the HB properties. Moreover, the changes in the emergent spectral energy distribution caused by these abundance changes are primarily responsible for explaining the hot subluminous HB stars. Although further evidence is needed to confirm that a late helium-core flash can account for the subluminous HB stars and the hot HB gap, we demonstrate that an understanding of these stars requires the use of appropriate theoretical models for their evolution, atmospheres, and spectra.

Brown, Thomas M.↗
NASA NTRS1993

Dynamical instability as the cause of the massive outbursts in Eta Carinae and other luminous blue variables

A new type of stellar envelope structure has been computationally discovered at very high stellar masses. The outer part of the envelope resembles a nearly detached, diffusely filled shell overlying an ultrahot surface of small radius. This structural anomaly is caused by a large iron bump occurring in the new opacities of Iglesias et al. (1992). The new stellar models with normal metallicity encounter a strong ionization-induced dynamical instability in the outer envelope as they rapidly transit the H-R diagram after the end of central hydrogen burning. Preliminary evolutionary and hydrodynamical calculations successfully mimic the most basic observed properties of Eta Carinae and other very luminous blue variables. The Humphreys-Davidson sloped line in the H-R diagram, however, seems to be unrelated to these variables, and is instead the observed terminus of the main-sequence phase of evolution if convective core overshooting is insignificant.

Stothers, Richard B.↗
NASA NTRS2001

Rheology of Diabase: Implications for Tectonics on Venus and Mars

Two important goals of our experimental investigation of the rheological behavior of diabase rocks were: (1) to determine flow laws describing their creep behavior over wide ranges of temperature, stress and strain rate and (2) to develop an understanding of the physical mechanisms by which these rocks flow under laboratory conditions. With this basis, a primary objective then was to construct constitutive equations that can be used to extrapolate from laboratory to planetary conditions. We specifically studied the rheological properties of both natural rock samples and synthetic aggregates. The former provided constraints for geologic systems, while the latter defined the relative contributions of the constituent mineral phases and avoided the influence of glass/melt found in natural samples. In addition, partially molten samples of crustal rock composition were deformed in shear to large strains (greater than 200%) important in crustal environments. The results of this research yielded essential rheological properties essential for models of crustal deformation on terrestrial planets, specifically Venus and Mars, as well as on the geodynamical evolution of these planets. Over the past three years, we also completed our investigation of the creep behavior of water ice with applications to the glaciers, ice sheets and icy satellites. Constitutive equations were determined that describe flow over a wide ranged of stress, strain rate, grain size and temperature. In the case of ice, three creep regimes were delineate. Extrapolation demonstrates that dislocation glide and grain boundary sliding processes dominate flow in ice I under planetary conditions and that diffusion creep is not an important deformation mechanism either in the laboratory or on icy satellites. These results have already been incorporated by other investigators into models describing, for example, the thickness and stability of the ice shell on Europa and to unravel long-standing discrepancies between field observations on glaciers and laboratory results.

Kohlstedt, David L.↗
NASA NTRS2014

NuSTAR Study of Hard X-ray Morphology and Spectroscopy G21.5-0.9

We present NuSTAR high-energy X-ray observations of the pulsar wind nebula (PWN)/supernova remnant G21.5−0.9. We detect integrated emission from the nebula up to approx. 40 keV, and resolve individual spatial features over a broad X-ray band for the first time. The morphology seen by NuSTAR agrees well with that seen by XMM-Newton and Chandra below 10 keV. At high energies, NuSTAR clearly detects non-thermal emission up to approx. 20 keV that extends along the eastern and northern rim of the supernova shell. The broadband images clearly demonstrate that X-ray emission from the North Spur and Eastern Limb results predominantly from non-thermal processes. We detect a break in the spatially integrated X-ray spectrum at approx. 9 keV that cannot be reproduced by current spectral energy distribution models, implying either a more complex electron injection spectrum or an additional process such as diffusion compared to what has been considered in previous work. We use spatially resolved maps to derive an energy-dependent cooling length scale, E(sup m) is directly proportional to L(E) with m = −0.21 plus or minus 0.01. We find this to be inconsistent with the model for the morphological evolution with energy described by Kennel & Coroniti. This value, along with the observed steepening in power-law index between radio and X-ray, can be quantitatively explained as an energy-loss spectral break in the simple scaling model of Reynolds, assuming particle advection dominates over diffusion. This interpretation requires a substantial departure from spherical magnetohydrodynamic, magnetic-flux-conserving outflow, most plausibly in the form of turbulent magnetic-field amplification.

radiation mechanisms↗
DOE OSTI2023

Effect of surface defects on damage and failure of dynamically driven cylindrical shells

Here, in this work, expanding cylinder experiments are performed using a gas gun on the aluminum 6061 alloy to understand the dynamic deformation and failure behavior of this material in the presence of surface defects in the form of scratches. The experiments are then modeled with the modified Tepla (for tensile plasticity) model, which is equipped with the damage yield function of Gurson [“Continuum theory of ductile rupture by void nucleation and growth: Part I—Yield criteria and flow rules for porous ductile media,” (1977)] and Tvergaard and Needleman [Acta Metall. 32(1), 157–169 (1984)], over-stress viscosity [F. Addessio and J. Johnson, J. Appl. Phys. 74(3), 1640–1648 (1993)], and the underlying viscoplastic model of Preston et al. [J. Appl. Phys. 93(1), 211–220 (2003)] (Preston–Tonks–Wallace model) for the dense material. The Tepla model parameters were calibrated using the Bayesian approach against experimentally measured free-surface velocity data obtained from plate impact experiments on the aluminum 6061 alloy. The evolution of radial expansion and shapes of the deformed cylinder from the simulations on a pristine cylinder wall and a cylinder wall with a longitudinal surface defect shows excellent agreement with the corresponding experimental results. Finally, the role of surface defect size and cylinder wall geometry on the dynamic strength of the cylinder wall was also investigated through a series of simulations.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2023

Energetic Electron Precipitation Driven by Electromagnetic Ion Cyclotron Waves from ELFIN’s Low Altitude Perspective

We review comprehensive observations of electromagnetic ion cyclotron (EMIC) wave-driven energetic electron precipitation using data collected by the energetic electron detector on the Electron Losses and Fields InvestigatioN (ELFIN) mission, two polar-orbiting low-altitude spinning CubeSats, measuring 50-5000 keV electrons with good pitch-angle and energy resolution. EMIC wave-driven precipitation exhibits a distinct signature in energy-spectrograms of the precipitating-to-trapped flux ratio: peaks at >0.5 MeV which are abrupt (bursty) (lasting ~17 s, or ΔL ~ 0.56) with significant substructure (occasionally down to sub-second timescale). We attribute the bursty nature of the precipitation to the spatial extent and structuredness of the wave field at the equator. Multiple ELFIN passes over the same MLT sector allow us to study the spatial and temporal evolution of the EMIC wave - electron interaction region. Case studies employing conjugate ground-based or equatorial observations of the EMIC waves reveal that the energy of moderate and strong precipitation at ELFIN approximately agrees with theoretical expectations for cyclotron resonant interactions in a cold plasma. Using multiple years of ELFIN data uniformly distributed in local time, we assemble a statistical database of ~50 events of strong EMIC wave-driven precipitation. Most reside at L ~ 5 – 7 at dusk, while a smaller subset exists at L ~ 8 – 12 at post-midnight. The energies of the peak-precipitation ratio and of the half-peak precipitation ratio (our proxy for the minimum resonance energy) exhibit an L-shell dependence in good agreement with theoretical estimates based on prior statistical observations of EMIC wave power spectra. The precipitation ratio’s spectral shape for the most intense events has an exponential falloff away from the peak (i.e., on either side of ~ 1.45 MeV). It too agrees well with quasi-linear diffusion theory based on prior statistics of wave spectra. It should be noted though that this diffusive treatment likely includes effects from nonlinear resonant interactions (especially at high energies) and nonresonant effects from sharp wave packet edges (at low energies). Sub-MeV electron precipitation observed concurrently with strong EMIC wave-driven >1 MeV precipitation has a spectral shape that is consistent with efficient pitch-angle scattering down to ~ 200-300 keV by much less intense higher frequency EMIC waves at dusk (where such waves are most frequent). At ~100 keV, whistler-mode chorus may be implicated in concurrent precipitation. These results confirm the critical role of EMIC waves in driving relativistic electron losses. Nonlinear effects may abound and require further investigation.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

Total absorption spectroscopy for the 𝛽 + decay strength distribution of 60 Ga

𝛽-decay properties play an important role in most astrophysical processes. In the absence of experimental data, astrophysical models rely on global theoretical calculations to provide the relevant properties. It is therefore important to provide strong experimental constraints when possible. In the case of 𝛽-decay, the most sensitive probe is the 𝛽-decay strength distribution. We report here on the first measurement of the latter quantity for the 𝛽 + decay of 60 Ga using the total absorption spectroscopy technique. The experimental results are compared to theoretical calculations often used in astrophysical models, namely the shell model and the quasiparticle random phase approximation (QRPA), as well as an extension of QRPA that includes higher-order nucleonic calculations. Both models are in reasonable agreement with the experimental results.

59 ≤ A ≤ 89↗
DOE OSTI2024

Structure and dynamics of magneto-inertial, differentially rotating laboratory plasmas

We present a detailed characterization of the structure and evolution of differentially rotating plasmas driven on the MAGPIE pulsed-power generator (1.4 MA peak current, 240 ns rise time). The experiments were designed to simulate physics relevant to accretion discs and jets on laboratory scales. A cylindrical aluminium wire array Z pinch enclosed by return posts with an overall azimuthal off-set angle was driven to produce ablation plasma flows that propagate inwards in a slightly off-radial trajectory, injecting mass, angular momentum and confining ram pressure to a rotating plasma column on the axis. However, the plasma is free to expand axially, forming a collimated, differentially rotating axial jet that propagates at ${\approx }100\,{\rm km}\,{\rm s}^{-1}$ . The density profile of the jet corresponds to a dense shell surrounding a low-density core, which is consistent with the centrifugal barrier effect being sustained along the jet's propagation. We show analytically that, as the rotating plasma accretes mass, conservation of mass and momentum implies plasma radial growth scaling as $r \propto t^{1/3}$ . As the characteristic moment of inertia increases, the rotation velocity is predicted to decrease and settle on a characteristic value ${\approx }20\,{\rm km}\,{\rm s}^{-1}$ . We find that both predictions are in agreement with Thomson scattering and optical self-emission imaging measurements.

Valenzuela-Villaseca, V. (ORCID:0000000167721441)↗
DOE OSTI2026

A stress-based fracture model for reacting metal ejecta

The evolution of reacting metal ejecta continues to be a topic of interest at the forefront of metals in reactive and extreme environments. Ejecta are small particles formed when the surface of a metal undergoes Richtmyer–Meshkov instability from a strong shock. Experiments have shown that in the case where ejecta are in ambient conditions that induce a reaction, the ejecta behave irregularly. The ejecta temperature rises and then plateaus, and the acceleration profile shows unexpected jumps. These variations are assumed to be related to the exothermic heat release and particle mass loss caused by the reaction. To explain this phenomenon, efforts to model this in simulations have increased. While current models can capture many of these physical processes, they currently assign a constant reaction shell thickness with little physical reasoning. This work remedies this problem by assigning a dynamic physically informed shell thickness to the reacting particles, using solid analysis. The shell thickness of the particles impacts the rate of change of reacted mass in the system, as well as the rate at which the particles react. The model is based on a simple stress–strain relationship and gives a dynamic assignment for when the reacting particle should begin to fracture. We compare our model to the previous computational and simulation data to analyze the effects of different model parameters.

42 ENGINEERING↗
NASA NTRS1991

Adaptive control with an expert system based supervisory level

Adaptive control is presently one of the methods available which may be used to control plants with poorly modelled dynamics or time varying dynamics. Although many variations of adaptive controllers exist, a common characteristic of all adaptive control schemes, is that input/output measurements from the plant are used to adjust a control law in an on-line fashion. Ideally the adjustment mechanism of the adaptive controller is able to learn enough about the dynamics of the plant from input/output measurements to effectively control the plant. In practice, problems such as measurement noise, controller saturation, and incorrect model order, to name a few, may prevent proper adjustment of the controller and poor performance or instability result. In this work we set out to avoid the inadequacies of procedurally implemented safety nets, by introducing a two level control scheme in which an expert system based 'supervisor' at the upper level provides all the safety net functions for an adaptive controller at the lower level. The expert system is based on a shell called IPEX, (Interactive Process EXpert), that we developed specifically for the diagnosis and treatment of dynamic systems. Some of the more important functions that the IPEX system provides are: (1) temporal reasoning; (2) planning of diagnostic activities; and (3) interactive diagnosis. Also, because knowledge and control logic are separate, the incorporation of new diagnostic and treatment knowledge is relatively simple. We note that the flexibility available in the system to express diagnostic and treatment knowledge, allows much greater functionality than could ever be reasonably expected from procedural implementations of safety nets. The remainder of this chapter is divided into three sections. In section 1.1 we give a detailed review of the literature in the area of supervisory systems for adaptive controllers. In particular, we describe the evolution of safety nets from simple ad hoc techniques, up to the use of expert systems for more advanced supervision capabilities.

Sullivan, Gerald A.↗
NASA NTRSDate not supplied

High EneRgy Observatory for Imaging X-rays (HEROIX) Mission Concept

The High EneRgy Observatory for Imaging X-rays (HEROIX) is a next-generation broadband X-ray space telescope concept under development as a Medium-Class Explorer mission. Building on more than three decades of replicated NiCo shell technology at NASA’s Marshall Space Flight Center, HEROIX will deliver 5 arcsecond half-power-diameter imaging resolution in the hard X-ray band. The observatory will incorporate four co-aligned telescopes with advanced multilayer coatings, extending the bandpass into the hard X-ray regime and providing an integrated effective area of 380 cm² at 30 keV. A suite of focal plane detectors will enable imaging capability throughout its 1–80 keV bandpass. This combination of angular resolution and high-energy coverage will open new windows into non-thermal processes in extreme astrophysical environments. HEROIXwill deliver transformative science, advancing the astrophysics community’s understanding of supernova physics, the X-ray binary population of the Galactic Center, accretion-driven galaxy evolution, and the origin of the Cosmic X-ray Background.

Nick Thomas↗
DOE OSTI2023

Mechanistic Insights on Permeation of Water over Iron Cations in Nanoporous Silicon Oxide Films for Selective H 2 and O 2 Evolution

Electrocatalysts encapsulated by an ultrathin and semipermeable oxide layer offer a promising avenue for efficient, selective, and cost-effective production of hydrogen through photoelectrochemical water splitting. This architecture is especially attractive for Z-scheme water splitting, for which a nanoporous oxide film can be leveraged to mitigate undesired, yet kinetically facile, reactions involving redox shuttles, such as aqueous iron cations, by limiting transport of these species to catalytically active sites. In this work, molecular dynamics simulations were combined with electrochemical measurements to provide a mechanistic understanding of permeation of water and Fe(III)/Fe(II) redox shuttles through nanoporous SiO 2 films. It is shown that even for SiO 2 pores with a width as small as 0.8 nm, water does not experience any energy barrier for permeating into the pores due to a favorable interaction with hydrophilic silanol groups on the oxide surface. In contrast, permeation of Fe(III) and Fe(II) into microporous SiO 2 pores is limited due to high energy barriers, which stem from a combination of distortion and dehydration of the second and third ion solvation shells. Furthermore, our simulations and experimental results show that SiO 2 coatings can effectively mitigate undesired Fe(III)/Fe(II) redox reactions at underlying electrodes by attenuating permeation of iron cations, while allowing water to permeate and thus participate in water splitting reactions. In a broader context, our study demonstrates that selectivity of solvated cations can be manipulated by controlling the pore size and surface chemistry of oxide films.

14 SOLAR ENERGY↗