Solar abundance determination from ultraviolet emission lines.
Relative solar abundance for O, Si and Fe determined from intensities of far UV emission lines of solar corona
SPECTRAL LINE↗
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Mapping soil types from multispectral scanner data.
Multispectral remote sensing and computer-implemented pattern recognition techniques were used for automatic ?mapping' of soil types. This approach involves subjective selection of a set of reference samples from a gray-level display of spectral variations which was generated by a computer. Each resolution element is then classified using a maximum likelihood ratio. Output is a computer printout on which the researcher assigns a different symbol to each class. Four soil test areas in Indiana were experimentally examined using this approach, and partially successful results were obtained.
Kristof, S. J.↗
The lithium-like spectra of K XVII through Mn XXIII in the extreme-ultraviolet region.
Identifications and classifications of spectral lines in the lithium-like spectra of the elements K through Mn is presented for the first time. The extrapolation procedures used to calculate these spectra are presented in detail. The excellent agreement between the predicted and measured lines establish the long-range extrapolation.
Goldsmith, S.↗
Helium abundance of the sun.
Critical review of the four methods that have been used to estimate the ratio of helium to hydrogen in the sun - the solar neutrino flux, spectral intensity of helium lines in prominences and the chromosphere, elemental abundance of solar cosmic rays, and variations of solar wind He/H. At present the measured value for the neutrino flux cannot be explained by any of the theoretical models of the sun, and thus the neutrino measurements cannot yield an estimate of He/H. Helium line intensity measurements give the most accurate values for He/H now available - i.e., 5 to 8% helium by number. However, these results refer to the chromosphere and prominences only, and questions of spatial and temporal variations of the observed quantities and of the inferred helium abundances have not yet been dealt with adequately.
Hirshberg, J.↗
Major and trace element concentrations in samples from 72275 and 72255
Analytical data have been obtained for Co, Sc, Hf, Zn, Cr, Ga, Rb, Cs, Ni, major elements, and rare earth elements in eight samples from boulder 1. The data for trace elements were obtained by radiochemical neutron activation analysis. Major elements, except Na and Mn, were obtained by atomic absorption spectral photometry. Values for Na and Mn were obtained by neutron activation analysis of the same powder that was later dissolved to provide the atomic absorption analyses.
Haskin, L. A.↗
Thermal IR imaging system using a self-scanned HgCdTe/CCD detector array
It is likely that future high resolution earth observation imaging systems will utilize self-scanned IR detectors. In an initial step toward this goal, an IR imaging system operating in the 10 to 12 micron spectral region has been developed. This system uses a 9-element HgCdTe/CCD linear array operating in the photoconductive mode, nine pre-amplifiers and a silicon CCD multiplexer integrated into a focal plane assembly. Opto-mechanical techniques are used to scan the scene and images are produced in real time. The imaging performance of this system is described and measurements of noise, responsivity, specific detectivity, and detector sensitivity profiles are presented. The requirements for more advanced detector arrays for use in future NASA remote sensing missions are also discussed.
Husain-Abidi, A. S.↗
A VLA radio-continuum survey of a sample of confirmed and marginal barium stars
Results are reported from a 6-cm VLA survey of five confirmed Ba II stars and eight mild Ba II stars, undertaken to search for evidence of gyrosynchrotron emission or thermal emission from the primary star's wind that is enhanced or photoionized by a white dwarf companion. Of these 13 stars, only Beta UMi was detected as a possible radio source at a flux level of 0.11 mJy (3sigma). The 6-cm radio luminosities (L6) of the other stars are as small as log L6 less than or equal to 14.0 and are an order of magnitude or more lower than the average levels found in RS CVn systems, but are consistent with the L6 upper limits previously found for stars of spectral type similar to the Ba II stars and normal elemental abundances. The upper limit to the radio luminosity for the possible mild Ba II star 56 Peg, when combined with its previously known X-ray luminosity, may provide useful constraints on the various models that have been proposed for this interesting object, once its orbital period is known.
Drake, Stephen A.↗
Effect of process conditions and chemical composition on the microstructure and properties of chemically vapor deposited SiC, Si, ZnSe, ZnS and ZnS(x)Se(1-x)
Subatmospheric pressure CVD processes have been developed to produce theoretically dense, highly pure, void-free and large area bulk materials, SiC, Si, ZnSe, ZnS and ZnS(x)Se(1-x). These materials are used for optical elements, such as mirrors, lenses and windows, over a wide spectral range from the VUV to the IR. We discuss the effect of CVD process conditions on the microstructure and properties of these materials, with emphasis on optical performance. In addition, we discuss the effect of chemical composition on the properties of the composite material ZnS(x)Se(1-x). We first present a general overview of the bulk CVD process and the relationship between process conditions, such as temperature, pressure, reactant gas concentration and growth rate, and the microstructure, morphology and properties of CVD-grown materials. Then we discuss specific results for CVD-grown SiC, Si, ZnSe, ZnS and ZnS(x)Se(1-x).
Pickering, Michael A.↗
Semi-volatiles at Mercury: Sodium (Na) and potassium (K)
Several lines of evidence now suggest that Mercury is a planet rich in moderately-volatile elements such as Na and K. Recent mid-infrared spectral observations of Mercury's equatorial and mid-latitude region near 120 degrees mercurian longitude indicate the presence of plagioclase feldspar. Spectra of Mercury's surface exhibit spectral activity similar to labradorite (plagioclase feldspar with NaAlSi3O8: 30-50 percent) and bytownite (NaAlSi3O8: 10-30 percent). These surface studies were stimulated by the relatively large abundance of Na and K observed in Mercury's atmosphere. An enhanced column of K is observed at the longitudes of Caloris Basin and of the antipodal terrain. Extreme heating at these 'hot' longitudes and severe fracturing suffered from the large impact event could lead to enhanced outgassing from surface or subsurface materials. Alternatively, sputtering from a surface enriched in K could be the source of the observed enhancement. Recent microwave measurements of Mercury also give indirect evidence of a mercurian regolith less FeO-rich than the Moon. An anomalously high index of refraction derived from the whole-disk integrated phase curve of Danjon may also be indicative of surface sulfides contributing to a regolith that is moderately volatile-rich. The recent exciting observations of radar-bright spots at high latitudes also indicate that a substance of high volume scattering, like ice, is present in shadowed regions. Other radar-bright spots have been seen at locations of Na enhancements on the atmosphere. All combined, these pieces of evidence point to a planet that is not severely depleted in volatiles or semi-volatiles.
Sprague, A.↗
Exobiology opportunities from Discovery-class missions
Discovery-class missions that are now planned, and those in the concept stage, have the potential to expand our knowledge of the origins and evolution of biogenic compounds, and ultimately, of the origins of life in the solar system. This class of missions, recently developed within NASA's Solar System Exploration Program, is designed to meet important scientific objectives within stringent guidelines--$150 million cap on development cost and a 3-year cap on the development schedule. The Discovery Program will effectively enable "faster, cheaper" missions to explore the inner solar system. The first two missions are Mars Environmental Survey (MESUR) Pathfinder and Near Earth Asteroid Rendezvous (NEAR). MESUR Pathfinder will be the first Discovery mission, with launch planned for November/December 1996. It will be primarily a technical demonstration and validation of the MESUR Program--a network of automated landers to study the internal structure, meteorology, and surface properties of Mars. Besides providing engineering data, Pathfinder will carry atmospheric instrumentation and imaging capabilities, and may deploy a microrover equipped with an alpha proton X-ray spectrometer to determine elemental composition, particularly the lighter elements of exobiological interest. NEAR is expected to be launched in 1998 and to rendezvous with a near-Earth asteroid for up to 1 year. During this time, the spacecraft will assess the asteroid's mass, size, density, map its surface topography and composition, determine its internal properties, and study its interaction with the interplanetary environment. A gamma ray or X-ray spectrometer will be used to determine elemental composition. An imaging spectrograph, with 0.35 to 2.5 micron spectral range, will be used to determine the asteroid's compositional disbribution. Of the 11 Discovery mission concepts that have been designated as warranting further study, several are promising in terms of determining the composition and chemical evolution of organic matter on small planetary bodies. The following mission concepts are of particular interest to the Exobiology Program: Cometary coma chemical composition, comet nucleus tour, near earth asteroid returned sample, small missions to asteroids and comets, and solar wind sample return. The following three Discovery mission concepts that have been targeted for further consideration are relevant to the study of the evolution of biogenic compounds: Comet nucleus penetrator, mainbelt asteroid rendezvous explorer, and the Mars polar Pathfinder.
Meyer, Michael A.↗
On the specta of X-ray bursters: Expansion and contraction stages
The theory of spectral formation during the explosion and contraction stages of X-ray bursters, which include the effects of Computonization and free-free absorption and emission, is described. Analytical expressions are provided for color ratios, and the spectral shape is given as a function of input parameters, elemental abundance, neutron star mass and radius, and Eddington ratio. An Eulerian calculation is used to determine the photospheric evolution accurately during the Eddington luminosity phase. The developed analytical theory for hydrodynamics of the expansion takes into account the dependence of Compton scattering opacity on electron temperature. An analytical expression is derived from the sonic point position and the value of the sonic velcoity. Using this value as a boundary condition at the sonic point, the velocity, density, and temperature profile are calculated throughout the whole photosphere. It is shown that the atmopsphere radiates spectra having a low-energy power-law shape and blackbody-like hard tail. In the expansion stage the spectra depend strongly on the temperature of the helium-burning zone at the neutron star surface. The X-ray photosheric radius increases to approximately 100 km or more, depending on the condition of the nuclear burning on the surface of the neutron star in the course of the expansion.
Titarchuk, Lev↗
Spectrum Preprocessing in the OPAD System
To determine the readiness of a rocket engine, and facilitate decisions on continued use of the engine before servicing is required, high-resolution optical spectrometers are used to acquire spectra from the exhaust plume. Such instruments are in place at the Technology Test Bed (TTB) stand at Marshall Space Flight Center (MSFC) and the A1 stand at Stennis Space Center (SSC). The optical spectrometers in place have a wide wavelength range covering the visible and near-infrared regions, taking approximately 8000 measurements at about one Angstrom spacing every half second. In the early stages of this work, data analysis was done manually. A simple spectral model produced a theoretical spectrum for given amount of elements and an operator visually matched the theoretical and real spectra. Currently, extensive software is being developed to receive data from the spectrometer and automatically generate an estimate of element amounts in the plume. It will result in fast and reliable analysis, with the capability of real-time performance. This software is the result of efforts of several groups but mainly it has been developed and used by scientists and combustion engineers, in their effort of understanding the underlying physical processes and phenomena and creating visualization and report generation facilities. Most of the software has been developed using the IDL language and programming environment which allows for extensive data visualization. Although this environment has been very beneficial, the resulting programs execute very slowly and are not easily portable to more popular, real-time environments. The need for portability and high speed of execution is becoming more apparent as the software matures moving out of the experimentation stage and into the production stage where ease of use and short response time are the most desirable features. The purpose of the work described here is to assist the scientists who developed the original IDL-based version in the conversion of the software into the real-time, production version. Specifically, a section of the software devoted to the preprocessing of the spectra has been converted into the C language. In addition, parts of this software which may be improved have been identified, and recommendations are given to improve the functionality and ease of use of the new version.
Katsinis, Constantine↗
The Synchrotron Shock Model Confronts a "Line of Death" in the BATSE Gamma-Ray Burst Data
The synchrotron shock model (SSM) for gamma-ray burst emission makes a testable prediction: that the observed low-energy power-law photon number spectral index cannot exceed -2/3 (where the photon model is defined with a positive index: $dN/dE \propto E{alpha}$). We have collected time-resolved spectral fit parameters for over 100 bright bursts observed by the Burst And Transient Source Experiment on board the {\it Compton Gamma Ray Observatory}. Using this database, we find 23 bursts in which the spectral index limit of the SSM is violated, We discuss elements of the analysis methodology that affect the robustness of this result, as well as some of the escape hatches left for the SSM by theory.
Preece, Robert D.↗
Molecular Spectroscopy in Astrophysics: The Case of Polycyclic Aromatic Hydrocarbons
The role of molecular spectroscopy in astrophysics and astrochemistry is discussed in the context of the study of large, complex, carbon-bearing molecules, namely, Polycyclic Aromatic Hydrocarbons or PAHs. These molecular species are now thought to be widespread in the interstellar medium in their neutral and ionized forms. Identifying the carriers responsible for unidentified interstellar spectral bands will allow to derive important information on cosmic elemental abundances as well as information on the physical conditions (density, temperature) reigning in specific interstellar environments. These, in turn, are key elements for a correct understanding of the energetic mechanisms that govern the origin and the evolution of the interstellar medium. A multidisciplinary approach - combining astronomical observations with laboratory simulations and theoretical modeling - is required to address these complex issues. Laboratory spectra of several PAHs, isolated at low temperature in inert gas matrices or seeded in a supersonic jet expansion, are discussed here and compared to the astronomical spectra of reddened, early type, stars. The electronic spectroscopy of PAHs in the ultraviolet, visible, and near-infrared domains is reviewed and an assessment of the potential contribution of PAHs to the interstellar extinction in the ultraviolet and in the visible is discussed.
Salama, Farid↗
Toroidal Varied-Line Space (TVLS) Gratings
It is a particular challenge to develop a stigmatic spectrograph for XUV wavelengths since the very low normal-incidence reflectance of standard materials most often requires that the design be restricted to a single optical element which must simultaneously provide both re-imaging and spectral dispersion. This problem has been solved in the past by the use of toroidal gratings with uniform line-spaced rulings (TULS). A number of solar EUV (Extreme Ultraviolet) spectrometers have been based on such designs, including SOHO/CDS, Solar-B/EIS, and the sounding rockets SERTS and EUNIS. More recently, Kita, Harada, and collaborators have developed the theory of spherical gratings with varied line-space rulings (SVLS) operated at unity magnification, which have been flown on several astronomical satellite missions. We now combine these ideas into a spectrometer concept that puts varied-line space rulings onto toroidal gratings. Such TVLS designs are found to provide excellent imaging even at very large spectrograph magnifications and beam-speeds, permitting extremely high-quality performance in remarkably compact instrument packages. Optical characteristics of two solar spectrometers based on this concept are described: SUMI, proposed as a sounding rocket experiment, and NEXUS, proposed for the Solar Dynamics Observatory mission.
Thomas, Roger J.↗
X-ray spectroscopy and imagery of supernova remnants with the Einstein Observatory
The two complementary spectroscopic instruments of the Einsten Observatory make possible X-ray spectroscopy of SNRs with considerably increased sensitivity and spectral resolution. The Solid State Spectrometer is a cryogenically cooled detector with 160 eV resolution, which suffices not only for the separation of lines due to different elements, but also the resolution of H-like, He-like and neutral lines from the same element for Si and above. The Focal Plane Crystal Spectrometer uses Bragg crystals to achieve excellent spectral resolution, but at the expense of sensitivity. Both instruments operate over most of the 0.2-4 keV energy band of the Einstein telescope, and are able to detect most of the important X-ray lines except the K lines of Fe and Ni.
Winkler, P. F.↗
Solar excitation of CdS/Cu2S photovoltaic cells
Solar radiation of five typical clear weather days and under a variety of conditions is used to determine the spectral distribution of the photonflux at different planes of a CdS/Cu2S solar cell. The fractions of reflected and absorbed flux are determined at each of the relevant interfaces and active volume elements of the solar cell. The density of absorbed photons is given in respect to spectral and spatial distribution. The variance of the obtained distribution, with changes in insolation and absorption spectra of the active solar cell layers, is indicated. A catalog of typical examples is given in the appendix.
Boer, K. W.↗
A spectral formalism for computing three-dimensional deformations due to surface loads. 1: Theory
We outline a complete spectral formalism for computing high spatial resolution three-dimensional deformations arising from the surface mass loading of a spherically symmetric planet. The main advantages of the formalism are that all surface mass loads are always described using a consistent mathematical representation and that calculations of deformation fields for various spatial resolutions can be performed by simpley altering the spherical harmonic degree truncation level of the procedure. The latter may be important when incorporating improved observational constraints on a particular surface mass load, when considering potential errors in the computed field associated with mass loading having a spatial scale unresolved by the observational constraints, or when treating a number of global surface mass loads constrained with different spatial resolutions. The advantages do not extend to traditional 'Green's function' approaches which involve surface element discretizations of the global mass loads. Another advantage of the spectral formalism, over the Green's function approach, is that a posteriori analyses of the computed deformation fields are easily performed. In developing the spectral formalism, we consider specific cases where the Earth's mantle is assumed to respond as an elastic, slightly anelastic, or linear viscoelastic medium. In the case of an elastic or slightly anelastic mantle rheology the spectral response equations incorporate frequency dependent Love numbers. The formalism can therefore be used, for example, to compute the potentially resonant deformational response associated with the free core nutation and Chandler wobble eigenfunctions. For completeness, the spectral response equations include both body forces, as arise from the gravitational attraction of the Sun and the Moon, and surface mass loads. In either case, and for both elastic and anelastic mantle rheologies, we outline a pseudo-spectral technique for computing the ocean adjustment associated with the total gravitational perturbation induced by the external forcing. Three-dimensional deformations computed using the usual Love number approach are generally referenced to an origin at the center of mass of the undeformed planet. We derive a spectral technique for transforming the results to an origin located at the center of mass of the deformed planet.
Mitrovica, J. X.↗