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NASA NTRS2000

Quantifying the Intercontinental and Global Reach and Effects of Pollution

The Atmospheric Chemistry Modeling Group is participating in an international effort to explore the projected interactions of the atmosphere with biota, human activity, and the natural environment over the next three decades. The group uses computer simulations and statistical analyses to compare theory and observations of the composition of the lower atmosphere. This study of global habitability change is part of a more ambitious activity to understand global habitability. This broad planetary understanding is central to planetary habitability, biomarker detection, and similar aspects of Astrobiology. The group has made highly detailed studies of immense intercontinental plumes that affect the chemistry of the global atmosphere, especially the region below the ozone (O3) layer whose chemical composition defines the conditions for healthy humans and the biosphere. For some decades there has been concern about the pollution from cities and industrial burning and its possible effect in increasing smog ozone, not only in continental regions, but also in plumes that spread downwind. Recently, there has been new concern about another kind of pollution plume. Projections for a greatly expanded aircraft fleet imply that there will be plumes of nitrogen oxides (NO(x)) from jet exhaust in the Northern Hemisphere downwind of major air traffic routes. Both of these are tied to large-scale O3 in the troposphere, where it is toxic to humans and plant tissues.

Chatfield, Robert B.↗

NASA NTRS1986

Constraints on the composition of Jupiter's stratospheric aerosols from ultraviolet photometry

The absolute reflectivity of Jupiter has been obtained in 50 A-wide regions centering on 0.221, 0.233, 0.252, and 0.330 microns from three series of IUE satellite spectra taken in November 1979. The data indicate a strong decrease in reflectivity for latitudes greater than about 30 deg, in keeping with Voyager measurements. An additional 24 spectra were also obtained in a west-east series along the equator, as well as near 40 deg N latitude. These data favor models in which the haze particles have effective radii within a factor of 2 of 0.2 microns. Near the equator, the haze aerosols produce much less absorption than near 40 deg N; the aerosol distributions and optical properties derived are noted to be more dependent on the assumed location and reflectivity of the top of the tropospheric cloud.

Tomasko, M. G.↗

DOE OSTI2025

Burning conditions and transportation pathways determine biomass-burning aerosol properties in the Ascension Island marine boundary layer

Abstract. African biomass-burning aerosol (BBA) in the southeast Atlantic Ocean (SEA) marine boundary layer (MBL) is an important contributor to Earth's radiation budget, yet its representation remains poorly constrained in regional and global climate models. Data from the Layered Atlantic Smoke Interactions with Clouds (LASIC) field campaign on Ascension Island (7.95° S, 14.36° W) provide insight into how burning conditions, fuel type, transport pathways, and atmospheric processing affect the chemical, microphysical, and optical properties of BBA between June and September 2017. A total of 10 individual plume events characterize the seasonal evolution of the BBA properties. Early-season inefficient fires, determined by low refractory black carbon to above-background carbon monoxide mixing ratios (rBC : ΔCO), led to enhanced concentrations of organic- and sulfate-rich aerosols. Mid-season efficient fires, determined by higher rBC : ΔCO values, led to rBC-enriched BBA. A mix of efficient and inefficient fires later in the season resulted in conflicting BBA properties. Prolonged transport (∼ 10 d) through the MBL and lower free troposphere (FT) facilitated chemical and aqueous-phase processing, which led to a reduction in organic aerosol mass concentrations. This resulted in lower organic aerosol (OA) to rBC (OA : rBC) mass ratios (2–5) in the MBL compared to higher values (5–15) in the nearby FT. These atmospheric and cloud oxidation processes yield more light-absorbing BBA and explain the notably low single-scattering albedo at 530 nm (SSA530) values (< 0.80) observed in the MBL. This study establishes a robust correlation between SSA530 and OA : rBC across the MBL and FT, underscoring the dependency of optical properties on chemical composition.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS2011

Evaluation of Convective Transport in the GEOS-5 Chemistry and Climate Model

The NASA Goddard Earth Observing System (GEOS-5) Chemistry and Climate Model (CCM) consists of a global atmospheric general circulation model and the combined stratospheric and tropospheric chemistry package from the NASA Global Modeling Initiative (GMI) chemical transport model. The subgrid process of convective tracer transport is represented through the Relaxed Arakawa-Schubert parameterization in the GEOS-5 CCM. However, substantial uncertainty for tracer transport is associated with this parameterization, as is the case with all global and regional models. We have designed a project to comprehensively evaluate this parameterization from the point of view of tracer transport, and determine the most appropriate improvements that can be made to the GEOS-5 convection algorithm, allowing improvement in our understanding of the role of convective processes in determining atmospheric composition. We first simulate tracer transport in individual observed convective events with a cloud-resolving model (WRF). Initial condition tracer profiles (CO, CO2, O3) are constructed from aircraft data collected in undisturbed air, and the simulations are evaluated using aircraft data taken in the convective anvils. A single-column (SCM) version of the GEOS-5 GCM with online tracers is then run for the same convective events. SCM output is evaluated based on averaged tracer fields from the cloud-resolving model. Sensitivity simulations with adjusted parameters will be run in the SCM to determine improvements in the representation of convective transport. The focus of the work to date is on tropical continental convective events from the African Monsoon Multidisciplinary Analyses (AMMA) field mission in August 2006 that were extensively sampled by multiple research aircraft.

Pickering, Kenneth E.↗

NASA NTRS2016

TPSAS-NF1676L-23432-DND

The POLSTRACC (POlar STRAtosphere in a Changing Climate) field campaign was conducted in the Arctic during December 2015 - March 2016 to investigate the chemical, microphysical, and dynamical processes of the Arctic lowermost stratosphere and upper troposphere. The primary measurement platform for POLSTRACC was the German HALO (High Altitude LOng range) research aircraft carrying a large suite of in situ and remote sensing instruments to measure key chemical species, tracers, as well as aerosol and cloud particles and meteorological parameters. Two primary science objectives of POLSTRACC are to improve our understanding of polar stratospheric cloud (PSC) particle characteristics and formation processes and investigate the impact of Arctic cirrus clouds on radiative forcing and chlorine activation. To complement the more focused measurements from the POLSTRACC field campaign, we have used spaceborne lidar measurements from CALIPSO to characterize PSC occurrence and composition, as well as the occurrence of Arctic cirrus during the 2015-2016 season on vortex-wide scales. In this paper, we present a general overview of the 2015-2016 winter, examine in detail the evolution of PSCs and cirrus during the season, and explore the unique aspects of this season in attempt to understand the underlying physical mechanisms.

Michael C Pitts↗

NASA NTRS1986

Radiative heating and cooling rates in the middle atmosphere

One of the limitations to the accurate calculation of radiative heating and cooling rates in the stratosphere and mesosphere has been the lack of accurate data on the atmospheric temperature and composition. Data from the LIMS experiment on Nimbus-7 has been extended to the South Pole with the aid of other observations. The data have been used as input to codes developed by Ramanathan and Dickinson to calculate the individual components and the net radiative heating rates from 100-0.1 mb. Solar heating due to ozone, nitrogen dioxide, carbon dioxide, water vapor and oxygen is shown to be nearly balanced by cooling in the thermal infrared spectral region due to carbon dioxide, ozone and water vapor. In the lower stratosphere, infrared transfer by ozone leads to heating that is sensitive to the distribution of tropospheric ozone, clouds and water vapor. The heating and cooling rates are adjusted slightly in order to satisfy the global mass balance. The results are in qualitative agreement with earlier calculations, but show additional detail. There is as strong temporal and vertical variation of cooling in the tropics. Radiative relaxation times are as short as 7 days or less at the stratopause.

Gille, John C.↗

NASA NTRSDate not supplied

Aerosol observations from SAGE III on the International Space Station: Visualizing Wildfires and Volcanic Eruptions

The Stratospheric Gas and Aerosol Experiment (SAGE III) aboard the International Space Station has been monitoring ozone, aerosols, and other trace gases in the stratosphere and troposphere since its 2017 launch. This NASA hyperwall presentation focuses on aerosol observations from SAGE, demonstrating its ability to observe volcanic eruptions and increasingly frequent wildfires in recent years, like Raikoke in the Kuril Islands and the western US fires. [Note that presentation would be made on the NASA hyperwall, so not all captions visible to the viewer can be viewed in the PDF.]

SAGE III↗

NASA NTRS2002

Sensitivity of Middle Atmospheric Analyses to the Representation of Gravity-Wave Drag in the DAO's Data Assimilation System

The damping of mesoscale gravity waves has important effects on the global circulation, structure, and composition of the atmosphere. A number of assimilation and forecast experiments have been conducted to examine the sensitivity of meteorological analyses and forecasts to the representation of gravity wave impacts in a data assimilation system (DAS). The experiments were conducted with the Finite-Volume (FV) DAS developed at NASA's Data Assimilation Office (DAO), The main purpose of this research is to determine the optimal combination of wave number, phase speed, wavelength, etc. for representing gravity-wave drag (GWD) in FVDAS. The GWD included in FVDAS includes a spectrum of waves, as would be forced by topography and transient motions (e.g., convection) in the troposphere. The sensitivity experiments are performed by modifying several parameters, such as the number of waves allowed, their wavelength, the background stress amplitude, etc. The results show that the assimilated fields are very sensitive to the number of gravity waves represented in the system, especially at high latitudes of the middle and upper stratosphere and mesosphere in winter. The analyzed stratopause temperature varies by up to 10K when the GWD scheme is modified from a multiple-wave scheme (using a stationary wave and waves with phase speeds of 10, 20, 30 and 40 m/s in each direction) to a single, stationary wave. Insight into the reality of the various versions of the GWD can be obtained by examining the "Observation minus Forecast" residuals from the FVDAS.

Li, Shuhua↗

DOE OSTI2022

The Atlantic Jet Response to Stratospheric Events: A Regime Perspective

The tropospheric response to Sudden Stratospheric Warmings (SSWs) is associated with an equatorward shift in the midlatitude jet and associated storm tracks, while Strong Polar Vortex (SPV) events elicit a contrasting response. Recent analyses of the North Atlantic jet using probability density functions of a jet latitude index have identified three preferred jet latitudes, raising the question of whether the tropospheric response to SSWs and SPVs results from a change in relative frequencies of these preferred jet regimes rather than a systematic jet shift. We explore this question using atmospheric reanalysis data from 1979 to 2018 (26 SSWs and 33 SPVs), and a 202-years integration of the Whole Atmosphere Community Climate Model (92 SSWs and 68 SPVs). Following SSWs, the northern jet regime becomes less common and the central and southern regimes become more common. These changes occur almost immediately following “split” vortex events, but are more delayed following “displacement” events. In contrast, the northern regime becomes more frequent and the southern regime less frequent following SPV events. Following SSWs, composites of 500-hPa geopotential heights, surface air temperatures, and precipitation most closely resemble composites of the southern jet regime, and are generally opposite in sign to the composites of the northern jet regime. These comparisons are reversed following SPVs. Thus, one possible interpretation is that the two southernmost regimes appear to be favored following SSWs, while the southernmost regime becomes less common following SPVs.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1981

In situ sensors for measurements in the global trosposphere

Current techniques available for the in situ measurement of ambient trace gas species, particulate composition, and particulate size distribution are reviewed. The operational specifications of the various techniques are described. Most of the techniques described are those that have been used in airborne applications or show promise of being adaptable to airborne applications. Some of the instruments described are specialty items that are not commercially-available. In situ measurement techniques for several meteorological parameters important in the study of the distribution and transport of ambient air pollutants are discussed. Some remote measurement techniques for meteorological parameters are also discussed. State-of-the-art measurement capabilities are compared with a list of capabilities and specifications desired by NASA for ambient measurements in the global troposphere.

Saeger, M. L.↗

NASA NTRSDate not supplied

TPSAS-NF1676L-32105-DND

NASA Langley Research Center is developing the High-Altitude Lidar Observatory (HALO) system to address the observational needs of NASA’s weather, climate, carbon cycle, and atmospheric composition focus areas. HALO is a multi-function airborne lidar being developed to measure atmospheric H2O and CH4 mixing ratios and aerosol/cloud/ocean optical properties using the Differential Absorption Lidar (DIAL) and High Spectral Resolution Lidar (HSRL) techniques, respectively. To respond to a wide range of airborne process studies, HALO can be rapidly reconfigured to provide either CH4 DIAL+HSRL, H2O DIAL+HSRL, or CH4 DIAL+H2O DIAL measurements using three different laser transmitters. During spring 2018 NASA Langley demonstrated the world’s first combined airborne CH4 DIAL and HSRL measurements from the Langley King Air aircraft during four test flights. The HALO methane configuration also participated in the Long Island Sound Tropospheric Ozone Study (LISTOS) air quality field campaign on the NASA B200 aircraft. The flown instrument configuration employed the DIAL technique at 1645 nm for column and multi-layer range resolved measurements of CH4 concentrations, and the HSRL technique at 532 nm to make independent, unambiguous retrievals of aerosol extinction and backscatter. It also employed the standard backscatter technique at 1064 nm and is polarization-sensitive at the 1064/532 nm wavelengths. The addition of the HSRL channels provides context to the airborne CH4 DIAL measurements such as source attribution, transport, and vertical mixing through mixed layer height retrievals, as well as providing the critical capability to validate aerosol induced biases from passive space-borne measurements of column CH4. In this presentation we focus on the instrument capabilities, initial CH4 measurements over oil and gas production sites in coordination with the ACT-America campaign, CH4 signatures over the Long Island Sound domain during the LISTOS campaign, and prospects for future airborne campaigns with cohosted payloads consisting of active and passive sensors.

Rory Barton-Grimley↗

NASA NTRSDate not supplied

Coupled Aerosol-Chemistry Simulations of the January 2022 Eruptions of Hunga Tonga-Hunga Ha’apai in the NASA GEOS Earth System Model

The January 2022 eruptions of the underwater Hunga Tonga-Hunga Ha’apai volcano injected more than 100 Tg of water vapor and approximately 0.5 Tg of sulfur dioxide into the stratosphere. Injected materials reached as high as ~55 km in altitude, while the main plume from the eruption travelled west over Australia and the Indian Ocean between about 20 – 30 km altitude. We investigate the transport and the impact of the erupted materials in coupled aerosol-chemistry simulations performed with the NASA Goddard Earth Observing System (GEOS) Earth system model. A sulfur mechanism introduced into the Global Modeling Initiative (GMI) stratospheric-tropospheric chemistry package allows for an interactive simulation of the water vapor-chemistry impacts, and the large water vapor perturbation results in rapid conversion of sulfur dioxide to sulfate aerosol in our aerosol mechanism. We report on the results of a multi-year ensemble of simulations performed with this system that include a control ensemble (no eruption), a water vapor-only injection ensemble, and a water vapor and sulfur dioxide injection ensemble. Simulations of the near-field aerosol and chemistry transport are compared to available measurements from OMPS-LP, OMPS-NM, CALIOP, MLS, and other sensors. The extended impact of the volcanic materials on the stratospheric composition and chemistry over the next several years is further investigated in forecast simulations.

Peter Colarco↗

NASA NTRS2000

Clear-Sky Closure Studies of Lower Tropospheric Aerosol and Water Vapor During ACE-2 Using Airborne Sunphotometer, Airborne In-Situ, Space-Borne, and Ground-Based Measurements

We report on clear-sky column closure experiments (CLEARCOLUMN) performed in the Canary Islands during the second Aerosol Characterization Experiment (ACE-2) in June/July 1997. We present CLEARCOLUMN results obtained by combining airborne sunphotometer and in-situ (optical particle counter, nephelometer, and absorption photometer) measurements taken aboard the Pelican aircraft, space-borne NOAA/AVHRR data and ground-based lidar and sunphotometer measurements. During both days discussed here, vertical profiles flown in cloud-free air masses revealed 3 distinctly different layers: a marine boundary layer (MBL) with varying pollution levels, an elevated dust layer, and a very clean layer between the MBL and the dust layer. A key result of this study is the achievement of closure between extinction or layer aerosol optical depth (AOD) computed from continuous in-situ aerosol size-distributions and composition and those measured with the airborne sunphotometer. In the dust, the agreement in layer AOD (lambda = 380-1060 nm) is 3-8%. In the MBL there is a tendency for the in-situ results to be slightly lower than the sunphotometer measurements (10-17% at lambda = 525 nm), but these differences are within the combined error bars of the measurements and computations.

Schmid, Beat↗

NASA NTRS2000

Clear-Sky Closure Studies of Lower Tropospheric Aerosol and Water Vapor During ACE-2 Using Airborne Sunphotometer, Airborne In-Situ, Space-Borne, and Ground-Based Measurements

Schmid, Beat↗

NASA NTRS2020

The Role of Oceanic Processes in the Initiation of Boreal Winter Intraseasonal Oscillations Over the Indian Ocean

Observational analyses and ocean general circulation model experiments were performed to understand the influence of oceanic processes on warm sea surface temperature anomalies (SSTAs) prior to convection initiation of boreal winter intraseasonal oscillations (ISOs), including the Madden‐Julian Oscillation (MJO), in the tropical Indian Ocean. We found 39 strong ISOs that passed over the Indian Ocean Warm Pool (WP) region during the November–April season of the 2001–2012 period. Seventeen of them (44%) initiated over the Seychelles‐Chagos Thermocline Ridge (SCTR) before propagating eastward to the WP and Maritime Continent. Including only global‐scale MJOs, 71% (24%) of the remaining MJO events initiated from the SCTR (WP). Four (seven) SCTR (WP) ISO events were preceded by SSTAs that were strongly influenced by wind stress‐driven oceanic processes; all four (2/7) SCTR (WP) events were MJOs. Composite analyses of the four oceanic process influenced SCTR MJO events showed that wind stress‐driven oceanic processes contributed about 30% (between 0.1 and 0.2 °C) of the preconvection warming in the SCTR, which coincides with the Intertropical Convergence Zone with mean SST > 28 °C. Reduced upwelling and entrainment played a more important role than horizontal advection in elevating the +SSTAs. Case studies revealed that the two ocean process‐influenced primary MJO SCTR events were also associated with oceanic equatorial Rossby waves. Furthermore, results of a linear atmospheric mixed layer model indicated that boundary layer processes related to SSTAs contributed approximately half of the total convergence during MJO initiation, relative to the effect of the free troposphere, for the Rossby wave‐influenced events.

MJO Initiation↗

NASA NTRS2010

Can the GEOS CCM Simulate the Temperature Response to Warm Pool El Nino Events in the Antarctic Stratosphere?

"Warm pool" (WP) El Nino events are characterized by positive sea surface temperature (SST) anomalies in the central equatorial Pacific. During austral spring. WP El Nino events are associated with an enhancement of convective activity in the South Pacific Convergence Zone, provoking a tropospheric planetary wave response and thus increasing planetary wave driving of the Southern Hemisphere stratosphere. These conditions lead to higher polar stratospheric temperatures and to a weaker polar jet during austral summer, as compared with neutral ENSO years. Furthermore, this response is sensitive to the phase of the quasi-biennial oscillation (QBO): a stronger warming is seen in WP El Nino events coincident with the easterly phase of the quasi-biennial oscillation (QBO) as compared with WP El Nino events coincident with a westerly or neutral QBO. The Goddard Earth Observing System (GEOS) chemistry-climate model (CCM) is used to further explore the atmospheric response to ENSO. Time-slice simulations are forced by composited SSTs from observed WP El Nino and neutral ENSO events. The modeled eddy heat flux, temperature and wind responses to WP El Nino events are compared with observations. A new gravity wave drag scheme has been implemented in the GEOS CCM, enabling the model to produce a realistic, internally generated QBO. By repeating the above time-slice simulations with this new model version, the sensitivity of the WP El Nino response to the phase of the quasi-biennial oscillation QBO is estimated.

Hurwitz, M. M.↗

NASA NTRS2011

Can the GEOS CCM Simulate the Temperature Response to Warm Pool El Nino Events in the Antarctic Stratosphere?

"Warm pool" (WP) El Nino events are characterized by positive sea surface temperature (SST) anomalies in the central equatorial Pacific. During austral spring, WP El Nino events are associated with an enhancement of convective activity in the South Pacific Convergence Zone, provoking a tropospheric planetary wave response and thus increasing planetary wave driving of the Southern Hemisphere stratosphere. These conditions lead to higher polar stratospheric temperatures and to a weaker polar jet during austral summer, as compared with neutral ENSO years. Furthermore, this response is sensitive to the phase of the quasi-biennial oscillation (QBO): a stronger warming is seen in WP El Nino events coincident with the easterly phase of the quasi-biennial oscillation (QBO) as compared with WP El Nino events coincident with a westerly or neutral QBO. The Goddard Earth Observing System (GEOS) chemistry-climate model (CCM) is used to further explore the atmospheric response to ENSO. Time-slice simulations are forced by composited SSTs from observed NP El Nino and neutral ENSO events. The modeled eddy heat flux, temperature and wind responses to WP El Nino events are compared with observations. A new gravity wave drag scheme has been implemented in the GEOS CCM, enabling the model to produce e realistic, internally generated QBO. By repeating the above time-slice simulations with this new model version, the sensitivity of the WP El Nino response to the phase of the quasi-biennial oscillation QBO is estimated.

Hurwitz, M. M.↗

NASA NTRS2012

Life Cycle of Midlatitude Deep Convective Systems in a Lagrangian Framework

Deep Convective Systems (DCSs) consist of intense convective cores (CC), large stratiform rain (SR) regions, and extensive non-precipitating anvil clouds (AC). This study focuses on the evolution of these three components and the factors that affect convective AC production. An automated satellite tracking method is used in conjunction with a recently developed multi-sensor hybrid classification to analyze the evolution of DCS structure in a Lagrangian framework over the central United States. Composite analysis from 4221 tracked DCSs during two warm seasons (May-August, 2010-2011) shows that maximum system size correlates with lifetime, and longer-lived DCSs have more extensive SR and AC. Maximum SR and AC area lag behind peak convective intensity and the lag increases linearly from approximately 1-hour for short-lived systems to more than 3-hours for long-lived ones. The increased lag, which depends on the convective environment, suggests that changes in the overall diabatic heating structure associated with the transition from CC to SR and AC could prolong the system lifetime by sustaining stratiform cloud development. Longer-lasting systems are associated with up to 60% higher mid-tropospheric relative humidity and up to 40% stronger middle to upper tropospheric wind shear. Regression analysis shows that the areal coverage of thick AC is strongly correlated with the size of CC, updraft strength, and SR area. Ambient upper tropospheric wind speed and wind shear also play an important role for convective AC production where for systems with large AC (radius greater than 120-km) they are 24% and 20% higher, respectively, than those with small AC (radius=20 km).

Feng, Zhe↗