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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1999

Sensitized Liquid Hydrazine Detonation Studies

Vapor-phase hydrazine (N2H4) is known to be very sensitive to detonation while liquid hydrazine is very insensitive to detonation, theoretically requiring extremely high pressures to induce initiation. A review of literature on solid and liquid explosives shows that when pure explosive substances are infiltrated with gas cavities, voids, and/or different phase contaminants, the energy or shock pressure necessary to induce detonation can decrease by an order of magnitude. Tests were conducted with liquid hydrazine in a modified card-gap configuration. Sensitization was attempted by bubbling helium gas through and/or suspending ceramic microspheres in the liquid. The hydrazine was subjected to the shock pressure from a 2 lb (0.9 kg) Composition C-4 explosive charge. The hydrazine was contained in a 4 in. (10.2 cm) diameter stainless steel cylinder with a 122 in(sup 3) (2 L) volume and sealed with a polyethylene cap. Blast pressures from the events were recorded by 63 high speed pressure transducers located on three radial legs extending from 4 to 115 ft (1.2 to 35.1 in) from ground zero. Comparison of the neat hydrazine and water baseline tests with the "sensitized" hydrazine tests indicates the liquid hydrazine did not detonate under these conditions.

Rathgeber, K. A.↗

NASA NTRS1999

Point Defect Distributions in ZnSe Crystals: Effects of Gravity Vector Orientation During Physical Vapor Transport Growth

ZnSe crystals were grown by the physical vapor transport technique under horizontal and vertical (stabilized and destabilized) configurations. Secondary ion mass spectroscopy and photoluminescence measurements were performed on the grown ZnSe samples to map the distributions of [Si], [Fe], [Cu], [Al] and [Li or Na] impurities as well as Zn vacancy, [V (sub Zn)]. Annealings of ZnSe under controlled Zn pressures were studied to correlate the measured photoluminescence emission intensity to the equilibrium Zn partial pressure. In the horizontal grown crystals the segregations of [Si], [Fe], [Al] and [V (sub Zn)] were observed along the gravity vector direction whereas in the vertically stabilized grown crystal the segregation of these point defects was radially symmetrical. No apparent pattern was observed on the measured distributions in the vertically destabilized grown crystal. The observed segregations in the three growth configurations were interpreted based on the possible buoyancy-driven convection in the vapor phase.

Su, Ching-Hua↗

NASA NTRS1999

Abundances and Distributions of Volatile Elements (Na, S, Cl, K) Within Lunar Volcanic Glass Spheres

This research developed and applied high-precision analytical methods (electron microprobe) to determine the major- and minor-element abundances (Si, Ti, A], Cr, Fe, Mn, Mg, Ca, Na, K) in three suites of Apollo 14 volcanic green glasses. Since the precision of these data was a factor of 5-10 better than previously published results, the data provided the strongest constraints yet achieved on the geochemical processes that operated at depths less than 400 kilometers inside the Moon. The results of this work were submitted to the 29th Lunar and Planetary Science Conference, formed the basis for a Master's Thesis, and were published in the top-tier geochemical journal. Additional high-precision data on the trace abundances of sodium (Na), sulfur (S), and potassium (K) in the Apollo 17 volcanic orange glasses (74220) were also acquired during this grant-period. These data show diffusion profiles within individual 200-micron diameter, glass spherules that were apparently generated during the fire-fountain eruption of this magma in the presence of a transient vapor phase. Although these results have not yet been published, publication is planned in 2001 after additional numerical modeling has been completed. This work has also catalyzed on-going collaborative work with Professor Timothy Grove (MIT) to analyze and understand the origin of the Apollo 15 volcanic green glasses. That work will be completed for publication in 2001.

Delano, John W.↗

NASA NTRS2000

Long-Term Cyclic Oxidation Behavior of Uncoated and Coated Re-108 and In-939 at 980 and 870 C

Very long-term cyclic oxidation behavior of Re108 and In939 with and without a protective coating was evaluated at 980 and 870 C, respectively. Re-108 and In-939 without a protective coating began to show a rapid weight loss at 3000 h due to scale spallation, indicating the need for an oxidation protective coating for longer than thousands of hours of oxidative life. NiAl-base coatings of a vapor phase aluminide (VPA), a pack aluminide (CODEP), and a slurry paint aluminide (SERMALOY J) were applied on Re-108 and In-939. The VPA and CODEP on Re-108 and all three coatings on In-939 showed excellent cyclic oxidation resistance out to 10,000 h. Coated alloys were annealed in an inert atmosphere to determine the loss of Al from the coating into the alloy substrate through diffusion. The Al loss from the coating through diffusion was twice as great as the Al loss through oxidation after 10,000 h of cyclic exposure. The oxidation life of VPA-coated Re-108 was estimated by calculating the amount of Al initially available for protective oxidation and the amount of Al lost through oxidation and diffusion.

Lee, K. N.↗

NASA NTRS2001

Inexpensive Method for Growing Unidirectional Oriented Materials Using Friction-Transferred Poly(tetrafluoroethylene) Substrates

In recent years, there has been an increasing interest in properties of unidirectional materials grown on highly oriented polymer surfaces such as the poly(tetrafluoroethylene) (PTFE) films coated onto smooth glass surfaces. In this technique, a thin PTFE film is deposited by sliding or rubbing a Teflon bar over a heated glass surface at a specific temperature. Depending on the pressure, temperature and sliding rate the thickness of deposited layers can be varied from 30 A to 150 A. The PTFE-coated substrate is simple yet surprising versatile for oriented growth of many organic, inorganic and polymer. The significant aspect of PTFE films is their unusual ability to molecularly align a wide variety of materials grown onto them from solution, melt or vapor phase deposition, at temperature below the melting point of PTFE (approx. 340 C). The PTFE structure may be derived, in part, from the multitude of ridges forming in the film and these ridges can presumably provide effective nucleation sites to induce the unidirectional growth of variety of materials. Electron diffraction studies of these films revealed that the PTFE macromolecules are oriented parallel to each other along the sliding direction. Direct observation of the film thickness, molecular structure and individual fluorine atoms from these highly oriented films were achieved using atomic force microscopy (AFM). In this paper, we also report the first direct observation of individual fluorine atoms, and the measurement of the fluorine-helix and carbon-helix radii to be 1.70 A and 0.54 A, respectively.

Lee, Jonathan A.↗

NASA NTRS2001

Advanced Life Support Research and Technology Development

A videograph outlining life support research. The Human Exploration and Development of Space (HEDS) Enterprise's goals are to provide life support self-sufficiency for human beings to carry out research and exploration productively in space, to open the door for planetary exploration, and for benefits on Earth. Topics presented include the role of NASA Ames, funding, and technical monitoring. The focused research areas discussed include air regeneration, carbon dioxide removal, Mars Life Support, water recovery, Vapor Phase Catalytic Ammonia Removal (VPCAR), solid waste treatment, and Supercritical Water Oxidation (SCWC). Focus is placed on the utilization of Systems Integration, Modeling and Analysis (SIMA) and Dynamic Systems Modeling in this research.

Kliss, Mark↗

NASA NTRS2002

Transmission Electron Microscopy of an In Situ Presolar Silicon Carbide Grain

We used a focused ion beam workstation to prepare ultra-thin sections of a presolar SiC grain. Our TEM studies indicate that the SiC formed by rapid vapor-phase condensation, trapping pre-existing graphite grains in random orientations. Additional information is contained in the original extended abstract.

Stroud, Rhonda M.↗

NASA NTRS2001

Partial Pressures for Several In-Se Compositions from Optical Absorbance of the Vapor

The optical absorbance of the vapor phase over various In-Se compositions between 33.3-60.99 at.% Se and 673-1418 K was measured and used to obtain the partial pressures of Se2(g) and In2Se(g). The results are in agreement with silica Bourdon gauge measurements for compositions between 50-61 at.%, but significantly higher than those from Knudsen cell and simultaneous Knudsen-torsion cell measurements. It is found that 60.99 at.% Se lies outside the sesquiselenide homogeneity range and 59.98 at.% Se lies inside and is the congruently melting composition. The Gibbs energy of formation of the liquid from its pure liquid elements between 1000-1300 K is essentially independent of temperature and falls between -36 to -38 kJ per g atomic weight for 50 and 56% Se at 1200 and 1300 K.

Brebrick, R. F.↗

NASA NTRS2003

Sensitivity of Precipitation Processes to Microphysics and Resolution in a Cloud-Resolving Model

The Goddard Cumulus Ensemble (GCE) model is used to examine the impact of various microphysical schemes, and vertical and horizontal resolution on the development, intensity and rainfall associated with mesoscale convective systems, idealized hurricanes and an ensemble of clouds. The model variables include horizontal and vertical velocities, potential temperature, perturbation pressure, turbulent kinetic energy, and mixing ratios of all water phases (vapor, liquid, and ice). The major characteristics of the GCE model are the explicit representation of warm rain and ice microphysical processes, and their complex interactions with solar and infrared radiative transfer processes, and with surface processes. For idealized hurricane, an axisymmetric version of the GCE model was developed and used successfully to simulate the tropical cyclogenesis process using both a Rankin vortex and saturated air within a specified radius as initial conditions. For mesoscale convective systems, the 3-D version of the GCE model was used to simulate squall lines that developed in the western Pacific, South China Sea, eastern Atlantic, South America and central U.S. For the cloud ensemble, the GCE model was integrated for several days in order to have good sampling of cloud statistics. In this paper, the sensitivities of hurricane intensity to various microphysical processes and model grid resolution will be examined. This will be mainly achieved by performing sensitivity tests using various horizontal (from 1- to 5-kilometers) and vertical resolutions (from 20- to 200-meters in the lower troposphere to 200- to 500-m in the middle and upper troposphere). Sensitivity tests using various microphysical schemes (warm rain only, and three ice with either graupel or hail) will also be performed. The PBL and diurnal variation of precipitation processes will also be evaluated. The budgets will be calculated for different regions (i.e., convective and stratiform regions).

Tao, Wei-Kao↗

NASA NTRS2003

Sensitivity of Precipitation Processes to Microphysics and Resolution in a Cloud-resolving Model

Tao, Wei-Kuo↗

NASA NTRS2003

Sensitivity of Precipitation Processes to Microphysics and Resolution in a Cloud-Resolving Model

The Goddard Cumulus Ensemble (GCE) model is used to examine the impact of various microphysical schemes, and vertical and horizontal resolution on the development, intensity and rainfall associated with mesoscale convective systems, idealized hurricanes and an ensemble of clouds. The model variables include horizontal and vertical velocities, potential temperature, perturbation pressure, turbulent kinetic energy, and mixing ratios of all water phases (vapor, liquid, and ice). The major characteristics of the GCE model are the explicit representation of warm rain and ice microphysical processes, and their complex interactions with solar and infrared radiative transfer processes, and with surface processes. For idealized hurricane, an axisymmetric version of the GCE model was developed and used successfully to simulate the tropical cyclogenesis process using both a Rankin vortex and saturated air within a specified radius as initial conditions. For mesoscale convective systems, the 3-D version of the GCE model was used to simulate squall lines that developed in the western Pacific, eastern Atlantic and central US. For the cloud ensemble, the GCE model was integrated for several days in order to have good sampling of cloud statistics. In this paper, the sensitivities of hurricane intensity to various microphysical processes and model grid resolution will be examined.

Tao, Wei-Kuo↗

NASA NTRS2003

Sensitivity of Precipitation Processes to Microphysics and Resolution in a Cloud Resolving Model

The Goddard Cumulus Ensemble (GCE) model examines the impact of various microphysical schemes, and vertical and horizontal resolution in the development, intensity and rainfall associated with mesoscale convective systems, idealized hurricanes and an ensemble of clouds. The model variables include horizontal and vertical velocities, potential temperature, perturbation pressure, turbulent kinetic energy, and mixing rations of all water phases (vapor, liquid and ice). The major characteristics of the GCE model are the explicit representation of warm rain and ice microphysical processes, and their complex interactions with solar and infrared radiative transfer processes and with surface processes. For idealized hurricanes, an axisymmetric version of the GCE model was developed and used to simulate the tropical cyclogenesis process using both a Rankin vortex and saturated air within a specified radius as initial conditions. For mesoscale convective systems, the 3-D version of the GCE model was use to simulate squall lines that developed in the western Pacific, South China Sea, eastern Atlantic, South America and central U.S. FOr the cloud ensemble, the GCE model was integrated for several days in order to have a good sampling of cloud statistics. In this paper, the sensitivities of hurricane intensity to various microphysical processes and model grid resolutio will be examined. This will be mainly achieved by performing sensitivity tests using various horizontal (from 1-to 5-km) and vertical resolutions (from 20- to 200-m in the lower troposphere to 200- to 500m in the middle and upper troposphere). Sensitivity test using various microphysical schemes (warm rain only, and three ice with either graupel or hail) will also be performed. The thermodynamic and water budget associated with various types of precipitation systems will also be evaluated. The budgets will be calculated for different regions (i.e., convective and stratiform regions).

Tao, Wei-Kuo↗

NASA NTRS2003

Interfacial Reaction Studies Using ONIOM

In this report, we focus on the calculations of the energetics and chemical kinetics of heterogeneous reactions for Organometallic vapor phase epitaxy (OMVPE). The work described in this report builds upon our own previous thermochemical and chemical kinetics studies. The first of these articles refers to the prediction of thermochemical properties, and the latter one deals with the prediction of rate constants for gaseous homolytic dissociation reactions. The calculations of this investigation are at the microscopic level. The systems chosen consisted of a gallium nitride (GaN) substrate, and molecular nitrogen (N2) and ammonia (NH3) as adsorbants. The energetics for the adsorption and the adsorbant dissociation processes were estimated, and reaction rate constants for the dissociation reactions of free and adsorbed molecules were predicted. The energetics for substrate decomposition was also computed. The ONIOM method, implemented in the Gaussian98 program, was used to perform the calculations. This approach has been selected since it allows dividing the system into two layers that can be treated at different levels of accuracy. The atoms of the substrate were modeled using molecular mechanics6 with universal force fields, whereas the adsorbed molecules were approximated using quantum mechanics, based on density functional theory methods with B3LYP functionals and 6-311G(d,p) basis sets. Calculations for the substrate were performed in slabs of several unit cells in each direction. The N2 and NH3 adsorbates were attached to a central location at the Ga-lined surface.

Cardelino, Beatriz H.↗

NASA NTRS2003

H2O-Silicate Microphysics in Ascending Volcanic Plumes on Mars

We begin this study with a simple investigation of the role of the particle size frequency distribution on adsorptive scavenging in the ascending cloud. We define a parcel of silicates and H2O, and allow that parcel to cool, monitoring the total H2O remaining in the vapor phase. In this case, we have defined 10(exp 7) kg of silicates in the test volume, with a log-normal size-frequency distribution, a mean grain size of 10(exp -5) m, and a minimum of 10(exp -6) square meters per particle. This is based on observations of terrestrial ash particles that reveal enormous internal surface area. We assume 10(exp 5) kg of H2O (approximately equal to 1 wt%). The results of this study show significant dependence of the H2O sequestered in the adsorbed phase.

Zent, A. P.↗

NASA NTRS2003

Studies of Elementary Reactions of Chemical Importance in the Atmospheres of Planets

The paper discusses the following: 1. F + Cl2 Kinetics. Absolute rate constant for the reaction F(P-2) with Cl2 has been measured using the discharge flow kinetics technique coupled to mass spectrometric detection at T = 180 - 360 K and 1 Torr He nominal pressure. 2. Vapor pressure system. The main effort on the vapor pressure system involved the design and construction of an insulated enclosure ("Bakeout Box") to improve the uniformity of heating during the bakeout process. 3. Sunphotometer System. This period saw the completion of the two-channel sunphotometer, its calibration, and two field deployments. 4. Vibrational-to-translation (V-T) transfer rates for light hydrocarbons at low temperatures are important parameters in thermal-structure models of the upper atmospheres of the outer planets and their satellites. However, the required data are either simply not available or do not extend to the low temperatures found in those systems. Because methane is such an important constituent in outer planet atmospheres, we have initiated a program to measure the temperature dependence of (V-T) rates for its relaxation by appropriate collision partners. 5. The central focus of this research has been the vapor phase nucleation and growth of metals/refractory species into small particles and the aggregation of these primary particles into larger structures. These topics are part of the broader goal of understanding the conditions under which interstellar dust grains condense from stellar outflows and how these small dust grains coagulate into larger bodies such as planetesimals or planets.

Nesbitt, Fred L.↗

NASA NTRS1960

Comparison of Theoretical and Experimental Values for the Effective Heat of Ablation of Ammonium Chloride

Thermodynamic properties of ammonium chloride have been obtained and applied to a theoretical analysis of the shielding mechanism which reduces the rate of heat transfer to a body when ablation takes place at the surface. The analysis has considered the mechanism as one in which the material sublimes directly from the solid to the vapor phase. The results of the computation are compared with the experimental results obtained from the Langley 700-kilowatt arc jet.

Welker, Jean E.↗

NASA NTRS2003

Thermal and Chemical Characterization of Composite Materials. MSFC Center Director's Discretionary Fund Final Report, Project No. ED36-18

The purpose of this research effort was to: (1) provide a concise and well-defined property profile of current and developing composite materials using thermal and chemical characterization techniques and (2) optimize analytical testing requirements of materials. This effort applied a diverse array of methodologies to ascertain composite material properties. Often, a single method of technique will provide useful, but nonetheless incomplete, information on material composition and/or behavior. To more completely understand and predict material properties, a broad-based analytical approach is required. By developing a database of information comprised of both thermal and chemical properties, material behavior under varying conditions may be better understood. THis is even more important in the aerospace community, where new composite materials and those in the development stage have little reference data. For example, Fourier transform infrared (FTIR) spectroscopy spectral databases available for identification of vapor phase spectra, such as those generated during experiments, generally refer to well-defined chemical compounds. Because this method renders a unique thermal decomposition spectral pattern, even larger, more diverse databases, such as those found in solid and liquid phase FTIR spectroscopy libraries, cannot be used. By combining this and other available methodologies, a database specifically for new materials and materials being developed at Marshall Space Flight Center can be generated . In addition, characterizing materials using this approach will be extremely useful in the verification of materials and identification of anomalies in NASA-wide investigations.

Stanley, D. C.↗

NASA NTRS2004

Non-Ballistic Vapor-Driven Ejecta

Impact-induced vaporization is a key component of early-time cratering mechanics. Previous experimental [1,2] and computational [e.g., 3] studies focused on the generation and expansion of vapor clouds in an attempt to better understand vaporization in hypervelocity impacts. Presented here is a new experimental approach to the study of impact-induced vaporization. The three-dimensional particle image velocimetry (3D PIV) system captures interactions between expanding vapor phases and fine particulates. Particles ejected early in the cratering process may be entrained in expanding gas phases generated at impact, altering their otherwise ballistic path of flight. 3D PIV allows identifying the presence of such non-ballistic ejecta from very early times in the cratering process.

Wrobel, K. E.↗