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At least 505 records · Page 28

Adiabatic and radiative cooling are both important causes of aerosol activation in simulated fog events in Europe

Aerosol–fog interactions affect the visibility in, and life cycle of, fog and are difficult to represent in weather and climate models. Here we explore processes that impact the simulation of fog droplet number concentrations (N d ) at sub-kilometer scale horizontal grid resolutions in the UK Met Office Unified Model. We modify the parameterization of aerosol activation to include droplet activation by radiative cooling in addition to adiabatic cooling and determine the relative importance of the two cooling mechanisms. We further test the sensitivity of simulated N d to: (a) interception of droplets by trees and buildings, (b) overestimation of updrafts in temperature inversions (which leads to artificially high N d values), and (c) potential mechanisms for droplet deactivation due to downward fluctuations in supersaturation. We evaluate our model against observations from the ParisFog and LANFEX field campaigns, building on evaluation described in the companion paper. Including radiative cooling in the activation mechanism improves how accurately we represent the liquid water path and the vertical structure of the fog in our LANFEX case study. However, with radiative cooling, the N d are overestimated for most of the ParisFog cases and for the LANFEX case. The time-averaged overestimate exceeds a factor of three (the normalized mean bias factor exceeds 2.0) in 4 out of 11 ParisFog cases. Our sensitivity studies demonstrate how these overestimates can be mitigated. Assuming the overestimate affects both radiative and adiabatic cooling, we find that although radiative cooling is more often the dominant source, both cooling sources can sometimes dominate activation.

Ghosh, Pratapaditya [Carnegie Mellon University, P↗

Diurnal stratospheric tide in meridional wind, 30 to 60 KM, by season and monthly mean temperatures, 20 to 60 KM, at 80 deg N and to 0 deg N

The diurnal component in meridional wind was observed for each season at twelve rocket stations. Amplitudes and phases are presented as a function of height-latitude or as vertical profiles. Many of the gross features of the tide persist throughout the year, but as they migrate in height and latitude the amplitude or phase at a given location may undergo large changes with season. Longitudinal variations in the diurnal tide are found in the mid-stratosphere, and it is suggested they are coupled with longitudinal variations in the tropospheric temperature structure.

Nastrom, G. D.↗

Diurnal stratospheric tide in meridional wind, 30 to 60 km, by season

The diurnal component in meridional wind is estimated for each season at twelve rocket stations. Amplitudes and phases are presented as a function of height-latitude or as vertical profiles. Many of the gross features of the tide persist throughout the year, but as they migrate in height and latitude the amplitude or phase at a given location may undergo large changes with season. Longitudinal variations in the diurnal tide are found in the mid-stratosphere, and it is suggested they are coupled with longitudinal variations in the tropospheric temperature structure.

Nastrom, G. D.↗

Carbon monoxide on Jupiter and implications for atmospheric convection

A study of the equilibrium and disequilibrium thermochemistry of the recently discovered carbon monoxide on Jupiter suggests that the presence of this gas in the visible atmosphere is a direct result of very rapid upward mixing from levels in the deep atmosphere where the temperature is about 1100 K and where carbon monoxide is thermodynamically much more stable. As a consequence the observed carbon monoxide mixing ratio is a sensitive function of the vertical eddy mixing coefficient. We infer a value for this latter coefficient which is about three to four orders of magnitude greater than that in the earth's troposphere. This result directly supports existing structural and dynamical theories implying very rapid convection in the deep Jovian atmosphere, driven by an internal heat source.

Prinn, R. G.↗

A climate index indicative of cloudiness derived from satellite infrared sounder data

In many current studies conducted to enhance the usefulness of meteorological satellite radiance data, one common objective is to infer conventional weather variables. The present investigation, on the other hand, is mainly concerned with the efficient retrieval (minimization of errors) of a nonstandard atmospheric descriptor. The atmosphere's Vertical Infrared Radiative Emitting Structure (VIRES) is retrieved. VIRES is described by the broadband infrared weighting function curve. The shapes of these weighting curves are primarily a function of the three-dimensional cloud structure. The weighting curves are retrieved by a method which uses satellite spectral radiance data. The basic theory involved in the VIRES retrieval procedure parallels the technique used to retrieve temperature soundings.

Abel, M. D.↗

Coupling of horizontal, vertical, and temporal resolving power of a satellite temperature sounder

This paper examines the interconnection between the vertical, horizontal, and temporal resolving power of satellite temperature-sounding system. Using a temperature cross section produced by interpolating a set of RAOBs taken at three locations in Texas; Shreveport, Louisiana; Jackson, Mississippi; and Montgomery, Alabama, and an artificially constructed temperature cross section, it was found that the horizontal and temporal resolving power are subject to strong controls imposed by the vertical resolving power of the sounder. Thus, to improve the horizontal or temporal resolving power it is necessary to improve the vertical resolving power' of the satellite instrument itself, or to extend the a priori external information to include correct horizontal and temporal structure.

Thompson, Owen E.↗

A Dynamical Model for The Jupiter Thermocline

A new conceptual model for the observed banded wind structure of the giant outer planets is proposed, assuming a smoothly distributed potential vorticity (PV) atop a layer of deeply seated, latitudinally variable stratification. With a vanishing horizontal entropy contrast presumably enforced at the bottom of the flow layer by the underlying convection, the thermal-wind balance of observed cloud-top motions implies a mapping of constant potential temperature surfaces, nearly vertical at upper tropospheric levels, down to a deeper, flatter, but variably sloped 'thermocline.' For a generally colder-poleward distribution of isentropes consistent with the strong equatorial jets of both Jupiter and Saturn, this kind of mapping would also imply a poleward decreasing static stability. The proposed temperature-stability distribution is just the reverse of the Earth's troposphere, where the strongest latitudinal potential temperature gradients are at the bottom instead of the top, with static stability generally increasing toward the pole. The warmer-stabler correlation for Jupiter would be consistent, however, with a nearly monotonic distribution of PV from low to high latitudes, over planetary scales for which the planetary vorticity dominates the relative vorticity of the jets. In this way efficient PV mixing for the isentropically bounded thermocline can account for the dynamical maintenance of the cyclonic flanks of the equatorial jet. Over latitudinal intervals comparable to the internal deformation scale, however, the gradient of the absolute vorticity is dominated by the flow curvature, with the local latitudinal gradient of the static stability proportional to the local potential temperature gradient and therefore the local variation in geostrophic velocity. The resulting correlation of velocities and vorticity gradients implies an alternation of the flow over the internal deformation radius set by the vertical entropy contrast.

Allison, Michael↗

The Galileo Probe: How it Has Changed Our Understanding of Jupiter

The Galileo Mission to Jupiter, which arrived in December of 1995, provided the first study by an orbiter, and the first in-situ sampling via an entry probe, of an outer planet atmosphere. The rationale for an entry probe is that, even from an orbiter, remote sensing of the jovian atmosphere could not adequately retrieve the information desired. This paper provides a current summary of the most significant aspects of the data returned from the Galileo entry probe. As a result of the probe measurements, there has been a reassessment of our understanding of outer planet formation and evolution of the solar system. The primary scientific objective of the Galileo probe was to determine the composition of the jovian atmosphere, which from remote sensing remained either very uncertain, or completely unknown, with respect to several key elements. The probe found that the global He mass fraction is. significantly above the value reported from the Voyager Jupiter flybys but is slightly below the protosolar value, implying that there has been some settling of He to the deep jovian interior. The probe He measurements have also led to a reevaluation of the Voyager He mass fraction for Saturn, which is now determined to be much closer to that of Jupiter. The elements C, N, S, Ar, Kr, Xe were all found to have global abundances approximately 3 times their respective solar abundances. This result has raised a number of fundamental issues with regard to properties of planetesimals and the solar nebula at the time of giant planet formation. Ne, on the other hand, was found to be highly depleted, probably as the result of it being carried along with helium as helium settles towards the deep interior. The global abundance of O was not obtained by the probe because of the influence of local processes at the probe entry site (PES), processes which depleted condensible species, in this case H2O, well below condensation levels. Other condensible species, namely NH3 and H2S, were similarly affected but attained their deep equilibrium mixing ratios before the maximum depth sampled by the probe. Processes that might be capable of producing such effects on the condensibles are still under investigation. Measured isotopic ratios of noble gases and other heavy elements are solar, and (D + (Sup 3)He)/H is the same to within measurement uncertainties as in the local interstellar medium. No thick clouds were detected, and in particular no significant water cloud, but the PES location clearly affected the probe measurements of clouds. In fact, the probe data must be understood in the context of the location of the PES, which was within what is termed a 5 micron hot spot, a local clearing in the clouds that is bright near the 5 microns spectral region. The thermal structure at the PES was determined from approximately 1000 km above the 1 bar pressure level (10(exp -9 bars)) to 132 km 1 bar (22bars). The probe showed the atmosphere to have a generally sub-adiabatic temperature gradient (static stability) of = 0.1 K/km to as deep as the probe made measurements. In the upper atmosphere the probe derived a maximum positive vertical temperature gradient of approximately 5 K/km, and maximum temperature of = 900 K. The energy sources producing the warm upper atmosphere have yet to be completely identified. At first glance, Doppler tracking of the probe indicates that the long observed cloud level zonal winds extend to levels at least as deep as the probe made measurements. Zonal wind increases from = 80 m/s at pressures less than a bar to about 180 m/s near 5 bars, and remains approximately constant with depth thereafter. However, there is a question as to whether the winds measured from probe tracking are representative of the general wind field, or are considerably influenced by localized winds associated with the PES.

Young, Richard E.↗

Ship-based Observations and Climate Model Simulations of Cloud Phase over the Southern Ocean

The Southern Ocean (SO) clouds exert a significant influence on the Earth’s radiation budget. Here we analyzed ship-based remote sensing observations of SO clouds over a five-month long DOE ARM Measurements of Aerosols, Radiation and Clouds over the Southern Oceans (MARCUS) field campaign to better understand cloud phase variability. We developed a method to classify eight categories of hydrometeors (ice, liquid, mixed phase, rain, drizzle, snow, aerosols, and clear sky) based on measurements of lidar, radar and radiosondes. Cloud thermodynamic phases (liquid, ice and mixed phase) at coarser scales were further derived to compare with the DOE Energy Exascale Earth System Model version 1 (E3SMv1) simulation and the Earth Model Column Collaboratory (EMC 2 ) instrument simulator. For a scale-aware comparison with climate model simulations, we found that spatially averaging the raw remote sensing data (e.g., backscatter, reflectivity) results in increased cloud cover and cloud liquid, whereas, directly averaging cloud phase from higher to lower resolution maintains clear air regions and is thus recommended for in-cloud frequency comparisons. For cloud thermodynamic phases in stratiform clouds, the E3SM underestimates cloud ice and overestimates cloud liquid at temperatures between -40 and 0°C. When latitudes increase, both observations and simulations show a transition of dominant phase from liquid to ice for cloud tops as well as for the entire cloud columns, but the model underestimation of ice phase is more severe at higher latitudes. Such model bias is unlikely caused by spatial scale differences or lack of heterogeneity in cloud vertical structure in the simulation.

54 ENVIRONMENTAL SCIENCES↗

Subsurface discontinuity detection by microwave radiometry.

Brief description of a joint program undertaken near Austin and San Antonio, Tex., to detect the presence of subsurface voids such as caverns and tunnels by microwave radiometry. Mi crowave radiometric temperature measurements using both vertical and horizontal polarization were taken with fixed-view angle traverses across three sites at two locations. No unambiguous correlation between the microwave temperature contours and the subsurface voids was observed at either location, but a correlation between microwave temperature and moisture patterns was observed at both locations. The large microwave temperature anomalies observed at all three sites indicated a sensitivity to near-surface structure and moisture distribution. A close correlation was noted between low soil-bearing strength values and the tunnel location at the San Antonio site.

Hruby, R. J.↗

On the oblateness and rotation rate of Neptune's atmosphere

Recent observations of a stellar occultation by Neptune give an oblateness of 0.022 + or - 0.004 for Neptune's atmosphere at the 1-microbar pressure level. This results is consistent with hydrostatic equilibrium at a uniform atmospheric rotation period of 15 hours, although the error bars on quantities used in the calculation are such that an 18-hour period is not excluded. The oblateness of a planetary atmosphere is determined from stellar occultations by measuring the times at which a specified point on immersion or emersion occultation profiles is reached. Whether this standard procedure for deriving the shape of the atmosphere is consistent with what is known about vertical and horizontal temperature gradients in Neptune's atmosphere is evaluated. The nature of the constraint placed on the interior mass distribution by an oblateness determined in this manner is consided, as is the effects of possible differential rotation. A 15-hour Neptune internal mass distribution is approximately homologous to Uranus', but an 18-hour period is not. The implications for Neptune's interior structure if its body rotation period is actually 18 hours are discussed.

Hubbard, W. B.↗

In Situ and Satellite Measured Temperature Comparability

Following the International Geophysical Year in the late 1950's, small meteorological rockets caught the interest of scientists as a potentially inexpensive method to obtain meteorological information (density, temperature, wind) above balloon-borne radiosonde altitudes. These small rocketsondes have served many important observational roles in terms of studies conducted of atmospheric structure and processes, enabling many new ideas about the atmosphere to emerge. Although no longer manufactured a small residual inventory of meteorological rocketsondes exist for specific research projects. The value of data from meteorological rocketsondes is without question but with their disappearance data from many different satellites are filling the need, some able to resolve high-altitude temperatures quite well. However, the rocketsonde vertical profile is more localized to the launch site whereas satellites move several kilometers per second. The objective of this presentation is to compare in situ temperature data with remotely measured/retrieved temperature data. There have been a number of U.S. conducted missions utilizing the passive falling sphere data that we use to verify the comparability of retrieved temperatures from these satellites. Missions, some as early as 1991, were conducted in polar, equatorial, and mid-latitude locations. An important aspect is that a single satellite profile compared to a falling sphere profile often does not agree while high density satellite measurements when averaged over an area near the rocketsonde data area seems to be in better agreement. Radiosonde temperature data are used in the analysis when appropriate

Schmidlin, F. J.↗

VALENTInE: A Concept for a New Frontiers Class Long Duration In-Situ Balloon Mission to Venus

Venus and Earth are similar in bulk composition, size, density, and approximate distance from the Sun, yet Venus’s modern-day climate and surface geology is distinctly different [1]. Previous missions to Venus revealed unusual volcanic features, possible continental crust, widespread volcanic plains, a weak magnetic field [2], and insights into the Venusian atmosphere [3,4]. Unfortunately, data from these missions were limited in spatial and temporal resolution and global extent. A future mission to Venus is critical to address fundamental questions surrounding the chemical composition and dynamics of the Venusian atmosphere [5], its geologic history [6,7], its internal structure [8,9], and its habitability throughout time [10,11]. We present the Venus Air and Land Expedition: a Novel Trailblazer for In situ Exploration (VALENTInE) mission to meet this need. VALENTInE is a variable altitude balloon that will passively float in Venus’s atmosphere between 45 and 55 km altitude. VALENTInE will acquire atmospheric data at varying latitudes and longitudes in addition to mapping the surface geomorphology and mineralogy across multiple terrains. Mission Objectives: The VALENTInE mission concept is driven by four main science objectives: 1. Determine whether the driving force of the superrotation of Venus’s atmosphere is caused by horizontal or vertical momentum transport. 2. Determine whether the atmospheric composition and noble gas inventory of the Venusian atmosphere is a product of outgassing from the initial protoplanetary source or if there are significant contributions from exogenic sources. 3. Determine whether the tesserae regions (particularly Aphrodite Terra) are felsic and relatively older than surrounding regions. 4. Determine if there is any evidence of a recent dynamo preserved in the rock record of Venus. Mission Overview: A balloon architecture provides a robust system that can survive long-term in the Venusian environment while taking accurate measurements of the lower cloud deck and surface. Two prior balloon missions to Venus, VEGA 1 and VEGA 2 in 1984, have demonstrated the potential for such planetary exploration; however, these missions were short-lived (46 hr), with limited range (54 km). Our spacecraft concept consists of a battery powered balloon with a gondola and flyby carrier stage (Fig. 1). Our novel design allows for at least 15 days of atmospheric exploration, including multiple ascents and descents in the Venus atmosphere. VALENTInE is baselined to launch in 2032, cruise on solar power for 128 days, enter, descend, and inflate (EDI) into Venus’s atmosphere above Aphrodite Terra, and float in Venus’s atmosphere for a total nominal mission duration of 15 days. The balloon, able to control its altitude by changing its buoyancy, will make one full circumnavigation every 4–8 days and move poleward ~1 o latitude per day; it will be passively directed by the horizontal air currents on Venus. The balloon can only be controlled in the z direction, and the expected latitude range is ±10° from EDI. The balloon itself will be a tracer for atmospheric structures such as zonal winds [5, 12]. During the 15-day operational period, there will be five dips to 45 km for a compositional study of the lower atmosphere and geological and magnetic mapping of the surface. Dips are used to take images and measurements closer to the surface and to obtain in situ vertical atmospheric profiles between 45 and 55 km. Instruments: The VALENTInE instrument payload will allow for extensive study of the geology, atmosphere, and interior of Venus. The instrument suite consists of six instruments. The mission profile for each instrument is shown in Fig. 2. Lower Atmosphere Meteorology Analyzer (LAMA) is an atmospheric structure instrument consisting of a thermometer, barometer, and accelerometer to continuously measure temperature and pressure as a function of altitude, longitude, and latitude. TracE and Noble Gas Investigator (TENGI) is aneutral mass spectrometer used to sample the dense atmosphere. TENGI will operate continuously at 45 km and 55 km and will measure D/H ratios, as well as Ne, Ar, and O isotopic ratios. Kilometer Scale Spectral Imager (KSSI) is amultispectral imager (850-1150 nm) used to resolve surface features on the order of km. Near InfraRed Multispectral Photometer (NIRMP) is an Infrared (IR) photometer used to image the surface through the clouds to characterize mineral assemblages at five different areas of the surface. NIRMP will be operated during dwell. ELevation REConnaissance (ELREC) is a light detection and ranging (LIDAR) instrument used for measuring topography at five different areas of the surface. The ELREC data will be combined with those of NIRMP to determine mineral assemblages and how they correlate to topography. Magnetic Exploration and Interior Detective (MEID) is a magnetometer used to detect any near-surface magnetic anomalies. The magnetometer will continuously operate at all altitudes. Mission Design: The spacecraft’s propulsion system will have a wet mass of 930 kg and will be launched on an Atlas V rocket. The spacecraft will jettison the payload upon arrival in Venus’s atmosphere before decelerating to orbital velocity. Figure 2. Notional power-dip profile while the balloon is on the dayside. Risks and Challenges: Raising and lowering the spacecraft to dip beneath the haze layer require a large amount of energy. This issue was partly compensated by limiting the number of dips over the 15 day prime mission. Power needs for pumping helium are reduced by slowing the descent speed, which consequently increases spatial resolution of in situ measurements between 45 and 55 km. The main limitation for the duration of the mission is the need to carry 15 days’ worth of batteries. The bus experiences external Venusian temperatures ranging from ~27°C at 55 km altitude to ~110°C at 45 km altitude. These high atmospheric temperatures require thermal protection for the bus (instruments, electronics, and flight systems) during its descent, dwell at 45 km, and ascent. The bus is maintained at a mechanically safe temperature range of -10°C to 50°C using white external paint, multi-layer insulation (MLI), mechanical/thermal isolation (e.g. Ti, composites), and ~57 kg of Phase Change Materials (PCM). Images and spectra taken below the haze dominate the available data transmission regardless of the time spent at 45 km. Therefore, less time at the lower altitude mainly reduces the coverage of in situ measurements there. Further, we assumed an unrealistically low-density material for the helium storage tanks on the gondola. However, this issue is partially resolved if we were to jettison 75% of the spent helium storage tanks. After the entry process, the balloon volume remains mostly inflated and storage tanks are required only for reducing balloon volume in dipping to 45 km. This mission was planned against an expected New Frontiers 5 (NF5) cost cap of $1B, as the NF5 call had not yet been released. The mission we describe fits within the predicted cost cap if the flyby carrier stage, responsible for powering the spacecraft during cruise and for relaying in situ measurements back to Earth, can be contributed by another space agency. Acknowledgments: We thank the JPL Planetary Science Summer School, especially A. Nash, J. Scully, K. Mitchell, L. Lowes, and J. Armijo, and our mentors from JPL Team X. Thank you to our review panel for their insightful review. References: [1] Kane, S. et al. (2019) JGR:Ps, 124 , 2015–2028. [2] Phillips, J. L., & Russell, C. T. (1987). JGR: Space Physics , 92 (A3), 2253-2263. [3] Nakamura, M. et al. (2018) Earth Planets Space, 70 (1), 144. [4] Svedhem, H. et al. (2009) JGR:P 114 (E5). [5] Limaye et al. (2009) Decadal Survey White Paper . [6] Ivanov, M. and Head, J. (2011) PSS, 59 (13) , 1559-1600. [7] Smrekar, S. et al. (2018) Space Sci Rev, 214 (5), 88. [8] O’Rourke, J. et al. (2018) EPSL, 502 , 46-56. [9] O’Rourke J. et al. (2019) GRL , (46), 5768–5777 [10] Way, M. et al. (2016) GRL, 43 (16), 8376-8383. [11] Way, M. et al. (2020) JGR:P, 125 (5), e2019JE006276. [12] Preston, R. A. et al. (1986) Science, 231 (4744), 1414-1416.

Mission Concept↗

Assimilation of Soil Moisture Observations Over Land Improves Analysis and Prediction of Tropical Cyclone Idai

Soil moisture conditions can impact the circulation and structure of a tropical cyclone (TC) when part or all of the circulation is over land. Dry land surface conditions may lead to faster dissipation of a TC over land, whereas very wet conditions may lead to a prolonged maintenance of its intensity. While this relationship is relatively well understood in theory, applications of these findings in the context of numerical weather prediction (NWP) have been limited. Here we present a case study that explores the potential of improving TC predictions through an improved soil moisture initialization in an NWP framework. Specifically, we examine the impact of assimilating observations from the NASA Soil Moisture Active Passive (SMAP) mission into the NASA Goddard Earth Observing System (GEOS) global weather model on the prediction of South-West Indian Ocean TC Idai (2019). SMAP provides accurate L-band (1.4 GHz) brightness temperatures (Tb) observations that are sensitive to soil moisture globally and at high revisit times of 2-3 days. It has previously been shown that the assimilation of SMAP Tbs significantly improves modeled land surface states. Here we evaluate: (i) forecasts initialized from an analysis that is comparable to the GEOS operational analysis (without SMAP Tb assimilation) and (ii) forecasts initialized from an analysis that additionally assimilates SMAP Tb observations. We find that in the analysis with SMAP assimilation, the TC has a better-defined, more aligned vertical structure over land relative to the control run; moreover, the analyzed TC size, as measured by the wind speed radius, better matches the observed TC size. We further find significant reductions in the forecast intensity error and the forecast along-track error, measured against observations. The largest error reductions occur at lead times of 36 to 72 hours, suggesting that the land with its longer memory gains in importance as a source of predictability at this timescale. An investigation of the underlying mechanisms leading to the skill improvements from SMAP data assimilation revealed that the assimilation of SMAP leads to wetter soil moisture conditions and an increased latent heat flux in the SMAP analysis, which results in a TC with higher column-integrated total moisture content and total energy compared to the control analysis.

Jana Kolassa↗

Convectively coupled Rossby–Gravity waves in a field campaign: How they are captured in reanalysis products

Abstract Convectively coupled equatorial waves are a significant source of atmospheric variability in the tropics. Current numerical models continue to struggle in simulating the coupled diabatic heating fields that are responsible for the development and maintenance of these waves. This study investigates how the diabatic fields associated with Mixed Rossby–Gravity waves (MRGs) are represented in four reanalysis products by using a unique observational dataset from the TRMM‐KWAJEX (Tropical Rainfall Measuring Mission‐Kwajalein Experiment) field campaign. These reanalyses include ERA5, Japanese 55‐year Reanalysis (JRA‐55), Climate Forecast System Reanalysis (CFSR), and Modern‐Era Retrospective Analysis for Research and Applications (MERRA). We found that all four reanalyses captured the MRG structures in winds and temperature, and to a lesser degree in the humidity field except in the boundary layer. However, only the ERA5 and MERRA reanalyses captured the gradual rise and succession of the diabatic heating from boundary layer turbulence, shallow convection, cumulus congestus, and deep convection within the waves. ERA5 is the only product that also captured the gradual rise of the subgrid‐scale vertical transport of moist static energy. All reanalysis products underestimated the diabatic heating from cumulus congestus. Results provide observational basis on what aspects of MRG can be trusted and what cannot in the reanalysis products.

Wang, Xiaocong↗

Temperature-independent giant dielectric response in transitional BaTiO 3 thin films

Ferroelectric materials exhibit the largest dielectric permittivities and piezoelectric responses in nature, making them invaluable in applications from supercapacitors or sensors to actuators or electromechanical transducers. The origin of this behavior is their proximity to phase transitions. However, the largest possible responses are most often not utilized due to the impracticality of using temperature as a control parameter and to operate at phase transitions. This has motivated the design of solid solutions with morphotropic phase boundaries between different polar phases that are tuned by composition and that are weakly dependent on temperature. Thus far, the best piezoelectrics have been achieved in materials with intermediate (bridging or adaptive) phases. But so far, complex chemistry or an intricate microstructure has been required to achieve temperature-independent phase-transition boundaries. Here, we report such a temperature-independent bridging state in thin films of chemically simple BaTiO3. A coexistence among tetragonal, orthorhombic, and their bridging low-symmetry phases are shown to induce continuous vertical polarization rotation, which recreates a smear in-transition state and leads to a giant temperature-independent dielectric response. The current material contains a ferroelectric state that is distinct from those at morphotropic phase boundaries and cannot be considered as ferroelectric crystals. We believe that other materials can be engineered in a similar way to contain a ferroelectric state with gradual change of structure, forming a class of transitional ferroelectrics. Similar mechanisms could be utilized in other materials to design low-power ferroelectrics, piezoelectrics, dielectrics, or shape-memory alloys, as well as efficient electro- and magnetocalorics.

36 MATERIALS SCIENCE↗

Experimental realization of classical Z 2 spin liquids in a programmable quantum device

We build and probe a Z 2 spin liquid in a programmable quantum device, the D-Wave DW-2000Q. Specifically, we observe the classical eight-vertex and six-vertex (spin ice) states and transitions between them. To realize this state of matter, we design a Hamiltonian with combinatorial gauge symmetry using only pairwise-qubit interactions and a transverse field, i.e., interactions which are accessible in this quantum device. The combinatorial gauge symmetry remains exact along the full quantum annealing path, landing the system onto the classical eight-vertex model at the endpoint of the path. The output configurations from the device allow us to directly observe the loop structure of the classical model. Moreover, we deform the Hamiltonian so as to vary the weights of the eight vertices and show that we can selectively attain the classical six-vertex (ice) model, or drive the system into a ferromagnetic state. Additionally, we present studies of the classical phase diagram of the system as a function of the eight-vertex deformations and effective temperature, which we control by varying the relative strengths of the programmable couplings, and we show that the experimental results are consistent with theoretical analysis. Finally, we identify additional capabilities that, if added to these devices, would allow us to realize Z 2 quantum spin liquids on which to build topological qubits.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Nimbus-7 Stratospheric and Mesospheric Sounder (SAMS) experiment data user's guide

The Stratospheric and Mesospheric Sounder (SAMS) aboard Nimbus-7 observes infrared radiation from the atmospheric limb. Global upper atmosphere temperature profiles and vertical concentrations of H2O, NO, N2O, CH4 and CO2 are derived from these measurements. The status of all channels was carefully monitored. Temperature and composition were retrieved from the measurements by linearizing the direct equation about an a priori profile and using an optimum statistical estimator to find the most likely solution. The derived temperature and composition profiles are archived on two tape products whose file structure and record formats are described in detail. The gridded retrieved temperature tape (GRID-T) contains daily day and night average temperatures at 62 pressure levels in a 2.5 degree latitude by 10 degree longitude grid extending from 67.5 degrees N to 50 degrees S. The zonal mean methane and nitrous oxide composition tape (ZMT-G) contains zonal mean day and night average CH4 and N2O mixing ratios at 31 pressure levels for 2.5 degrees latitude zones extending from 67.5 degrees N to 50 degrees S.

Taylor, F. W.↗