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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 505 records · Page 28

Performance evaluations of oxidation-resistant carbon-carbon composites in simulated hypersonic vehicle environments

An evaluation is made of the oxidation-protection requirements of carbon-carbon composite (CCC) structural components in a hypersonic vehicle aerothermodynamic environment, where maximum test temperatures in air are of the order of 2800 F, and pressures range from 0.03 to 1.0 atm. The specimens were exposed to high humidity between tests. Attention was given to the effects of coating composition and thickness, and of substrate architecture and surface preparation, on the oxidation resistance of CCCs. Both surface preparation and coating chemistry have a profound effect on coating adherence and longevity.

Barrett, D. M.↗

Sublimation rates of carbon monoxide and carbon dioxide from comet nuclei at large distances from the Sun

One of the more attractive among the plausible scenarios for the major emission event recently observed on Comet Halley at a heliocentric distance of 14.3 AU is activation of a source of ejecta driven by an icy substance much more volatile than water. As prerequisite for the forthcoming detailed analysis of the imaging observations of this event, a simple model is proposed that yields the sublimation rate versus time at any location on the surface of a rotating cometary nucleus for two candidate ices: carbon monoxide and carbon dioxide. The model's variable parameters are the comet's heliocentric distance r and the Sun's instantaneous zenith angle z.

Sekanina, Zdenek↗

Large deflection random response of flat and blade stiffened carbon-carbon panels

The large deflection random response of flat and blade-stiffened carbon-carbon panels is studied both experimentally and analytically. The experimental data was obtained from tests performed in the Thermal Acoustic Fatigue Apparatus at NASA Langley. The analytical results were generated using a numerical simulation program that used the measured acoustic pressure as input. Comparisons of the measured and simulated power spectral densities are presented for several locations on each panel. A comparison of the rms strains at various locations on each panel is also discussed. The measured rms strains were generally a factor of two larger than the predicted. The effect of the nonlinearity was overpredicted at higher sound spectrum levels.

Robinson, J. H.↗

Structural analysis of an NDE-inspected carbon-carbon component

In this research, it is demonstrated that the integration of nondestructive evaluation with the finite element method (a quantitative NDE/FEM approach) can be used for analysis and behavior prediction of advanced materials, such as fiber composites, after processing and during in-service testing. First, stress, strain, and energy data were calculated by the finite element method for square plates with a 10 percent difference in the material properties between specified segments, i.e., between the center and the outside section or between two halves of the plate. This demonstrated the efficiency of the method in predicting variations in the structural behavior based on small material property differences. Then, finite element analyses and actual axial compression tests were performed on a Space Shuttle brake stator made from woven carbon-carbon composites. The material properties used in the numerical modeling of the stator were previously characterized at a large number of points on the component by quantitative NDE-procedures, i.e., ultrasonics and radiography. The results from the experimental compressive loading tests were used to verify the NDE/FEM results. Good agreement was found for most parameters.

Striz, A. G.↗

Fatigue and flexural response of advanced carbon-carbon composites at room and elevated temperatures

The flexural response of SiC-coated carbon-carbon composites (ACC-4) at room and elevated temperatures is presented. Three-point bending tests were performed on virgin and mission-cycled specimens, and the variation in flexural strength is examined. The load-deflection behavior of the material at various temperatures is investigated, and the Weibull (1939) analysis of the strength data is performed. Micrographs of various cross sections in the damaged zone were taken, and the failure mechanisms are discussed. Fatigue tests were conducted under flexural loads, and the S-N diagram with the corresponding Weibull analysis are presented. Untested as well as fractured specimens under static and dynamic loading were C-scanned to identify the damaged zone and visualize the extent of the damage. Failure analyses are presented for both static and cyclic loading on the basis of NDE, the micrographs, and the experimental data.

Mahfuz, Hassan↗

Emittance measurements of Space Shuttle orbiter reinforced carbon-carbon

The spectral and total normal emittance of the Reinforced Carbon-Carbon (RCC) used on Space Shuttle nose cap and wing leading edges has been measured at room temperature and at surface temperatures of 1200 to 2100 K. These measurements were made on virgin and two flown RCC samples. Room temperature directional emittance data were also obtained and were used to determine the total hemispherical emittance of RCC as a function of temperature. Results of the total normal emittance for the virgin samples showed good agreement with the current RCC emittance design curve; however, the data from the flown samples showed an increase in the emittance at high temperature possibly due to exposure from flight environments.

Caram, Jose M.↗

Sublimation rates of carbon monoxide and carbon dioxide from comets at large heliocentric distances

Using a simple model for outgassing from a small flat surface area, the sublimation rates of carbon monoxide and carbon dioxide, two species more volatile than water ice that are known to be present in comets, are calculated for a suddenly activated discrete source on the rotating nucleus. The instantaneous sublimation rate depends upon the comet's heliocentric distance and the Sun's zenith angle at the location of the source. The values are derived for the constants of CO and CO2 in an expression that yields the local rotation-averaged sublimation rate as a function of the comet's spin parameters and the source's cometocentric latitude.

Sekanina, Zdenek↗

Emittance measurements of Space Shuttle Orbiter Reinforced Carbon-Carbon

The spectral and total normal emittance of the Reinforced Carbon-Carbon (RCC) used on Space Shuttle Orbiter nose-cap and wing leading edges has been measured at room temperature and at surface temperatures of 1200 to 2100 K. These measurements were made on virgin and two flown RCC samples. Room temperature directional emittance data were also obtained and were used to determine the total hemispherical emittance of RCC as a function of temperature. Results of the total normal emittance for the virgin samples showed good agreement with the current RCC emittance design curve; however, the data from the flown samples showed an increase in the emittance at high temperature possibly due to exposure from flight environments.

Caram, Jose M.↗

Arc-jet tests of coated carbon-carbon materials

The testing of coated carbon-carbon materials at high temperature in a nonequilibrium arc-driven environment is examined. Material specimens were exposed to high energy supersonic air exhausting from the NASA-Ames Research Center's 20-MW arc-jet facility. The materials were heated to required temperatures with arc-heated air for specified lengths of time. A total of 23 models were tested in two groups. In the first group of 19 samples, there were several samples that survived low test conditions and several more that survived intermediate test conditions that provided surface temperatures up to 3850 deg Rankine, but none survived when the surface temperature exceeded 4000 deg Rankine. The last four test samples with their higher surface temperatures did not fully survive either if the survival criterion is that the material must be reusable after the test.

Sheldahl, Robert E.↗

Partitioning of Nb, Mo, Ba, Ce, Pb, Th and U between immiscible carbonate and silicate liquids: Evaluating the effects of P2O5,F, and carbonate composition

Previously we have reported carbonate liq./silicate liq. partition coefficients (D) for a standard suite of trace elements (Nb, Mo, Ba, Ce, Pb, Th, and U) and Ra and Pa as well. In brief, we have found that immiscible liquid partitioning is a strong function of temperature. As the critical temperature of the carbonate-silicate solvus is approached, all partition coefficients approach unity. Additionally, for the overwhelming majority of the partitioning elements, InD is a linear function of 'ionic field strength,' z/r, where z is the charge of the partitioned cation and r is its ionic radius.

Jones, J. H.↗

Compilation of reinforced carbon-carbon transatlantic abort landing arc jet test results

This document consists of the entire test database generated to support the Reinforced Carbon-Carbon Transatlantic Abort Landing Study. RCC components used for orbiter nose cap and wing leading edge thermal protection were originally designed to have a multi-mission entry capability of 2800 F. Increased orbiter range capability required a predicted increase in excess of 3300 F. Three test series were conducted. Test series #1 used ENKA-based RCC specimens coated with silicon carbide, treated with tetraethyl orthosilicate, sealed with Type A surface enhancement, and tested at 3000-3400 F with surface pressure of 60-101 psf. Series #2 used ENKA- or AVTEX-based RCC, with and without silicon carbide, Type A or double Type AA surface enhancement, all impregnated with TEOS, and at temperatures from 1440-3350 F with pressures from 100-350 psf. Series #3 tested ENKA-based RCC, with and without silicon carbide coating. No specimens were treated with TEOS or sealed with Type A. Surface temperatures ranged from 2690-3440 F and pressures ranged from 313-400 psf. These combined test results provided the database for establishing RCC material single-mission-limit temperature and developing surface recession correlations used to predict mass loss for abort conditions.

Milhoan, James D.↗

Analysis of the Shuttle Orbiter reinforced carbon-carbon oxidation protection system

Reusable, oxidation-protected reinforced carbon-carbon (RCC) has been successfully flown on all Shuttle Orbiter flights. Thermal testing of the silicon carbide-coated RCC to determine its oxidation characteristics has been performed in convective (plasma Arc-Jet) heating facilities. Surface sealant mass loss was characterized as a function of temperature and pressure. High-temperature testing was performed to develop coating recession correlations for predicting performance at the over-temperature flight conditions associated with abort trajectories. Methods for using these test data to establish multi-mission re-use (i.e., mission life) and single mission limits are presented.

Williams, S. D.↗

Carbon-Carbon Heat Pipe Testing and Evaluation

This report discusses development and proof-of-concept testing of a new lightweight carbon-carbon (C-C) space radiator heat pipe developed under the NASA Civil Space Technology Initiative (CSTI) High Capacity Power Program. The heat pipe was filled with potassium working fluid and tested for 11 hours including startup from ambient temperature with the working fluid initially in the frozen state to near 700 K condenser temperature. Steady-state heat pipe input power during testing was facility limited to about 300 watts, representing about 50 percent of the design input power. Post test inspection showed the heat pipe to be in excellent condition after eight thermal cycles from ambient to steady-state operating temperature. Potential applications, ranging from small spacecraft heat rejection to aircraft and terrestrial uses, are discussed.

Juhasz, Albert J.↗

Fatigue characterization of advanced carbon-carbon composites

Response of quasi-isotropic laminates of SiC coated Carbon-Carbon (C/C) composites under flexural fatigue are investigated at room temperature. Virgin as well as mission cycled specimens are tested to study the effects of thermal and pressure cycling on the fatigue performance of C/C. Tests were conducted in three point bending with a stress ratio of 0.2 and frequency of 1 Hz. Fatigue strength of C/C has been found to be considerably high - approximately above 85 percent of the ultimate flexural strength. The fatigue strength appears to be decreasing with the increase in the number of mission cycling of the specimens. This lower strength with the mission cycled specimens is attributed to the loss of interfacial bond strength due to thermal and pressure cycling of the material. C/C is also found to be highly sensitive to the applied stress level during cyclic loading, and this sensitivity is observed to increase with the mission cycling. Weibull characterization on the fatigue data has been performed, and the wide scatter in the Weibull distribution is discussed. Fractured as well as untested specimens were C-scanned, and the progressive damage growth during fatigue is presented.

Mahfuz, Hassan↗

Composite heat pipe development status: Development of lightweight prototype carbon-carbon heat pipe with integral fins and metal foil liner

This report discusses development and proof-of-concept testing of a new lightweight carbon-carbon (C-C) space radiator heat pipe, carried out under the NASA Civil Space Technology Initiative (CSTI) High Capacity Power Program. The prototype heat pipe, equipped with a niobium-zirconium foil liner, was filled with potassium working fluid and tested for 11 hours, including startup from ambient temperature with the working fluid initially in the frozen state to near 700 K condenser temperature. Steady-state heat pipe input power during testing was facility limited to about 300 watts. Post test inspection showed the heat pipe to be in excellent condition after eight thermal cycles from ambient to steady-state operating temperature. Utilization of other liner materials and working fluids would greatly extend the spectrum of service temperatures for this technology, with potential applications ranging from small spacecraft heat rejection to aircraft and terrestrial uses.

Juhasz, Albert J.↗

Effect of the nonlinearity of the carbonate system on partial pressure of carbon dioxide in the oceans

Partial pressure of CO2 is a nonlinear function of several seawater properties. Due to the nonlinearity in this relationship, the partial pressure of a uniform ocean would be different from that of a nonuniform ocean with the same bulk seawater properties. Assuming uniformity of seawater properties at some temporal and spatial scales in carbon models leads to systematic errors in partial pressure of CO2. In this paper we evaluate the magnitude of these errors. We partition the Geochemical Ocean Sections Study and Transient Tracers in the Oceans data according to the horizontal structure of several box models from the literature. Our results suggest that assumption of uniformity at large scales leads to understanding of underestimation of global surface ocean partial pressure of CO2 by at least 3 - 12 microatm. Nonlinear effects also introduce systematic errors in the buffer factor estimated from bulk seawater properties. We find the standard deviation of partial pressure of CO2 to be an indicator of the magnitude of the nonlinear effects. We discuss the implications of these errors for some conclusions drawn from carbon models. Biogeochemical processes, such as mixing, gas exchange, or biological activity, influence the distribution of the seawater properties. A shift in spatial or temporal patterns of these processes can modify the nonuniformity of the seawater properties and thus alter the partial pressure of the surface waters, even if the mean intensities of the processes remain constant.

Trela, Piotr↗

Textural and Carbon Isotopic Analyses of Modern Carbonate Microbialites: Possible Ancient and Martian Analogs

Many modem and ancient carbonate deposits around the world have been recognized as microbial buildups or microbialites. Ancient microbialite structures have been divided into two basic categories based on their internal fabric or texture. They include stromatolites which have a predominantly laminated internal fabric and thrombolites which have an open-porous clotted fabric, that lacks laminae. The origin of these two basic microbial fabrics is still being debated in the literature. Understanding the origin and the various microorganisms involved in forming these modem fabrics is the key to the interpretation of similar fabrics in ancient and possibly Martian rocks. Therefore, detailed studies are needed on the microbiological makeup and origin of the fabrics in modem microbialites. Such studies may serve as analogs for ancient and Martian microbialites in the future. The purpose of this study is to examine the textures and carbon isotopic signatures of the following modem microbialites from the Bahamas: 1) a modem subtidal microbialite from Iguana Cay, Bahamas and 2) a modem microbial mat (stromatolite) from a hypersaline pond on Lee Stocking Island, Bahamas.

Thompson, Joel B.↗

Oxidation of Reinforced Carbon-Carbon Subjected to Hypervelocity Impact

This paper presents results from arc jet tests conducted at the NASA Johnson Space Center on reinforced carbon-carbon (RCC) samples subjected to hypervelocity impact. The RCC test specimens are representative of RCC components used on the Space Shuttle Orbiter. The arc jet testing established the oxidation characteristics of RCC when hypervelocity projectiles, simulating meteoroid/orbital debris, impact the RCC material. In addition to developing correlations for use in trajectory simulations, we discuss analytical modeling of the increased material oxidation in the impacted area using measured hole growth data. Entry flight simulations are useful in assessing the increased Space Shuttle RCC component degradation as a result of impact damage and the hot gas flow through an enlarging hole into the wing leading-edge cavity.

Curry, Donald M.↗