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At least 505 records · Page 28

Health Benefits of Particle Filtration

The evidence of health benefits of particle filtration in homes and commercial buildings is reviewed. Prior reviews of papers published before 2000 are summarized. The results of 16 more recent intervention studies are compiled and analyzed. Also, reviewed are four studies that modeled health benefits of using filtration to reduce indoor exposures to particles from outdoors. Prior reviews generally concluded that particle filtration is, at best, a source of small improvements in allergy and asthma health effects; however, many early studies had weak designs. A majority of recent intervention studies employed strong designs and more of these studies report statistically significant improvements in health symptoms or objective health outcomes, particularly for subjects with allergies or asthma. The percent age improvement in health outcomes is typically modest, for example, 7percent to 25percent. Delivery of filtered air to the breathing zone of sleeping allergic or asthmatic persons may be more consistently effective in improving health than room air filtration. Notable are two studies that report statistically significant improvements, with filtration, in markers that predict future adverse coronary events. From modeling, the largest potential benefits of indoor particle filtration may be reductions in morbidity and mortality from reducing indoor exposures to particles from outdoor air.

54 ENVIRONMENTAL SCIENCES↗

WE-G-BRD-07: Automated MR Image Standardization and Auto-Contouring Strategy for MRI-Based Adaptive Brachytherapy for Cervix Cancer

Purpose: MRI-based adaptive brachytherapy (ABT) is an emerging treatment modality for patients with gynecological tumors. However, MR image intensity non-uniformities (IINU) can vary from fraction to fraction, complicating image interpretation and auto-contouring accuracy. We demonstrate here an automated MR image standardization and auto-contouring strategy for MRI-based ABT of cervix cancer. Methods: MR image standardization consisted of: 1) IINU correction using the MNI N3 algorithm, 2) noise filtering using anisotropic diffusion, and 3) signal intensity normalization using the volumetric median. This post-processing chain was implemented as a series of custom Matlab and Java extensions in MIM (v6.4.5, MIM Software) and was applied to 3D T2 SPACE images of six patients undergoing MRI-based ABT at 3T. Coefficients of variation (CV=σ/µ) were calculated for both original and standardized images and compared using Mann-Whitney tests. Patient-specific cumulative MR atlases of bladder, rectum, and sigmoid contours were constructed throughout ABT, using original and standardized MR images from all previous ABT fractions. Auto-contouring was performed in MIM two ways: 1) best-match of one atlas image to the daily MR image, 2) multi-match of all previous fraction atlas images to the daily MR image. Dice’s Similarity Coefficients (DSCs) were calculated for auto-generated contours relative to reference contours for both original and standardized MR images and compared using Mann-Whitney tests. Results: Significant improvements in CV were detected following MR image standardization (p=0.0043), demonstrating an improvement in MR image uniformity. DSCs consistently increased for auto-contoured bladder, rectum, and sigmoid following MR image standardization, with the highest DSCs detected when the combination of MR image standardization and multi-match cumulative atlas-based auto-contouring was utilized. Conclusion: MR image standardization significantly improves MR image uniformity. The combination of MR image standardization and multi-match cumulative atlas-based auto-contouring produced the highest DSCs and is a promising strategy for MRI-based ABT for cervix cancer.

60 APPLIED LIFE SCIENCES↗

A Comparison of Maps and Power Spectra Determined from South Pole Telescope and Planck Data

We study the consistency of 150 GHz data from the South Pole Telescope (SPT) and 143 GHz data from the \textit{Planck} satellite over the 2540 $\text{deg}^2$ patch of sky covered by the SPT-SZ survey. We first visually compare the maps and find that the map residuals appear consistent with noise after we account for differences in angular resolution and filtering. To make a more quantitative comparison, we calculate (1) the cross-spectrum between two independent halves of SPT 150 GHz data, (2) the cross-spectrum between two independent halves of \textit{Planck} 143 GHz data, and (3) the cross-spectrum between SPT 150 GHz and \textit{Planck} 143 GHz data. We find the three cross-spectra are well-fit (PTE = 0.30) by the null hypothesis in which both experiments have measured the same sky map up to a single free parameter characterizing the relative calibration between the two. As a by-product of this analysis, we improve the calibration of SPT data by nearly an order of magnitude, from 2.6\% to 0.3\% in power; the best-fit power calibration factor relative to the most recent published SPT calibration is $1.0174 \pm 0.0033$. Finally, we compare all three cross-spectra to the full-sky \textit{Planck} $143 \times 143$ power spectrum and find a hint ($\sim$1.5$\sigma$) for differences in the power spectrum of the SPT-SZ footprint and the full-sky power spectrum, which we model and fit as a power law in the spectrum. The best-fit value of this tilt is consistent between the three cross-spectra in the SPT-SZ footprint, implying that the source of this tilt---assuming it is real---is a sample variance fluctuation in the SPT-SZ region relative to the full sky. Despite the precision of our tests, we find no evidence for systematic errors in either data set. The consistency of cosmological parameters derived from these datasets is discussed in a companion paper.

79 ASTRONOMY AND ASTROPHYSICS↗

Distance determination to eight galaxies using expanding photosphere method

Type IIP supernovae (SNe) are recognized as independent extragalactic distance indicators; however, keeping in mind the diverse nature of their observed properties as well as the availability of good quality data, more and newer events need to be tested for their applicability as reliable distance indicators. We use early photometric and spectroscopic data of eight Type IIP SNe to derive distances to their host galaxies by using the expanding photosphere method (EPM). For five of these, the EPM is applied for the first time. In this work, we improved EPM application by using SYNOW estimated velocities and by semi-deconvolving the broadband filter responses while deriving color temperatures and blackbody angular radii. We find that the derived EPM distances are consistent with that derived using other redshift-independent methods.

79 ASTRONOMY AND ASTROPHYSICS↗

Building 235-F Goldsim Fate And Transport Model

Savannah River National Laboratory (SRNL) personnel, at the request of Area Completion Projects (ACP), evaluated In-Situ Disposal (ISD) alternatives that are under consideration for deactivation and decommissioning (D&D) of Building 235-F and the Building 294-2F Sand Filter. SRNL personnel developed and used a GoldSim fate and transport model, which is consistent with Musall 2012, to evaluate relative to groundwater protection, ISD alternatives that involve either source removal and/or the grouting of portions or all of 235-F. This evaluation was conducted through the development and use of a Building 235-F GoldSim fate and transport model. The model simulates contaminant release from four 235-F process areas and the 294-2F Sand Filter. In addition, it simulates the fate and transport through the vadose zone, the Upper Three Runs (UTR) aquifer, and the Upper Three Runs (UTR) creek. The model is designed as a stochastic model, and as such it can provide both deterministic and stochastic (probabilistic) results. The results show that the median radium activity concentrations exceed the 5 ?Ci/L radium MCL at the edge of the building for all ISD alternatives after 10,000 years, except those with a sufficient amount of inventory removed. A very interesting result was that grouting was shown to basically have minimal effect on the radium activity concentration. During the first 1,000 years grouting may have some small positive benefit relative to radium, however after that it may have a slightly deleterious effect. The Pb-210 results, relative to its 0.06 ?Ci/L PRG, are essentially identical to the radium results, but the Pb-210 results exhibit a lesser degree of exceedance. In summary, some level of inventory removal will be required to ensure that groundwater standards are met.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Estimation of attitude sensor timetag biases

This paper presents an extended Kalman filter for estimating attitude sensor timing errors. Spacecraft attitude is determined by finding the mean rotation from a set of reference vectors in inertial space to the corresponding observed vectors in the body frame. Any timing errors in the observations can lead to attitude errors if either the spacecraft is rotating or the reference vectors themselves vary with time. The state vector here consists of the attitude quaternion, timetag biases, and, optionally, gyro drift rate biases. The filter models the timetags as random walk processes: their expectation values propagate as constants and white noise contributes to their covariance. Thus, this filter is applicable to cases where the true timing errors are constant or slowly varying. The observability of the state vector is studied first through an examination of the algebraic observability condition and then through several examples with simulated star tracker timing errors. The examples use both simulated and actual flight data from the Extreme Ultraviolet Explorer (EUVE). The flight data come from times when EUVE had a constant rotation rate, while the simulated data feature large angle attitude maneuvers. The tests include cases with timetag errors on one or two sensors, both constant and time-varying, and with and without gyro bias errors. Due to EUVE's sensor geometry, the observability of the state vector is severely limited when the spacecraft rotation rate is constant. In the absence of attitude maneuvers, the state elements are highly correlated, and the state estimate is unreliable. The estimates are particularly sensitive to filter mistuning in this case. The EUVE geometry, though, is a degenerate case having coplanar sensors and rotation vector. Observability is much improved and the filter performs well when the rate is either varying or noncoplanar with the sensors, as during a slew. Even with bad geometry and constant rates, if gyro biases are independently known, the timetag error for a single sensor can be accurately estimated as long as its boresight is not too close to the spacecraft rotation axis.

Sedlak, J.↗

Identifying spatiotemporal patterns in opioid vulnerability: investigating the links between disability, prescription opioids and opioid-related mortality

Background: The opioid crisis remains one of the most daunting and complex public health problems in the United States. This study investigates the national epidemic by analyzing vulnerability profiles of three key factors: opioid-related mortality rates, opioid prescription dispensing rates, and disability rank ordered rates. Methods: This study utilizes county level data, spanning the years 2014 through 2020, on the rates of opioid-related mortality, opioid prescription dispensing, and disability. To successfully estimate and predict trends in these opioid-related factors, we augment the Kalman Filter with a novel spatial component. To define opioid vulnerability profiles, we create heat maps of our filter’s predicted rates across the nation’s counties and identify the hotspots. In this context, hotspots are defined on a year-by-year basis as counties with rates in the top 5% nationally. Results: Our spatial Kalman filter demonstrates strong predictive performance. From 2014 to 2018, these predictions highlight consistent spatiotemporal patterns across all three factors, with Appalachia distinguished as the nation’s most vulnerable region. Starting in 2019 however, the dispensing rate profiles undergo a dramatic and chaotic shift. Conclusions: The initial primary drivers of opioid abuse in the Appalachian region were likely prescription opioids; however, it now appears that abuse is sustained by illegal drugs. Additionally, we find that the disabled subpopulation may be more at risk of opioid-related mortality than the general population. Public health initiatives must extend beyond controlling prescription practices to address the transition to and impact of illicit drug use.

60 APPLIED LIFE SCIENCES↗

Legacy Survey of Space and Time Data Preview 2: visit_table dataset type

We present Rubin Data Preview 2 (DP2), the second data preview from the NDF-DOE Vera C. Rubin Observatory. Data Preview 2 (DP2) comprises coadds, detection catalogs, and ancillary data products; and when fully released will also include single-epoch images and difference images. DP2 is derived from observations acquired by the LSST Science Camera (LSSTCam) on the Simonyi Survey Telescope at the Summit Facility on Cerro Pachón, Chile, primarily during the on-sky commissioning campaign between 2025-04-16 and 2025-09-21, supplemented by observations taken between 2025-10-25 and 2026-01-06 that overlap the commissioning footprint. The DP2 footprint comprises the Science Validation wide-area survey, five Deep Drilling Fields, and a number of targeted small-field regions, including Trifid and Lagoon, Prawn, M49, and New Horizons, all observed as part of the Rubin First Look campaign. Each field was imaged in up to six broad photometric bands, ugrizy, and coadded to produce deep imaging covering an estimated 3,000 deg2. The addition of single-visit-only areas expands the total DP2 footprint to an estimated 15,000 deg2, with coverage in at least one filter. The median per-visit PSF FWHM across the wide-area survey ranges from 1.17 arcsec in the z band to 1.26 arcsec in g and r bands. The deepest field, reaches estimated coadded 5σ depths of u=26 mag, g=26.8 mag, r=26.3 mag, i=26.1 mag, z=25.3 mag, y=23.9 mag. Based on a roughly five-month primary observing baseline and covering only part of the eventual LSST footprint, DP2's area, depth, and multiband coverage nonetheless support a broad range of early science investigations ahead of LSST Data Release This dataset is a subset of the full data release consisting of the visit_table dataset type. These are metadata, including dates and filters for every visit. This release contains 1 dataset of this type.

79 ASTRONOMY AND ASTROPHYSICS↗

The Fiber Optic System for the Advanced Topographic Laser Altimeter System (ATLAS) Instrument

The Advanced Topographic Laser Altimeter System (ATLAS) Instrument has been in integration and testing over the past 18 months in preparation for the Ice, Cloud and Land Elevation Satellite - 2 (ICESat-2) Mission, scheduled to launch in 2017. ICESat-2 is the follow on to ICESat which launched in 2003 and operated until 2009. ATLAS will measure the elevation of ice sheets, glaciers and sea ice or the "cryosphere" (as well as terrain) to provide data for assessing the earth's global climate changes. Where ICESat's instrument, the Geo-Science Laser Altimeter (GLAS) used a single beam measured with a 70 m spot on the ground and a distance between spots of 170 m, ATLAS will measure a spot size of 10 m with a spacing of 70 cm using six beams to measure terrain height changes as small as 4 mm. The ATLAS pulsed transmission system consists of two lasers operating at 532 nm with transmitter optics for beam steering, a diffractive optical element that splits the signal into 6 separate beams, receivers for start pulse detection and a wavelength tracking system. The optical receiver telescope system consists of optics that focus all six beams into optical fibers that feed a filter system that transmits the signal via fiber assemblies to the detectors. Also included on the instrument is a system that calibrates the alignment of the transmitted pulses to the receiver optics for precise signal capture. The larger electro optical subsystems for transmission, calibration, and signal receive, stay aligned and transmitting sufficiently due to the optical fiber system that links them together. The robust design of the fiber optic system, consisting of a variety of multi fiber arrays and simplex assemblies with multiple fiber core sizes and types, will enable the system to maintain consistent critical alignments for the entire life of the mission. Some of the development approaches used to meet the challenging optical system requirements for ATLAS are discussed here.

global climate changes↗

A Model-Driven Visualization Tool for Use with Model-Based Systems Engineering Projects

Model-Based Systems Engineering (MBSE) promotes increased consistency between a system's design and its design documentation through the use of an object-oriented system model. The creation of this system model facilitates data presentation by providing a mechanism from which information can be extracted by automated manipulation of model content. Existing MBSE tools enable model creation, but are often too complex for the unfamiliar model viewer to easily use. These tools do not yet provide many opportunities for easing into the development and use of a system model when system design documentation already exists. This study creates a Systems Modeling Language (SysML) Document Traceability Framework (SDTF) for integrating design documentation with a system model, and develops an Interactive Visualization Engine for SysML Tools (InVEST), that exports consistent, clear, and concise views of SysML model data. These exported views are each meaningful to a variety of project stakeholders with differing subjects of concern and depth of technical involvement. InVEST allows a model user to generate multiple views and reports from a MBSE model, including wiki pages and interactive visualizations of data. System data can also be filtered to present only the information relevant to the particular stakeholder, resulting in a view that is both consistent with the larger system model and other model views. Viewing the relationships between system artifacts and documentation, and filtering through data to see specialized views improves the value of the system as a whole, as data becomes information

relational databases↗

Rarefying Spectra of Whispering-Gallery-Mode Resonators

A method of cleaning the mode spectra of whispering-gallery-mode (WGM) optical resonators has been devised to make such resonators more suitable for use as narrow-band optical filters. The method applies, more specifically, to millimeter- sized whispering-gallery-mode optical resonators that are made of crystalline electro-optical materials and have ultrahigh values of the resonance quality factor (Q). The mode spectrum of such a resonator is typically dense, consisting of closely spaced families of modes; as such, the spectrum is not well suited for narrow-band filtering, in which there is a need for strong rejection of side modes. Cleaning as used here signifies rarefying the spectrum so that what remains consists mostly of a single desired family of modes or, at worst, a few mode families that are more widely spaced in frequency than are the mode families in the original, non-rarefied spectrum. The spectrum-cleaning method exploits the fact that various WGM mode families occupy various positions near the equator at the rim of a resonator disk. In this method, a damper in the form of a prism or other polished piece of material having an index of refraction greater than that of the resonator material is placed in contact with the rim of the resonator at such a position that the Qs of most or all of the undesired mode families are greatly reduced while the Q of the desired mode family is reduced by only a tolerably small amount. In an alternative method that has been considered, the mode spectrum would be cleaned through special design of the shape of the rim, but fabrication of the rim in a special shape is a complicated task. The advantage of the present method, relative to the alternative method, is that special shaping of the rim is not necessary and the damping prism can be emplaced after the resonator has been fabricated.

Savchenkov, Anatoliy↗

SU-C-BRC-04: Efficient Dose Calculation Algorithm for FFF IMRT with a Simplified Bivariate Gaussian Source Model

Purpose: To develop an efficient and accurate independent dose calculation algorithm with a simplified analytical source model for the quality assurance and safe delivery of Flattening Filter Free (FFF)-IMRT on an Elekta Versa HD. Methods: The source model consisted of a point source and a 2D bivariate Gaussian source, respectively modeling the primary photons and the combined effect of head scatter, monitor chamber backscatter and collimator exchange effect. The in-air fluence was firstly calculated by back-projecting the edges of beam defining devices onto the source plane and integrating the visible source distribution. The effect of the rounded MLC leaf end, tongue-and-groove and interleaf transmission was taken into account in the back-projection. The in-air fluence was then modified with a fourth degree polynomial modeling the cone-shaped dose distribution of FFF beams. Planar dose distribution was obtained by convolving the in-air fluence with a dose deposition kernel (DDK) consisting of the sum of three 2D Gaussian functions. The parameters of the source model and the DDK were commissioned using measured in-air output factors (Sc) and cross beam profiles, respectively. A novel method was used to eliminate the volume averaging effect of ion chambers in determining the DDK. Planar dose distributions of five head-and-neck FFF-IMRT plans were calculated and compared against measurements performed with a 2D diode array (MapCHECK™) to validate the accuracy of the algorithm. Results: The proposed source model predicted Sc for both 6MV and 10MV with an accuracy better than 0.1%. With a stringent gamma criterion (2%/2mm/local difference), the passing rate of the FFF-IMRT dose calculation was 97.2±2.6%. Conclusion: The removal of the flattening filter represents a simplification of the head structure which allows the use of a simpler source model for very accurate dose calculation. The proposed algorithm offers an effective way to ensure the safe delivery of FFF-IMRT.

60 APPLIED LIFE SCIENCES↗

A description of the Galactic Center excess in the Minimal Supersymmetric Standard Model

Observations with the Fermi Large Area Telescope (LAT) indicate an excess in gamma rays originating from the center of our Galaxy. A possible explanation for this excess is the annihilation of Dark Matter particles. We have investigated the annihilation of neutralinos as Dark Matter candidates within the phenomenological Minimal Supersymmetric Standard Model (pMSSM). An iterative particle filter approach was used to search for solutions within the pMSSM. We found solutions that are consistent with astroparticle physics and collider experiments, and provide a fit to the energy spectrum of the excess. The neutralino is a Bino/Higgsino or Bino/Wino/Higgsino mixture with a mass in the range 84–92 GeV or 87–97 GeV annihilating into W bosons. A third solutions is found for a neutralino of mass 174–187 GeV annihilating into top quarks. The best solutions yield a Dark Matter relic density 0.06<Ωh{sup 2}<0.13. These pMSSM solutions make clear forecasts for LHC, direct and indirect DM detection experiments. If the pMSSM explanation of the excess seen by Fermi-LAT is correct, a DM signal might be discovered soon.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

EXPLORING THE z = 3-4 MASSIVE GALAXY POPULATION WITH ZFOURGE: THE PREVALENCE OF DUSTY AND QUIESCENT GALAXIES

Our understanding of the redshift z > 3 galaxy population relies largely on samples selected using the popular ''dropout'' technique, typically consisting of UV-bright galaxies with blue colors and prominent Lyman breaks. As it is currently unknown if these galaxies are representative of the massive galaxy population, we here use the FOURSTAR Galaxy Evolution (ZFOURGE) survey to create a stellar mass-limited sample at z = 3-4. Uniquely, ZFOURGE uses deep near-infrared medium-bandwidth filters to derive accurate photometric redshifts and stellar population properties. The mass-complete sample consists of 57 galaxies with log M >10.6, reaching below M {sup *} at z = 3-4. On average, the massive z = 3-4 galaxies are extremely faint in the observed optical with median R{sub tot}{sup AB}=27.48±0.41 (rest-frame M {sub 1700} = –18.05 ± 0.37). They lie far below the UV luminosity-stellar mass relation for Lyman break galaxies and are about ∼100 × fainter at the same mass. The massive galaxies are red (R – K {sub s} {sub AB} = 3.9 ± 0.2; rest-frame UV-slope β = –0.2 ± 0.3) likely from dust or old stellar ages. We classify the galaxy spectral energy distributions by their rest-frame U–V and V–J colors and find a diverse population: 46{sub −6−17}{sup +6+10}% of the massive galaxies are quiescent, 40{sub −6−5}{sup +6+7}% are dusty star-forming galaxies, and only 14{sub −3−4}{sup +3+10}% resemble luminous blue star-forming Lyman break galaxies. This study clearly demonstrates an inherent diversity among massive galaxies at higher redshift than previously known. Furthermore, we uncover a reservoir of dusty star-forming galaxies with 4 × lower specific star-formation rates compared to submillimeter-selected starbursts at z > 3. With 5 × higher numbers, the dusty galaxies may represent a more typical mode of star formation compared to submillimeter-bright starbursts.

79 ASTRONOMY AND ASTROPHYSICS↗

A high-speed one-dimensional detector for time-resolved small -angle X-ray scattering : design and characterization.

A high-speed one-dimensional detector for time-resolved small-angle x-ray scattering has been designed and built for experiments at the Advanced Photon Source of Argonne National Laboratory. This detector is made from a 500-?m thick by 150-mm diameter ultra-high-purity n-type silicon wafer. The electrodes, which are a series of concentric rings that are deposited in the wafer, integrate the scattered x-rays over the azimuthal angle and, thereby, produce a one-dimensional detector. This design yields 128 rings, which allows parallel processing of the signal from each ring. The readout electronics consist of transimpedance front-end amplifiers, one for each ring, followed by active pulse-shaping filters. The amplifier signals are digitized using 12-bit analog-to-digital converters, one per ring, which operate at 20 MHz. The frame rate of the system is 271 kHz. Up to 220 - 1 scattering profiles may be stored on a random access memory chip and transferred to a data file at a rate of 16 x 103 profiles/sec. For X-ray energies between 3.5 and 13.2 keV the efficiency exceeds 80%. The resolving time of the electronics is 300 ns, which is sufficient to isolate electronically a single pulse of scattered x-rays when the synchrotron is operated in a hybrid or asymmetric fill pattern. Therefore, laser-pump/x-ray-probe experiments can be performed without a mechanical shutter. Examples of time-resolved speckle and the kinetics of the formation of sodium chloride particles are presented. This detector is capable of acquiring small-angle x-ray scattering profiles over multiple time scales, which are needed to characterize many chemical, physical, and biological processes. In addition, this detector may be tested and calibrated before experimental runs, without access to an intense beam of x-rays, with alpha particles from a radioactive source such as 241Am.

43 PARTICLE ACCELERATORS↗

SU-F-R-40: Robustness Test of Computed Tomography Textures of Lung Tissues to Varying Scanning Protocols Using a Realistic Phantom Environment

Purpose: The reliability of computed tomography (CT) textures is an important element of radiomics analysis. This study investigates the dependency of lung CT textures on different breathing phases and changes in CT image acquisition protocols in a realistic phantom setting. Methods: We investigated 11 CT texture features for radiation-induced lung disease from 3 categories (first-order, grey level co-ocurrence matrix (GLCM), and Law’s filter). A biomechanical swine lung phantom was scanned at two breathing phases (inhale/exhale) and two scanning protocols set for PET/CT and diagnostic CT scanning. Lung volumes acquired from the CT images were divided into 2-dimensional sub-regions with a grid spacing of 31 mm. The distribution of the evaluated texture features from these sub-regions were compared between the two scanning protocols and two breathing phases. The significance of each factor on feature values were tested at 95% significance level using analysis of covariance (ANCOVA) model with interaction terms included. Robustness of a feature to a scanning factor was defined as non-significant dependence on the factor. Results: Three GLCM textures (variance, sum entropy, difference entropy) were robust to breathing changes. Two GLCM (variance, sum entropy) and 3 Law’s filter textures (S5L5, E5L5, W5L5) were robust to scanner changes. Moreover, the two GLCM textures (variance, sum entropy) were consistent across all 4 scanning conditions. First-order features, especially Hounsfield unit intensity features, presented the most drastic variation up to 39%. Conclusion: Amongst the studied features, GLCM and Law’s filter texture features were more robust than first-order features. However, the majority of the features were modified by either breathing phase or scanner changes, suggesting a need for calibration when retrospectively comparing scans obtained at different conditions. Further investigation is necessary to identify the sensitivity of individual image acquisition parameters.

60 APPLIED LIFE SCIENCES↗

Secondary Pollutants from Ozone Reaction with Ventilation Filters and Degradation of Filter Media Additives

Prior research suggests that chemical processes taking place on the surface of particle filters employed in buildings may lead to the formation of harmful secondary byproducts. We investigated ozone reactions with fiberglass, polyester, cotton/polyester and polyolefin filter media, as well as hydrolysis of filter media additives. Studies were carried out on unused media, and on filters that were installed for 3 months in buildings at two different locations in the San Francisco Bay Area. Specimens from each filter media were exposed to {approx}150 ppbv ozone in a flow tube under a constant flow of dry or humidified air (50percent RH). Ozone breakthrough was recorded for each sample over periods of {approx}1000 min; the ozone uptake rate was calculated for an initial transient period and for steady-state conditions. While ozone uptake was observed in all cases, we did not observe significant differences in the uptake rate and capacity for the various types of filter media tested. Most experiments were performed at an airflow rate of 1.3 L/min (face velocity = 0.013 m/s), and a few tests were also run at higher rates (8 to 10 L/min). Formaldehyde and acetaldehyde, two oxidation byproducts, were quantified downstream of each sample. Those aldehydes (m/z 31 and 45) and other volatile byproducts (m/z 57, 59, 61 and 101) were also detected in real-time using Proton-Transfer Reaction - Mass Spectrometry (PTR-MS). Low-ppbv byproduct emissions were consistently higher under humidified air than under dry conditions, and were higher when the filters were loaded with particles, as compared with unused filters. No significant differences were observed when ozone reacted over various types of filter media. Fiberglass filters heavily coated with impaction oil (tackifier) showed higher formaldehyde emissions than other samples. Those emissions were particularly high in the case of used filters, and were observed even in the absence of ozone, suggesting that hydrolysis of additives, rather than ozonolysis, is the main formaldehyde source in those filters. Emission rates of formaldehyde and acetaldehyde were not found to be large enough to substantially increase indoor concentrations in typical building scenarios. Nevertheless, ozone reactions on HVAC filters cannot be ignored as a source of low levels of indoor irritants.

54 ENVIRONMENTAL SCIENCES↗

Radiological Monitoring of Waste Treatment Plant

Scheduled waste in West Malaysia is handled by Concession Company and is stored and then is incinerated. It is known that incineration process may result in naturally occurring radioactive materials (NORM) to be concentrated. In this study we have measured three samples consist of by-product from the operation process such as slag, filter cake and fly ash. Other various environmental media such as air, surface water, groundwater and soil within and around the plant have also been analysed for their radioactivity levels. The concentration of Ra-226, Ac-228 and K-40 in slag are 0.062 Bq/g, 0.016 Bq/g and 0.19 Bq/g respectively. The total activity (Ra{sub eq}) in slag is 99.5 Bq/kg. The concentration in fly ash is 0.032 Bq/g, 0.16 Bq/g and 0.34 Bq/g for Ra-226, Ac-228 and K-40 respectively resulting in Raeq of 287.0 Bq/kg. For filter cake, the concentration is 0.13 Bq/g, 0.031 Bq/g and 0.33 Bq/g for Ra-226, Ac-228 and K-40 respectively resulting in Raeq of 199.7 Bq/kg. The external radiation level ranges from 0.08 {mu}Sv/h (Administrative building) to 0.35 {mu}Sv/h (TENORM storage area). The concentration level of radon and thoron progeny varies from 0.0001 to 0.0016 WL and 0.0006 WL to 0.002 WL respectively. For soil samples, the activity ranges from 0.11 Bq/g to 0.29 Bq/g, 0.06 Bq/g to 0.18 Bq/g and 0.065 Bq/g to 0.38 Bq/g for Ra-226, Ac-228 and K-40 respectively. While activity in water, except for a trace of K-40, it is non-detectable.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗