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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 505 records · Page 28

Slab reformer

Slab-shaped high efficiency catalytic reformer configurations particularly useful for generation of fuels to be used in fuel cell based generation systems. A plurality of structures forming a generally rectangular peripheral envelope are spaced about one another to form annular regions, an interior annular region containing a catalytic bed and being regeneratively heated on one side by a hot combustion gas and on the other side by the gaseous products of the reformation. An integrally mounted combustor is cooled by impingement of incoming oxidant.

Spurrier, Francis R.↗

Update on ASME AG-1 and Revision of the DOE Nuclear Air Cleaning Handbook - 20536

The American Society of Mechanical Engineers AG-1 Code on Nuclear Air and Gas Treatment is updated every two years. This paper provides an overview of issues being discussed within AG-1 committee meetings and revisions that will be included in the next version of the code. Additional information is provided on issues being discussed ranging from media velocity limits, control of airflow using actual versus and standard cubic feet per minute. Navigation and identification of applicable high-efficiency particulate air (HEPA) filter code sections can be confusing for those unfamiliar with AG-1. A general reorganization of filtration code sections clarifies geometry, flow, and performance envelopes for nuclear grade HEPA filters. The initial step consists of establishment of Section FN covering qualification of conventional, ceramic, metal, and high strength fibrous glass media. Future filter sections are currently expected to be characterized by geometry and flow direction (axial vs. radial). The Department of Energy's (DOE) Nuclear Air Cleaning Handbook (NACH) is also undergoing revision. An update on the status of that effort, along with issues and changes being considered. The original charter of the AG-1 Code was specific to commercial nuclear power plants, and to safety-related air cleaning systems. This has evolved over the years to include normal non-safety ventilation systems and process gas systems. Corollary guidance for DOE facilities has been available in several editions of the Nuclear Air Cleaning Handbook, starting with ORNL-NSIC 65. The latest edition of the Handbook, 2003, is undergoing revision and modifications. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Estimating the Rebound Effect of the U.S. Road Freight Transport

The United States (U.S.) road freight sector has continued to grow over recent decades. Growth in road freight could result in more fuel consumption and hence increased greenhouse gas emissions. Policymakers have attempted to manage the growth of energy usage through improved fuel economy based on technological advances. However, such improvements may not lead to anticipated goals because of the rebound effect, where improvements in energy efficiency trigger more travel and energy consumption that offsets energy savings. Thus, this study aims to determine the potential rebound effect from improved energy efficiency in the U.S. road freight sector. Eight fuel cost models are applied and asymmetric price response is incorporated in estimating the U.S. road freight sector’s rebound effect from 1980 to 2016. In addition, a recently developed data envelopment analysis is applied to determine the annual rebound effect in the road freight sector. The results suggest that, after accounting for the asymmetric price response, the average rebound effect of the U.S. road freight sector ranges from 6.9% to 8.8%, a level considerably less than that found for several industrialized countries and emerging economies. However, a considerable increase in the rebound effect has been seen in more recent years. Here, the findings suggest that overlooking the rebound effect in environmental policies could impede the goal of reducing total energy consumption and accompanying emissions. Policymakers should incorporate the rebound effect from efficiency enhancement in policy development and utilize some potential programs to reduce the adverse influence of rebound effect in related policies.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Contributing to Net Zero Building: High Energy Efficient EIFS Wall Systems

The team led by Dow Corning collaborated to increase the thermal performance of exterior insulation and finishing systems (EIFS) to reach R-40 performance meeting the needs for high efficiency insulated walls. Additionally, the project helped remove barriers to using EIFS on retrofit commercial buildings desiring high insulated walls. The three wall systems developed within the scope of this project provide the thermal performance of R-24 to R-40 by incorporating vacuum insulation panels (VIPs) into an expanded polystyrene (EPS) encapsulated vacuum insulated sandwich element (VISE). The VISE was incorporated into an EIFS as pre-engineered insulation boards. The VISE is installed using typical EIFS details and network of trained installers.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Application of reference-free natural background–oriented schlieren photography for visualizing leakage sites in building walls

Air leakage in buildings can cause health and comfort concerns for occupants and can contribute to mold growth on building materials, or in extreme conditions, rot of building materials. Unwanted air leakage through the building envelope also contributes to approximately 4 quadrillion Btu (1172 TWh) of energy consumption per year in the building sector in the United States. Locating and sealing leakage sites can improve the energy efficiency, comfort, air quality, and moisture durability of the building stock. Typical methods of finding leakage sites, such as infrared imaging and smoke tracing, rely on concurrent blower door operation, which can also measure the total leakage rate of the building. Smoke tracing can be disruptive to occupants, and infrared imaging and smoke tracing cannot measure the contribution of individual leaks to prioritize sealing efforts. Here, an optical fluid flow imaging technique, reference-free natural background–oriented schlieren imaging, was adapted to visualize air exfiltration. This is the first step in developing a method to noninvasively locate and measure exfiltration or infiltration sites so that sealing efforts can be prioritized. Experimental results of this technique are presented, demonstrating the method's applicability to visualizing exfiltration through three common building claddings in an outdoor environment. Key variables impacting the performance of this technique when applied to building leakage are also discussed.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Rapidly evolving and luminous transients from Pan-STARRS1

In the past decade, several rapidly evolving transients have been discovered whose timescales and luminosities are not easily explained by traditional supernovae (SNe) models. The sample size of these objects has remained small due, at least in part, to the challenges of detecting short timescale transients with traditional survey cadences. Here we present the results from a search within the Pan-STARRS1 Medium Deep Survey (PS1-MDS) for rapidly evolving and luminous transients. We identify 10 new transients with a time above half-maximum (t {sub 1/2}) of less than 12 days and –16.5 > M > –20 mag. This increases the number of known events in this region of SN phase space by roughly a factor of three. The median redshift of the PS1-MDS sample is z = 0.275 and they all exploded in star-forming galaxies. In general, the transients possess faster rise than decline timescale and blue colors at maximum light (g {sub P1} – r {sub P1} ≲ –0.2). Best-fit blackbodies reveal photospheric temperatures/radii that expand/cool with time and explosion spectra taken near maximum light are dominated by a blue continuum, consistent with a hot, optically thick, ejecta. We find it difficult to reconcile the short timescale, high peak luminosity (L > 10{sup 43} erg s{sup –1}), and lack of UV line blanketing observed in many of these transients with an explosion powered mainly by the radioactive decay of {sup 56}Ni. Rather, we find that many are consistent with either (1) cooling envelope emission from the explosion of a star with a low-mass extended envelope that ejected very little (<0.03 M {sub ☉}) radioactive material, or (2) a shock breakout within a dense, optically thick, wind surrounding the progenitor star. After calculating the detection efficiency for objects with rapid timescales in the PS1-MDS we find a volumetric rate of 4800-8000 events yr{sup –1} Gpc{sup –3} (4%-7% of the core-collapse SN rate at z = 0.2).

79 ASTRONOMY AND ASTROPHYSICS↗

Novel PCM Integration with Electrical Heat Pump for Demand Response

In this paper, we examine the potential for using phase change material (PCM) as a thermal storage medium for improving the efficiency as well as enabling grid-responsive control of heat pump (HP) systems. Previous research in PCM integration in buildings has primarily been focused on integration with building envelopes. An objective of our research is to design a novel and practical PCM integration with existing HP systems. High-fidelity models for building, HP and PCM are developed to facilitate the model-based predictive control (MPC) design. To optimize the operation of HP and PCM, we introduce an optimization problem considering various constraints for both comfort and hardware constraints. We include experimental results in which a house fleet are optimized to minimize their power consumption or electricity cost. We numerically demonstrate the designs potential for reducing power consumption or electricity cost by 13% or 19%, respectively.

Dong, Jin↗

A New Generation of Building Insulation by Foaming Polymer Blend Materials with CO 2

Advanced thermal insulation is among the most effective technologies in transforming our nation’s energy system and contributing to DOE’s stated goal of 50% less building energy consumption by 2030. The installation of an advanced thermal insulation would prevent energy waste without the need for any maintenance, and ISTN conservatively estimates that the commercialization of such a new technology would contribute to annual U.S. energy savings of 0.361 Quads and $8 billion in annual economic savings. The key challenge to improving building insulation is to maintain and surpass the industry standard of R-5 per inch insulation value in a cost-competitive manner. Improvements in R-value without cost-efficiency are not likely to impact the market given the cost-sensitive nature of the construction industry (insulation is already the lowest-cost component of the building envelope). However, significantly higher insulating value at competitive costs is extremely appealing to the market given the greater potential to save on energy consumption and costs over the long-term. Thus, our goal is to develop a super-thermal insulation with 50% greater insulation value (R-9 to R-10 per inch) and manufacturing costs that are equal on a per-R-value basis (< $0.70/ft 2 ).

36 MATERIALS SCIENCE↗

Residential Slab Component Calculations

Modern residential building energy codes provide a component tradeoff mechanism by which builders can trade reductions in the efficiency of some building components in trade for corresponding improvement in other components. One common tradeoff approach is based on maintaining a building "UA value," which represents the building envelope's overall thermal conductance. The building UA is the sum of individual component UA values, each of which is calculated as the product of the component's U-factor and area. Current codes, however, provide little guidance on including slab-on-grade components in the overall UA calculation. This brief provides information on calculating effective slab UA values and provides recommended text for building codes.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

The standard 20 AH cell, a status report

Progress of four contractors in producing standard 20 AH nickel-cadmium cells meeting a capacity requirement of 24 + or - 2 AH and an envelope requirement listed in NASA/GSFC specification S-711-17 is reported. Among the requirements were 10 burn in cycles 24 C, 0 C, and 35 C capacity tests, charge efficiency tests and precharge verification tests.

Halpert, G.↗

The design of an ultra-low sidelobe offset-fed 1.22m antenna for use in the broadcasting satellite service

A feed design and reflector geometry were determined for an ultra low sidelobe offset fed 1.22 meter antenna suitable for use in the 12 GHz broadcasting satellite service. Arbitrary constraints used to evaluate the relative merits of the feed horns and range of f/D geometries are: minimum efficiency of 55 percent, -30 dB first sidelobe level (relative to on axis gain), a 0 dBi plateau beyond the near in sidelobe region, and a Chebyshev polynomial based envelope (borrowed from filter theory) for the region from the -3 dB beamwidth points to the 0 dBi plateau region. This envelope is extremely stringent but the results of this research effort indicate that two steps of corrugated feed and a cluster array of small 1 lambda horns do meet the constraints. A set of performance specifications and a mechanical design suitable for a consumer oriented market in the broadcasting satellite service was developed. Costs for production quantities of 10,000 units/yr. are estimated to be around $150.

Janky, J. M.↗

Chirped arrays of diode lasers for supermode control

Nonuniform structures of phase-locked diode lasers, which make it possible to discriminate efficiently against all the higher order array supermodes (lateral modes) are proposed. In these nonuniform arrays, the effective mode index in each channel varies across the array. Consequently, the envelopes of the various supermodes, including the highest order one, differ significantly from each other. Thus, by proper tailoring of the gain distribution across the array, one can conveniently select the fundamental supermode. Such fundamental supermode oscillation is essential in order to obtain single lobe, diffraction limited beams and minimal spectal spread from phase-locked laser arrays.

Kapon, E.↗

Durability Characterization of Low Ice Adhesion and Impact Resistance Coatings

Glaze, rime and mixed icing conditions can cause significant variation in aerodynamic performance, fuel efficiency, and flight safety. For commercial aircraft, active icing mitigation strategies are utilized to enable safe flight within icing conditions according to the FAR Part 25/29 Appendix C icing envelope. For general aviation and unmanned aerial vehicles that cannot support active anti-icing technologies, avoidance is the only recourse. Passive approaches have been investigated to reduce weight and energy consumption for active systems and to expand the operational envelope for smaller aircraft. Coatings are one passive method to reduce or mitigate ice accretion on frontal surfaces of commercial aircraft with the greatest region of interest being wing leading edges. Aircraft wing leading edges represent an extreme environment. Durability must be considered for any material to be applied as a coating in this area. Currently, there are no specifications regarding coating durability of a low ice adhesion material applied on the wing leading edge. Therefore, a reasonable starting point is to use the durability specifications put forth for an aircraft external coating. Besides the tests called out in these specifications, others were included such as Taber abrasion to simulate wear and erosion. Beyond durability, performance metrics with regards to adhesion strength of accreted in-flight (i.e., impact) icing are central to determine coating usefulness. Determination of this property though is particularly challenging and only a few facilities have the capability to quantify this. An instrument at NASA Langley Research Center [Adverse Environment Rotary Test Stand Jr., (AERTS Jr.)], based on the AERTS system at The Pennsylvania State University, allows for screening numerous coatings subjected to the icing environment. To establish a benchmark for comparison with research coatings, a state-of-the-art (SOA) commercial aircraft coating was subjected to an array of salient durability and performance experiments. The same tests were conducted using a baseline epoxy (BE) resin formulation that demonstrated some initial promising results for comparison. Results from this initial screening will be discussed herein.

Miranda L Beaudry↗

HACA's Heritage: A Free‐Radical Pathway to Phenanthrene in Circumstellar Envelopes of Asymptotic Giant Branch Stars

Abstract The hydrogen‐abstraction/acetylene‐addition (HACA) mechanism has been central for the last decades in attempting to rationalize the formation of polycyclic aromatic hydrocarbons (PAHs) as detected in carbonaceous meteorites such as in Murchison. Nevertheless, the basic reaction mechanisms leading to the formation of even the simplest tricyclic PAHs like anthracene and phenanthrene are still elusive. Here, by exploring the previously unknown chemistry of the ortho ‐biphenylyl radical with acetylene, we deliver compelling evidence on the efficient synthesis of phenanthrene in carbon‐rich circumstellar environments. However, the lack of formation of the anthracene isomer implies that HACA alone cannot be responsible for the formation of PAHs in extreme environments. Considering the overall picture, alternative pathways such as vinylacetylene‐mediated reactions are required to play a crucial role in the synthesis of complex PAHs in circumstellar envelopes of dying carbon‐rich stars.

Yang, Tao↗

HACA's Heritage: A Free-Radical Pathway to Phenanthrene in Circumstellar Envelopes of Asymptotic Giant Branch Stars

The hydrogen-abstraction/acetylene-addition (HACA) mechanism has been central for the last decades in attempting to rationalize the formation of polycyclic aromatic hydrocarbons (PAHs) as detected in carbonaceous meteorites such as in Murchison. Nevertheless, the basic reaction mechanisms leading to the formation of even the simplest tricyclic PAHs like anthracene and phenanthrene are still elusive. By exploring the previously unknown chemistry of the ortho -biphenylyl radical with acetylene, we deliver compelling evidence on the efficient synthesis of phenanthrene in carbon-rich circumstellar environments. However, the lack of formation of the anthracene isomer implies that HACA alone cannot be responsible for the formation of PAHs in extreme environments. Considering the overall picture, alternative pathways such as vinylacetylene-mediated reactions are required to play a crucial role in the synthesis of complex PAHs in circumstellar envelopes of dying carbon-rich stars.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A simplified approach to uncertainty quantification for orbits in impulsive deflection scenarios

For the majority of near-Earth Asteroid (NEA) impact scenarios, optimal deflection strategies use a massive impactor or a nuclear explosive, either of which produce an impulsive change to the orbit of the object. However, uncertainties regarding the object composition and the efficiency of the deflection event lead to a non-negligible uncertainty in the deflection delta-velocity. Propagating this uncertainty through the resulting orbit will create a positional uncertainty envelope at the original impact epoch. In this work, we calculate a simplified analytic evolution for impulsively deflected NEAs and perform a full propagation of uncertainties that is nonlinear in the deflection delta-velocity vector. This provides an understanding of both the optimal deflection velocities needed for a given scenario, as well as the resulting positional uncertainty and corresponding residual impact probability. Confidence of a successful deflection attempt as a function of launch opportunities is also discussed for a specific case.

79 ASTRONOMY AND ASTROPHYSICS↗

Histidine 375 Modulates CD4 Binding in HIV-1 CRF01_AE Envelope Glycoproteins

The envelope glycoproteins (Envs) from human immunodeficiency virus type 1 (HIV-1) mediate viral entry. The binding of the HIV-1 gp120 glycoprotein to CD4 triggers conformational changes in gp120 that allow high-affinity binding to its coreceptors. In contrast to all other Envs from the same phylogenetic group, M, which possess a serine (S) at position 375, those from CRF01_AE strains possess a histidine (H) at this location. This residue is part of the Phe43 cavity, where residue 43 of CD4 (a phenylalanine) engages with gp120. Here we evaluated the functional consequences of replacing this residue in two CRF01_AE Envs (CM244 and 92TH023) by a serine. We observed that reversion of amino acid 375 to a serine (H375S) resulted in a loss of functionality of both CRF01_AE Envs as measured by a dramatic loss in infectivity and ability to mediate cell-to-cell fusion. While no effects on processing or trimer stability of these variants were observed, decreased functionality could be linked to a major defect in CD4 binding induced by the replacement of H375 by a serine. Importantly, mutations of residues 61 (layer 1), 105 and 108 (layer 2), and 474 to 476 (layer 3) of the CRF01_AE gp120 inner domain layers to the consensus residues present in group M restored CD4 binding and wild-type levels of infectivity and cell-to-cell fusion. These results suggest a functional coevolution between the Phe43 cavity and the gp120 inner domain layers. Altogether, our observations describe the functional importance of amino acid 375H in CRF01_AE envelopes. IMPORTANCE A highly conserved serine located at position 375 in group M is replaced by a histidine in CRF01_AE Envs. Here we show that H375 is required for efficient CRF01_AE Env binding to CD4. Furthermore, this work suggests that specific residues of the gp120 inner domain layers have coevolved with H375 in order to maintain its ability to mediate viral entry.

59 BASIC BIOLOGICAL SCIENCES↗

Information Management Workflow and Tools Enabling Multiscale Modeling Within ICME Paradigm

With the increased emphasis on reducing the cost and time to market of new materials, the need for analytical tools that enable the virtual design and optimization of materials throughout their processing - internal structure - property - performance envelope, along with the capturing and storing of the associated material and model information across its lifecycle, has become critical. This need is also fueled by the demands for higher efficiency in material testing; consistency, quality and traceability of data; product design; engineering analysis; as well as control of access to proprietary or sensitive information. Fortunately, material information management systems and physics-based multiscale modeling methods have kept pace with the growing user demands. Herein, recent efforts to establish workflow for and demonstrate a unique set of web application tools for linking NASA GRC's Integrated Computational Materials Engineering (ICME) Granta MI database schema and NASA GRC's Integrated multiscale Micromechanics Analysis Code (ImMAC) software toolset are presented. The goal is to enable seamless coupling between both test data and simulation data, which is captured and tracked automatically within Granta MI®, with full model pedigree information. These tools, and this type of linkage, are foundational to realizing the full potential of ICME, in which materials processing, microstructure, properties, and performance are coupled to enable application-driven design and optimization of materials and structures.

Materials Engineering↗