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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 505 records · Page 28
All sourcesNASA NTRSDOE OSTI
DOE OSTI2010

Single-well experimental design for studying residual trapping of superciritcal carbon dioxide

The objective of our research is to design a single-well injection-withdrawal test to evaluate residual phase trapping at potential CO{sub 2} geological storage sites. Given the significant depths targeted for CO{sub 2} storage and the resulting high costs associated with drilling to those depths, it is attractive to develop a single-well test that can provide data to assess reservoir properties and reduce uncertainties in the appraisal phase of site investigation. The main challenges in a single-well test design include (1) difficulty in quantifying the amount of CO{sub 2} that has dissolved into brine or migrated away from the borehole; (2) non-uniqueness and uncertainty in the estimate of the residual gas saturation (S{sub gr}) due to correlations among various parameters; and (3) the potential biased S{sub gr} estimate due to unaccounted heterogeneity of the geological medium. To address each of these challenges, we propose (1) to use a physical-based model to simulation test sequence and inverse modeling to analyze data information content and to quantify uncertainty; (2) to jointly use multiple data types generated from different kinds of tests to constrain the Sgr estimate; and (3) to reduce the sensitivity of the designed tests to geological heterogeneity by conducting the same test sequence in both a water-saturated system and a system with residual gas saturation. To perform the design calculation, we build a synthetic model and conduct a formal analysis for sensitivity and uncertain quantification. Both parametric uncertainty and geological uncertainty are considered in the analysis. Results show (1) uncertainty in the estimation of Sgr can be reduced by jointly using multiple data types and repeated tests; and (2) geological uncertainty is essential and needs to be accounted for in the estimation of S{sub gr} and its uncertainty. The proposed methodology is applied to the design of a CO{sub 2} injection test at CO2CRC's Otway Project Site, Victoria, Australia.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2019

Ultra-High Resolution Elemental/Isotopic Mass Spectrometry (m/?m> 1,000,000): Coupling of the Liquid Sampling-Atmospheric Pressure Glow Discharge with an Orbitrap Mass Spectrometer for Applications in Biological Chemistry and Environmental Analysis

Many fundamental questions of astrophysics, biochemistry, and geology rely on the ability to accurately and precisely measure the mass and abundance of isotopes. Taken a step further, the capacity to perform such measurements on intact molecules provides insights into processes in diverse biological systems. Described here is the coupling of a combined atomic and molecular (CAM) ionization source, the liquid sampling-atmospheric pressure glow discharge (LS-APGD) microplasma, with a commercially available ThermoScientific Fusion Lumos mass spectrometer. Demonstrated for the first time is the ionization and isotopically-resolved fingerprinting of a long-postulated, but never mass-spectrometrically observed, bi-metallic complex Hg:Se-cysteine. Such a complex has been implicated as having a role in observations of Hg detoxification by selenoproteins/amino acids. Demonstrated as well is the ability to mass spectrometrically-resolve the geochronologically important isobaric 87Sr and 87Rb species (?m ~ 0.3 mDa, mass resolution m/?m ? 1,700,000). The mass difference in this case reflects the beta-decay of the 87Rb to the stable Sr isotope. These two demonstrations highlight what may be a significant change in bioinorganic and atomic mass spectrometry, with impact expected across a broad spectrum of the physical, biological and geological sciences.

Hoegg, Edward D.↗
DOE OSTI2011

Predictive Models of CO 2 Sequestration Dynamics Based on Multiscale Experiments and Theoretical Analysis

CO 2 sequestration operations in deep subsurface geologic formations involve complex multiphase interactions that are not fully understood. This research project was aimed at developing such an understanding with focus on the detailed pore-scale physics and the development of a framework to translate the pore-scale physics to the Darcy and larger scales.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1972

Geological material discrimination from Nimbus satellite data

An analysis was made of Nimbus satellite data to determine its suitability in determining the physical properties of surface materials. Attempts were also made to use these data in developing analytical techniques for handling data from other earth resources and meteorological satellites.

Pohn, H. A.↗
NASA NTRS1991

Mars Elysium Basin - Geologic/volumetric analysis of a young lake and exobiologic implications

Geologic, physiographic, and topographic data on the Elysium Basin on the Martial lowland plains are used to determine the former volume of water in the basin and the sources of this water. The maximum extent of the paleolake was estimated to be about 2,000,000 sq km, with a water volume of 850,000 cu km or more, supplied to the basin from many sources in the highlands via inflow channels. The climatic and biological implications that the Elysium-Basin sea or lake might have had are discussed.

Scott, D. H.↗
DOE OSTI2013

3D characterization of the Astor Pass geothermal system, Nevada

The Astor Pass geothermal system resides in the northwestern part of the Pyramid Lake Paiute Reservation, on the margins of the Basin and Range and Walker Lane tectonic provinces in northwestern Nevada. Seismic reflection interpretation, detailed analysis of well cuttings, stress field analysis, and construction of a 3D geologic model have been used in the characterization of the stratigraphic and structural framework of the geothermal area. The area is primarily comprised of middle Miocene Pyramid sequence volcanic and sedimentary rocks, nonconformably overlying Mesozoic metamorphic and granitic rocks. Wells drilled at Astor Pass show a ~1 km thick section of highly transmissive Miocene volcanic reservoir with temperatures of ~95°C. Seismic reflection interpretation confirms a high fault density in the geothermal area, with many possible fluid pathways penetrating into the relatively impermeable Mesozoic basement. Stress field analysis using borehole breakout data reveals a complex transtensional faulting regime with a regionally consistent west-northwest-trending least principal stress direction. Considering possible strike-slip and normal stress regimes, the stress data were utilized in a slip and dilation tendency analysis of the fault model, which suggests two promising fault areas controlling upwelling geothermal fluids. Both of these fault intersection areas show positive attributes for controlling geothermal fluids, but hydrologic tests show the ~1 km thick volcanic section is highly transmissive. Thus, focused upwellings along discrete fault conduits may be confined to the Mesozoic basement before fluids diffuse into the Miocene volcanic reservoir above. This large diffuse reservoir in the faulted Miocene volcanic rocks is capable of sustaining high pump rates. Understanding this type of system may be helpful in examining large, permeable reservoirs in deep sedimentary basins of the eastern Basin and Range and the highly fractured volcanic geothermal reservoirs in the Snake River Plain.

15 GEOTHERMAL ENERGY↗
DOE OSTI2015

On the development of the quantitative texture analysis and its application in solving problems of the Earth sciences

A history of texture analysis (TA) evolution is shown, beginning from the first experimental and theoretical attempts to find and characterize preferred orientations of crystal lattices of grains in real polycrystalline samples. Stages of formation of TA theoretical apparatus, its basic elements, and also application of its capabilities for quantitatively describing anisotropic properties of textured samples are discussed. Attention is also paid to the limitations and difficulties associated with the analysis. The application of the quantitative TA apparatus is demonstrated by example describing elastic properties of textured materials up to multiphase samples containing pores and cracks. A wide scope of TA includes the analysis based on neutron scattering which has been effectively developed at the Frank Laboratory of Neutron Physics. A practical opportunity to determine the bulk crystallographic textures of single-phase and multiphase materials is offered by the use of modern neutron diffractometers, including the SKAT diffractometer at the IBR-2 pulsed reactor. This is especially important for studying samples of natural rocks. The examples given show how the neutron scattering data for the quantitative TA are used in combination with other physical and petrological methods for solving fundamental problems of geology and geophysics based on the analysis of a structure and properties of the Earth’s lithosphere matter. The review includes a detailed list of references of original works concerning the TA elaboration, overview publications and monographs, and also information on the most popular TA-related software.

36 MATERIALS SCIENCE↗
NASA NTRS1991

Venus mapping

Semicontrolled image mosaics of Venus, based on Magellan data, are being compiled at 1:50,000,000, 1:10,000,000, 1:5,000,000, and 1:1,000,000 scales to support the Magellan Radar Investigator (RADIG) team. The mosaics are semicontrolled in the sense that data gaps were not filled and significant cosmetic inconsistencies exist. Contours are based on preliminary radar altimetry data that is subjected to revision and improvement. Final maps to support geologic mapping and other scientific investigations, to be compiled as the dataset becomes complete, will be sponsored by the Planetary Geology and Geophysics Program and/or the Venus Data Analysis Program. All maps, both semicontrolled and final, will be published as I-maps by the United States Geological Survey. All of the mapping is based on existing knowledge of the spacecraft orbit; photogrammetric triangulation, a traditional basis for geodetic control on planets where framing cameras were used, is not feasible with the radar images of Venus, although an eventual shift of coordinate system to a revised spin-axis location is anticipated. This is expected to be small enough that it will affect only large-scale maps.

Batson, R. M.↗
DOE OSTI2017

High-Resolution Characterization of Comingled Contaminants in the Deep Vadose Zone, Hanford Site, Washington - 17387

The contaminated deep vadose zone in the Central Plateau of the Hanford Site in Washington state presents a unique challenge to remediation. The Comprehensive Environmental Response, Compensation, and Liability Act, commonly known as the CERCLA project responsible for addressing these deep contaminants is designated as the 200-Deep Vadose Zone Operable Unit (DV-1 project). The vadose zone is 55-82 meters (180-270 feet) thick and is contaminated with both radiological and chemical contaminants from multiple historical waste streams. The mobile contaminants from this waste are still present in the deep vadose zone and pose a potential threat to the groundwater. Characterizing the nature and extent of the comingled mobile contaminants is an important step before assessing possible remedial alternatives. One factor controlling the migration and distribution of subsurface contaminants is the lithologic heterogeneity of the vadose zone sediments. A sampling plan for the DV-1 project includes continuous sediment core collection and analysis to identify key lithologic factors (i.e., small-scale bedding and structural features) that act as barriers, preferential pathways or conduits for mobile contaminants migrating through the vadose zone. Over six hundred meters (2,000 feet) of intact sediment core from 26 boreholes were collected in 1.5 meters (5 feet) long, 10 centimeter (4-inch) diameter segments. These intact sediment samples provide significant improvement in the level of detail and understanding of mechanisms and features controlling contaminant distribution that is not possible with traditional homogenized drill cuttings or conventional split-spoon samples. Detailed geological descriptions and photographs of the intact core are correlated to high-resolution geophysical logs which aid in the development of a comprehensive contaminant distribution profile of the borehole. These lithologic interpretations are used to define specific depth intervals for sampling based on changes in moisture, lithology, and elevated gamma radiation. The selected samples are analyzed for contaminants of concern, geochemical parameters, and hydraulic properties. Significant lithologic features observed in the intact cores include sharp contact boundaries to graded bedding, iron-oxide and carbonate cementation, silty laminations, clastic dike intrusions, and soft sediment deformation. Preliminary geologic logs integrated with the sample analysis indicate features that correlate to the variable distribution of contaminants both laterally and vertically. Integration of measured hydraulic parameters to lithologic units in individual borehole profiles provide key inputs for more precise geo-framework and vadose zone flux models supporting the DV-1 project. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2010

Geologic controls influencing CO2 loss from a leaking well.

Injection of CO2 into formations containing brine is proposed as a long-term sequestration solution. A significant obstacle to sequestration performance is the presence of existing wells providing a transport pathway out of the sequestration formation. To understand how heterogeneity impacts the leakage rate, we employ two dimensional models of the CO2 injection process into a sandstone aquifer with shale inclusions to examine the parameters controlling release through an existing well. This scenario is modeled as a constant-rate injection of super-critical CO2 into the existing formation where buoyancy effects, relative permeabilities, and capillary pressures are employed. Three geologic controls are considered: stratigraphic dip angle, shale inclusion size and shale fraction. In this study, we examine the impact of heterogeneity on the amount and timing of CO2 released through a leaky well. Sensitivity analysis is performed to classify how various geologic controls influence CO2 loss. A 'Design of Experiments' approach is used to identify the most important parameters and combinations of parameters to control CO2 migration while making efficient use of a limited number of computations. Results are used to construct a low-dimensional description of the transport scenario. The goal of this exploration is to develop a small set of parametric descriptors that can be generalized to similar scenarios. Results of this work will allow for estimation of the amount of CO2 that will be lost for a given scenario prior to commencing injection. Additionally, two-dimensional and three-dimensional simulations are compared to quantify the influence that surrounding geologic media has on the CO2 leakage rate.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1976

Geochemistry

The most effective strategy for the geochemical study of a planet is to proceed systematically with the mineralogical and chemical characterization of its materials in accordance with geologically determined priorities. It is insufficient merely to analyze chemically the surface rocks. To appreciate the meaning of a chemical analysis, some assessment must be made of the geologic history of the sample - what its source and mode of origin are and what processes have operated upon the sample to cause chemical fractionation. Determination of mineralogy, texture, lithology, and other properties of the rock that might be relevant to origin is, therefore, necessary.

Carr, M. H.↗
NASA NTRS1995

Aerolian erosion, transport, and deposition of volcaniclastic sands among the shifting sand dunes, Christmas Lake Valley, Oregon: TIMS image analysis

Remote sensing is a tool that, in the context of aeolian studies, offers a synoptic view of a dune field, sand sea, or entire desert region. Blount et al. (1990) presented one of the first studies demonstrating the power of multispectral images for interpreting the dynamic history of an aeolian sand sea. Blount's work on the Gran Desierto of Mexico used a Landsat TM scene and a linear spectral mixing model to show where different sand populations occur and along what paths these sands may have traveled before becoming incorporated into dunes. Interpretation of sand transport paths and sources in the Gran Desierto led to an improved understanding of the origin and Holocene history of the dunes. With the anticipated advent of the EOS-A platform and ASTER thermal infrared capability in 1998, it will become possible to look at continental sand seas and map sand transport paths using 8-12 mu m bands that are well-suited to tracking silicate sediments. A logical extension of Blount's work is to attempt a similar study using thermal infrared images. One such study has already begun by looking at feldspar, quartz, magnetite, and clay distributions in the Kelso Dunes of southern California. This paper describes the geology and application of TIMS image analysis of a less-well known Holocene dune field in south central Oregon using TIMS data obtained in 1991.

Edgett, Kenneth S.↗
DOE OSTI2013

Comprehensive, Quantitative Risk Assessment of CO 2 Geologic Sequestration (Final Technical Report)

A Quantitative Failure Modes and Effects Analysis (QFMEA) was developed to conduct comprehensive, quantitative risk assessments on CO 2 capture, transportation, and sequestration or use in deep saline aquifers, enhanced oil recovery operations, or enhanced coal bed methane operations. The model identifies and characterizes potential risks; identifies the likely failure modes, causes, effects and methods of detection; lists possible risk prevention and risk mitigation steps; estimates potential damage recovery costs, mitigation costs and costs savings resulting from mitigation; and ranks (prioritizes) risks according to the probability of failure, the severity of failure, the difficulty of early failure detection and the potential for fatalities. The QFMEA model generates the necessary information needed for effective project risk management. Diverse project information can be integrated into a concise, common format that allows comprehensive, quantitative analysis, by a cross-functional team of experts, to determine: What can possibly go wrong? How much will damage recovery cost? How can it be prevented or mitigated? What is the cost savings or benefit of prevention or mitigation? Which risks should be given highest priority for resolution? The QFMEA model can be tailored to specific projects and is applicable to new projects as well as mature projects. The model can be revised and updated as new information comes available. It accepts input from multiple sources, such as literature searches, site characterization, field data, computer simulations, analogues, process influence diagrams, probability density functions, financial analysis models, cost factors, and heuristic best practices manuals, and converts the information into a standardized format in an Excel spreadsheet. Process influence diagrams, geologic models, financial models, cost factors and an insurance schedule were developed to support the QFMEA model. Comprehensive, quantitative risk assessments were conducted on three (3) sites using the QFMEA model: (1) SACROC Northern Platform CO 2 -EOR Site in the Permian Basin, Scurry County, TX, (2) Pump Canyon CO 2 -ECBM Site in the San Juan Basin, San Juan County, NM, and (3) Farnsworth Unit CO 2 -EOR Site in the Anadarko Basin, Ochiltree County, TX. The sites were sufficiently different from each other to test the robustness of the QFMEA model.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Parts-Per-Million Carbonate Mineral Quantification with Thermogravimetric Analysis–Mass Spectrometry

Mitigating the deleterious effects of climate change requires the development and implementation of carbon capture and storage technologies. To expand the monitoring, verification, and reporting (MRV) capabilities of geologic carbon mineralization projects, we developed a thermogravimetric analysis–mass spectrometry (TGA–MS) methodology to enable quantification of <100 ppm calcite (CaCO 3 ) in complex samples. We extended TGA–MS calcite calibration curves to enable a higher measurement resolution and lower limits of quantification for evolved CO 2 from a calcite–corundum mixture. We demonstrated <100 ppm carbonate mineral quantification with TGA–MS for the first time, an outcome applicable across earth, environmental, and materials science fields. We applied this carbonate quantification method to a suite of Columbia River Basalt Group (CRBG) well cuttings recovered in 2009 from Pacific Northwest National Laboratory’s Wallula #1 Well. Our execution of this new combined calcite and calcite–corundum calibration curve TGA–MS method on our CRBG sample suite indicated average carbonate contents of 0.050 wt % in flow interiors (caprocks) and 0.400 wt % in interflow zones (reservoirs) in the upper 1250 m of the Wallula #1 Well. Finally, by advancing our knowledge of continental flood basalt-hosted carbonates in the mafic subsurface and reaching new TGA–MS quantification limits for carbonate minerals, we expand MRV capabilities and support the commercial-scale deployment of carbon mineralization projects in the Pacific Northwest United States and beyond.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1975

Computer-aided analysis of Skylab multispectral scanner data in mountainous terrain for land use, forestry, water resource, and geologic applications

The author has identified the following significant results. One of the most significant results of this Skylab research involved the geometric correction and overlay of the Skylab multispectral scanner data with the LANDSAT multispectral scanner data, and also with a set of topographic data, including elevation, slope, and aspect. The Skylab S192 multispectral scanner data had distinct differences in noise level of the data in the various wavelength bands. Results of the temporal evaluation of the SL-2 and SL-3 photography were found to be particularly important for proper interpretation of the computer-aided analysis of the SL-2 and SL-3 multispectral scanner data. There was a quality problem involving the ringing effect introduced by digital filtering. The modified clustering technique was found valuable when working with multispectral scanner data involving many wavelength bands and covering large geographic areas. Analysis of the SL-2 scanner data involved classification of major cover types and also forest cover types. Comparison of the results obtained wth Skylab MSS data and LANDSAT MSS data indicated that the improved spectral resolution of the Skylab scanner system enabled a higher classification accuracy to be obtained for forest cover types, although the classification performance for major cover types was not significantly different.

Hoffer, R. M.↗
NASA NTRS1995

Global Stratigraphy of Venus: Analysis of a Random Sample of Thirty-Six Test Areas

The age relations between 36 impact craters with dark paraboloids and other geologic units and structures at these localities have been studied through photogeologic analysis of Magellan SAR images of the surface of Venus. Geologic settings in all 36 sites, about 1000 x 1000 km each, could be characterized using only 10 different terrain units and six types of structures. These units and structures form a major stratigraphic and geologic sequence (from oldest to youngest): (1) tessera terrain; (2) densely fractured terrains associated with coronae and in the form of remnants among plains; (3) fractured and ridged plains and ridge belts; (4) plains with wrinkle ridges; (5) ridges associated with coronae annulae and ridges of arachnoid annulae which are contemporary with wrinkle ridges of the ridged plains; (6) smooth and lobate plains; (7) fractures of coronae annulae, and fractures not related to coronae annulae, which disrupt ridged and smooth plains; (8) rift-associated fractures; and (9) craters with associated dark paraboloids, which represent the youngest 1O% of the Venus impact crater population (Campbell et al.), and are on top of all volcanic and tectonic units except the youngest episodes of rift-associated fracturing and volcanism; surficial streaks and patches are approximately contemporary with dark-paraboloid craters. Mapping of such units and structures in 36 randomly distributed large regions (each approximately 10(exp 6) sq km) shows evidence for a distinctive regional and global stratigraphic and geologic sequence. On the basis of this sequence we have developed a model that illustrates several major themes in the history of Venus. Most of the history of Venus (that of its first 80% or so) is not preserved in the surface geomorphological record. The major deformation associated with tessera formation in the period sometime between 0.5-1.0 b.y. ago (Ivanov and Basilevsky) is the earliest event detected. In the terminal stages of tessera fon-nation, extensive parallel linear graben swarms representing a change in the style of deformation from shortening to extension were formed on the tessera and on some volcanic plains that were emplaced just after, and perhaps also during the latter stages of the major compressional phase of tessera emplacement. Our stratigraphic analyses suggest that following tessera formation, extensive volcanic flooding resurfaced at least 85% of the planet in the form of the presently-ridged and fractured plains. Several lines of evidence favor a high flux in the post-tessera period but we have no independent evidence for the absolute duration of ridged plains emplacement. During this time, the net state of stress in the lithosphere apparently changed from extensional to compressional, first in the form of extensive ridge belt development, followed by the formation of extensive wrinkle ridges on the flow units. Subsequently, there occurred local emplacement of smooth and lobate plains units which are presently essentially undefortned. The major events in the latest 10% of the presently preserved history of Venus (less than 50 m.y. ago) are continued rifting and some associated volcanism, and the redistribution of eolian material largely derived from impact crater deposits.

Basilevsky, Alexander T.↗