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At least 505 records · Page 28

Silicon production process evaluations

Engineering design of the third distillation column in the process was accomplished. The initial design is based on a 94.35% recovery of dichlorosilane in the distillate and a 99.9% recovery of trichlorosilane in the bottoms. The specified separation is achieved at a reflux ratio of 15 with 20 trays (equilibrium stages). Additional specifications and results are reported including equipment size, temperatures and pressure. Specific raw material requirements necessary to produce the silicon in the process are presented. The primary raw materials include metallurgical grade silicon, silicon tetrachloride, hydrogen, copper (catalyst) and lime (waste treatment). Hydrogen chloride is produced as by product in the silicon deposition. Cost analysis of the process was initiated during this reporting period.

Source record↗

Development of an all-metal thick film cost effective metallization system for solar cells

Improved thick film solar cell contacts for the high volume production of low cost silicon solar arrays are needed. All metal screenable pastes made from economical base metals and suitable for application to low to high conductivity silicon were examined. Silver fluoride containing copper pastes and fluorocarbon containing copper pastes were discussed. The effect of hydrogen on the adhesion of metals to silicon was investigated. A cost analysis of various paste materials is provided.

Ross, B.↗

Observational constraints on circumstellar dust

There is an enormous range in the properties of stars that are losing mass. The red giants responsible for injecting roughly half or more of the material into the interstellar medium are reviewed. The physical properties are described for the out flowing gases. Broadband observation constaints on the dust are described by use of spectrum analysis. Circumstellar dust is identified by carbon-carbon and carbon-hydrogen bonds.

Jura, M.↗

The winds of high luminosity late-type bright stars

The occurrence and characteristics of the Fe II line asymmetries were studied to determine the radial dependence of the wind velocity for each star. The dependence of the Fe II profiles on spectral type and luminosity class and thus the variation of the velocity fields with stellar type was also investigated. This allows the generality of the results reported for alpha Ori by Carpenter (1984b) to be judged. In addition, new atomic data was used along with observations of the C II (UV 0.01) multiplet to estimate N(sub e) in the stellar winds. Measures of relative Fe II fluxes can be used in a probability-of-escape model to determine the opacity and hydrogen column density versus height in the chromosphere of each star. Finally, analysis of the fluorescent Fe II lines (pumped by Ly alpha) near 2507 A will yield estimates of the intrinsic stellar Ly alpha flux that cannot be measured directly because of interstellar and circumstellar absorption. One important goal of the effort was to acquire high resolution spectra of the whole 2300 to 3200 A region of 13 luminous K and M stars as a data base that will be enormously valuable in planning observations with the Hubble Space Telescope High Resolution Spectrograph. It is also proposed to follow up the recent discovery of significant variations in the Fe II chromospheric emission line profiles from the M-giant Gamma Cru for the purpose of determining the underlying cause of the variations.

Stencel, Robert E.↗

A high-frequency servosystem for fuel control in hypersonic engines

A hydrogen fuel-flow valve with an electrohydraulic servosystem is described. An analysis of the servosystem is presented along with a discussion of the limitations imposed on system performance by nonlinearities. The response of the valve to swept-frequency inputs is experimentally determined and compared with analytical results obtained from a computer model. The valve is found to perform favorably for frequencies up to 200 Hz.

Simon, Donald L.↗

SSME improved characterization using highly instrumented engine test data

This paper discusses the analysis of Space Shuttle Main Engine (SSME) 3001 test data and its applications to steady-state models. Engine 3001 is a highly instrumented Phase II (current configuration) SSME that was tested at the Technology Test Bed facility located at Marshall Space Flight Center. A test series covering a carefully selected range of operating conditions was performed during 1991. An analysis of pressure, temperature and flowrate data was performed to evaluate the ability of steady-state models to accurately characterize the internal system of an SSME. Much of the special instrumentation was used to acquire data never before measured at the engine level prior to Engine 3001 testing. The analysis revealed that modifications are needed to improve model calculations of internal Hydrogen and Oxygen flows. Modifying steady-state models to more accurately simulate the internal flow system of an SSME should improve both engine performance evaluations and prediction capabilities.

Piekarski, Brian↗

Seismological procedures for ZZ Ceti stars and an application to G 117-B15A

In this paper, we outline the procedure for seismological analysis of the ZZ Ceti stars, which are pulsating white dwarfs with hydrogen atmospheres. We use G 117-B15A as the example for this process and derive constraints on the mass and internal structure. The hydrogen layer mass is either about 10(-4)M* or 10(-7)M* depending on whether the l = 1 mode near 215 s is k = 2 or k = 1, respectively. In both cases, the best fitting mass is 0.60M solar, in agreement with spectroscopic log g values.

Bradley, P. A.↗

Antarctic Photochemistry: Uncertainty Analysis

Understanding the photochemistry of the Antarctic region is important for several reasons. Analysis of ice cores provides historical information on several species such as hydrogen peroxide and sulfur-bearing compounds. The former can potentially provide information on the history of oxidants in the troposphere and the latter may shed light on DMS-climate relationships. Extracting such information requires that we be able to model the photochemistry of the Antarctic troposphere and relate atmospheric concentrations to deposition rates and sequestration in the polar ice. This paper deals with one aspect of the uncertainty inherent in photochemical models of the high latitude troposphere: that arising from imprecision in the kinetic data used in the calculations. Such uncertainties in Antarctic models tend to be larger than those in models of mid to low latitude clean air. One reason is the lower temperatures which result in increased imprecision in kinetic data, assumed to be best characterized at 298K. Another is the inclusion of a DMS oxidation scheme in the present model. Many of the rates in this scheme are less precisely known than are rates in the standard chemistry used in many stratospheric and tropospheric models.

Stewart, Richard W.↗

Constraining the Evolution of ZZ Ceti

We report our analysis of the stability of pulsation periods in the DAV star (pulsating hydrogen atmosphere white dwarf) ZZ Ceti, also called R548. On the basis of observations that span 31 years, we conclude that the period 213.13 s observed in ZZ Ceti drifts at a rate dP/dt 5 (5.5 plus or minus 1.9) x 10(exp -15) ss(sup -1), after correcting for proper motion. Our results are consistent with previous P values for this mode and an improvement over them because of the larger time base. The characteristic stability timescale implied for the pulsation period is |P||P(raised dot)|greater than or equal to 1.2 Gyr, comparable to the theoretical cooling timescale for the star. Our current stability limit for the period 213.13 s is only slightly less than the present measurement for another DAV, G117-B15A, for the period 215.2 s, establishing this mode in ZZ Ceti as the second most stable optical clock known, comparable to atomic clocks and more stable than most pulsars. Constraining the cooling rate of ZZ Ceti aids theoretical evolutionary models and white dwarf cosmochronology. The drift rate of this clock is small enough that we can set interesting limits on reflex motion due to planetary companions.

Mukadam, Anjum S.↗

Lunar Resource Utilization: Development of a Reactor for Volatile Extraction from Regolith

The extraction and processing of planetary resources into useful products, known as In- Situ Resource Utilization (ISRU), will have a profound impact on the future of planetary exploration. One such effort is the RESOLVE (Regolith and Environment Science, Oxygen and Lunar Volatiles Extraction) Project, which aims to extract and quantify these resources. As part of the first Engineering Breadboard Unit, the Regolith Volatiles Characterization (RVC) reactor was designed and built at the NASA Glenn Research Center. By heating and agitating the lunar regolith, loosely bound volatiles, such as hydrogen and water, are released and stored in the reactor for later analysis and collection. Intended for operation on a robotic rover, the reactor features a lightweight, compact design, easy loading and unloading of the regolith, and uniform heating of the regolith by means of vibrofluidization. The reactor performance was demonstrated using regolith simulant, JSC1, with favorable results.

Kleinhenz, Julie E.↗

Propulsion Investigation for Zero and Near-Zero Emissions Aircraft

As world emissions are further scrutinized to identify areas for improvement, aviation s contribution to the problem can no longer be ignored. Previous studies for zero or near-zero emissions aircraft suggest aircraft and propulsion system sizes that would perform propulsion system and subsystems layout and propellant tankage analyses to verify the weight-scaling relationships. These efforts could be used to identify and guide subsequent work on systems and subsystems to achieve viable aircraft system emissions goals. Previous work quickly focused these efforts on propulsion systems for 70- and 100-passenger aircraft. Propulsion systems modeled included hydrogen-fueled gas turbines and fuel cells; some preliminary estimates combined these two systems. Hydrogen gas-turbine engines, with advanced combustor technology, could realize significant reductions in nitrogen emissions. Hydrogen fuel cell propulsion systems were further laid out, and more detailed analysis identified systems needed and weight goals for a viable overall system weight. Results show significant, necessary reductions in overall weight, predominantly on the fuel cell stack, and power management and distribution subsystems to achieve reasonable overall aircraft sizes and weights. Preliminary conceptual analyses for a combination of gas-turbine and fuel cell systems were also performed, and further studies were recommended. Using gas-turbine engines combined with fuel cell systems can reduce the fuel cell propulsion system weight, but at higher fuel usage than using the fuel cell only.

Snyder, Christopher A.↗

Synthesis and analysis of jet fuel from shale oil and coal syncrudes

Thirty-two jet fuel samples of varying properties were produced from shale oil and coal syncrudes, and analyzed to assess their suitability for use. TOSCO II shale oil and H-COAL and COED syncrudes were used as starting materials. The processes used were among those commonly in use in petroleum processing-distillation, hydrogenation and catalytic hydrocracking. The processing conditions required to meet two levels of specifications regarding aromatic, hydrogen, sulfur and nitrogen contents at two yield levels were determined and found to be more demanding than normally required in petroleum processing. Analysis of the samples produced indicated that if the more stringent specifications of 13.5% hydrogen (min.) and 0.02% nitrogen (max.) were met, products similar in properties to conventional jet fuels were obtained. In general, shale oil was easier to process (catalyst deactivation was seen when processing coal syncrudes), consumed less hydrogen and yielded superior products. Based on these considerations, shale oil appears to be preferred to coal as a petroleum substitute for jet fuel production.

Gallagher, J. P.↗

A Consolidated Block Grant Proposal to Carry Out the Analysis of Data from the ISO Satellite

This block grant covers the activities of three research groups at STScI: search for cold molecular hydrogen in the galaxy; dust characterization in circumstellar shells around evolved massive stars; and the relationship between dust absorption and emission in galaxies. We proposed to group the efforts and resources available to several approved ISO projects in order to more efficiently deal with the data reduction and analysis. We give a brief description of primary objectives and scope of each project, along with the final status of the project as of the expiration date of the grant. Owing to many delays on the part of the ISO Project, the calibrated data was received very late, which resulted in significant delays in deriving the results. In addition, for one of the components of this project, the ISO data was finally determined to be of too low a quality to be useful.

Allen, Ron↗

Venus nighttime hydrogen bulge

The concentration of atomic hydrogen in the Venus thermosphere near 165 km altitude and approximately 18 deg north latitude has been derived from Pioneer Venus in situ measurements of H(+), O(+), O and CO2 concentrations, under the assumption of chemical equilibrium. Altitude profiles of derived H concentration suggest that chemical equilibrium prevails to an altitude of at least 200 km on the dayside and to 165 km on the nightside. Measurements below these limits were made by the ion and neutral mass spectrometers on the orbiter spacecraft between December 1978 and July 1979, while periapsis traversed a complete diurnal cycle. The hydrogen concentration is found to rise sharply at both terminators from a dayside value of approximately 50,000/cu cm, and to exhibit an asymmetric nightside distribution with a peak density in the predawn sector approximately 400 times greater than the dayside value. Analysis suggests that wind-induced diffusion, combined with exospheric return flow, can account for the observed hydrogen behavior. The large day-night temperature contrast enhances advective transport, which produces the large H concentration diurnal variation; the shift of the H concentration nighttime maximum toward dawn is caused by atmospheric superrotation.

Brinton, H. C.↗

Applications of chemiluminescence to bacterial analysis

Luminol chemiluminescence method for detecting bacteria was based on microbial activation of the oxidation of the luminol monoanion by hydrogen peroxide. Elimination of the prior lysing step, previously used in the chemiluminescence technique, was shown to improve considerably the reproducibility and accuracy of the method in addition to simplifying it. An inexpensive, portable photomultiplier detector was used to measure the maximum light intensity produced when the sample is added to the reagent. Studies of cooling tower water show that the luminol chemiluminescence technique can be used to monitor changes in viable cell population both under normal conditions and during chlorine treatment. Good correlation between chemiluminescence and plate counts was also obtained in the analysis of process water used in paper mills. This method showed good potential for monitoring the viable bacteria populations in activated sludge used in waste treatment plants to digest organic matter.

Searle, N. D.↗

Extended atmospheres of outer planet satellites and comets

The cometary hydrogen particle-trajectory model was used successfully to analyze observations of Comet P/Encke. The Pioneer Venus Orbiter Ultraviolet Spectrometer observed the comet at 1216A (hydrogen Lyman-alpha) on 15 April 1984, when the comet was .58 AU from the Sun and 1.02 AU from Venus. The analysis implies a production rate at .58 AU of 3.3 x 10 to the 28th power/sec of the water molecules which photodissociate to produce the observed hydrogen.

Smyth, W. H.↗

High resolution Lyman alpha observations of comet Kohoutek /1973f/ near perihelion

The hydrogen Lyman-alpha emission line of comet Kohoutek (1973f) was observed and resolved by the high-dispersion Skylab/ATM S082B spectrograph shortly after the comet's perihelion passage (29-31 December 1973). The Lyman-alpha line width was determined from three different exposures of the comet nuclear region. A simplified analysis of the optical thickness effects showed that this line width is consistent with the established hydrogen outflow velocity of 8 to 10 km/sec.

Keller, H. U.↗

Hydrogen emission from Jupiter: Hydrogen emission from sunlit atmosphere of Saturn

Successful IUE observations of the equatorial sunlit atmosphere of Jupiter and Saturn have been obtained. Spectra containing atomic and molecular hydrogen and solar reflection continuum emissions have been analyzed, with the purpose of determining the long term temporal behavior of the electroglow process. Quantitative estimates have been established for the first time using a model analysis of the short wavelength region of the spectrum. Both systems show varying degrees of long term variability in hydrogen emission rate, but the time scale is too short to determine whether there is a dependence on solar cycle activity. As part of the emission modeling program, a preliminary point source spreading function for the IUE SWP instrument has been established, suggesting a wavelength dependence in spectral line width different from previous analyses. Further IUE observations are planned for both Jupiter and Saturn.

Shemansky, D. E.↗