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TESS Data Release Notes: Sector 24, DR35

These Data Release Notes provide information on the processing and export of data from the Transiting Exoplanet Survey Satellite (TESS). The data products included in this data release are full frame images (FFIs), target pixel fi les, light curve fi les, collateral pixel fi les, cotrending basis vectors (CBVs), and Data Validation (DV) reports, time series, and associated xml fi les. These data products were generated by the TESS Science Processing Operations Center (SPOC, Jenkins et al., 2016) at NASA Ames Research Center from data collected by the TESS instrument, which is managed by the TESS Payload Operations Center (POC) at Massachusetts Institute of Technology (MIT). The format and content of these data products are documented in the Science Data Products Description Document (SDPDD). The SPOC science algorithms are based heavily on those of the Kepler Mission science pipeline, and are described in the Kepler Data Processing Handbook (Jenkins, 2019).2 The Data Validation algorithms are documented in Twicken et al. (2018) and Li et al. (2019). The TESS Instrument Handbook (Vanderspek et al., 2018) contains more information about the TESS instrument design, detector layout, data properties, and mission operations. The TESS Mission is funded by NASA's Science Mission Directorate.

TESS↗

Are Deep Energy Retrofits in Commercial Buildings Including Window Upgrades?

U.S. Commercial buildings account for about 20% of total U.S. energy consumption. Because the thermal performance of windows significantly affects building energy efficiency and HVAC system performance, best practice guidance often includes window and envelope improvements in conjunction with HVAC upgrades to optimize energy use and improve occupant comfort. It is an open question, however, regarding how often these best practices are implemented in the field. This paper aims to address that gap by conducting a literature review and a series of interviews with commercial building auditing and management professionals to explore the factors that drive window retrofits in commercial buildings. The paper explores a range of case studies from deep energy retrofits across the globe, comparing projects with and without window retrofits. The primary goals of this review are to: (1) provide data from real-world case studies illustrating the role of windows in deep energy renovations and HVAC upgrades, (2) conduct retrofit cost analyses for windows and high-performance HVAC systems and (3) offer insights into how window upgrade decisions are made and when they are implemented as part of deep energy retrofits. Most of the retrofit studies focused exclusively on high performance HVAC upgrades without considering how window upgrades might further enhance the overall energy efficiency of commercial buildings. Interviews with building industry experts shed light on the key factors influencing deep energy retrofit decisions and what factors tip the scales in favor of including window measures with more comprehensive retrofit projects.

Cort, Katherine↗

WET Water Resources: A Google Earth Engine Python API Tool to Automate Wetland Extent Mapping Using Radar Satellite Sensors for Wetland Management and Monitoring

Wetland ecosystems are annually or seasonally wet transition zones between land and water. They provide a range of ecosystem services such as water filtration, flood mitigation, and carbon sequestration, as well as hosting biodiversity hotspots. Although they fulfill fundamental physical and natural processes, wetland extent and health are threatened by anthropogenic influences related to urbanization, population increase, pollution, and climate change. Recognizing the need to quantitatively monitor changes in these recently threatened ecosystems in a timely and cost-effective way, we developed a Google Earth Engine (GEE) Python API tool for automated wetland extent mapping using optical and radar satellite sensors that can be applied globally. The tool will significantly improve wetland change analysis and monitoring as SAR data provides high resolution (5-10 m) imagery, unaffected by cloud cover and light availability (day vs. night), common limitations for other remotely sensed sensors. The tool utilizes Copernicus Sentinel-1 C-band and NISAR L-band (once operational and available on the GEE repository) synthetic aperture radar (SAR) imagery. During image preprocessing, we applied a Terra Moderate Resolution Imaging Spectroradiometer (MODIS) snow product to determine regional snow coverage, which affects land classification sensitivity. Calibration and validation were conducted through a historical change and sensitivity analysis of the Sudd wetland located in central Sudan. The tool was the first of its kind, as it enables NISAR data processing through an open-source GEE repository, further expanding and improving the utility of NASA Earth observations and contributing to NASA Open Science initiatives. We anticipate the tool will be used by researchers and practitioners interested in wetland monitoring and management.

Inundation↗

WET Water Resources: A Google Earth Engine Python API Tool to Automate Wetland Extent Mapping Using Radar Satellite Sensors for Wetland Management and Monitoring

Wetland ecosystems are annually or seasonally wet transition zones between land and water. They provide a range of ecosystem services such as water filtration, flood mitigation, and carbon sequestration, as well as hosting biodiversity hotspots. Although they fulfill fundamental physical and natural processes, wetland extent and health are threatened by anthropogenic influences related to urbanization, population increase, pollution, and climate change. Recognizing the need to quantitatively monitor changes in these recently threatened ecosystems in a timely and cost-effective way, we developed a Google Earth Engine (GEE) Python API tool for automated wetland extent mapping using optical and radar satellite sensors that can be applied globally. The tool will significantly improve wetland change analysis and monitoring as the optical and SAR data proves high resolution (5-10 m) imagery, and SAR data is unaffected by cloud cover and light availability (day vs. night), which are common limitations for other remotely sensed sensors. The tool utilizes Copernicus Sentinel-1 C-band and NISAR L-band synthetic aperture radar (SAR) imagery. During image preprocessing, we applied a MODIS snow mask product to mask global snow coverage, which would affect land classification sensitivity. Calibration and validation were conducted through a historical change and sensitivity analysis of the Sudd watershed located in central Sudan. The tool was the first of its kind, as it enables NISAR data processing through an open-source GEE repository, further expanding and improving the utility of NASA Earth observations and contributing to NASA Open Science initiatives. We anticipate the tool will be used by researchers and practitioners interested in wetland monitoring and management..

Lori Berberian↗

Topologically trivial gap-filling in superconducting Fe(Se,Te) by one-dimensional defects

Abstract Structural distortions and imperfections are a crucial aspect of materials science, on the macroscopic scale providing strength, but also enhancing corrosion and reducing electrical and thermal conductivity. At the nanometre scale, multi-atom imperfections, such as atomic chains and crystalline domain walls have conversely been proposed as a route to topological superconductivity, whose most prominent characteristic is the emergence of Majorana Fermions that can be used for error-free quantum computing. Here, we shed more light on the nature of purported domain walls in Fe(Se,Te) that may host 1D dispersing Majorana modes. We show that the displacement shift of the atomic lattice at these line-defects results from sub-surface impurities that warp the topmost layer(s). Using the electric field between the tip and sample, we manage to reposition the sub-surface impurities, directly visualizing the displacement shift and the underlying defect-free lattice. These results, combined with observations of a completely different type of 1D defect where superconductivity remains fully gapped, highlight the topologically trivial nature of 1D defects in Fe(Se,Te).

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Hybrid chemical characterization of latent images in EUV resist with 12 nm half-pitch features

With the advancement of high numerical aperture extreme ultraviolet (EUV) lithography, the new platform will enable chipmakers to achieve critical dimensions of 8 nm. However, resist materials face significant challenges in delivering increased sensitivity while managing rising stochastic variations. We aim to develop comprehensive techniques to characterize the chemical profile of latent images, stored in EUV resists after exposure and postexposure baking, which is essential for understanding the origin of stochastic effects. Infrared photo-induced force microscopy (IR PiFM) is a bimodal atomic force microscopy technique combined with an infrared light source, allowing for simultaneous sub-5 nm topographic and chemical characterization within a localized environment. Critical-dimension resonant soft X-ray scatterometry (CD-RSoXS) provides statistical data that reveal structural and chemical information for comparative analysis. For the first time, IR PiFM has been used to chemically map the latent images of EUV resists (after exposure and postexposure baking) at a record high resolution of 12 nm half-pitch, enabling nondestructive analysis of patterns prior to development. Furthermore, CD-RSoXS offers direct experimental observation and comparison of exposed, postexposure baked, and developed patterns, which align with the IR PiFM results. We demonstrate that the IR PiFM technique offers valuable insights into both high spatial resolution and local chemical information simultaneously. In addition, CD-RSoXS provides statistical results that support our main findings. This hybrid metrology approach leverages a multifaceted dataset by combining the most reliable information from each source, which is essential for a comprehensive understanding of the stochastic effects in EUV lithography processes.

O’Reilly, Padraic↗

Earth benefits from space life sciences

The applications to medicine of various results from space exploration are examined. Improvements have been made in the management of cardiovascular disease, in particular the use of the ultrasonic scanner to image arteries in three dimensions, the use of excimer lasers to disrupt arterial plaques in coronary blood vessels, and the use of advanced electrodes for cardiac monitoring. A bone stiffness analyzer has helped to diagnose osteoporosis and aid in its treatment. An automated light microscope system is used for chromosome analysis, and an X-ray image intensifier called Lixiscope is used in emergency medical care. An advanced portable defibrillator has been developed for the heart, and an insulin delivery system has been derived from space microminiaturization techniques.

Garshnek, V.↗

Monitoring and control technologies for bioregenerative life support systems/CELSS

The development of a controlled Ecological Life Support System (CELSS) will require NASA to develop innovative monitoring and control technologies to operate the different components of the system. Primary effort over the past three to four years has been directed toward the development of technologies to operate a biomass production module. Computer hardware and software required to operate, collect, and summarize environmental data for a large plant growth chamber facility were developed and refined. Sensors and controls required to collect information on such physical parameters as relative humidity, temperature, irradiance, pressure, and gases in the atmosphere; and PH, dissolved oxygen, fluid flow rates, and electrical conductivity in the nutrient solutions are being developed and tested. Technologies required to produce high artificial irradiance for plant growth and those required to collect and transport natural light into a plant growth chamber are also being evaluated. Significant effort was directed towards the development and testing of a membrane nutrient delivery system required to manipulate, seed, and harvest crops, and to determine plant health prior to stress impacting plant productivity are also being researched. Tissue culture technologies are being developed for use in management and propagation of crop plants. Though previous efforts have focussed on development of technologies required to operate a biomass production module for a CELSS, current efforts are expanding to include technologies required to operate modules such as food preparation, biomass processing, and resource (waste) recovery which are integral parts of the CELSS.

Knott, William M.↗

Development and Implementation of NASA's Lead Center for Rocket Propulsion Testing

With the new millennium, NASA's John C. Stennis Space Center (SSC) continues to develop and refine its role as rocket test service provider for NASA and the Nation. As Lead Center for Rocket Propulsion Testing (LCRPT), significant progress has been made under SSC's leadership to consolidate and streamline NASA's rocket test infrastructure and make this vital capability truly world class. NASA's Rocket Propulsion Test (RPT) capability consists of 32 test positions with a replacement value in excess of $2B. It is dispersed at Marshall Space Flight Center (MSFC), Johnson Space Center (JSC)-White Sands Test Facility (WSTF), Glenn Research Center (GRC)-Plum Brook (PB), and SSC and is sized appropriately to minimize duplication and infrastructure costs. The LCRPT also provides a single integrated point of entry into NASA's rocket test services. The RPT capability is managed through the Rocket Propulsion Test Management Board (RPTMB), chaired by SSC with representatives from each center identified above. The Board is highly active, meeting weekly, and is key to providing responsive test services for ongoing operational and developmental NASA and commercial programs including Shuttle, Evolved Expendable Launch Vehicle, and 2nd and 3rd Generation Reusable Launch Vehicles. The relationship between SSC, the test provider, and the hardware developers, like MSFC, is critical to the implementation of the LCRPT. Much effort has been expended to develop and refine these relationships with SSC customers. These efforts have met with success and will continue to be a high priority to SSC for the future. To data in the exercise of its role, the LCRPT has made 22 test assignments and saved or avoided approximately $51M. The LCRPT directly manages approximately $30M annually in test infrastructure costs including facility maintenance and upgrades, direct test support, and test technology development. This annual budges supports rocket propulsion test programs which have an annual budget in excess of $150M. As the LCRPT continues to develop, customer responsiveness and lower cost test services will be major themes. In that light, SSC is embarking on major test technology development activities ensuring long range goals of safer, more responsive, and more cost effective test services are realized. The LCRPT is also focusing on the testing requirements for advanced propulsion systems. This future planning is key to defining and fielding the ability to test these new technologies in support of the hardware developers.

Dawson, Michael C.↗

NASA Tech Briefs, April 2008

Topics covered include: Gas Sensors Based on Coated and Doped Carbon Nanotubes; Tactile Robotic Topographical Mapping Without Force or Contact Sensors; Thin-Film Magnetic-Field-Response Fluid-Level Sensor for Non-Viscous Fluids; Progress in Development of Improved Ion-Channel Biosensors; Simulating Operation of a Complex Sensor Network; Using Transponders on the Moon to Increase Accuracy of GPS; Controller for Driving a Piezoelectric Actuator at Resonance; Coaxial Electric Heaters; Dual-Input AND Gate From Single-Channel Thin-Film FET; High-Density, High-Bandwidth, Multilevel Holographic Memory; Fabrication of Gate-Electrode Integrated Carbon-Nanotube Bundle Field Emitters; Hydroxide-Assisted Bonding of Ultra-Low-Expansion Glass; Photochemically Synthesized Polyimides; Optimized Carbonate and Ester-Based Li-Ion Electrolytes; Compact 6-DOF Stage for Optical Adjustments; Ultrasonic/Sonic Impacting Penetrators; Miniature, Lightweight, One-Time-Opening Valve; Supplier Management System; Improved CLARAty Functional-Layer/Decision-Layer Interface; JAVA Stereo Display Toolkit; Remote-Sensing Time Series Analysis, a Vegetation Monitoring Tool; PyPele Rewritten To Use MPI; Data Assimilation Cycling for Weather Analysis; Hydrocyclone/Filter for Concentrating Biomarkers from Soil; Activating STAT3 Alpha for Promoting Healing of Neurons; and Probing a Spray Using Frequency-Analyzed Light Scattering.

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A Comprehensive Simulation Study to Evaluate Future Vehicle Energy and Cost Reduction Potential

Under the umbrella of EERE’s Office of Sustainable Transportation, the U.S. Department of Energy’s (DOE) Vehicle Technologies Office (VTO) and Hydrogen and Fuel Cell Technologies Office (HFTO) seek to develop sustainable, affordable, and efficient technologies for transportation of goods and people. Translating investments in advanced transportation component technologies and powertrains to estimate the potential for vehicle-level fuel savings is critical to understanding DOE’s impact and success in this mission For this study, Argonne National Laboratory (Argonne) simulated technologies funded by VTO and HFTO for light-duty vehicles across the following: Powertrain configurations (conventional, power-split hybrid electric vehicle, extended-range electric vehicle, battery electric drive, and fuel-cell vehicles); Vehicle classes (compact car, mid-size car, small sport utility vehicle [SUV], mid-size SUV, and pickup truck); Fuels (gasoline, diesel, natural gas, hydrogen, and battery electricity). We assessed each technology for five different timeframes: laboratory years 2015 (reference), 2020, 2025, 2030, and 2045. We assumed a delay of 5 years between laboratory year and model year (i.e., the year the technology is introduced into production). Finally, we included uncertainties for both technology performance and cost by considering two cases (note that these cases are not intended as predictions of future performance): Low case , aligned with DOE technology manager estimates of expected original equipment manufacturer (OEM) improvements based on business as usual regulatory and market environments; High case , aligned with aggressive technology advancements based on research and development (R&D) targets developed through support by VTO and HFTO. We estimated the energy and cost impact of different technologies using Autonomie (Argonne undated), a state-of-the-art vehicle system simulation tool developed by Argonne and used to assess the energy consumption, performance, and cost of multiple advanced vehicle technologies. The tool comprises a complete set of vehicle models to assess impacts across a wide range of classes (from light- to heavy-duty), powertrain configurations (from conventional to hybrid electric vehicles [HEVs], fuel cell electric vehicles [FCEVs], plug-in hybrid electric vehicles [PHEVs], and battery electric vehicles [BEVs]), components, and control strategies, including vehicle-level and component-level controls developed and calibrated using dynamometer test data. Autonomie has been used to support a wide range of studies: analyzing various component technologies, sizing powertrain components to meet different vehicle requirements, comparing the benefits of powertrain configurations, optimizing both heuristic and route-based vehicle energy control, and predicting transportation energy use when paired with a traffic modeling tool such as POLARIS. This report documents the assumptions made and the vehicle-level energy consumption benefits and associated technology costs estimated for various types of light-duty vehicles. Details regarding vehicle assumptions and simulation results are available in the spreadsheets accompanying this report.

08 HYDROGEN↗

Full spectrum optical constant interface to the Materials Project

Optical constants characterize the interaction of materials with light and are important properties in material design. Here we present a Python-based Corvus workflow for simulations of full spectrum optical constants from the visible and ultraviolet to hard x-ray wavelengths based on the real-space Green’s function code FEFF10 and structural data from the Materials Project (MP). The Corvus workflow manager and its associated tools provide an interface to FEFF10 and the MP database. The workflow parallelizes the FEFF computations of optical constants over all absorption edges for each material in the MP database specified by a unique MP-ID. The workflow tools determine the distribution of computational resources needed for that case. Similarly, the optical constants for selected sets of materials can be computed in a single-shot. Additionally, to illustrate the approach, we present results for several elemental solids in the periodic table, as well as a sample compound, and compare our predictions with experimental results. In addition, we provide a database of calculated results for all elements for which there is a stable elemental solid at standard conditions available in the Materials Project database. As in x-ray absorption spectra, these results are interpreted in terms of an atomic-like background and fine-structure contributions.

36 MATERIALS SCIENCE↗

Evaluation of Technologies for Destruction of LDR Organics in Hanford Tank Waste

Aqueous Hanford tank wastes contain soluble organics and some tanks contain small amounts (<100 mg/L) of organics that are regulated under the Land Disposal Restrictions (LDR) portions of the Resource Conservation and Recovery Act (RCRA). Most of these organics can be removed by evaporation, but some are not. Methods to destroy/remove organics that are regulated by the LDR section of the RCRA and that are not removed by evaporation may be needed if ambient temperature waste treatment processes are used to immobilize aqueous Hanford tank wastes. To identify viable and compatible organic removal or destruction pretreatment methods an evaluation was performed by a team of researchers. The team utilized a Systems Engineering Approach that examines all aspects of the technology, based on information available in the literature and the experience of the team members. That evaluation led to recommendations by the team to perform testing on technologies to determine efficacy in destroying organics in Hanford tank waste liquids. The primary technologies recommended are chemical oxidants, including permanganate, peroxymonosulfate or peroxydisulfate (PMS/PDS), hydrogen peroxide, and ozone. Ultraviolet light irradiation of the stream with a solid catalyst sorbent is also recommended for testing. A generalized description of the test program is also included.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

ATLAS-1 Video News Release

Allen Kenitzer, from Marshall Space Flight Center (MSFC), narrates this NASA Kennedy Space Center video presenting a MSFC-Television news release describing the overall scientific objectives of the Atmospheric Laboratory for Applications in Science-1 (ATLAS-1) Spacelab mission. Byron Lichtenberg (NASA Science Astronaut) and Anthony O'Neil (ATLAS-1 Mission Manager) explain that the 13 sophisticated and complementary instruments carried in shuttle Atlantis' payload bay are designed to identify the chemical species in our atmosphere, to measure the Sun's energy falling on and entering the atmosphere, to study the behavior of charged particles in the electric and magnetic fields surrounding the earth, and to gather ultraviolet light from stars and galaxies. ATLAS-1 is the first Spacelab flight of the National Aeronautics and Space Administration's (NASA's) Mission to Planet Earth.

Source record↗

NASA's Robotic Lunar Exploration Program (RLEP) 2 Mission

Before returning humans to the Moon for mankind's seventh lunar landing, NASA will embark upon a series of robotic missions to prepare the way for further exploration. These missions, part of the Robotic Lunar Exploration Program (RLEP), are designed to acquire decisive knowledge about the moon as well as to develop infrastructure needed to sustain human exploration in the lunar environment. Here we focus on the second mission in the RLEP program, RLEP-2, the first dedicated to landing in the south polar region of the moon. Managed by NASA's Marshall Space Flight Center in Huntsville, Alabama, along with the Applied Physics Laboratory and NASA Goddard Space Flight Center, RLEP-2 will build upon knowledge gained from the Chandraayan-1 and Lunar Robotic Orbiter orbital missions, to help further the prospects for sustainable human exploration on the moon. This mission will characterize the lighting environment in the polar region, critically important to understanding the amount of power available and to the thermal design of hardware, as well as explore the nature and distribution of volatiles that may be present in permanently shadowed regions of polar craters. We shall review the current status of the mission, articulate the results of onoging trade studies in power, surface mobility, launch vehicles, measurements and instrumentation, and navigation/communication, as well as discuss the primary mission objectives in detail.

Horack, John M.↗

Developing a Machine-Learning-Based Processing Framework for Twitter and Other Crowdsourced Data

Crowdsourced data streams such as Twitter and other social media are important sources of real-time and historical global information for Earth science applications. At the NASA Goddard Earth Sciences Data and Information Services Center (GES DISC), we have been exploring the Twitter data stream for its potential in augmenting the validation program of NASA's Global Precipitation Measurement (GPM) mission. To realize this potential, we need to increase the information density and enhance the quality of filtered precipitation tweets. We have implemented various components of a machine learning (ML)-based processing infrastructure for crowdsourced data that outputs, in this instance, useful and usable information derived from precipitation tweets. We have test enriched the Twitter stream with higher quality active tweets from those knowingly contributing to our effort and from existing crowdsourced programs (e.g., mPING, CoCoRaHS). We have experimented with various algorithms for processing tweets, including Naà ve Bayes, Convolutional Neural Network (CNN), Hierarchical Attention Network (HAN), and semi-supervised learning (with tri-training). Our current work focuses on (1) automated review of Earth science-related publications to determine relationships between discipline research needs and ML algorithms; (2) investigating Sequential Generative Adversarial Network (SeqGAN) for processing precipitation tweets for anomaly detection; and (3) managing crowdsourced data in a way that is compatible with existing NASA satellite data archives and using the data for ML applications. Key results include (1) network visualization of NLP-processed publications in various Earth science disciplines; (2) difference between GPM-linked, generated tweets and collected actual tweets that is small for GPM-determined light to moderate rain cases and high for GPM-determined heavy rain cases; and (3) identification of MongoDB for storing raw tweets and Zarr format for gridded tweets (compatible with GPM data). Our results have taken us a step closer to an operational ML-based tweet processing infrastructure and have already demonstrated that tweet-derived precipitation information is potentially useful for validation of Earth science satellite data.

Teng, William↗

Inducing Circularly Polarized Single-Photon Emission via Chiral-Induced Spin Selectivity

One of the central aims of the field of spintronics is the control of individual electron spins to effectively manage the transmission of quantized data. One well-known mechanism for controlling electronic spin transport is the chiral-induced spin-selectivity (CISS) effect in which a helical nanostructure imparts a preferential spin orientation on the electronic transport. One potential application of the CISS effect is as a transduction pathway between electronic spin and circularly polarized light within nonreciprocal photonic devices. Here in this work, we identify and quantify the degree of chiral-induced spin-selective electronic transport in helical polyaniline films using magnetoconductive atomic force microscopy (mcAFM). We then induce circularly polarized quantum light emission from CdSe/CdS core/shell quantum dots placed on these films, demonstrating a degree of circular polarization of up to ~21%. Utilizing time-resolved photoluminescence microscopy, we measure the radiative lifetime difference associated with left- and right-handed circular polarizations of single emitters. These lifetime differences, in combination with Kelvin probe mapping of the variation of surface potential with magnetization of the substrate, help establish an energy level diagram describing the spin-dependent transport pathways that enable the circularly polarized photoluminescence.

36 MATERIALS SCIENCE↗

Recycling polyolefin plastic waste at short contact times via rapid joule heating

Abstract The chemical deconstruction of polyolefins to fuels, lubricants, and waxes offers a promising strategy for mitigating their accumulation in landfills and the environment. Yet, achieving true recyclability of polyolefins into C 2 -C 4 monomers with high yields, low energy demand, and low carbon dioxide emissions under realistic polymer-to-catalyst ratios remains elusive. Here, we demonstrate a single-step electrified approach utilizing Rapid Joule Heating over an H-ZSM-5 catalyst to efficiently deconstruct polyolefin plastic waste into light olefins (C 2 -C 4 ) in milliseconds, with high productivity at much higher polymer-to-catalyst ratio than prior work. The catalyst is essential in producing a narrow distribution of light olefins. Pulsed operation and steam co-feeding enable highly selective deconstruction (product fraction of >90% towards C 2 -C 4 hydrocarbons) with minimal catalyst deactivation compared to Continuous Joule Heating. This laboratory-scale approach demonstrates effective deconstruction of real-life waste materials, resilience to additives and impurities, and versatility for circular polyolefin plastic waste management.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗