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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 505 records · Page 28

Debris/ice/TPS assessment and photographic analysis for shuttle mission STS-44

A debris/ice/TPS assessment and photographic analysis was conducted for space shuttle mission STS-44. Debris inspection of the flight elements and launch pad were performed before and after the launch. Ice/frost conditions on the external tank were assessed by the use of computer programs, nomographs, and infrared scanner data during cryogenic loading of the vehicle followed by on-pad visual inspection. High speed photography was analyzed after launch to identify ice/debris sources and evaluate potential vehicle damage and/or in-flight anomalies. The debris/ice/TPS conditions and photographic analysis of mission STS-44 are documented, along with their overall effect on the space shuttle program.

Katnik, Gregory N.↗

Debris/ice/TPS assessment and photographic analysis for Shuttle Mission STS-33R

A debris/ice/Thermal Protection System (TPS) assessment and photographic analysis was conducted for Space Shuttle Mission STS-33R. Debris inspections of the flight elements and launch pad are performed before and after launch. Ice/frost conditions on the external tank are assessed by the use of computer programs, nomographs, and infrared scanner data during cryogenic loading of the vehicle followed by on-pad visual inspection. High speed photography is analyzed after launch to identify ice/debris sources and evaluate potential vehicle damage and/or in-flight anomalies. This report documents the debris/ice/TPS conditions and photographic analysis of Mission STS-33R, and their overall effect on the Space Shuttle Program.

Stevenson, Charles G.↗

Debris/ice/TPS assessment and photographic analysis for shuttle mission STS-31R

A Debris/Ice/Thermal Protection System (TPS) assessment and photographic analysis was conducted for Space Shuttle Mission STS-31R. Debris inspections of the flight elements and launch pad are performed before and after launch. Ice/frost conditions on the External Tank are assessed by the use of computer programs, nomographs, and infrared scanner data during cryogenic loading of the vehicle followed by on-pad visual inspection. High speed photography is analyzed after launch to identify ice/debris sources and evaluate potential vehicle damage and/or in-flight anomalies. The debris/ice/TPS conditions and photographic analysis of Mission STS-31R, is presented along with their overall effect on the Space Shuttle Program.

Katnik, Gregory N.↗

The effects of solid rocket motor effluents on selected surfaces and solid particle size, distribution, and composition for simulated shuttle booster separation motors

A series of three tests was conducted using solid rocket propellants to determine the effects a solid rocket plume would have on thermal protective surfaces (TPS). The surfaces tested were those which are baselined for the shuttle vehicle. The propellants used were to simulate the separation solid rocket motors (SSRM) that separate the solid rocket boosters (SRB) from the shuttle launch vehicle. Data cover: (1) the optical effects of the plume environment on spacecraft related surfaces, and (2) the solid particle size, distribution, and composition at TPS sample locations.

Jex, D. W.↗

Debris/ice/TPS assessment and photographic analysis for Shuttle Mission STS-28R

A Debris/Ice/TPS assessment and photographic analysis was conducted for Space Shuttle Mission STS-28R. Debris inspections of the flight elements and launch pad are performed before and after launch. Ice/Frost conditions on the External Tank are assessed by the use of computer programs, nomographs, and infrared scanner data during cryogenic loading of the nomographs, and infrared scanner data during cryogenic loading of the vehicle followed by on-pad visual inspection. High speed photography is analyzed after launch to identify ice/debris sources and evaluate potential vehicle damage and/or in-flight anomalies. The debris/ice/TPS conditions and photographic analysis of Mission STS-28R is documented along with their overall effect on the Space Shuttle Program.

Stevenson, Charles G.↗

The Space Transportation System summer environment on launch pad

This paper describes a 2D flow and thermalanalysis to determine the solar effect on the Space Shuttle launch components subsequent to the external tank (ET) loading operation in extremely hot conditions. An existing CFD code Parabolic Hyperbolic or Elliptical Numerical Integration Code Series was used in the study. The analysis was done for a 2D slice between planes perpendicular to the longitudinal axis of the STS and passing through the lower portions of the Redesigned Solid Rocket Motors (RSRMs), the ET, and the wing of the Orbiter. The results are presented as local and average values of the heat transfer coefficient, and the Nusselt number, and the surface temperature around the RSRMs and the ET. Solar heating effects increased the surface temperatures of the RSRMs by 9-11 F. Higher prelaunch surface temperatures measured on the east and west RSRMs (in the inboard region between the RSRMs and the ET) during 19 most recent launches of the STS are correlated as a function of the ambient temperature.

Ahmad, R. A.↗

A Metal Organic Framework Derived Solid Electrolyte for Lithium–Sulfur Batteries

Lithium–sulfur batteries (LSBs) are currently considered as promising candidates for next-generation energy storage technologies. However, their practical application is hindered by the critical issue of the polysulfide-shuttle. Herein, a metal organic framework (MOF)-derived solid electrolyte is presented to address it. The MOF solid electrolyte is developed based on a Universitetet i Oslo (UIO) structure. By grafting a lithium sulfonate (-SO 3 Li) group to the UIO ligand, both the ionic conductivity and the polysulfide-suppression capability of the resulting -SO 3 Li grafted UIO (UIOSLi) solid electrolyte are greatly improved. After integrating a Li-based ionic liquid (Li-IL), lithium bis(trifluoromethanesulfonyl)imide in 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, the resulting Li-IL/UIOSLi solid electrolyte exhibits an ionic conductivity of 3.3 × 10 -4 S cm -1 at room temperature. Based on its unique structure, the Li-IL/UIOSLi solid electrolyte effectively restrains the polysulfide shuttle and suppresses lithium dendritic growth. Lithium–sulfur cells with the Li-IL/UIOSLi solid electrolyte and a Li 2 S 6 catholyte show stable cycling performance that preserves 84% of the initial capacity after 250 cycles with a capacity-fade rate of 0.06% per cycle.

25 ENERGY STORAGE↗

Exposure of spacecraft coatings (S0010)

The objectives of this LDEF experiment are to determine the effects of both the Shuttle-induced environment and the space radiation environment on selected sets of spacecraft thermal control coatings. The experimental approach is to passively expose samples of thermal control coatings to Shuttle-induced and space radiation environments and to return the samples for postflight evaluation and comparison with preflight measurements to determine the effects of the environmental exposure. Optical measurements of the samples will include total normal emittance and spectral reflectance. The experiment will utilize a 6 in. deep peripheral tray and an experiment exposure control canister (EECC). The EECC will provide protection for some of the samples against exposure to the launch and reentry environments. The EECC will be programmed to open about 2 weeks after LDEF deployment and close pior to LDEF retrieval by the Shuttle and reentry. Some samples will not be housed in the EECC and will be exposed to the Shuttle-induced environment during launch and reentry. Comparison of the data from these samples with data from samples in the EECC will yield information about possible contamination induced degradation effects.

Slemp, W. S.↗

Solvent Effects on Catalytic Reactions and Related Phenomena at Liquid-Solid Interfaces

Catalytic reactions involve the direct interaction of reactants, intermediates and products with the catalyst surface. We not only need to control the atomic structure and electronic properties of the active site, but also explore the multiple molecular interactions that occur beyond the active site; they play an essential role in altering the binding and reactivity of surface species. In liquid-phase catalysis, solvents provide additional degrees of freedom in the design of the catalytic process for desirable activity and selectivity. Here, the multi-faceted effects of solvents have a profound impact on the catalyst performance by restricting the mass transfer to the site, tuning the chemical potential of the surface species, competing for active sites, stabilizing the initial and transition states, and causing mechanistic changes by participating in the kinetically relevant elementary steps. This review addresses the different aspects of solvent effects, using a few prototype solid-liquid interfaces to illustrate these fundamental features. Recent experimental and computational studies that provide new insight at the molecular level are examined. Solvent structures in the proximity of the catalyst surface are discussed along with their influence in molecular binding and reaction at the solid-liquid interfaces. Furthermore, opportunities to alter such a solid-liquid interaction by tuning the wettability of the catalyst surfaces are explored.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Abort separation study of a shuttle orbiter and external tank at hypersonic speeds

The effects of several parameters on the relative motions of a space shuttle orbiter design and its external tank were determined during staging for the return-to-launch-site abort mode. The parameters included angle of attack, dynamic pressure, flight-path angle, pitch rate, elevon effectiveness and the use of thrust applied to the tank. The relative positions of each component were determined by a separation trajectory computer program which incorporated data obtained in wind-tunnel tests with the orbiter and tank in proximity. These tests were conducted at Mach 10.3 in a continuous-flow hypersonic tunnel. All separation cases were initiated at a constant Mach number of 10 with an assumed sideslip angle of 0 deg.

Bernot, P. T.↗

Effect of internal convection and internal radiation on the structural temperatures of Space Shuttle Orbiter

Structural performance and resizing of the finite-element thermal analysis computer program was used in the reentry heat transfer analysis of the space shuttle orbiter. One midfuselage cross section and one midspan wing segment were selected to study the effects of internal convection and internal radiation on the structural temperatures. The effect of internal convection was found to be more prominent than that of internal radiation in the orbiter thermal analysis. Without these two effects, the calculated structural temperatures at certain stations could be as much as 45 to 90 percent higher than the measured values. By considering internal convection as free convection, the correlation between the predicted and measured structural temperatures could be improved greatly.

Ko, William L.↗

The Effect of Acoustic Disturbances on the Operation of the Space Shuttle Main Engine Fuel Flowmeter

The Space Shuttle Main Engine (SSME) uses a turbine fuel flowmeter (FFM) in its Low Pressure Fuel Duct (LPFD) to measure liquid hydrogen flowrates during engine operation. The flowmeter is required to provide accurate and robust measurements of flow rates ranging from 10000 to 18000 GPM in an environment contaminated by duct vibration and duct internal acoustic disturbances. Errors exceeding 0.5% can have a significant impact on engine operation and mission completion. The accuracy of each sensor is monitored during hot-fire engine tests on the ground. Flow meters which do not meet requirements are not flown. Among other parameters, the device is screened for a specific behavior in which a small shift in the flow rate reading is registered during a period in which the actual fuel flow as measured by a facility meter does not change. Such behavior has been observed over the years for specific builds of the FFM and must be avoided or limited in magnitude in flight. Various analyses of the recorded data have been made prior to this report in an effort to understand the cause of the phenomenon; however, no conclusive cause for the shift in the instrument behavior has been found. The present report proposes an explanation of the phenomenon based on interactions between acoustic pressure disturbances in the duct and the wakes produced by the FFM flow straightener. Physical insight into the effects of acoustic plane wave disturbances was obtained using a simple analytical model. Based on that model, a series of three-dimensional unsteady viscous flow computational fluid dynamics (CFD) simulations were performed using the MSFC PHANTOM turbomachinery code. The code was customized to allow the FFM rotor speed to change at every time step according to the instantaneous fluid forces on the rotor, that, in turn, are affected by acoustic plane pressure waves propagating through the device. The results of the simulations show the variation in the rotation rate of the flowmeter due to the interaction of the flow straightener wakes and the upstream propagating acoustic waves. A detailed analysis of the acoustic disturbance effects is presented along with an assessment of the impact on measurement accuracy.

Marcu, Bogdan↗

Force and moment tests to determine the interaction effects of the reaction control system jet plumes on the space shuttle Orbiter aerodynamics at Mach Number 6 (Test OA352)

The purpose of this test was to expand the existing Space Shuttle aerodynamics and Reaction Control System (RCS) data base to support the Glide Return to Launch Site (GRTLS) abort trajectory and the new Digital Autopilot. An existing model of the orbiter was used to investigate the aerodynamic effects of several combinations of RCS thrusters and thruster momentum ratios at Mach number 6. Two separate model installations were used to achieve an angle-of-attack range of -11 to 46 deg. The test was conducted at a unit Reynolds number of 0.8 x 10 to the 6th per foot.

Cayse, Robert W.↗

Effects of the six engine air breathing propulsion system on space shuttle orbiter subsonic stability and control characteristics

Experimental aerodynamic investigations were conducted on a 0.0405 scale representation of the -89B space shuttle orbiter in the 7.75 x 11.00 foot low speed wind tunnel during the time period September 4 - 14, 1973. The primary test objective was to optimize the air breathing propulsion system nacelle cowl-inlet design and to determine the aerodynamic effects of this design on the orbiter stability and control characteristics. Nacelle cowl-inlet optimization was determined from total pressure - static pressure measurements obtained from pressure rakes located in the left hand nacelle pod at the engine face station. After the optimum cow-inlet design, consisting of a 7 deg cowl lip angle, short cowl, 7 deg short diverter, and a nacelle toe-in angle of 5 deg was selected, the aerodynamic effects of various locations of this design were investigated. The 3 pod - 6 Nacelle configuration was tested both underwing and overwing in three different longitudinal locations. Orbiter control effectiveness, both with and without Nacelles, was investigated at elevon deflections of 0 deg, -10 deg and +15 deg and at aileron deflections of 0 deg and +10 deg about 0 deg elevon.

Mennell, R. C.↗

Exploring Fluoropyridine Electrolytes in Li–S Batteries: Balancing Performance and Stability across Temperatures

A novel high-donor 3-fluoropyridine (3FPy) electrolyte has been introduced for use in Li-S batteries, demonstrating an inhibition effect on the polysulfide shuttle, even without the addition of LiNO 3 . In this study, fluoropyridine electrolytes, including 2-fluoropyridine (2FPy) and 3FPy electrolytes, are studied using electrochemical analysis, mass spectrometry (MS), and high-performance liquid chromatography (HPLC) methods. Collision-induced dissociation spectra revealed that Li + preferentially solvates with different fluoropyridines, with 2FPy exhibiting a stronger interaction due to ortho-fluorine's influence, compared to 4FPy and 3FPy. However, MS and HPLC analyses showed that 2FPy is reactive with polysulfides, while 3FPy offers high solubility for polysulfides and sulfur without reacting with them at room temperature. Further, despite 3FPy performing well at room temperature, further electrochemistry studies at elevated (60 °C) and reduced (0 °C) temperatures reveal the challenges. At high temperatures, LiNO 3 is essential to suppress the polysulfide shuttle; and at low temperatures, the performance with the 3FPy electrolyte significantly lags behind that of the ether-based electrolyte.

25 ENERGY STORAGE↗