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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 505 records · Page 28

Integration of Retail and Wholesale Markets: Modeling Framework and Stability Analysis

As power systems cope with increasing amounts of renewable generation, there is an increasing need to engage flexible demand-side resources and distributed energy resources (DERs) into power systems operations. However engagine millions of DERs in a reliable manner into power systems operations can be a challenging problem. Retail markets can facilitate this by providing a platform to aggregate the flexibility of DERs and bid the aggregate flexibility into wholesale markets. However, unlike generators (which can typically be modeled accurately with capacity constraints and ramping limits), most flexible loads have physical dynamics (like air conditioners) that couples their flexibility over time. This coupling could have unintended undesirable consequences (for example, instability and oscillations in prices and other physical quantities). In this paper, we propose a simple model to capture evolution of load flexibility over time and analyze stability of the interconnection between wholesale and retail electricity markets. We prove that under a natural model of flexibility evolution (assuming a constant base load), oscillations cannot occur and prices converge to a unique equilibrium model quickly.

Ramachandran, Thiagarajan↗

(Doublon) Benchmarking of Different Inverse Point Kinetics Implementations for an Autocorrected Reactimeter Algorithm

In November 2017, the Transient Reactor Test Facility returned to operation. Since that time, many transient test series have been completed, such as the Transient Heatsink Overpower Response capsule (THOR), the Transient Water Irradiation System for TREAT (TWIST), and Sirius. Each has provided valuable data for materials performance and reactor safety that can be applied in future designs. During each experimental series, detector count rates provided important information on the core behavior during transients. However, a limitation of these data is that variations in the neutron distribution during experiments can cause errors when attempting to infer reactivity evolution from detector signals. Neutron physics codes can be used to compute the flux shape variations. However, this is a poor solution when the experimental data is used for code verification, validation and uncertainty quantification. Indeed, if the output of the code is used both as a reference and to correct what the reference is compared to, the circular dependency limits the quality of the verification, validation and uncertainty quantification approach. To overcome this problem, the autocorrected reactimeter algorithm (ACRA) has been developed. This approach infers a time-dependent reactivity evolution by testing different spatial corrections and selecting the one that minimizes reactivity variations when the core is in a frozen configuration (i.e., when there is no variation in parameters affecting reactivity). However, the scope of this method was limited to transients where there were negligible thermal feedback. Indeed, the core is never in a frozen configuration when the fuel temperature varies during the whole transient. This is our motivation for developing an improved version of the ACRA that does not require frozen configurations. To develop this new algorithm, we need a precise and unbiased implementation of the inverse point kinetic equations (IPKEs) as any error in the reactivity evaluation will be propagated into the choice of the optimal spatial correction. Indeed, the previous reactimeter algorithm would use approximations, such as a negligible flux amplitude derivative, to focus on rapidity. For the numerical validation of ACRA, we aim at absolute error under for reactivity derived from signals similar to the one of this study. In this summary, we test eight different IPKE implementations. Each will process a mockup signal built for this study, similar to those that the future ACRA will process. Each reactivity output will be compared to the reference reactivity that has been used to generate the mockup signal. The implementation minimizing the difference with the reference reactivity will be used in the development of a new ACRA formulation.

73 - NUCLEAR PHYSICS AND RADIATION PHYSICS↗

The Long Term Evolution of ASASSN-14li

We present late-time optical spectroscopy taken with the Large Binocular Telescope's Multi-Object Double Spectrograph, late-time Swift UVOT and X-ray Telescope observations, as well as improved All-Sky Automated Survey for SuperNovae (ASAS-SN) pre-discovery limits on the nearby (d = 90.3 Mpc, z = 0.0206) tidal disruption event (TDE) ASASSN-14li. The late-time optical spectra show Hα emission well in excess of that seen in the SDSS host galaxy spectrum, indicating that the processes powering the luminous flares associated with TDEs can operate for several hundreds of days. The Swift observations reveal the presence of lingering apparently thermal UV (TUV ~ 3.5 × 10 4 K) and X-ray (TX ~ 7 × 10 5 K) emission. The characteristic temperatures evolve by, at most, a factor of ~2 over the 600 d follow-up campaign. The X-ray, UV and Hα luminosities evolve roughly in tandem and at a rate that is consistent with a power-law decay at late times. This behaviour is in stark contrast with the majority of optically discovered TDEs, which are X-ray faint and evolve on shorter time-scales. Finally, we address how the unique properties of ASASSN-14li can be used to probe the relationship between the TDE rate and host galaxy properties.

79 ASTRONOMY AND ASTROPHYSICS↗

Simultaneously Dual Modification of Ni-Rich Layered Oxide Cathode for High-Energy Lithium-Ion Batteries

A critical challenge in the commercialization of layer-structured Ni-rich materials is the fast capacity drop and voltage fading due to the interfacial instability and bulk structural degradation of the cathodes during battery operation. Herein, with the guidance of theoretical calculations of migration energy difference between La and Ti from the surface to the inside of LiNi 0.8 Co 0.1 Mn 0.1 O 2 , for the first time, Ti-doped and La 4 NiLiO 8 -coated LiNi 0.8 Co 0.1 Mn 0.1 O 2 cathodes are rationally designed and prepared, via a simple and convenient dual-modification strategy of synchronous synthesis and in situ modification. Impressively, the dual modified materials show remarkably improved electrochemical performance and largely suppressed voltage fading, even under exertive operational conditions at elevated temperature and under extended cutoff voltage. Further studies reveal that the nanoscale structural degradation on material surfaces and the appearance of intergranular cracks associated with the inconsistent evolution of structural degradation at the particle level can be effectively suppressed by the synergetic effect of the conductive La 4 NiLiO 8 coating layer and the strong Ti—O bond. The present work demonstrates that our strategy can simultaneously address the two issues with respect to interfacial instability and bulk structural degradation, and it represents a significant progress in the development of advanced cathode materials for high-performance lithium-ion batteries.

36 MATERIALS SCIENCE↗

Competing effects of Kerr nonlinearity and K-photon absorptions on continuous-wave laser inscriptions

Material processing with laser offers a reliable tool in a large variety of micromachining technology, ranging from on-disc inscriptions to cell ablations through DNA combing and imprinting for fabrications of micro and nanofluidic devices. In these applications lasers are designed to operate in specific regimes characterized by their powers and wavelengths, so understanding characteristic properties of the distinct possible laser operation regimes turns out to be a relevant step toward optimization of their uses as well as improvement of the technology. In this work we examine the stability of a model of femtosecond laser intended for laser inscriptions in nonlinear transparent media, taking into consideration the laser-induced material damage and multiphoton ionization. The model approximates the laser dynamics by a complex Ginzburg–Landau equation with a Kerr plus a high-order nonlinear term accounting for K-photon ionization, coupled to a Drude equation for time evolution of the electron plasma density. Following the Benjamin–Feir instability theory it is shown that depending on characteristic parameters of the model, multiphoton ionization processes can stabilize continuous-wave or pulse regimes. These parameters include the group-delay dispersion, the linear and nonlinear gains, the phase shift per roundtrip and the plasma ionization rate.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Enabling BWR fuel rod analysis in the BISON fuel performance code

Nuclear fuel vendors around the world are pursuing approaches to sustain the existing nuclear reactor fleet consisting primarily of pressurized-water reactors (PWRs) and boiling-water reactors (BWRs). To support the industry's efforts, advanced modeling and simulation tools need to be capable of analyzing both legacy reactor concepts. BWR fuel rods are significantly different than those used in PWRs, which can affect fuel performance analysis. BWR fuel rods include: (1) an extensive use of gadolinia dopant as a burnable absorber, (2) an axial variation in fuel enrichment and gadolinia content, (3) the inclusion of a liner on the inner cladding surface to mitigate the impact of pellet-clad mechanical interaction (which impacts hydrogen and hydride distribution), (4) a lower initial fill gas pressure, (5) bottom-entry control rods, and (6) a lower coolant pressure that results in the two-phase flow boiling phenomenon. Although the primary focus of BISON has been in the area of PWR and advanced reactor fuel analyses, this paper presents the developments in BISON to support BWR fuel performance analysis. An overview of the models that account for the effects of gadolinia is highlighted. Internal mesh generation capabilities to include a liner is presented. Normal operating and transient (reactivity insertion accident) demonstration problems are presented to illustrate the impact of gadolinia, the hydrogen and hydride evolution due to the presence of the liner, and BISON's ability to simulate axially varying enrichments and dopant concentration. Bottom-entry control effects are captured by the axial power peaking factors present in the demonstration cases. Comparisons to integral experiments from the Halden IFA-681 experiments are discussed as initial validation. Reasonable comparisons are obtained for fuel centerline temperature and rod internal pressure as a function of time. In conclusion, simulations of additional experiments containing Gd 2 O 3 -bearing fuel are necessary to completely validate the code for BWR applications.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Instantaneous tracking of earthquake growth with elastogravity signals

Rapid and reliable estimation of large earthquake magnitude (above 8) is key to mitigating the risks associated with strong shaking and tsunamis. Standard early warning systems based on seismic waves fail to rapidly estimate the size of such large earthquakes. Geodesy-based approaches provide better estimations, but are also subject to large uncertainties and latency associated with the slowness of seismic waves. Recently discovered speed-of-light prompt elastogravity signals (PEGS) have raised hopes that these limitations may be overcome, but have not been tested for operational early warning. Here we show that PEGS can be used in real time to track earthquake growth instantaneously after the event reaches a certain magnitude. We develop a deep learning model that leverages the information carried by PEGS recorded by regional broadband seismometers in Japan before the arrival of seismic waves. After training on a database of synthetic waveforms augmented with empirical noise, we show that the algorithm can instantaneously track an earthquake source time function on real data. Our model unlocks ‘true real-time’ access to the rupture evolution of large earthquakes using a portion of seismograms that is routinely treated as noise, and can be immediately transformative for tsunami early warning.

58 GEOSCIENCES↗

Influence of 3D plasmoid dynamics on the transition from collisional to kinetic reconnection

Within the resistive magnetohydrodynamic model, high-Lundquist number reconnection layers are unstable to the plasmoid instability, leading to a turbulent evolution where the reconnection rate can be independent of the underlying resistivity. However, the physical relevance of these results remains questionable for many applications. First, the reconnection electric field is often well above the runaway limit, implying that collisional resistivity is invalid. Furthermore, both theory and simulations suggest that plasmoid formation may rapidly induce a transition to kinetic scales, due to the formation of thin current sheets. Here, this problem is studied for the first time using a first-principles kinetic simulation with a Fokker-Planck collision operator in 3D. The low-β reconnecting current layer thins rapidly due to Joule heating before the onset of the oblique plasmoid instability. Linear growth rates for standard (k y = 0) tearing modes agree with semicollisional boundary layer theory, but the angular spectrum of oblique (|k y |>0) modes is significantly narrower than predicted. In the nonlinear regime, flux-ropes formed by the instability undergo complex interactions as they are advected and rotated by the reconnection outflow jets, leading to a turbulent state with stochastic magnetic field. In a manner similar to previous 2D results, super-Dreicer fields induce a transition to kinetic reconnection in thin current layers that form between flux-ropes. These results may be testable within new laboratory experiments.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Infrared imaging systems for wall protection in the W7-X stellarator (invited)

Here, Wendelstein 7-X aims at quasi-steady state operation with up to 10 MW of heating power for 30 min. Power exhaust will be handled predominantly via 10 actively water cooled CFC (carbon-fiber-reinforced carbon) based divertor units designed to withstand power loads of 10 MW/m 2 locally in steady state. If local loads exceed this value, a risk of local delamination of the CFC and failure of entire divertor modules arises. Infrared endoscopes to monitor all main plasma facing components are being prepared, and near real time software tools are under development to identify areas of excessive temperature rise, to distinguish them from non-critical events, and to trigger alarms. Tests with different cameras were made in the recent campaign. Long pulse operation enforces additional diagnostic design constraints: for example, the optics need to be thermally decoupled from the endoscope housing. In the upcoming experimental campaign, a graphite scraper element, in front of the island divertor throat, will be tested as a possible means to protect the divertor pumping gap edges during the transient discharge evolution.

47 OTHER INSTRUMENTATION↗

Integrated modeling of advanced tokamaks for tearing mode avoidance on DIII-D

Understanding the physics of the onset and evolution of tearing modes (TMs) in tokamak plasmas is crucial for high-performance steady-state operations. The onset condition of (m,n) = (2,1) tearing stability, $Δ′$ > $Δ_c^′$> 0, has been studied in DIII-D steady-state hybrid discharges with accurate equilibrium reconstruction and well-measured plasma profiles. Here, m is the poloidal mode number and n is the toroidal mode number. The onset of n = 1 TMs is carefully identified using the Mirnov array to determine in-phase signals for the onset time and using electron cyclotron emission measurements to trace back from the saturated island width in the experiments for both initial island width and its growth rate. The tearing stability index $Δ′$ at TM onset is calculated in multiple ways, using the modified Rutherford equation and using the PEST-III or resistive DCON magnetohydrodynamic codes, and the results are in reasonable agreement with each other. The calculated $Δ′$ is compared with an analytical formula of the tearing stability threshold $Δ_c^′$ to determine the condition for the mode onset, $Δ′$ > $Δ_c^′$. Finally, the local gradient effect of the plasma current and the pressure profiles on the tearing stability is investigated in terms of the difference between $Δ′$ and $Δ_c^′$ through a series of modeled equilibria with the parametric variations. A database of experimental mode instability onsets is compatible with the simulated regions of instability obtained from the parametric variations.

Linear stability analysis↗

SMART – A Comprehensive Research and Development Program to Demonstrate Application of Machine Learning for Supporting CCS Deployment

Presentation material for a paper presented at the GHGT-17 conference, Calgary, Canada, October 20-24, 2024. The objective of the US Department of Energy’s SMART Initiative, i.e., Science-informed Machine Learning (ML) for Accelerating Real-Time Decisions in Subsurface Applications, is to showcase how the utilization of ML can significantly improve efficiency and effectiveness of field-scale commercial carbon storage operations. This paper will present the results from the current phase of SMART (field deployment) for demonstrating the applicability of ML-based tools and workflows for: (a) virtual learning during the pre-injection permitting phase, (b) advanced storage reservoir imaging to better characterize fractures and faults, and (c) dynamic storage reservoir modelling and optimization to inform operational decision making and visualization of system evolution.

CO2 geologic storage↗

SMART – A Comprehensive Research and Development Program to Demonstrate Application of Machine Learning for Supporting CCS Deployment

The objective of the US Department of Energy’s SMART Initiative, i.e., Science-informed Machine Learning (ML) for Accelerating Real-Time Decisions in Subsurface Applications, is to showcase how the utilization of ML can significantly improve efficiency and effectiveness of field-scale commercial carbon storage operations. This paper will present the results from the current phase of SMART (field deployment) for demonstrating the applicability of ML-based tools and workflows for: (a) virtual learning during the pre-injection permitting phase, (b) advanced storage reservoir imaging to better characterize fractures and faults, and (c) dynamic storage reservoir modelling and optimization to inform operational decision making and visualization of system evolution.

Siriwardane, Hema↗

Kinetic Coupling of Water Splitting and Photoreforming on SrTiO 3 -Based Photocatalysts

Coupling the anodic half-reactions of overall water splitting and oxygenate photoreforming (i.e., proton reduction and oxygenate oxidations) on Al-doped SrTiO3 decorated with a co-catalyst enables efficient photocatalytic H2 generation along with oxygenate conversion without accumulating undesired intermediates such as formaldehyde. The net H2-evolution rates result from the interplay between water oxidation, oxygenate oxidation, and the back-reaction of H2 and O2 to water. When the latter pathway is quantitatively suppressed (e.g., on RhCrOx co-catalyst or in excess of oxygenated hydrocarbons), the initial H2-evolution rates are independent of the oxygenate nature and concentration. This is a consequence of the reduction equivalents for H2-evolution provided by water oxidation compensating changes in the rates of oxygenate conversion. Thus, under conditions of suppressed back-reaction, water and oxygenate oxidations have equal quantum efficiencies. The selectivities to water and oxygenate oxidation depend on oxygenate nature and concentration. Transformations mediated by indirect hole transfer dominate as a result of the water oxidation at the anode and the associated intermediates generated in O2-evolution catalysis (e.g. ·OH, ·O and ·OOH). On the undecorated semiconductor, the O2 produced during overall water splitting is reductively activated to participate in glycerol oxidation without consuming evolved H2. Acknowledgements The authors would like to thank ESRF in Grenoble, France, for providing beam time at the ID26 station for XAFS experiments. K.E.S. gratefully acknowledges financial support by the Fond der Chemischen Industrie (FCI). J.A.L. and O.Y.G. acknowledge support for his contribution by the Laboratory Directed Research and Development Program at Pacific Northwest National Laboratory, a multi-program national laboratory operated by Battelle for the U.S. Department of Energy. The authors thank Xaver Hecht for BET measurements, Martin Neukamm for SEM and AAS measurements and Dr. Udishnu Sanyal for TEM imaging. Christine Schwarz is acknowledged for technical assistance in NMR experiments.

Sanwald, Kai E.↗

Assessment of ITER radiation environment during the remote-handling operation of In-Vessel components with D1SUNED

During ITER operational life, a remote-handled cask will be used to transfer In-Vessel components to the Hot Cell for maintenance, storage and decommissioning purposes. Due to the distribution of penetrations for system allocation in the facility, the radiation field of each transfer operation presents a high spatial variability; all operations must be studied independently for workers and electronics protection. In this paper, we present a fully representative approach to describe the radiation environment during the complete remote-handling scenario of In-Vessel components in the ITER facility. The impact of all relevant radiation sources during different stages of the operation is addressed. As-built structures and 2020 baseline designs are considered to produce the most detailed neutronics model of the Tokamak Complex, the 400,000-tonne civil structure hosting the tokamak, up to date. Novel capabilities of the D1SUNED code have allowed to compute the integral dose, the dose rate and the photon-induced neutron flux of both moving and static radiation sources. Time bins are included in the simulations to compute the dose rate caused by In-Vessel components at all positions along the transfer. The time evolution of the dose rate is built in video format with a 1-m resolution, especially valuable for hot-spots identification.

42 ENGINEERING↗

A Computational Review of Privacy-Preserving Mechanisms for the Smart Grid

Smart grid technologies have rapidly become one of the largest and most comprehensive sources of data for the modern utility. For the most part, data streams are seen as an essential tool that enable utilities to carry their day-to-day business operations, but they also create the need for efficient and secure data management strategies. In the context of the smart grid, ensuring data privacy is becoming an increasing concern due to a combination of factors that range from shifts in operational paradigms and rapid technology evolution to changes in legislation. Furthermore, researchers have highlighted the risks associated with improperly protected energy records. For example, energy consumption data from homes could be used to infer the behaviors and habits of home occupants through activity recognition or user profiling (Fan, 2017), which may lead to unfair service pricing, targeted advertising, or other personal security violations. Similarly, Electric Vehicles’ (EVs) charging metadata could be used to reveal private information about the owner such as their payment methods, preferred charging stations, and other locational and timing information that could be used to reconstruct the vehicle owner’s behaviors. The privacy of user data, even when used for statistical analysis or machine learning training processes, also needs to be carefully considered, as an individual’s private traits may still be vulnerable if their inclusion/exclusion greatly impacts the result or could be linked to a public dataset through cross-reference. The breach of user privacy also has severe impacts for organizations that store, transmit, or work on the data in the form of diminishing the public’s trust in them while potentially incurring legal consequences (e.g., fines and suspensions under the European Union General Data Protection Regulation, Health Insurance Portability and Accountability Act, etc.). Because of these risks, several privacy-preserving mechanisms are available to help organizations comply with privacy legislations and prevent the unauthorized and malicious use of user data. In light of these concerns, this report focuses on performing a computational review of privacy-preserving mechanisms that have received a significant amount of interest in literature. It specifically focuses on 1) homomorphic encryption, 2) zero-knowledge proofs, 3) differential privacy, and 4) federated learning. It is worth noting that although many of the methods presented in this document rely on cryptographic primitives, their intent is not to provide perfect secrecy, but rather to enable users to maintain privacy, and thus they shall not be compared or equated to other constructs that are aimed to address cybersecurity constructs.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Progress Towards Treating the Sludges Produced During Spent Fuel Processing - 19546

As a consequence of over 50 years of Magnox reprocessing, Sellafield site is in possession of significant quantities of Magnox sludge. This sludge material is the by-product of corrosion of the magnesium based Magnox metal that clads the Magnox fuel elements. Retrievals and processing of this material poses a significant challenge as corrosion of Magnox metal has occurred under a variety of conditions and over a significant period of time, in a variety of locations. Devising processes to treat heterogeneous materials offers a significant challenge to identify technologies with robust envelopes of acceptance, to effectively operate together. This is further compounded by difficulties defining test programmes and materials for testing that will provide assurance that nonradioactive testing is suitably representative or bounding. An overview of the significant body of work undertaken to process Sellafield's Magnox sludge is provided, from the thousands of commercially sensitive reports generated over the past five decades. This covers the sampling, characterisation, strategy and process evolution, technology development and test materials. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Predicting Geologic Behavior in Carbon Storage Projects Using Graph Neural Network

This study was invited to presented at NVIDIA's GTC conference to highlight the potential of Graph Neural Network as a novel and promising methodology for predicting pressure and saturation evolution in carbon storage projects. Carbon capture and storage (CCS) technology plays a pivotal role in mitigating greenhouse gas emissions, facilitating the transition to a low-carbon future. Effective management of subsurface reservoirs is essential to ensure the safe and efficient storage of captured carbon dioxide (CO₂). Accurate predictions of pressure and saturation over time are critical for evaluating the long-term performance and integrity of CCS projects. In recent years, Graph Neural Network (GNN) has emerged as a powerful framework for analyzing complex data in graph-structured domains. This abstract explores the application of GNN to forecast pressure and saturation evolution in carbon storage projects. Traditional numerical simulations of subsurface reservoirs have proven successful in providing pressure and saturation forecasts. However, these simulations involve massive amounts of computational effort and require extensive domain expertise for proper model calibration and validation. Graph Neural Operator offers an alternative approach that harnesses the inherent graph structure of reservoirs, where nodes represent reservoir grid cells and edges represent the geological connectivity between them.

Shih, Chung Yan↗