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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 523 records · Page 29
All sourcesNASA NTRSDOE OSTI
NASA NTRS1995

An ammonia monitor for the water industry

Following the emergence of the European Community as a unified trading and economic entity, the various member states are required to follow certain directives governing their social affairs. Many of these directives concern the quality of the air we breathe, and the water that we use for consumption or in industrial processes. In order to comply with these directives a major overhaul of the water industry in the UK was required. For example, in many coastal towns and resorts there has never been any formal sewage treatment since, traditionally, all waste was dumped at sea through outfall pipes. Because this is no longer acceptable, whole new treatment systems are required.

Brokenshire, J. L.↗
NASA NTRS1999

The Spatial Variation of Water and Ammonia near Jupiter's Great Red Spot

The CSHELL spectrometer at NASA's Infrared Telescope Facility was used in August 1996 to observe Jupiter at 5.18 microns. This wavelength sounds the 3-8 bar region in Jupiter's deep troposphere. A 1-arcsec-wide slit was aligned east-west on Jupiter and stepped from north to south across the Great Red Spot (GRS). Within our spectral bandpass are absorption lines of NH3 and a hot band of CH4. Radiative transfer models indicate that the strength of the CH4 feature is anti-correlated with gaseous H2O between 3 and 6 bars. The CH4 feature is predicted to be very strong for H2O abundances less than 10ppm and it should vanish when H2O > 300ppm. The depths of the observed CH4 and NH3 absorption features varied dramatically near the GRS. The center and east side (planetocentric) of the GRS is dry in both volatiles as indicated by strong CH4 absorption and a weak NH3 line. The CH4 line vanishes and the NH3 feature grows stronger on the west side of the GRS. We interpret this as due to a real variation in both volatiles - H2O and NH3 - due to a common dynamical mechanism. Water clouds are expected to be accompanied by saturated gaseous H2O profiles between 3 and 5 bars. The Galileo imaging team (Banfield et al 1998 Icarus 135, p230) deduced the presence of a cloud near the 4-bar level northwest of the GRS. Our data indicate that this same region is volatile rich; thus the combination of the two datasets provides a compelling case for a water cloud at this location. The deep volatile abundance does not correlate with 5-micron continuum opacity near the GRS. This suggests that the spatial variation of the 5-micron flux near the GRS is due primarily to NH3 clouds, rather than H2O clouds.

Bjoraker, G. L.↗
NASA NTRS1986

Summary Abstract: Vibrations of Ammonia on the Cu (100) Surface

Recently, the TR frequencies for NH3 molecularly adsorbed on Cu(100) have been measured by infrared laser-induced photodesorption using a tunable laser operating in the group frequency range. Additionally, photodesorption, photo-fragmentation, and photoionization has been observed using a CO2 laser in the 10 microns range. In this contribution we report on work in progress where we use quantum chemical methods to analyze the shifts in the NH, frequencies relative to the gas phase upon chemisorption. We also compute the Cu- N stretch vibration, which has been observed experimentally,and the change in the IR intensities associated with chemisorption; this change is insufficient by itself to explain the increased photoionization efficiency observed.

Pettersson, Lars G. M.↗
NASA NTRS2001

Yb fiber laser pumped mid-IR source based on difference frequency generation and its application to ammonia detection

A Yb fiber laser pumped cw narrow-linewidth tunable mid-IR source based on a difference frequency generation (DFG) in a periodically poled LiNbO3 (PPLN) crystal for trace gas detection was demonstrated. A high power Yb fiber laser and a distributed feedback (DFB) laser diode were used as DFG pump sources. This source generated mid-IR at 3 microns with a powers of ~2.5 microW and a spectral linewidth of less than 30 MHz. A frequency tuning range of 300 GHz (10 cm-1) was obtained by varying the current and temperature of the DFB laser diode. A high-resolution NH3 absorption Doppler-broadened spectrum at 3295.4 cm-1 (3.0345 microns) was obtained at a cell pressure of 27 Pa from which a detection sensitivity of 24 ppm m was estimated.

NASA Discipline Environmental Health↗
NASA NTRS1998

Unraveling the 10 micron "silicate" feature of protostars: the detection of frozen interstellar ammonia

We present infrared spectra of four embedded protostars in the 750-1230 cm-1 (13.3-8.1 microns) range. For NGC 7538 IRS 9, a new band is reported at 1110 cm-1 (9.01 microns, and several others may be present near 785, 820, 900, 1030, and 1075 cm-1 (12.7, 12.2, 11.1, 9.71, and 9.30 microns). The band 1110 cm-1 is attributed to frozen NH3. Its position and width imply that the NH3 is frozen in a polar, H2O-rich interstellar ice component. The NH3/H2O ice ratio inferred for NGC 7538 IRS 9 is 0.1, making NH3 as important a component as CH3OH and CO2 in the polar ices along this line of sight. At these concentrations, hydrogen bonding between the NH3 and H2O can account for much of the enigmatic low-frequency wing on the 3240 cm-1 (3.09 microns) H2O interstellar ice band. The strength of the implied NH3 deformation fundamental at 1624 cm-1 (6.158 microns) can also account for the absorption at this position reported by ISO.

NASA Center ARC↗