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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 523 records · Page 29
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Singly Reduced Iridium Chromophores: Synthesis, Characterization, and Photochemistry

One-electron reduced photosensitizers have been invoked as crucial intermediates in photoredox catalysis, including multiphoton excitation and electrophotocatalytic processes. However, such reduced chromophores have been less investigated, limiting mechanistic studies of their associated electron transfer processes. Here, we report a total of 11 different examples of isolable singly reduced iridium chromophores. Chemical reduction of a cyclometalated iridium complex with potassium graphite affords a 19-electron species. Structural and spectroscopic characterizations reveal a ligand-centered reduction product. The reduced chromophore absorbs a wide range of light from ultraviolet to near-infrared and exhibits photoinduced bimolecular electron transfer reactivity. Furthermore, these studies shed light on elusive reduced iridium chromophores in both ground and excited states, providing opportunities to investigate a commonly invoked intermediate in photoredox catalysis.

14 SOLAR ENERGY↗
NASA NTRS1991

Modeling, simulation, and flight characteristics of an aircraft designed to fly at 100,000 feet

A manned real time simulation of a conceptual vehicle, the stratoplane, was developed to study the problems associated with the flight characteristics of a large, lightweight vehicle. Mathematical models of the aerodynamics, mass properties, and propulsion system were developed in support of the simulation and are presented. The simulation was at first conducted without control augmentation to determine the needs for a control system. The unaugmented flying qualities were dominated by lightly damped dutch roll oscillations. Constant pilot workloads were needed at high altitudes. Control augmentation was studied using basic feedbacks. For the longitudinal axis, flight path angle, and pitch rate feedback were sufficient to damp the phugoid mode and to provide good flying qualities. In the lateral directional axis, bank angle, roll rate, and yaw rate feedbacks were sufficient to provide a safe vehicle with acceptable handling qualities. Intentionally stalling the stratoplane to very high angles of attack (deep stall) was studied as a means of enable safe and rapid descent. It was concluded that the deep stall maneuver is viable for this class of vehicle.

Sim, Alex G.↗
DOE OSTI2026

Denudation, solute export, landscape evolution modeling, and geographic information system data for the East River watershed, Colorado, USA (2020-2024)

This data package contains geographic information system (GIS) layers and tabular datasets associated with the study of lithologic controls on denudation, solute export, carbon-scaling relationships, and transient landscape evolution in the East River watershed near Crested Butte, Colorado, USA. The package includes GIS layers used to produce the Figure 2 map, including drainage, hillshade, lithology, sample locations, and basin polygons, together with comma-separated value (CSV) tables and matching CSV data dictionaries. One group of tables reports sample-level and catchment-level information for river-sediment samples analyzed for in situ-produced cosmogenic beryllium-10 (10Be), including sample names, outlet elevations, geographic coordinates, upstream drainage area, rock-type classes, production-rate scaling scheme, analyzed nuclide, catchment-averaged denudation rates, and associated lower and upper analytical uncertainties. Sample and catchment attributes provide the basis for comparing denudation rates across intrusive, shale, sedimentary, and mixed-lithology settings. A second group of tables reports supporting information for landscape-evolution modeling and the mapped geologic framework of the study area. Included files list parameter values and definitions for the two-phase landscape-evolution simulations, summarize full-domain model erosion fluxes and topographic metrics for different simulation configurations, provide a fixed-area carbon-model scaling table, and summarize mapped geologic units within the East River study domain, including geologic code, formation name, lithologic description, mapped area, and lithologic class grouping. Model outputs and geologic summaries support interpretation of transient landscape behavior and its relation to the mapped distribution of shale, intrusive, sedimentary, and surficial units. A third group of tables reports hydrologic and hydrochemical information used to quantify dissolved export from the watershed. Included files provide site-level values for drainage area, mean annual solute export, standard error of annual export, area-normalized solute yield, and equivalent weathering rate for five East River monitoring sites, along with metadata describing the number, sampling cadence, and date range of discharge records and partial and full total dissolved solids observations used in the solute-yield analyses. The package also contains a supplementary daily ion-load time series with daily mean discharge, discharge observation counts, dissolved concentrations, and daily loads for calcium, magnesium, sodium, potassium, chloride, sulfate, nitrate, fluoride, dissolved silica, charge-balance bicarbonate, and total dissolved solids. The package contains GIS files, comma-separated value files (.csv), CSV data dictionaries, a file-level metadata table, a package-tree text file, and a readme text file.

10Be↗
NASA NTRS1986

Pressure Systems Energy Release Protection (Gas Pressurized Systems)

A survey of studies into hazards associated with closed or pressurized system rupture and preliminary guidelines for the performance design of primary, secondary, and protective receptors of these hazards are provided. The hazards discussed in the survey are: blast, fragments, ground motion, heat radiation, biological, and chemical. Performance guidelines for receptors are limited to pressurized systems that contain inert gas. The performance guidelines for protection against the remaining unaddressed degenerative hazards are to be covered in another study.

Brown, S. J.↗
DOE OSTI2022

Statistical properties of sites visited by independent random walks

The set of visited sites and the number of visited sites are two basic properties of the random walk trajectory. Here, we consider two independent random walks on hyper-cubic lattices and study ordering probabilities associated with these characteristics. The first is the probability that during the time interval (0, t), the number of sites visited by a walker never exceeds that of another walker. The second is the probability that the sites visited by a walker remain a subset of the sites visited by another walker. Using numerical simulations, we investigate the leading asymptotic behaviors of the ordering probabilities in spatial dimensions d = 1, 2, 3, 4. We also study the time evolution of the number of ties between the number of visited sites. We show analytically that the average number of ties increases as a 1 ln t with a 1 = 0.970 508 in one dimension and as (ln t) 2 in two dimensions.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2023

Mycorrhizal status and host genotype interact to shape plant nutrition in field grown maize ( Zea mays ssp. mays )

Arbuscular mycorrhizal fungi (AMF) establish symbioses with the major cereal crops, providing plants with increased access to nutrients while enhancing their tolerance to toxic heavy metals. However, not all plant varieties benefit equally from this association. In this study, we used quantitative trait loci (QTL) mapping to evaluate the combined effect of host genotypic variation (G) and AMF across 141 genotypes on the concentration of 20 mineral elements in the leaves and grain of field grown maize (Zea mays spp. mays). Our mapping design included selective incorporation of a castor AMF-incompatibility mutation, allowing estimation of AMF, QTL and QTLxAMF effects by comparison of mycorrhizal and non-mycorrhizal plants. Overall, AMF compatibility was associated with higher concentrations of boron (B), copper (Cu), molybdenum (Mo), phosphorus (P), selenium (Se) and zinc (Zn) and lower concentrations of arsenic (As), iron (Fe), magnesium (Mg), manganese (Mn), potassium (K) and strontium (Sr). In addition to effects on individual elements, pairwise correlation matrices for element concentration differed between mycorrhizal and non-mycorrhizal plants. We mapped 22 element QTLs, including 18 associated with QTLxAMF effects that indicate plant genotype-specific differences in the impact of AMF on the host ionome. Although there is considerable interest in AMF as biofertilizers, it remains challenging to estimate the impact of AMF in the field. Our design illustrates an effective approach for field evaluation of AMF effects. Furthermore, we demonstrate the capacity of the ionome to reveal host genotype-specific variation in the impact of AMF on plant nutrition.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1977

Solar thermoelectric generators

The methods, the findings and the conclusions of a study for the design of a Solar Thermoelectric Generator (STG) intended for use as a power source for a spacecraft orbiting the planet Mercury are discussed. Several state-of-the-art thermoelectric technologies in the intended application were considered. The design of various STG configurations based on the thermoelectric technology selected from among the various technologies was examined in detail and a recommended STG design was derived. The performance characteristics of the selected STG technology and associated design were studied in detail as a function of the orbital characteristics of the STG in Mercury and throughout the orbit of Mercury around the sun.

Source record↗
NASA NTRS1986

Gyrating and intermediate ion distributions upstream from the earth's bow shock

Study of ISEE 2 fast plasma data reveals that many suprathermal ion events that in previous studies would have been identified as intermediate ion events are actually gyrating ion events. Of 190 apparently intermediate ion events selected on the basis of their signature in energy-time spectrograms, half are actually found to be gyrating ion events. Using a model bow shock, the shock geometries and spacecraft locations for the observed gyrating and intermediate ion events are compared and found to be quite similar. Both gyrating and intermediate ion events are found to be associated with upstream MHD-like wave activity. Most gyrating ion events are associated with large-amplitude, monochromatic, weakly compressive waves, whereas many intermediate ion events are associated with smaller-amplitude, nonmonochromatic, weakly compressive waves. Some intermediate ion events are found to have no associated waves. Detailed study of the gyrating ion distributions reveals that the distributions are typically gyrotropic within about 4 earth radii of the bow shock, whereas at larger distances (up to about 10 earth radii) upstream from the shock the distributions are frequently 'gyrophase bunched'. In light of these observational characteristics, it is concluded that gyrating ion distributions are most likely generated both through coherent wave disruption of field-aligned beams and through reflection of solar wind ions off the shock.

Fuselier, S. A.↗
NASA NTRS1981

A theoretical interpretation of Forbush decreases

An analysis is presented of the intensity variations of relativistic cosmic rays, at 1 AU, which are associated with the passage of a flare shock wave. The magnitude and time profile obtained is similar to that observed in flare-induced Forbush decreases, and the principal cause of the energy reduction is an increase in adiabatic cooling of the arriving particles due to prolonged containment behind the compressed field of the flare shock wave. The large decreases calculated for the smaller diffusion coefficients are inconsistent with observation, implying larger mean free paths than those traditionally assumed at these rigidities. The method presented may be used to study intensity variations associated with other large-scale structures of the interplanetary field, such as corotating interaction regions.

Gall, R.↗
NASA NTRS1994

Metal-line absorption at Z(sub abs) approximately Z(sub em) from associated galaxies

For a preliminary study of whether C IV absorption at Z(sub abs) approximately Z(sub em) is related to associated galaxy companions, we have collected data from a sample of 10 quasars with 0.15 less than z less than 0.65 for which high-resolution optical and UV spectroscopy is available from the literature, and for which we have deep optical images and limited spectroscopy. We also present new optical spectra for two of our samples. Four of these quasars have associated C IV absorption systems. In thes four fields, there are eight galaxies with M(sub r) less than -19.0 mag within 35 kpc of the quasar (projected distance, assuming they are at the quasar redshift), which may be candidates for the associated C IV absorption. This observed density of galaxies near quasars with associated C IV absorption is significantly greater than that for a control sample of quasars chosen from the literature. This result suggests that galaxies near the quasar line of sight may be linked with associated C IV absorption. None of these quasars show associated Mg II absorption, despite the presence of galaxies very near the line of sight, suggesting a Mg II 'proximity effect,' where ionizing flux from the quasar destroys the Mg(+) from at least the outer parts of the galaxies. Three quasars are located in rich galaxy clusters, but none of these quasars are found to have associated C IV absorption. This suggests that galaxies in rich clusters associated with quasars are less likely to be metal-line absorbers. It is plausible that the extended galaxy halos which may be responsible for the absorptions are stripped from galaxies in these dense environments. While it seems that at Z approximately 0.6 rich clusters do not cause them, associated C IV absorption systems at higher redshift may be explained by associated clusters if there has been evolution in the properties of galaxy halos in dense environments.

Ellingson, E.↗
NASA NTRS1987

Nonequilibrium radiation during re-entry at 10 km/s

The direct simulation Monte Carlo method, including a real air model with thermal radiation, is applied to the flows associated with the two sets of measurements that are directly relevant to the projected aeroassisted orbital transfer vehicle. The first is a shock tube measurement of the radiation from a 10 km/s shock wave in air that was made at AVCO in 1962. The second is the flight data that was obtained from the Project Fire re-entry test vehicles in 1964. The calculations for both cases were made with a program that models the one-dimensional flow along a stagnation streamline. The shock standoff distance for the Fire vehicle was obtained from the theoretical studies that were associated with its launch. The simulation employed a partly phenomenological model for the nonequilibrium radiation. It was found that the results from the calculation were consistent with the measured radiation in each case, and also with the convective heat transfer data for the Fire vehicle. The uncertainties associated with the spectral absorptance and recombination probability at the surface appear to be as serious as those associated with the reaction rates.

Bird, G. A.↗
NASA NTRS1985

Modification of the Electromagnetic Levitator (EML) Hardware

The goals of this project are: (1) to study the upgrade requirements and approaches needed for incorporation of an Electromagnetic Levitator (EML) into the shuttle orbiter, (2) to work with members of the Electromagnetic Containerless Processing science working group (SWG) to define future experiments for the EML, and (3) to assist these investigators in further development of ground-based experiment techniques to the limits possible in the terrestrial gravitational environment. Present work is directed toward: (1) upgrading the EML flight apparatus to meet requirements of safety and integration interfaces with the MSL orbiter carrier, (2) development of new experiment components required to carry out approved experiments in undercooled solidification and associated fluid flow studies directed by MIT, and (3) construction, test, qualification and integration assistance for the EML MSL flight package.

Frost, R. T.↗
DOE OSTI2025

Effects of Subhalos on Interpreting Highly Magnified Sources Near Lensing Caustics

Large magnification factors near gravitational lensing caustics of galaxy-cluster lenses allow the study of individual stars or compact stellar associations at cosmological distances. We study how the presence of sub-galactic subhalos, an inevitable consequence of cold dark matter, can alter the property of caustics and hence change the interpretation of highly magnified sources that lie atop them. First, we consider a galaxy-cluster halo populated with subhalos sampled from a realistic subhalo mass function calibrated to N-body simulations. Then, we compare a semianalytical approximation and an adaptive ray-shooting method that we employ to quantify the property of the caustics. As a case study, we investigate Earendel, a z = 6.2 candidate of magnified single- or multiple-star system with a lone lensed image atop the critical curve in the Sunrise Arc. We find that the source size constraint (≲0.3 pc) previously derived from macrolens models should be relaxed by a factor of a few to 10 when subhalos are accounted for, therefore allowing the possibility of a compact star cluster. The subhalos could introduce an astrometric perturbation that is ≲0$^{"}_{.}$5, which does not contradict observation. These conclusions are largely robust to changes in the subhalo population. Subhalos therefore should be seriously accounted for when interpreting the astrophysical nature of similar highly magnified sources uncovered in recent high-z observations.

Caustic curve↗
NASA NTRS1993

Design and Testing of a One-Third Scale Soyuz TM Descent Module Spartan Conversion Project Super Loki Instrumentation

The 1992-1993 senior Aerospace Engineering Design class continued work on the post landing configurations for the Assured Crew Return Vehicle. The Assured Crew Return Vehicle will be permanently docked to the space station fulfilling NASA's commitment of Assured Crew Return Capability in the event of an accident or illness aboard the space station. The objective of the project was to give the Assured Crew Return Vehicle Project Office data to feed into their feasibility studies. Three design teams were given the task of developing models with dynamically and geometrically scaled characteristics. Groups one and two combined efforts to design a one-third scale model of the Russian Soyuz TM Descent Module, and an on-board flotation system. This model was designed to determine the flotation characteristics and test the effects of a rigid flotation and orientation system. Group three designed a portable water wave test facility to be located on campus. Because of additional funding from Thiokol Corporation, testing of the Soyuz model and flotation systems took place at the Offshore Technology Research Center. Universities Space Research Association has been studying the use of small expendable launch vehicles for missions which cost less than 200 million dollars. The Crusader2B. which consists of the original Spartan first and second stage with an additional Spartan second stage and the Minuteman III upper stage is being considered for this task. University of Central Florida project accomplishments include an analysis of launch techniques, a modeling technique to determine flight characteristics, and input into the redesign of an existing mobile rail launch platform.

Anderson, Loren A.↗
NASA NTRS2004

Polarimetric Scanning Radiometer C and X Band Microwave Observations During SMEX03

Soil Moisture Experiments 2003 (SMEX03) was the second in a series of field campaigns using the NOAA Polarimetric Scanning Radiometer (PSR/CX) designed to validate brightness temperature data and soil moisture retrieval algorithms for the Advanced during SMEX03 were: calibration and validation of AMSR-E brightness temperature observations over different climate/vegetation regions of the US. (Alabama, Georgia, Oklahoma), identification of possible sources of Radio Frequency Interference (RFI), comparison of X-band observations from TRMM Microwave Imager (TMI), AMSR-E and PSR/CX, and exploring the potential of soil moisture retrieval algorithms using C and X band imagery in diverse landscapes. In the current investigation, more than one hundred flightlines of PSR/CX data were extensively processed to produce gridded brightness temperature products for the four study regions. Variations associated with soil moisture were not as large as hoped for due to the lack of significant rainfall in Oklahoma. Observations obtained over Alabama include a wide range of soil moisture and vegetation conditions for C and X band frequencies. These results clearly showed a lack of sensitivity to rainfall/soil moisture under forest canopy cover. Quantitative comparisons made between the PSR/CX, AMSR-E for validated that both the PSR/CX and AMSR-E data were well calibrated. X band comparisons of the PSR/CX high resolution and AMSR-E and TMI low-resolution data indicated a linear scaling for the range of conditions studied in SMEX03. These results will form the basis for further soil moisture investigations.

Jackson, Thomas J.↗
NASA NTRS1995

Mass Spectrometric Study of Sulfur Vapor

It is well known that sulfur catenates and forms oligmers ranging from S2 to S20. The actual number of species present in the vapor depends on several factors and has been the subject of many studies (e.g.: ref. 1). The main problem associated with the mass spectrometric studies is the tendency of the sulfur vapor to depolymerize or break up into smaller units under the ion source conditions. Therefore, one has to employ lower electron impact energies to identify the true abundances of various species present in the sulfur vapor and the pathways of dissociation.

Sulfur Vapor↗
NASA NTRSDate not supplied

Long-Term Health Risk Quantification

Astronauts face hazards during spaceflight, including space radiation exposure, isolation and confinement, traveling far distances from Earth, reduced gravity levels, and closed and hostile environments. These hazards drive the definition of human health and performance risks associated with spaceflight. NASA’s Human System Risk Board maintains the human spaceflight risk posture for in-mission risks, as well as post-flight, Long-Term Health (LTH)risks potentially occurring later in the astronaut’s life. LTH risk encompasses the timeframe from immediately post-flight, through the rest of an astronaut’s career, through retirement, and until death. Possible LTH risk outcomes include the time and interventions needed for the astronaut to return to preflight physiological states after experiencing spaceflight hazards and recovery from any in-mission medical events that persist into the post-flight timeframe. It includes chronic complications that may arise due to experiencing in-flight medical conditions or injuries and medical conditions that occur later in life with a higher probability of occurrence or with more severity because of their spaceflight exposure. Finally, LTH risk outcomes can also include a reduction in life expectancy due to spaceflight exposures. There have been 144 medical conditions identified by NASA’s Lifetime Surveillance of Astronaut Health team to be associated with LTH risk. Epidemiological studies have been performed for some of these conditions to determine if astronauts suffer from an increased prevalence or severity of the condition due to their spaceflight experience compared to a comparable cohort .Differences in astronaut mortality or morbidity due to spaceflight experience were not detected in several of these studies. There were two cases where a modest increase in the incidence rate of astronaut LTH outcomes was detected. The first suggested an increase in the incidence of melanoma cases in astronauts, where the number of cases in astronauts were similar to the elevated number of cases observed in airplane pilots. The second provided some evidence of elevated numbers of cardiovascular disease events in astronauts compared to an appropriate healthy comparator cohort, which may warrant additional investigation. The lack of detection of LTH risk outcomes should not ease concerns about astronaut LTH. The studies highlighted here constitute only a small portion of the potential LTH conditions that could occur. Once epidemiological studies are performed on all conditions, significant findings may be detected. The analysis of astronaut LTH also suffers from limited numbers of data points because of the limited numbers of astronauts overall and the even fewer who have reached an age where LTH outcomes may begin to manifest. As shuttle and ISS astronauts begin to age and increase the feasibility of analysis, LTH outcomes may be detected. An application of risk quantification is the use of risk metrics within trade studies for resource prioritization and decision making. Trade studies regarding countermeasures to LTH risk outcomes would benefit from a quantification of LTH risk. NASA has ground-based processes in place such as astronaut screening and access to continuous medical monitoring and care during and after their astronaut career which are the main methods for mitigating LTH risk. In-mission countermeasures, such as acceptable levels of medical care and available countermeasures to counter spaceflight related physiological decrements, can mitigate a poor health and performance status immediately post-flight. Identifying appropriate risk metrics, obtaining valid quantities for them, and tying them to LTH countermeasures are necessary steps for realizing their use in trade studies. This presentation will highlight the challenges associated with the identification, quantification, and utilization of LTH risk metrics

Beth Lewandowski↗