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At least 523 records · Page 29

Application of a Fiber Optic Distributed Strain Sensor System to Woven E-Glass Composite

A distributed strain sensing system utilizing a series of identically written Bragg gratings along an optical fiber is examined for potential application to Composite Armored Vehicle health monitoring. A vacuum assisted resin transfer molding process was used to fabricate a woven fabric E-glass/composite panel with an embedded fiber optic strain sensor. Test samples machined from the panel were mechanically tested in 4-point bending. Experimental results are presented that show the mechanical strain from foil strain gages comparing well to optical strain from the embedded sensors. Also, it was found that the distributed strain along the sample length was consistent with the loading configuration.

Anastasi, Robert F.↗

Direct binary search for improved coherent beam shaping and optical differentiation wavefront sensing

Spatially dithered distributions of binary amplitude pixels are optimized using a full direct binary search taking into account the experimental configuration for amplitude modulation of coherent waves. This design process is shown to yield a significant reduction of the noise induced by binarization and pixelation over the region of interest. In this study, we demonstrate this approach for beam shaping and optical differentiation wavefront sensing, where the region of interest is in an image plane of the pixel distribution and in the far field of the pixel distribution, respectively. Lastly, the observed reduction in error compared to a standard error diffusion algorithm is significant for both applications because it improves performance without the tighter fabrication tolerance and cost associated with smaller pixels.

47 OTHER INSTRUMENTATION↗

Computing an Optimal Entanglement Path with Throughput and Fidelity Considerations

Entanglement distribution is a core function of quantum networks essential for operations including teleportation, distributed quantum sensing, and multisite computation. Entanglement throughput and fidelity are two critical performance measures that depend on the quantum transmission along the links and swapping operations at the repeaters along the path. We study the problem of computing a end-to-end entanglement path that satisfies both fidelity and throughput requirements, leveraging qubit buffers at the nodes and considering the sequential swapping order. We show that the general problem of simultaneously satisfying both metrics to be NP-hard, and develop an algorithm to maximize throughput subject to a given fidelity threshold. We introduce the concepts of entanglement probability distribution and path domination and exploit them in the design of our algorithm. Extensive numerical results show that our algorithm can find optimal solutions in networks with thousands of nodes in less than a second. We also describe practical and possible implementation aspects of this algorithm in terms of devices and architecture support.

Xue, Guoliang [Arizona State University]↗

Cascaded Sapphire Fiber Bragg Gratings Inscribed by Femtosecond Laser for Molten Steel Studies

This research reports a distributed fiber optic high-temperature sensing system tailored for applications in the steel industry and various other sectors. Recent advancements in optical sensor technology have led to the exploration of sapphire crystal fibers as a solution for sensing in harsh environments. Utilizing a femtosecond (fs) laser, cascaded fiber Bragg gratings (FBGs) were meticulously fabricated within a multimode sapphire optical fiber. These FBGs endowed the system with distributed sensing capabilities and underwent rigorous testing under extreme temperatures, reaching up to 1800 °C. Here, the study delves into the investigation of the FBG reflection spectrum, facilitated by the development of a sophisticated multimode demodulation system, which contributed to the attainment of precise temperature measurements with a performance accuracy of 99.9%. Demonstrating exceptional thermal stability, the sapphire FBGs endured temperatures of 1600 °C for a sustained duration of 22 h. Furthermore, this article explores the application of distributed temperature sensing employing multiple sapphire FBGs, showcasing their utility in temperature measurements related to molten steel studies.

47 OTHER INSTRUMENTATION↗

A Fiber Bragg Grating Temperature Sensor for 2-400 K

We demonstrate fiber optic, multiplexible temperature sensing using a fiber Bragg grating (FBG) with an operational range of 2-400 K, and a temperature resolution better than 10 mK for temperatures < 12 K. This represents a significant reduction in the lowest usable temperature as well as a significant increase in sensitivity at cryogenic temperatures compared with previously reported multiplexible solutions. This is accomplished by mounting the section of the fiber with a FBG on a polytetrafluoroethylene coupon, which has a non-negligible coefficient of thermal expansion down to < 4 K. The sensors exhibit a good stability over multiple temperature cycles and acceptable sensor-to-sensor repeatability. Possible applications for this sensor include distributed temperature sensing across superconducting elements and cryogenic temperature measurements in environments where electrical measurements are impractical or unsafe.

Zaynetdinov, Madrakhim↗

A Contrast in Use of Metrics in Earth Science Data Systems

In recent years there has been a surge in the number of systems for processing, archiving and distributing remotely sensed data. Such systems, working independently as well as in collaboration, have been contributing greatly to the advances in the scientific understanding of the Earth system, as well as utilization of the data for nationally and internationally important applications. Among such systems, we consider those that are developed by or under the sponsorship of NASA to fulfill one of its strategic objectives: "Study Earth from space to advance scientific understanding and meet societal needs." NASA's Earth science data systems are of varying size and complexity depending on the requirements they are intended to meet. Some data systems are regarded as NASA's "Core Capabilities" that provide the basic infrastructure for processing, archiving and distributing a set of data products to a large and diverse user community in a robust and reliable manner. Other data systems constitute "Community Capabilities". These provide specialized and innovative services to data users and/or research products offering new scientific insight. Such data systems are generally supported by NASA through peer reviewed competition. Examples of Core Capabilities are 1. Earth Observing Data and Information System (EOSDIS) with its Distributed Active Archive Centers (DAACs), Science Investigator-led Processing Systems (SIPSs), and the EOS Clearing House (ECHO); 2. Tropical Rainfall Measurement Mission (TRMM) Science Data and Information System (TSDIS); 3. Ocean Data Processing System (ODPS); and 4. CloudSat Data Processing Center. Examples of Community Capabilities are projects under the Research, Education and Applications Solutions Network (REASON), and Advancing Collaborative Connections for Earth System Science (ACCESS) Programs. In managing these data system capabilities, it is necessary to have well-established goals and to measure progress relative to them. Progress is measured through "metrics", which can be a combination of quantitative as well as qualitative assessments. The specific metrics of interest depend on the user of the metrics as well as the type of data system. The users of metrics can be data system managers, program managers, funding agency or the public. Data system managers need metrics for assessing and improving the performance of the system and for future planning. Program managers need metrics to assess progress and the value of the data systems sponsored by them. Also, there is a difference in the metrics needed for core capabilities that tend to be more complex, larger and longer-term compared to community capabilities and the community capabilities that tend to be simpler, smaller and shorter-term. Even among community capabilities there are differences; hence the same set of metrics does not apply to all. Some provide data products to users, some provide services that enable better utilization of data or interoperability among other systems, and some are a part of a larger project where provision of data or services is only a minor activity. There is also a contrast between metrics used for internal and external purposes. Examples of internal purposes are: ensuring that the system meets its requirements, and planning for evolution and growth. Examples of external purposes are: providing to sponsors indicators of success of the systems, demonstrating the contributions of the system to overall program success, etc. This paper will consider EOSDIS, REASON and ACCESS programs to show the various types of metrics needed and how they need to be tailored to the types of data systems while maintaining the overall management goals of measuring progress and contributions made by the data systems.

Ramapriyan, Hampapuram↗

An Integrated View of Hydraulic Induced Fracture Geometry in Hydraulic Fracture Test Site 2

Until relatively recently, most of our understanding about the geometry of hydraulically induced fractures in unconventional reservoirs has been inferred by patterns observed via microseismic monitoring. Important information, such as fracture-azimuth, fracture-length, height-growth and other geometric data has been determined from microseismic “event clouds”, which in turn has been used to interpret a stimulated reservoir volume (SRV). It is important to note that relatively limited microseismic results have been acquired in conjunction with other diagnostics and validated in a consistent manner. The Hydraulic Fracture Test Site 2 (HFTS2) in the Permian Delaware Basin provides a unique opportunity to compare the frac geometry interpretations derived from multiple frac diagnostic tools and at multiple scales. The integrated view that emerges from all the frac diagnostic tools is that in HFTS2 the geometries of hydraulically induced fractures are not random and with a highly complex branching architecture. In fact, the fracs are mostly vertical, parallel plana domains, and both vertically and horizontally asymmetrical. The hydraulically induced fractures have a very consistent azimuth with a strike that matches SHmax. At the distance corresponding to the spacing between nearby wells in HFTS2, ~ 660 ft, the pattern of strain interceptions observed from Low Frequency Distributed Acoustic Sensing (LF-DAS) shows far-field dimensions that are consistent with the stage length dimensions at the stimulated well. In general, larger stages with higher number of clusters create larger number of interceptions and wider stimulated intervals than that of shorter stages with the same cluster to cluster spacing and fewer clusters. The hydraulically induced fractures also show a clear tendency to preferentially grow upwards as shown by the microseismic data, by the relative lower number of LF-DAS interceptions in nearby deeper wells and finally by the observed LF-DAS strain patterns in the vertical observation well. In the near field, the geometries of the fracture domains are also consistent. As shown by the distributed strain measurements obtained during production via the monitoring of Rayleigh Frequency Shift (RFS), each cluster has a separate, non-overlapping, frac-zone-domain that are generally centered around the locations of each perforation cluster. Overall, the hydraulically induced fractures in HFTS2 are interpreted as occurring in swarms associated with individual clusters, each with its own unique geometry but with similar predictable geometric and propagation tendencies. The comprehensive frac diagnostic program in HFTS2, the well-pad layout that permits the investigation of the Downloaded from http://onepetro.org/URTECONF/proceedings-pdf/21URTC/1-21URTC/D011S018R003/2477511/urtec-2021-5396-ms.pdf/1 by Carol Worster on 28 February 2022 URTeC 5396 2 impact that nearby producing wells has on frac geometry, together with an innovative Design of Experiment (DofE) that includes sequential-fracing, consistent cluster-to-cluster distances and few single-perforation cluster stages, has allowed us to gain a unique perspective about the geometry of the induced hydraulic fractures on this pad. Finally, the HFTS2 dataset has also provided us with a better understanding of the applicability and limitations of the different diagnostic tools.

58 GEOSCIENCES↗

Simulated Vision-based Approach and Landing System for Advanced Air Mobility

Advanced Air Mobility (AAM) aircraft require precision approach and landing systems (PALS) in several environments, such as urban, suburban, and rural. It is challenging to implement current state-of-the-art methods approved for automated approach and landing for AAM operations with challenges such as GPS degradation in urban environments and visual navigation aids like the glideslope and localizer being narrow and not allowing alternative incoming landing angles at vertiports. However, existing technology and systems, i.e., the instrument landing system (ILS) with glideslope and localizer indicators that use vision, IR, radar, or GPS methods, provide baseline perception and sensing requirements for AAM aircraft approach and landing. This paper focuses on vision-based PAL and computer vision feature correspondence methods to demonstrate a baseline navigation system while adhering to the Federal Aviation Administration requirements and regulations about heliport design (FAA AC 150/5390-2C), which is one of the closest references for vertiport requirements and regulations. The coplanar pose from orthography and scaling with iterations (COPOSIT) algorithm determines pose estimation, which feeds into an Extended Kalman filter that combines IMU with vision to create a vision-based approach and landing (VAL) sensor fusion navigation solution for GPS-denied environments. The VAL navigation solution provides promising simulation results for AAM PALS with Hough circle detection and feature correspondence, which demonstrate robustness to false positives. This paper incorporates moderately high- fidelity simulations with computer graphics rendering to show a distributed sensor network to track an AAM aircraft during approach and landing to compare with the aircraft’s onboard vision-based navigation solution.

distributed sensing↗

Reservoir Response to Thermal and High-Pressure Well Stimulation Efforts at Raft River, Idaho

An injection stimulation test begun at the Raft River geothermal reservoir in June, 2013 has produced a wealth of data describing well and reservoir response via high-resolution temperature logging and distributed temperature sensing, seismic monitoring, periodic borehole televiewer logging, periodic stepped flow rate tests and tracer injections before and after stimulation efforts. The hydraulic response demonstrates continually increasing injectivity, reflected in varying flow rate response to nearly constant injection pressure, but features of the hydraulic response provide information about different characteristics of the reservoir. Changes in injectivity immediately following high-flow rate tests suggest that hydro shearing has altered the near-well permeability structure, while pressure response during those tests indicates that near-well permeability is relatively homogeneous and low but that the well is near, but not well connected to, a zone of higher transmissivity. Long-term changes in injectivity are believed to reflect propagation of the injection cooling front through low permeability zones. Two dimensional flow and heat transport simulations are used to demonstrate how the timescale of pressure response may relate to length scales of permeability distribution.

Well stimulation, injectivity, enhanced geothermal↗

Distributed Thermal Response Multi-Source Modeling to Evaluate Heterogeneous Subsurface Properties

A thorough assessment of thermal properties in heterogeneous subsurface is necessary in design of low-temperature borehole heat exchangers (BHEs). For this study, a distributed thermal response test (DTRT), which combines distributed temperature sensing (DTS) with a conventional thermal response test (TRT), was conducted in a U-bend geothermal loop installed in an open borehole at the University of Illinois at Urbana-Champaign to estimate thermal properties by analyzing the thermal response of different geologic materials while applying a constant heat input rate. Fiber-optic cables in the DTRT were deployed both inside the U-bend geothermal loop and in the center of the borehole to improve the accuracy of calculated heat-loss rates and borehole temperature profile measurements. To assess the subsurface thermal conductivity during the heating phase of the DTRT, a single-source model and a multi-source model, both based on the infinite line source method, were developed using the borehole temperature data and temperatures inside and along the outside of the loop, separately. The two models returned similar thermal conductivity values. The multi-source modeling has the advantage of predicting the thermal conductivity of heterogeneous geologic materials from borehole temperature profiles during the DTRT heating phase. Additionally, based on the distributed thermal conductivity measured in the borehole, estimates were made for both radial thermal impacts and the rate of heat loss in the BHE.

58 GEOSCIENCES↗

Assessing Carbon Properties in Coastal Waters with a New Observing System Testbed

Large rainfall events over land can lead to a substantial flux of carbon and nutrients to estuaries and the coastal ocean. In the mid-Atlantic on the east coast of North America (35° - 42° N), these events often happen due to tropical storm activity as well as less predictable anomalously large midlatitude storms or abrupt spring snow melt runoff. Storms can directly impact the coastal carbon cycle via export of carbon from land to sea, while also stimulating phytoplankton production due to the influx of nutrients to the coastal ocean. To assess the impact of high precipitation and river flow events on the coastal carbon cycle, we have integrated multiple observing platforms in an analytical framework to dynamically observe carbon-related properties. The new observing system testbed (NOS-T) allows for an estimate of phytoplankton and organic carbon stocks in the surface ocean, with a goal of providing near real time analytical capability. A case study of high river discharge in the mid-Atlantic in the summer and fall of 2018 and 2021 were used to examine how riverine carbon manifests along the land-estuary-ocean continuum particularly in Chesapeake Bay. Chesapeake Bay was chosen as the study site because of long term monitoring by the Chesapeake Bay Program and a robust and well-developed regional biogeochemical modeling system, the Chesapeake Bay Environmental Forecast System (CBEFS), that is publicly available. There is also new capability in Chesapeake Bay to combine hyperspectral radiometric data from the Aerosol Robotic Network site that is online in 2022 with in-water observations of optical properties. Precipitation data from the Global Precipitation Measurement IMERG data set was used to establish triggering criteria for storm carbon flux observation. USGS and in-water carbon data were used to establish statistical models to estimate the mass flux of organic carbon into Chesapeake Bay using measured river discharge. The year 2018 was examined as there was record rainfall and near record river flow in the late summer. The CBEFS modeling was compared with in-water estimates of dissolved organic carbon (DOC) to assess the model’s ability to capture storm fluxes of carbon to the ecosystem. Multiple satellite platforms were also used to assess how remote sensing using passive Earth orbiting sensors can be used to observe carbon in this complex coastal region. A set of recommendations have been established to improve sensing capability to measure aquatic carbon during storm events. A unique challenge in these dynamic inland waters is how rapidly carbon fluxes can evolve in space and time, with many sources contributing to the water leaving reflectance that satellites can observe. To improve our ability to quantify carbon stocks and fluxes in near real time, a suite of satellite sensors and high-resolution modeling capability is needed, all supplemented by in situ monitoring. Future inclusion of in-water observations that would be deployed when the system reaches triggering criteria, as well as taskable orbital instruments, will improve estimates of ocean carbon properties and provide the ability to calculate major carbon stocks and fluxes in near real time following episodic storm events.

land-ocean continuum↗

Robust Carbon Dioxide Plume Imaging Using Joint Tomographic Inversion of Seismic Onset Time and Distributed Pressure and Temperature Measurements (Final Report)

We develop and demonstrate rapid and cost-effective methodologies for spatiotemporal tracking of CO2 plumes during geologic sequestration using joint inversion of seismic data and distributed pressure and temperature measurements. Key elements of our methodology are: (a) a computationally efficient approach to pressure and temperature propagation, (b) analysis of time lapse seismic data using a novel ‘seismic onset time’ approach to detect fluid front propagation, and (c) data assimilation and uncertainty assessment via joint inversion of pressure, temperature and time lapse seismic data, and (d) validating the numerical tomographic inversion using a CO2 injection demonstration projects, specifically data collected from the from the Petra Nova Parish Holdings CCUS project in the West Ranch Field, Texas and the Chester-16 reef CO2 injection site in Northern Michigan which is part of the DOE Midwestern Carbon Sequestration Project. The research team is led by Texas A&M University and includes Battelle as a subcontractor with support from Shell, Anadarko, Chevron and JX Nippon. A carbon dioxide (CO2) water-alternating-gas (WAG) pilot was conducted to gain insights into tertiary oil recovery potential via CO2 flood in the West Ranch Field as part of the Petra Nova project, the world’s largest post-combustion CO2 capture and utilization initiative. With a fluvial formation geology and large contrasts in permeability, this is a challenging and novel application of CO2 enhanced oil recovery (EOR). We build a predictive dynamic model of the subsurface that incorporates the multiphase and compositional data acquired during the pilot operation. The calibrated model is used for the carbon dioxide plume imaging. The study began with an initialization of the pilot sector model extracted from a calibrated full-field model. The pilot model calibration follows a two-step hierarchical workflow. First, we performed a large-scale update of the permeability distribution by integrating available bottomhole pressure and multiphase production data. In the second step, local permeability field is fine-tuned using a streamline-based method to match CO2 breakthrough times at the producers. The predictive capability of the calibrated model was verified through two blind validation tests: (1) the model showed good agreement with saturation logs acquired at two observation wells; and (2) the model reproduced the CO2 recovery as a fraction of the injected CO2. The use of seismic onset times has shown great promise for integrating near-continuous seismic surveys for updating geologic models. In this study, we analyze the impact of seismic survey frequency on the onset time approach aiming to extend the application of onset time to infrequent seismic surveys. In addition, we quantitatively examine the nonlinearity of the onset time method and compare it to the commonly used amplitude inversion method. We carry out a sensitivity analysis of seismic survey frequency based on the complete seismic survey data (over 175 surveys) of steam injection in a heavy oil reservoir (Peace River Unit) in Canada. Our results show that an adequate onset time map can be obtained from the infrequent seismic surveys by interpolation between seismic surveys as long as there is no change in the dominant underlying physics between the successive surveys. The study also shows that nonlinearity of the onset time method can be -smaller than that of the amplitude inversion method by several orders of magnitude. Application to the Brugge benchmark case shows that the onset time method obtains comparable permeability update as the traditional seismic amplitude inversion method with faster computation and improved convergence characteristics. We extend the streamline-based data integration approach to incorporate distributed temperature sensor (DTS) data using the concept of thermal tracer travel time. Then, a hierarchical workflow composed of evolutionary and streamline methods is employed to jointly history match the DTS and pressure data. Finally, CO2 saturation and streamline maps are used to visualize the CO2 plume movement during the sequestration process. The hierarchical workflow is applied to a carbon sequestration project in a carbonate reef reservoir within the Northern Niagaran Pinnacle Reef Trend in Michigan, USA. The monitoring data set consists of distributed temperature sensing (DTS) data acquired at the injection well and a monitoring well, flowing bottom-hole pressure data at the injection well, and time-lapse pressure measurements at several locations along the monitoring well. The history matching results indicate that the CO2 movement is mostly restricted to the intended zones of injection which is consistent with an independent warm-back analysis of the temperature data. In addition to employing simulation models and inverse methods for CO2 plume imaging, we also initialized a data-driven technology for detecting inter-well connectivity based on production and pressure data. Our machine-learning framework is built on the statistical recurrent unit (SRU) model and interprets well-based injection/production data into inter-well connectivity without relying on a geologic model. We test it on synthetic and field-scale CO2 EOR projects utilizing the water-alternating-gas (WAG) process. The validation of the proposed data-driven inter-well connectivity assessment is performed using synthetic data from simulation models where inter-well connectivity can be easily measured using the streamline-based flux allocation. The SRU model is shown to offer excellent prediction performance on the synthetic case. Despite significant measurement noise and frequent well shut-ins imposed in the field-scale case, the SRU model offers good prediction accuracy, the overall relative error of the phase production rates at most producers ranges from 10% to 30%. It is shown that the dominant connections identified by the data-driven method and streamline method are in close agreement. Texas A&M University, the lead organization in the project, was primarily responsible for the development of tomographic approaches for CO2 plume mapping in conjunction with distributed pressure, temperature and seismic onset time data. Battelle, as a subcontractor, was primarily responsible for the development of analytical and empirical methods for analyzing transient injection rate and pressure data from point/line sources such as injection and monitoring wells. An additional area of emphasis for Battelle was the use of machine learning for such tasks as inferring reservoir connectivity information from injection-production data, and identifying variable importance for machine learning-based proxy models developed from full-physics simulations. The two organizations also collaborated on the application of the tomographic inversion methodology for a field data set.

02 PETROLEUM↗

Multi-Agent Swarm State of the Art Report

The Next-Generation Multi-Agent Swarm (NGS) Study conducted by NASA’s Ames Research Center for NASA’s Space Technology Mission Directorate (STMD) will develop a comprehensive understanding of emerging multi-agent swarm capabilities. The study aims to identify existing swarm capabilities and asses their potential for persistent lunar space situational awareness, surface monitoring, and distributed autonomy demonstrations. A key objective is to inform the design of a next-generation multi-agent swarm that can perform autonomous distributed remote sensing, position, navigation, and timing (PNT) services, automated deployment that leverages autonomy, edge computing, and interoperable networking to enable cooperative operations without the need for immediate human operation. This study will address specific shortfalls identified by STMD, including intelligent multi-agent constellations, autonomy, edge computation, position, navigation, and timing for small spacecraft, small spacecraft propulsion, and space situational awareness (1625, 1438, 1433, 1557, 1431, 1430, 1589). The NASA Ames Mission Design Center (MDC) will provide subject matter expertise to support systems engineering trades, while experts in autonomy and spacecraft swarms in NASA’s Intelligent Systems Division will lead the study and focus on identifying emerging next-generation swarm capabilities. The study objectives include: capturing the current state-of-the-art for multi-agent swarm capabilities, evaluating technologies and creating technology roadmaps, and developing at least one new technology demonstration mission concept. This initial NGS study report surveys the current state of the art in technology areas relevant for the next-generation multi-agent swarm design. Our primary focus is on surveying relevant deployed space systems1, supplemented with selective analysis of relevant proposed missions and technology developments that have yet to fly.

agent↗

Application of Sapphire-Fiber-Bragg-Grating-Based Multi-Point Temperature Sensor in Boilers at a Commercial Power Plant

Readily available temperature sensing in boilers is necessary to improve efficiencies, minimize downtime, and reduce toxic emissions for a power plant. The current techniques are typically deployed as a single-point measurement and are primarily used for detection and prevention of catastrophic events due to the harsh environment. In this work, a multi-point temperature sensor based on wavelength-multiplexed sapphire fiber Bragg gratings (SFBGs) were fabricated via the point-by-point method with a femtosecond laser. The sensor was packaged and calibrated in the lab, including thermally equilibrating at 1200 °C, followed by a 110-h, 1000 °C stability test. After laboratory testing, the sensor system was deployed in both a commercial coal-fired and a gas-fired boiler for 42 days and 48 days, respectively. The performance of the sensor was consistent during the entire test duration, over the course of which it measured temperatures up to 950 °C (with some excursions over 1000 °C), showing the survivability of the sensor in a field environment. The sensor has a demonstrated measurement range from room temperature to 1200 °C, but the maximum temperature limit is expected to be up to 1900 °C, based on previous work with other sapphire based temperature sensors.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The initial appraisal of buried DAS system in CO2CRC Otway Project: the comparison of buried standard fibre-optic and helically wound cables using 2D imaging

This study aims to assess the ability of shallow distributed acoustic sensing (DAS) to serve as a cost-effective seismic sensor array for permanent monitoring applications. To this end, as part of the CO2CRC seismic monitoring program, a fibre-optic DAS array was deployed alongside a permanently buried geophone array at the Otway Project site (Victoria, Australia). The DAS array consisted of a standard commercially available tactical fibre-optic cable, which was deployed in 0.8m deep trenches. A custom-designed helically wound (HW) cable was also deployed in one of the DAS trenches for comparison of the cable designs. Simultaneous acquisition of the seismic data was carried out using 3000 vibroseis source points and geophones, DAS standard and HW cables. For initial assessment of the seismic images acquired with DAS and to compare different cable designs, preliminary 2D seismic reflection processing is conducted on both DAS cables and geophone data along a single 2D line. The geophone data processing guided processing of the DAS data. Several shallow structures (100-450ms) and some important reflectors at 450-600ms are observed on the final DAS images. Comparison of the two different DAS cable types demonstrated that seismic imaging would benefit DAS technology. However, the benefit of utilising HW cable is modest compared with the standard cable. The workflows and results of this study pave the way for processing of the 3D seismic data set acquired with the DAS array, as well as further detailed analysis of the DAS cables and the system itself.

47 OTHER INSTRUMENTATION↗

Measurement and simulation of heat exchange in fractured bedrock using inert and thermally degrading tracers

Multicomponent groundwater tracer tests were conducted in a well-characterized field site in Altona, NY using inert carbon-cored nanoparticles and a thermally degrading phenolic compound. Experiments were conducted in a mesoscale reservoir consisting of a single subhorizontal bedding plane fracture located 7.6 m below ground surface contained between two wells separated by 14.1 m. The reservoir rock, initially at 11.78C, was heated using 748C water. During the heating process, a series of tracer tests using thermally degrading tracers were used to characterize the progressive in situ heating of the fracture. Fiber-Optic Distributed Temperature Sensing (FODTS) was used to measure temperature rise orthogonal to the fracture surface at 10 locations. Recovery of the thermally degrading tracer’s product was increased as the reservoir was progressively heated indicating that the advancement of the thermal front was proportional to the mass fraction of the thermally degrading tracer recovered. Both GPR imaging and FODTS measurements reveal that flow was reduced to a narrow channel which directly connected the two wells and led to rapid thermal breakthrough. Computational modeling of inert tracer and heat transport in a two-dimensional discrete fracture demonstrate that subsurface characterization using inert tracers alone could not uniquely characterize the Altona field site. However, the inclusion of a thermally degrading tracer may permit accurate subsurface temperature monitoring. At the Altona field site, however, fluid-rock interactions appear to have increased reaction rates relative to laboratory-based measurements made in the absence of rock surfaces.

58 GEOSCIENCES↗

Failure of Taylor's hypothesis in the atmospheric surface layer and its correction for eddy-covariance measurements

Taylors’ frozen turbulence hypothesis suggests that all turbulent eddies are advected by the mean streamwise velocity, without changes in their properties. This hypothesis has been widely invoked to compute Reynolds’ averaging using temporal turbulence data measured at a single point in space. However, in the atmospheric surface layer, the exact relationship between convection velocity and wavenumber k has not been fully revealed since previous observations were limited by either their spatial resolution or by the sampling length. Using Distributed Temperature Sensing (DTS), acquiring turbulent temperature fluctuations at high temporal and spatial frequencies, we computed convection velocities across wavenumbers using a phase spectrum method. We found that convection velocity decreases as k –1/3 at the higher wavenumbers of the inertial subrange instead of being independent of wavenumber as suggested by Taylor's hypothesis. We further corroborated this result using large eddy simulations. Applying Taylor's hypothesis thus systematically underestimates turbulent spectrum in the inertial subrange. As a result, a correction is proposed for point-based eddy-covariance measurements, which can improve surface energy budget closure and estimates of CO 2 fluxes.

54 ENVIRONMENTAL SCIENCES↗

Transistor-Based Work-Function Measurement of Metal–Organic Frameworks for Ultra-Low-Power, Rationally Designed Chemical Sensors

A classic challenge in chemical sensing is selectivity. Metal–organic frameworks (MOFs) are an exciting class of materials because they can be tuned for selective chemical adsorption. Adsorption events trigger work-function shifts, which can be detected with a chemical-sensitive field-effect transistor (power ≈microwatts). Here, several case studies were used towards generalizing the sensing mechanism, ultimately towards our metal-centric hypothesis. HKUST-1 was used as a proof-of-principle humidity sensor. The response is thickness independent, meaning the response is surface localized. ZIF-8 is demonstrated to be an NO 2 -sensing material, and the response is dominated by adsorption at metal sites. Finally, MFM-300(In) shows how standard hard–soft acid–base theory can be used to qualitatively predict sensor responses. This paper sets the groundwork for using the tunability of metal–organic frameworks for chemical sensing with distributed, scalable devices.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗