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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 523 records · Page 29

Optical studies of hydrogen above 200 gigapascals - Evidence for metallization by band overlap

Direct optical observations of solid hydrogen to pressures in the 250-gigapascal range at 77 K are reported. Hydrogen samples appear nearly opaque at the maximum pressures. Measurements of absorption and Raman spectra provide evidence that electronic excitations in the visible region begin at about 200 gigapascals. The optical data are consistent with a band-overlap mechanism of metallization.

Mao, N. K.↗

Results of examination of silvered Teflon from the Long Duration Exposure Facility

Pieces of silvered Teflon thermal control blanket from seventeen locations on the Long Duration Exposure Facility (LDEF) were studied. Results of the measurements of surface texturing, and mechanical, electrical and thermal properties are presented. Photos of the blankets, scanning electron microscope pictures, infrared spectra, and surface analysis results are presented. Contamination issues relative to performance of the blankets are discussed. The variation in measured properties are reported as a function of exposure conditions.

Rousslang, Ken W.↗

Cosmic rays from primordial black holes

The quark and gluon emission from primordial black holes (PBHs) which may have formed from initial density perturbations or phase transitions in the early universe are investigated. If the PBHs formed from scale-invariant initial density perturbations in the radiation dominated era, it is found that the emission can explain or contribute significantly to the extragalactic photon and interstellar cosmic-ray electron, positron, and antiproton spectra around 0.1-1 GeV. In particular, the PBH emission strongly resembles the cosmic-ray gamma-ray spectrum between 50 and 170 MeV. The upper limits on the PBH density today from the gamma-ray, e(+), e(-), and antiproton data are comparable, provided that the PBHs cluster to the same degree as the other matter in the Galactic halo.

Macgibbon, Jane H.↗

dc modulation noise in thin film magnetic recording disk media

A study of dc modulation noise as a function of magnetic layer thickness has been conducted for plated longitudinal low-noise Co-alloy disk media with a range of 900 to 1100 Oe. The noise, produced by the application of a reverse longitudinal dc field to a uniformly magnetized disk, supplies data regarding the uniformity of the disk. A spectrum analyzer measures the noise by means of electronic detection, and noise spectra and autocorrelation functions calculated with a model are compared to the experimental results. The model correlates with experimental data to more than 0.99. The maximum distance between effective transitions diminishes from 2.8 microns to 1 micron when the thickness of the magnetic layer is increased from 25 nm to 60 nm. The maximum average transition amplitude is found to be independent of thickness, and is bounded by 0.001 of the saturation magnetization.

Katti, R. R.↗

Closed-Shell Polycyclic Aromatic Hydrocarbon Cations: A New Category of Interstellar Polycyclic Aromatic Hydrocarbons

Density functional theory has been employed to calculate the harmonic frequencies and intensities of a range of polycyclic aromatic hydrocarbon (PAH) cations that explore both size and electronic structure effects of the infrared spectroscopic properties of these species. The sample extends the size range of PAH species considered to more than 50 carbon atoms and includes several representatives from each of two heretofore unexplored categories of PAH cations: (1) fully benzenoid PAH cations whose carbon skeleton is composed of an odd number of carbon atoms (C(sub odd) PAHs); and (2) protonated PAH cations (HPAH+). Unlike the radical electronic structures of the PAH cations that have been the subject of previous theoretical and experimental work, the species in these two classes have a closed-shell electronic configuration. The calculated spectra of circumcoronene, C54H18 in both neutral and (radical) cationic form are also reported and compared with those of the other species. Overall, the C(sub odd) PAHs spectra are dominated by strong CC stretching modes near 1600 cm(exp -1) and display spectra that are remarkably insensitive to molecular size. The HPAH+ species evince a more complex spectrum consistent with the added contributions of aliphatic modes and their generally lower symmetry. Finally, for both classes of closed-shell cations, the intensity of the aromatic CH stretching modes is found to increase with molecular size far out of proportion with the number of CH groups, approaching a value more typical of neutral PAHs for the largest species studied.

Hudgins, Douglas M.↗

A Theoretical Investigation of the Infrared Spectroscopic Properties of Closed-Shell Polycyclic Aromatic Hydrocarbon Cations

Density functional theory has been employed to calculate the harmonic frequencies and intensities of a range of PAH cations which explore both size and electronic structure effects on the infrared spectroscopic of these species. The sample extends the size range of PAH species considered to more than 50 carbon atoms and includes several representatives from each of two heretofore unexplored categories of PAH cations: (1) fully benzenoid PAH cations whose carbon skeleton is composed of an odd number of carbon atoms and (2) protonated PAH cations. Unlike the radical electronic structures of the PAH cations that have been the subject of previous theoretical and experimental work, the species in these two classes have a closed-shell electronic configuration. The calculated spectra of circumcoronene, C54H18, in both neutral and (radical) cationic form are also reported and compared to those of the other species. Closed-shell species are inherently less reactive than radical (or open-shell) cations and are known to play a role in combustion chemistry. Since interstellar PAHs are typically exposed to abundant atomic hydrogen and are thought to originate under pseudo-combustion conditions in carbon-rich circumstellar shells, such species may represent an important component of the interstellar PAH population. Furthermore, species larger than 50 carbon atoms are more representative of the size of the typical interstellar PAH. Overall, as has been the case for previous studies of PAH radical cations, the general pattern of band positions and intensities are consistent with that of the interstellar infrared emission spectrum. In addition, the spectra of closed-shell and open-shell cations are found to converge with increasing molecular size and are found to be relatively similar for species containing about 50 carbon atoms.

Hudgins, Douglas M.↗

Theoretical Model Images and Spectra for Comparison with HESSI and Microwave Observations of Solar Flares

We have computed bremsstrahlung and gyrosynchrotron images and spectra from a model flare loop. Electrons with a power-law energy distribution are continuously injected at the top of a semi-circular magnetic loop. The Fokker-Planck equation is integrated to obtain the steady-state electron distribution throughout the loop. Coulomb scattering and energy losses and magnetic mirroring are included in the model. The resulting electron distributions are used to compute the radiative emissions. Sample images and spectra are presented. We are developing these models for the interpretation of the High Energy Solar Spectroscopic Imager (HESSI) x-ray/gamma ray data and coordinated microwave observations. The Fokker-Planck and radiation codes are available on the Web at http://hesperia.gsfc.nasa.gov/hessi/modelware.htm This work is supported in part by the NASA Sun-Earth Connection Program.

Fisher, Richard R.↗

Interplanetary Radiation and Internal Charging Environment Models for Solar Sails

A Solar Sail Radiation Environment (SSRE) model has been developed for defining charged particle environments over an energy range from 0.01 keV to 1 MeV for hydrogen ions, helium ions, and electrons. The SSRE model provides the free field charged particle environment required for characterizing energy deposition per unit mass, charge deposition, and dose rate dependent conductivity processes required to evaluate radiation dose and internal (bulk) charging processes in the solar sail membrane in interplanetary space. Solar wind and energetic particle measurements from instruments aboard the Ulysses spacecraft in a solar, near-polar orbit provide the particle data over a range of heliospheric latitudes used to derive the environment that can be used for radiation and charging environments for both high inclination 0.5 AU Solar Polar Imager mission and the 1.0 AU L1 solar missions. This paper describes the techniques used to model comprehensive electron, proton, and helium spectra over the range of particle energies of significance to energy and charge deposition in thin (less than 25 micrometers) solar sail materials.

Minow, Joseph I.↗

Precipitating relativistic electrons - Their long-term effect on stratospheric odd nitrogen levels

Using electron count rate data at geostationary orbit, daily energy spectra, extending from 30 keV to 15 MeV, have been developed for trapped relativistic electrons at 6.6 earth radii. These spectra have been used to model the flux of these electrons into the atmosphere at 120 km. Energy deposition calculations permit daily sources of HO(x) and NO(y) to be calculated at auroral and subauroral latitudes due to relativistic electron precipitation (REP) for the period June 13, 1979, through June 4, 1988. Both short-term and long-term source variations are quite large over the period considered. The results suggest that a significant contribution to the anomalously large and unexplained global O3 declines between 1979 and 1985 has been made by the catalytic destruction of O3 by odd nitrogen in the lower stratosphere at mid to high latitudes. The results also provide evidence for a clear and strong linkage between solar variability, the state of the magnetosphere, and the chemical climatological state of the middle and lower atmosphere.

Callis, Linwood B.↗

Model calculations of the radiation dose and LET spectra on LDEF and comparisons with flight data

Ionizing radiation environment models, a 3-D spacecraft mass model, and radiation transport codes have been used to predict the radiation dose and linear energy transfer (LET) spectra measured at various locations on the LDEF satellite. The predictions are compared with thermoluminescent dosimeter measurements of the trapped proton and electron doses and with LET spectra measured by plastic nuclear track detectors. The predicted vs observed comparisons indicate some of the uncertainties of present ionizing radiation environment models for low Earth-orbit missions.

LDEF Project↗

Auroral electron acceleration and atmospheric interactions - /1/ Rocket-borne observations and /2/ scattering calculations

Electron energy and pitch angle spectra are obtained by an instrumented rocket payload launched across a pre-midnight auroral arc. The interaction of the incident electron beam with the atmosphere is described through transport theory including inelastic and multiple-elastic scattering of electrons by neutrals. A two-stream approximation to the electron transport equation is used to compute the hemispherically averaged upcoming electron transport that resulted from the measured downcoming intensity. The model of Evans (1974) is employed to infer a primary electron spectrum within the discrete arc.

Pulliam, D. M.↗

A search for parallel electric fields by observing secondary electrons and photoelectrons in the low-altitude auroral zone

Model calculations are performed demonstrating the effect of weak parallel electric fields on the differential spectra of the low-energy electrons observed in the inverted-V electron precipitation events in the topside ionosphere. A comparison of the altitude dependence of the observed spectra with the model calculations shows that there can be, on average, no more than a 2-V potential drop between the altitudes of 400 and 900 km, corresponding to a distributed parallel dc electric field of less than 4 microV/m under the inverted-V electron precipitation regions. Statistical results are presented on the spectral dependence of secondary electrons on the inverted-V primary beam parameters.

Fung, Shing F.↗

Gamma-ray emission and electron acceleration in solar flares

Recent observations have extended the spectra of the impulsive phase of flares to the GeV range. Such high-energy photons can be produced either by electron bremsstrahlung or by decay of pions produced by accelerated protons. In this paper we investigate the effects of processes which become important at high energies. We examine the effects of synchrotron losses during the transport of electrons as they travel from the acceleration region in the corona to the gamma-ray emission sites deep in the chromosphere and photosphere, and the effects of scattering and absorption of gamma rays on their way from the photosphere to space instruments. These results are compared with the spectra from so-called electron-dominated flares, observed by GRS on the Solar Maximum Mission, which show negligible or no detectable contribution from accelerated protons. The spectra of these flares show a distinct steepening at energies below 100 keV and a rapid falloff at energies above 50 MeV. Following our earlier results based on lower energy gamma-ray flare emission we have modeled these spectra. We show that neither the radiative transfer effects, which are expected to become important at higher energies, nor the transport effects (Coulomb collisions, synchrotron losses, or magnetic field convergence) can explain such sharp spectral deviations from a simple power law. These spectral deviations from a power law are therefore attributed to the acceleration process. In a stochastic acceleration model the low-energy steepening can be attributed to Coulomb collision and the rapid high-energy steepening can result from synchrotron losses during the acceleration process.

Petrosian, Vahe↗

Time-resolved measurements of nonthermal X-ray emission of Ti XXI lines in electron-cyclotron-heated tokamak plasmas

The observation of heliumlike titanium spectra with 20 ms temporal resolution during high-power injection of electron cyclotron heating (ECH) of up to 250 ms pulse length into the Doublet III tokamak is reported. The prominent lines in the spectra and the observed dielectronic satellite lines from the autoionizing lithiumlike ionization states are given. The intensity of the resonance line 1s2 1S0 - 1s 2p 1P1 is found to be extremely sensitive to the ECH power. Time-resolved line ratios are also presented. It is concluded that a significant departure from a Maxwellian distribution of electrons exists in the present ECH plasmas.

Lee, P.↗

A bi-directional charged particle telescope to observe flux, energy spectrum and angular distribution of relativistic and non-relativistic particles

A Charged Particle Telescope (CPT) was designed, fabricated and calibrated to make the following observations: (1) discrimination between various singly charged particles, e.g., electrons, muons and protons, in about 5 to 100 MeV energy range; (2) measurement of the flux and the energy of the charged particles incident to the telescope from two opposite directions and stopping in the telescope, thus obtaining flux and energy spectrum of downward and upward moving charged particles; and (3) measurement of the broad angular distribution of selected particles as a function of azimuthal angle. This telescope can be used to study low energy electron, muon and proton energy spectra. The experiment was flown in a high altitude balloon from Hyderabad, India, in December 1984. This same equipment is also useful in ground level electron, muon spectrum study.

Verma, S. D.↗

The O IV and S IV intercombination lines in solar and stellar ultraviolet spectra

New calculations of O IV electron density diagnostic emission-line ratios involving the 1399.8, 1401.2, 1404.8, and 14076.4 A transitions are presented. A comparison of these calculations with observational data from a quiet solar region, a sunspot, and an active region obtained with the High Resolution Telescope and Spectrograph (HRTS), two flares observed with the SO82B spectrograph on board Skylab, and Hubble Space Telescope (HST) observations by the Goddard High Resolution Spectrograph (GHRS) of Capella, gives good results using the ratio R(sub 1) = I(1407.4 A)/I(1401.2 A). However, the electron density obtained using the ratio R(sub 2) = I(1407.4 A)/I(1404.8 A) is often an order of magnitude smaller. The O IV 1404.8 A line is blended with the S IV 1404.8 A line, and we investigate whether this ratio may still be used as a density diagnostic if the S IV 1406.1 A line intensity is used to correct for the presence of S IV 1404.8 A, using previous S IV calculations by Dufton et al. We still find systematic differences compared to density determinations from line ratios that do not involve the O IV 1404.8 A line, which we suggest are due to errors in earlier theoretical calculations of the S IV atomic data, and also possibly to previously unconsidered fluorescent pumping of the upper level of the S IV 1404.8 A transition.

Cook, J. W.↗

Properties of Cathodoluminescence for Cryogenic Applications of SiO2-based Space Observatory Optics and Coatings

Disordered thin film SiO2SiOx coatings undergoing electron-beam bombardment exhibit cathodoluminescence, which can produce deleterious stray background light in cryogenic space-based astronomical observatories exposed to high-energy electron fluxes from space plasmas. As future observatory missions push the envelope into more extreme environments and more complex and sensitive detection, a fundamental understanding of the dependencies of this cathodoluminescence becomes critical to meet performance objectives of these advanced space-based observatories. Measurements of absolute radiance and emission spectra as functions of incident electron energy, flux, and power typical of space environments are presented for thin (60-200 nm) SiO2SiOx optical coatings on reflective metal substrates over a range of sample temperatures (40-400 K) and emission wavelengths (260-5000 nm). Luminescent intensity and peak wavelengths of four distinct bands were observed in UVVISNIR emission spectra, ranging from 300 nm to 1000 nm. A simple model is proposed that describes the dependence of cathodoluminescence on irradiation time, incident flux and energy, sample thickness, and temperature.

electron-beam bombardment↗