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DOE OSTI2026

Insights into Rotational and Translational Dynamics in Mixtures of Ethylene Glycol and Choline Chloride Using Nuclear Magnetic Resonance Techniques

This work examines molecular dynamics and interactions in ethylene glycol–choline chloride (EG–ChCl) mixtures across 0–33 mol % ChCl, spanning the true eutectic region near 17–20 mol % and the commonly used 1:2 formulation. We combine pulsed-field-gradient (PFG) diffusion, fast-field-cycling (FFC) relaxometry, temperature-dependent 13 C T 1 , and nuclear Overhauser effect spectroscopy (NOESY) to disentangle local from macroscopic dynamics. PFG and FFC show that both translational and average rotational motions largely track the strong increase in viscosity with ChCl content, with ethylene glycol consistently diffusing faster than the choline cation and no global dynamical anomaly at the eutectic composition. More subtle, site-specific composition effects nevertheless emerge. The ratio of the diffusion coefficient of the hydroxyl group of choline to the diffusion coefficient of the methyl group of choline displays a shallow minimum in the 17–25 mol % region, indicating a modest change in how the hydroxyl-bearing end of choline samples the underlying translational motion relative to the methyl groups. 13 C T 1 analysis shows that rotational correlation times at 25 °C generally increase with ChCl, reflecting viscosity-coupled slowing, while the CH 2 –N α site exhibits a small but reproducible deviation from this monotonic trend near the eutectic. NOESY spectra at similar compositions reveal enhanced cross-relaxation between EG and choline protons, consistent with increased headgroup–solvent contact density rather than a wholesale structural rearrangement. Overall, our multitechnique study demonstrates that EG–ChCl dynamics are predominantly viscosity-dominated, with the eutectic region acting as a subtle dynamical crossover where specific choline segments become maximally coupled to the hydrogen-bond network. These insights refine the structure–dynamics picture of choline-chloride DESs and provide practical guidance for tuning composition in electrochemical, separation, and catalytic applications.

diffusion↗

NASA NTRS2001

Muscle sympathetic nerve responses to physiological changes in prostaglandin production in humans

Previous studies suggest that prostaglandins may contribute to exercise-induced increases in muscle sympathetic nerve activity (MSNA). To test this hypothesis, MSNA was measured at rest and during exercise before and after oral administration of ketoprofen, a cyclooxygenase inhibitor, or placebo. Twenty-one subjects completed two bouts of graded dynamic and isometric handgrip to fatigue. Each exercise bout was followed by 2 min of postexercise muscle ischemia. The second exercise bouts were performed after 60 min of rest in which 11 subjects were given ketoprofen (300 mg) and 10 subjects received a placebo. Ketoprofen significantly lowered plasma thromboxane B(2) in the drug group (from 36 +/- 6 to 22 +/- 3 pg/ml, P < 0.04), whereas thromboxane B(2) in the placebo group increased from 40 +/- 5 to 61 +/- 9 pg/ml from trial 1 to trial 2 (P < 0.008). Ketoprofen and placebo did not change sympathetic and cardiovascular responses to dynamic handgrip, isometric handgrip, and postexercise muscle ischemia. There was no relationship between thromboxane B(2) concentrations and MSNA or arterial pressure responses during both exercise modes. The data indicate that physiological increases or decreases in prostaglandins do not alter exercise-induced increases in MSNA and arterial pressure in humans. These findings suggest that contraction-induced metabolites other than prostaglandins mediate MSNA responses to exercise in humans.

Clinical Trial↗

NASA NTRS2021

Coastal California Water Resources II: Utilizing NASA Earth Observations to Detect and Assess the Impacts of Estuarine Breach Events for Improved Coastal Wetland Monitoring and Management

Estuaries are dynamic environments that provide a host of vital ecosystem services. California’s Marine Life Protection Act protects such ecosystems by creating Marine Protected Areas. California has approximately 440,000 acres of estuarine habitats as well as 23 Estuarine Marine Protected Areas (EMPAs); thus, in situ data collection is often difficult due to time and resource constraints. This project used remote sensing to gather data that examined the health and dynamics of California EMPAs in order to supplement ground-based field measurements. Through the use of Landsat 8 Operational Land Imager (OLI) and Thermal Infrared Sensor (TIRS), Sentinel-2 Multispectral Instrument (MSI) and Sentinel-1 C-band Synthetic Aperture Radar (C-SAR), this project assessed mouth state, inundation extent, turbidity, temperature, and tidal measurements for observable estuaries. The Normalized Water Difference Index from Sentinel-2 MSI captured estuary mouth state and inundation extent. Landsat 8 OLI and Sentinel-2 MSI detected differences in water quality metrics that correlated to changes in estuary mouth state (i.e., open or closed). The team’s California Estuary Assessment (CEA) tool in Google Earth Engine was successful in analyzing estuary mouth state, inundation, and water quality. It was most effective when breach events were larger than 10 meters in resolution, water surface was smooth, and imagery was unimpeded by algae or sun glint. The CEA tool will allow the partners, the Ocean Protection Council, Central Coast Wetlands Group, Southern California Coastal Water Research Project, and University of California Los Angeles (UCLA) and Davis (UCD), to better understand estuary dynamics and more effectively conduct in situ estuary monitoring.

Sarah Payne↗

DOE OSTI2025

Distinct effect of Kondo physics on crystal field splitting in electron and spin spectroscopies

Magnetic anisotropy is a key feature of rare earth materials from permanent magnets to heavy fermions. Here we explore the complex interplay of Kondo physics and anisotropy, and their effect on different experimental probes of magnetic anisotropy in a minimal 𝐽=3/2 Anderson impurity model using the numerical renormalization group. While anisotropy suppresses Kondo screening, virtual valence fluctuations enhance the anisotropy. We find distinct renormalization of the magnetic anisotropy measured via dynamical spin response (inelastic neutron scattering) versus electronic excitations in the impurity spectral function (resonant inelastic x-ray and scanning tunneling spectroscopy). The two measurement types have different responses and dependencies on the temperature and Kondo scales.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

DOE OSTI2025

Ab Initio Study of the Beryllium Isotopes 7 Be to 12 Be

We present a systematic ab initio study of the low-lying states in beryllium isotopes from 7 Be to 12 Be using nuclear lattice effective field theory with the N 3 ⁢LO interaction. Our calculations achieve good agreement with experimental data for energies, radii, and electromagnetic properties. We introduce a novel, model-independent method to quantify nuclear shapes, uncovering a distinct pattern in the interplay between positive and negative parity states across the isotopic chain. By combining Monte Carlo sampling of the many-body density operator with a novel nucleon-grouping algorithm, the prominent two-center cluster structures, the emergence of one-neutron halo, complex nuclear molecular dynamics such as 𝜋 orbital and 𝜎 orbital, emerge naturally.

binding energy & masses↗

NASA NTRS1970

Normally Expected Aberrations in the 8-hour Dynamic EKG

The establishment of norms for interpreting long term dynamic electrocardiograms is attempted by correlating a completely disease symptom and cardiac risk factor free sample with a non-pure sample in the direction of normality on various variables. Out of a population of 362 subjects exposed to dynamic electrocardiogram testing, a discrimination between normals and abnormals in terms of traditional risk factors was observed. The two groups differed significantly on the following variables: cholesterol, smoking, systolic blood pressure, white blood count, fasting blood sugar, uric acid, resting EKG, year of birth, and coronary insufficiency.

Fleck, R. L.↗

NASA NTRS1984

Natural environment design criteria for the Advanced X-ray Astrophysics Facility (AXAF) definition and preliminary design

This document provides the natural environment design criteria requirements for use in the Advanced X-Ray Astrophysics Facility (AXAF) definition and preliminary design studies. The atmospheric dynamic and thermodynamic environments, meteoroids, radiation, magnetic fields, and physical constants are all addressed. This information will enable all groups involved in the definition and preliminary design studies to proceed with a common and consistent set of natural environment criteria requirements.

Greene, W. M.↗

NASA NTRS1985

Natural environment design criteria for the Space Station definition and preliminary design

The natural environment design criteria for the Space Station Program (SSP) definition and preliminary design are presented. Information on the atmospheric, dynamic and thermodynamic environments, meteoroids, radiation, magnetic fields, physical constants, etc. is provided with the intension of enabling all groups involved in the definition and preliminary design studies to proceed with a common and consistent set of natural environment criteria requirements. The space station program elements (SSPE) shall be designed with no operational sensitivity to natural environment conditions during assembly, checkout, stowage, launch, and orbital operations to the maximum degree practical.

Vaughan, W. W.↗

NASA NTRS1987

Parallel processors and nonlinear structural dynamics algorithms and software

An explicit-explicit subcycling procedure for the finite element analysis of structural dynamics is developed. This procedure has relaxed the usual constraint of requiring integer time step ratios for adjacent nodal groups. This allows for greater advantage to be taken of local stability criteria, and thus improves the efficiency of the explicit time integrator. Example problems are included to demonstrate the accuracy and stability of the method.

Belytschko, Ted↗

NASA NTRS1989

Explicit-explicit subcycling with non-integer time step ratios for structural dynamic systems

Neal, Mark O.↗

NASA NTRS1988

Robust operative diagnosis as problem solving in a hypothesis space

This paper describes an approach that formulates diagnosis of physical systems in operation as problem solving in a hypothesis space. Such a formulation increases robustness by: (1) incremental hypotheses construction via dynamic inputs, (2) reasoning at a higher level of abstraction to construct hypotheses, and (3) partitioning the space by grouping fault hypotheses according to the type of physical system representation and problem solving techniques used in their construction. It was implemented for a turbofan engine and hydraulic subsystem. Evaluation of the implementation on eight actual aircraft accident cases involving engine faults provided very promising results.

Abbott, Kathy H.↗

NASA NTRS1996

Fast 3D Net Expeditions: Tools for Effective Scientific Collaboration on the World Wide Web

Two new technologies, the FASTexpedition and Remote FAST, have been developed that provide remote, 3D (three dimensional), high resolution, dynamic, interactive viewing of scientific data. The FASTexpedition permits one to access scientific data from the World Wide Web, take guided expeditions through the data, and continue with self controlled expeditions through the data. Remote FAST permits collaborators at remote sites to simultaneously view an analysis of scientific data being controlled by one of the collaborators. Control can be transferred between sites. These technologies are now being used for remote collaboration in joint university, industry, and NASA projects. Also, NASA Ames Research Center has initiated a project to make scientific data and guided expeditions through the data available as FASTexpeditions on the World Wide Web for educational purposes. Previously, remote visualization of dynamic data was done using video format (transmitting pixel information) such as video conferencing or MPEG (Motion Picture Expert Group) movies on the Internet. The concept for this new technology is to send the raw data (e.g., grids, vectors, and scalars) along with viewing scripts over the Internet and have the pixels generated by a visualization tool running on the viewers local workstation. The visualization tool that is currently used is FAST (Flow Analysis Software Toolkit). The advantages of this new technology over using video format are: (1) The visual is much higher in resolution (1280x1024 pixels with 24 bits of color) than typical video format transmitted over the network. (2) The form of the visualization can be controlled interactively (because the viewer is interactively controlling the visualization tool running on his workstation). (3) A rich variety of guided expeditions through the data can be included easily. (4) A capability is provided for other sites to see a visual analysis of one site as the analysis is interactively performed. Control of the analysis can be passed from site to site. (5) The scenes can be viewed in 3D using stereo vision. (6) The network bandwidth for the visualization using this new technology is much smaller than when using video format. (The measured peak bandwidth used was 1 Kbit/sec whereas the measured bandwidth for a small video picture was 500 Kbits/sec.) This talk will illustrate the use of these new technologies and present a proposal for using these technologies to improve science education.

Watson, Val↗

NASA NTRS2008

Dispersion-Enhanced Laser Gyroscope

We analyze the effect of a highly dispersive element placed inside a modulated optical cavity on the frequency and amplitude of the output modulation to determine the conditions for enhanced gyroscopic sensitivities. The element is treated as both a phase and amplitude filter, and the time-dependence of the cavity field is considered. Both atomic gases (two-level and multi-level) and optical resonators (single and coupled) are considered and compared as dispersive elements. We find that it is possible to simultaneously enhance the gyro scale factor sensitivity and suppress the dead band by using an element with anomalous dispersion that has greater loss at the carrier frequency than at the side-band frequencies, i.e., an element that simultaneously pushes and intensifies the perturbed cavity modes, e.g. a two-level absorber or an under-coupled optical resonator. The sensitivity enhancement is inversely proportional to the effective group index, becoming infinite at a group index of zero. However, the number of round trips required to reach a steady-state also becomes infinite when the group index is zero (or two). For even larger dispersions a steady-state cannot be achieved, and nonlinear dynamic effects such as bistability and periodic oscillations are predicted in the gyro response.

Smith, David D.↗

NASA NTRS2009

Coastal Observations of Weather Features in Senegal during the AMMA SOP-3 Period

During 15 August through 30 September 2006, ground and aircraft measurements were obtained from a multi-national group of students and scientists in Senegal. Key measurements were aimed at investigating and understanding precipitation processes, thermodynamic and dynamic environmental conditions, cloud, aerosol and microphysical processes and spaceborne sensors (TRMM, CloudSat/Calipso) validation. Ground and aircraft instruments include: ground based polarimetric radar, disdrometer measurements, a course and a high-density rain gauge network, surface chemical measurements, a 10 m flux tower, broadband IR, solar and microwave measurements, rawinsonde and radiosonde measurements, FA-20 dropsonde, in situ microphysics and cloud radar measurements. Highlights during SOP3 include ground and aircraft measurements of squall lines, African Easterly Waves (AEWs), Saharan Air Layer advances into Senegal, and aircraft measurements of AEWs -- including the perturbation that became Hurricane Isaac.

Jenkins, G.↗

NASA NTRS2019

Tracking Aerosol Convective Interactions Experiment (TRACER) Science Plan

Convective clouds play an important role in the Earth's climate system as a driver of large-scale circulations and a primary mechanism for the transport of heat, moisture, aerosols, and momentum throughout the troposphere. Despite their climatic importance, multi-scale models continue to have persistent biases produced by insufficient representation of convective clouds. This is the result of an incomplete understanding of key processes such as convective initiation, updraft and downdraft dynamics, cloud and precipitation microphysics, and aerosol-convection interactions.The Aerosol-Cloud-Precipitation-Climate Initiative, an international research group dedicated to advancing understanding of aerosol impacts on clouds relevant to climate, has identified the Houston, Texas region as an optimal location for targeted studies of aerosol-convection interactions within frequently developing isolated deep convection. Houston lies within a humid subtropical climate regime, where onshore flow and sea-breeze convection interact with a range of aerosol conditions associated with Houston's urban and industrial emissions. Pilot studies have suggested that convective clouds in this region are potentially significantly impacted by the varying aerosol conditions.

Jensen, M.↗

NASA NTRS2014

Portable Simulator for On-Board International Space Station Emergency Training

The crew on-board the International Space Station (ISS) have to be prepared for any possible emergency. The emergencies of most concern are a fire, depressurization or a toxic atmosphere. The crew members train on the ground before launch but also need to practice their emergency response skills while they are on orbit for 6 months. On-Board Training (OBT) events for emergency response proficiency used to require the crew and ground teams to use paper "scripts" that showed the path through the emergency procedures. This was not very realistic since the participants could read ahead and never deviate from this scripted path. The new OBT emergency simulator allows the crew to view dynamic information on an iPad only when it would become available during an event. The simulator interface allows the crew member to indicate hatch closures, don and doff masks, read pressures, and sample smoke or atmosphere levels. As the crew executes their actions using the on-board simulator, the ground teams are able to monitor those actions via ground display data flowing through the ISS Ku Band communication system which syncs the on-board simulator software with a ground simulator which is accessible in all the control centers. The OBT Working Group (OBT WG), led by the Chief Training Office (CTO) at Johnson Space center is a Multilateral working group with partners in Russia, Japan, Germany and U.S.A. The OBTWG worked together to create a simulator based on these principles: (a) Create a dynamic simulation that gives real-time data feedback; (b) Maintain real-time interface between Mission Control Centers and crew during OBTs; (c) Provide flexibility for decision making during drill execution; (d) Materially reduce Instructor and Flight Control Team man-hour costs involved with developing, updating, and maintaining emergency OBT cases/scenarios; and (e) Introduce an element of surprise to emergency scenarios so the team can't tell the outcome of the case by reading ahead in a paper script. This paper details some of the background as the project evolved with the International Partners. It also provides more details on how the simulator information for the crew is also shared with the ground teams. Finally, the paper will discuss how this remote simulator concept can be useful for future, longer term space missions.

Bolt, Kathy↗

NASA NTRS2010

Massive Star Formation of the SGR a East H (sub II) Regions Near the Galactic Center

A group of four compact H II regions associated with the well-known 50 km/s molecular cloud is the closest site of on-going star formation to the dynamical center of the Galaxy, at a projected distance of approximately 6 pc. We present a study of ionized gas based on the [Ne II] (12.8 micron) line, as well as multi-frequency radio continuum, Hubble Space Telescope Pa alpha, and Spitzer Infrared Array Camera observations of the most compact member of the H II group, Sgr A East H II D. The radio continuum image at 6 cm shows that this source breaks up into two equally bright ionized features, D1 and D2. The spectral energy distribution of the D source is consistent with it being due to a 25 =/- 3 solar mass star with a luminosity of 8 +/- 3 x 10(exp 4) Solar luminosity . The inferred mass, effective temperature of the UV source, and the ionization rate are compatible with a young O9-B0 star. The ionized features D1 and D2 are considered to be ionized by UV radiation collimated by an accretion disk. We consider that the central massive star photoevaporates its circumstellar disk on a timescale of 3x (exp 4) years giving a mass flux approximately 3 x 10(exp -5) Solar Mass / year and producing the ionized material in D1 and D2 expanding in an inhomogeneous medium. The ionized gas kinematics, as traced by the [Ne II] emission, is difficult to interpret, but it could be explained by the interaction of a bipolar jet with surrounding gas along with what appears to be a conical wall of lower velocity gas. The other H II regions, Sgr A East A-C, have morphologies and kinematics that more closely resemble cometary flows seen in other compact H II regions, where gas moves along a paraboloidal surface formed by the interaction of a stellar wind with a molecular cloud.

Yusef-Zadeh, F.↗

NASA NTRS2022

Brief Communication: Preliminary ICESat-2 (Ice, Cloud and Land Elevation Satellite-2) Measurements of Outlet Glaciers Reveal Heterogeneous Patterns of Seasonal Dynamic Thickness Change

Dynamic changes of marine-terminating outlet glaciers are projected to be responsible for about half of future ice loss from the Greenland Ice Sheet. However, we lack a unified, process-based understanding that can explain the observed dynamic changes of all outlet glaciers. Many glaciers undergo seasonal dynamic thickness changes, and classifying the patterns of seasonal thickness change can improve our understanding of the processes that drive glacier behavior. The Ice, Cloud and land Elevation Satellite-2 (ICESat-2) provides space-based, seasonally repeating altimetry measurements of the ice sheets, allowing us to quantify near-termini seasonal dynamic thickness patterns of 37 outlet glaciers around the Greenland Ice Sheet. We classify the glaciers into seven common patterns of seasonal thickness change over a 2-year period from 2019 to 2020. We find small groupings of neighboring glaciers with similar patterns of seasonal thickness change, but, within larger sectors of the ice sheet, patterns of seasonal thickness change are mostly heterogeneous. Future studies can build upon our results by extending these time series, comparing seasonal dynamic thickness changes with external forcings, such as ocean temperature and meltwater runoff, and with other dynamic variables such as seasonal glacier velocity and terminus position changes.

Christian J Taubenberger↗