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DOE OSTI2022

The Toughness of High-Strength Steel Weld Metals

Low-temperature phase transformation (LTPT) welding consumables are a new class of welding wires developed to mitigate hydrogen-induced cracking in the welding of high-strength steels without preheating or postweld heat treatment. LTPT weld metals have a high strength, but their toughness needs further investigation. LTPT weld metals predominately contain a martensite microstructure, which is necessary to achieve high strength; however, martensitic weld metals containing oxide inclusions have relatively poor toughness. For this study, three welding processes — gas metal arc welding (GMAW), gas tungsten arc welding (GTAW), and hot wire GTAW — were investigated. Optical microscopy, scanning electron microscopes, and transmission electron microscopes were employed for characterization. The role of the shielding gas in the formation of oxide inclusions in LTPT weld metals was investigated. The formation of oxide inclusions in the weld metals was related to the CO 2 in the shielding gas. When 100% Ar or a pure inert shielding gas mixture was used for all three welding processes, oxide inclusions were greatly reduced, and the weld metal toughness improved considerably, matching the base metal toughness. The mechanism by which inclusions promote fracture propagation in the weld metal was proposed.

36 MATERIALS SCIENCE↗

DOE OSTI2022

Mechanical Response and Processability of Wet-Laid Recycled Carbon Fiber PE, PA66 and PET Thermoplastic Composites

The interest in recycled carbon fiber (rCF) is growing rapidly and the supply chain for these materials is gradually being established. However, the processing routes, material intermediates and properties of rCF composites are less understood for designers to adopt them into practice. This paper provides a practical pathway for rCFs in conjunction with low cost and, for the most part, commodity thermoplastic resins, namely polyethylene (PE), polyamide 66 (PA66) and polyethylene terephthalate (PET). Industrially relevant wet-laid (WL) process routes have been adopted to produce mats using two variants of WL mats, namely (a) high speed wet-laid inclined wire to produce broad good ‘roll’ forms and (b) 3DEPTM process patented by Materials Innovation Technologies (MIT)-recycled carbon fiber (RCF), now Carbon Conversions, which involves mixing fibers and water and depositing the fibers on a water-immersed mold. These are referred to as ‘sheet’ forms. The produced mats were evaluated for their processing into composites as ‘fully consolidated mats’ and ‘non-consolidated’ as-produced mats. Comprehensive mechanical data in terms of tensile strength, tensile modulus and impact toughness for rCF C/PE, C/PA66 and C/PET are presented. The work is of high value to sustainable composite designers and modelers.

compression molding↗

DOE OSTI2017

The Cloud Feedback Model Intercomparison Project (CFMIP) contribution to CMIP6

Our primary objective of CFMIP is to inform future assessments of cloud feedbacks through improved understanding of cloud–climate feedback mechanisms and better evaluation of cloud processes and cloud feedbacks in climate models. But, the CFMIP approach is also increasingly being used to understand other aspects of climate change, and so a second objective has now been introduced, to improve understanding of circulation, regional-scale precipitation, and non-linear changes. CFMIP is supporting ongoing model inter-comparison activities by coordinating a hierarchy of targeted experiments for CMIP6, along with a set of cloud-related output diagnostics. CFMIP contributes primarily to addressing the CMIP6 questions How does the Earth system respond to forcing? and What are the origins and consequences of systematic model biases? and supports the activities of the WCRP Grand Challenge on Clouds, Circulation and Climate Sensitivity. A compact set of Tier 1 experiments is proposed for CMIP6 to address this question: (1) what are the physical mechanisms underlying the range of cloud feedbacks and cloud adjustments predicted by climate models, and which models have the most credible cloud feedbacks? Additional Tier 2 experiments are proposed to address the following questions. (2) Are cloud feedbacks consistent for climate cooling and warming, and if not, why? (3) How do cloud-radiative effects impact the structure, the strength and the variability of the general atmospheric circulation in present and future climates? (4) How do responses in the climate system due to changes in solar forcing differ from changes due to CO 2 , and is the response sensitive to the sign of the forcing? (5) To what extent is regional climate change per CO 2 doubling state-dependent (non-linear), and why? (6) Are climate feedbacks during the 20th century different to those acting on long-term climate change and climate sensitivity? (7) How do regional climate responses (e.g. in precipitation) and their uncertainties in coupled models arise from the combination of different aspects of CO 2 forcing and sea surface warming? CFMIP also proposes a number of additional model outputs in the CMIP DECK, CMIP6 Historical and CMIP6 CFMIP experiments, including COSP simulator outputs and process diagnostics to address the following questions. How well do clouds and other relevant variables simulated by models agree with observations? What physical processes and mechanisms are important for a credible simulation of clouds, cloud feedbacks and cloud adjustments in climate models? Which models have the most credible representations of processes relevant to the simulation of clouds? How do clouds and their changes interact with other elements of the climate system?

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2016

Integration of nitrogen dynamics into the Noah-MP land surface model v1.1 for climate and environmental predictions

Climate and terrestrial biosphere models consider nitrogen an important factor in limiting plant carbon uptake, while operational environmental models view nitrogen as the leading pollutant causing eutrophication in water bodies. The community Noah land surface model with multi-parameterization options (Noah-MP) is unique in that it is the next-generation land surface model for the Weather Research and Forecasting meteorological model and for the operational weather/climate models in the National Centers for Environmental Prediction. Here in this study, we add a capability to Noah-MP to simulate nitrogen dynamics by coupling the Fixation and Uptake of Nitrogen (FUN) plant model and the Soil and Water Assessment Tool (SWAT) soil nitrogen dynamics. This model development incorporates FUN's state-of-the-art concept of carbon cost theory and SWAT's strength in representing the impacts of agricultural management on the nitrogen cycle. Parameterizations for direct root and mycorrhizal-associated nitrogen uptake, leaf retranslocation, and symbiotic biological nitrogen fixation are employed from FUN, while parameterizations for nitrogen mineralization, nitrification, immobilization, volatilization, atmospheric deposition, and leaching are based on SWAT. The coupled model is then evaluated at the Kellogg Biological Station – a Long Term Ecological Research site within the US Corn Belt. Results show that the model performs well in capturing the major nitrogen state/flux variables (e.g., soil nitrate and nitrate leaching). Furthermore, the addition of nitrogen dynamics improves the modeling of net primary productivity and evapotranspiration. The model improvement is expected to advance the capability of Noah-MP to simultaneously predict weather and water quality in fully coupled Earth system models.

58 GEOSCIENCES↗

NASA NTRS1973

Space shuttle solid rocket booster recovery system definition, volume 1

The performance requirements, preliminary designs, and development program plans for an airborne recovery system for the space shuttle solid rocket booster are discussed. The analyses performed during the study phase of the program are presented. The basic considerations which established the system configuration are defined. A Monte Carlo statistical technique using random sampling of the probability distribution for the critical water impact parameters was used to determine the failure probability of each solid rocket booster component as functions of impact velocity and component strength capability.

Source record↗

NASA NTRS1974

Boron/aluminum-graphite/resin advanced fiber composite hybrids

An investigation was conducted to determine the fabrication feasibility and to assess the potential of adhesively-bonded metal and resin matrix fiber composite hybrids as an advanced material, for aerospace and other structural applications. The results of fabrication studies and of evaluation of physical and mechanical properties show that using this hybrid concept it is possible to design a composite which, when compared to nonhybrid composites, has improved transverse strength, transverse stiffness, and impact resistance with only a small penalty on density and longitudinal properties. The results also show that laminate theory is suitable for perdicting the structural response of such hybrids. The sequence of fracture modes indicates that these types of hybrids can be readily designed to meet fail-safe requirements.

Chamis, C. C.↗

NASA NTRS1974

Strengthening of oxidation resistant materials for gas turbine applications

Silicon nitride and silicon carbide ceramics were treated to form compressive surface layers. On the silicon carbide, quenching and thermal exposure treatments were used, and on the silicon nitride, quenching, carburizing, and a combination of quenching and carburizing were used. In some cases substantial improvements in impact resistance and/or flexural strength were observed. The presence of compressive surface stresses was demonstrated by slotted rod tests.

Kirchner, H. P.↗

NASA NTRS1975

Boron/aluminum graphite/resin advanced fiber composite hybrids

Fabrication feasibility and potential of an adhesively bonded metal and resin matrix fiber-composite hybrid are determined as an advanced material for aerospace and other structural applications. The results show that using this hybrid concept makes possible a composite design which, when compared with nonhybrid composites, has greater transverse strength, transverse stiffness, and impact resistance with only a small penalty on density and longitudinal properties. The results also show that laminate theory is suitable for predicting the structural response of such hybrids. The sequence of fracture modes indicates that these types of hybrids can be readily designed to meet fail-safe requirements.

Chamis, C. C.↗

NASA NTRS1974

Boron/aluminum-graphite/resin advanced fiber composite hybrids

An investigation was conducted to determine the fabrication feasibility and to assess the potential of adhesively-bonded metal and resin matrix fiber composite hybrids as an advanced material, for aerospace and other structural applications. The results of fabrication studies and of evaluation of physical and mechanical properties show that using this hybrid concept it is possible to design a composite which, when compared to nonhybrid composites, has improved transverse strength, transverse stiffness, and impact resistance with only a small penalty on density and longitudinal properties. The results also show that laminate theory is suitable for predicting the structural response of such hybrids. The sequence of fracture modes indicates that these types of hybrids can be readily designed to meet fail-safe requirements.

Chamis, C. C.↗

NASA NTRS1980

Ultrasonic evaluation of impact-damaged graphite fiber composite

Unidirectional Hercules AS/3501-6 graphite fiber epoxy composites are subjected to repeated controlled low-velocity drop-weight impacts in the laminate direction. The degradation is ultrasonically monitored using through-thickness attenuation and a modified stress wave factor, SWF. There are correlations between the number of drop-weight impacts, the residual tensile strength, the through-thickness attenuation and the SWF.

Williams, J. H., Jr.↗

NASA NTRS1984

Evolution of grains in a turbulent solar nebula

In the present computation of the evolution of grain size distribution in a turbulent disk for turbulent solar nebula models, using realistic collisional outcomes and strengths of grain aggregates, the half space above the central plane of the disk is divided into a series of levels. At each level, the size distribution is represented by the population of a series of discrete size bins, each spanning an order of magnitude in mass. Coagulation, erosion, or disruption, occur for various combinations of relative particle sizes and velocities, together with assumed material strength, based on experimental impact data. The calculation is one-dimensional, in that it is performed at a single radial location in the disk.

Weidenschilling, S. J.↗

NASA NTRS1987

Experimental evidence for non-proportional growth of large craters

Evidence from laboratory impact experiments is indicating that increasing crater aspect ratios (diameter:depth) can result from increasing both velocity and projectile size without invoking unusual impactor conditions. An extensive data base of experimental impact cratering was analyzed for a variety of impactors and impact velocities for low strength targets. These data indicate a change in cratering efficiency that appears to be related to the onset of projectile deformation or rupture. When all projectile types and sizes are considered, one finds two contrasting relationships between crater aspect ratio and impactor parameter. These relationships are briefly considered.

Schultz, Peter H.↗

NASA NTRS1988

Towards a damage tolerance philosophy for composite materials and structures

A damage-threshold/fail-safe approach is proposed to ensure that composite structures are both sufficiently durable for economy of operation, as well as adequately fail-safe or damage tolerant for flight safety. Matrix cracks are assumed to exist throughout the off-axis plies. Delamination onset is predicted using a strain energy release rate characterization. Delamination growth is accounted for in one of three ways: either analytically, using delamination growth laws in conjunction with strain energy release rate analyses incorporating delamination resistance curves; experimentally, using measured stiffness loss; or conservatively, assuming delamination onset corresponds to catastrophic delamination growth. Fail-safety is assessed by accounting for the accumulation of delaminations through the thickness. A tension fatigue life prediction for composite laminates is presented as a case study to illustrate how this approach may be implemented. Suggestions are made for applying the damage-threshold/fail-safe approach to compression fatigue, tension/compression fatigue, and compression strength following low velocity impact.

Obrien, T. Kevin↗

NASA NTRS1990

Towards a damage tolerance philosophy for composite materials and structures

O'Brien, T. Kevin↗

NASA NTRS1991

Fine structure and resonance transitions in C(+)

Significant features in the collision strengths for electron-impact excitation of the fine-structure transition 2P0 1/2 - 2P0 3/2 and the resonance transition 2P0 - 2D in C(+) are discussed based on improved calculations. The former transition gives rise to a well-known (2,3) line in the infrared spectra of many astrophysical sources.

Blum, Robert D.↗

NASA NTRS1992

The Zhamanshin impact feature: A new class of complex crater?

The record of 10-km-scale impact events of Quaternary age includes only two 'proven' impact structures: the Zhamanshin Impact Feature (ZIF) and the Bosumtwi Impact Crater (BIC). What makes these impact landforms interesting from the standpoint of recent Earth history is their almost total lack of morphologic similarity, in spite of similar absolute ages and dimensions. The BIC resembles pristine complex craters on the Moon to first order (i.e., 'U'-shaped topographic cross section with preserved rim), while the ZIF displays virtually none of the typical morphologic elements of a 13- to 14-km-diameter complex crater. Indeed, this apparent lack of a craterlike surficial topographic expression initially led Soviet geologists to conclude that the structure was only 5.5 to 6 km in diameter and at least 4.5 Ma in age. However, more recent drilling and geophysical observations at the ZIF have indicated that its pre-erosional diameter is at least 13.5 km, and that its age is most probably 0.87 Ma. Why the present topographic expression of a 13.5-km complex impact crater less than 1 m.y. old most closely resembles heavily degraded Mesozoic shield craters such as Lappajarvi is a question of considerable debate. Hypotheses for the lack of a clearly defined craterlike form at the ZIF include a highly oblique impact, a low-strength 'cometary' projectile, weak or water-saturated target materials, and anomalous erosion patterns. The problem remains unresolved because typical erosion rates within the arid sedimentary platform environment of central Kazakhstan in which the ZIF is located are typically low; it would require at least a factor of 10 greater erosion at the ZIF in order to degrade the near-rim ejecta typical of a 13.5-km complex crater by hundreds of meters in only 0.87 Ma, and to partially infill an inner cavity with 27 cu km (an equivalent uniform thickness of infill of 166 m). Our analysis of the degree of erosion and infill at the ZIF calls for rates in the 0.19 to 0.38 mm/yr range over the lifetime of the landform, which are a factor of 10 to 20 in excess of typical rates for the Kazakhstan semidesert.

Garvin, J. B.↗

NASA NTRS1991

Development of stitching reinforcement for transport wing panels

The NASA Advanced Composites Technology (ACT) program has the objective of providing the technology required to obtain the full benefit of weight savings and performance improvements offered by composite primary aircraft structures. Achieving the objective is dependent upon developing composite materials and structures which are damage tolerant and economical to manufacture. Researchers are investigating stitching reinforcement combined with resin transfer molding to produce materials meeting the ACT program objective. Research is aimed at materials, processes, and structural concepts for application in both transport wings and fuselages, but the emphasis to date has been on wing panels. Empirical guidelines are being established for stitching reinforcement in structures designed for heavy loads. Results are presented from evaluation tests investigating stitching types, threads, and density (penetrations per square inch). Tension strength, compression strength, and compression after impact data are reported.

Palmer, Raymond J.↗

NASA NTRS1992

Manufacture and performance of carbon/epoxy 3-D woven composites

This paper evaluates 3-D orthogonal woven carbon/epoxy composites. Preforms were manufactured on an automatic 3-D weaving machine developed at N.C. State University. Matrix infiltration was conducted at MBB Central Laboratories. Testing was carried out at both locations and the joint results will be reported. The properties investigated include: interlaminar shear strength, compression, compression after impact, bending, tensile and penetration resistance. The 3-D orthogonal woven composites were compared with laminated and other 3-D composites made with preforms having interlock structure. C-scans were used to examine the quality of infiltration and the damage area after impact. The performance of the composites made from the 3-D orthogonal preforms showed superior properties compared to the other composites. The penetration resistance test showed unexpectedly very good performance.

Brandt, J.↗