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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 523 records · Page 29

Propynal, an Interstellar Molecule with an Exceptionally Strong C≡C Infrared Band - Laboratory Infrared Data and Applications

Isomers with the formula C3H2O have intrigued and puzzled astronomers and astrochemists for many years, with propynal and cyclopropenone, but not propadienone, known to be interstellar. However, there is a severe lack of laboratory spectra of the solid phases of these compounds with which to investigate their interstellar chemistry. Here we present the first infrared spectra of amorphous and crystalline forms of propynal, HCC-C(O)H, at multiple temperatures. Band positions are tabulated and band strengths are derived in terms of absorption coefficients and integrated intensities. Optical constants are calculated for amorphous propynal, refractive indices are measured, and densities are estimated. Three laboratory astrochemistry applications are described, including a new spectral identification in an earlier paper. It is shown that propynal's C≡C infrared absorbance is about 30,000% stronger than the corresponding feature in acetylene. This band's intensity and spectral position make it an attractive candidate for astronomical searches involving interstellar ices.

astrochemistry – ISM: molecules↗

Propynal, an Interstellar Molecule with an Exceptionally Strong C≡C Infrared Band - Laboratory Infrared Data and Applications

Isomers with the formulaC3H2Ohave intrigued and puzzled astronomers and astrochemists for many years, with propynal and cyclopropenone, but not propadienone, known to be interstellar. However, there is a severe lack of laboratory spectra of the solid phases of these compounds with which to investigate their interstellar chemistry. Here we present the first infrared spectra of amorphous and crystalline forms of propynal, HCC C(O)H, at multiple temperatures. Band positions are tabulated and band strengths are derived in terms of absorption coefficients and integrated intensities. Optical constants are calculated for amorphous propynal, refractive indices aremeasured, and densities are estimated. Three laboratory astrochemistry applications are described, including a new spectral identification in an earlier paper. It is shown that propynal’s C C infrared absorbance is about 30 000 per cent stronger than the corresponding feature in acetylene. This band’s intensity and spectral position make it an attractive candidate for astronomical searches involving interstellar ices.

astrochemistry – ISM: molecules↗

Interstellar Ices and Radiation-Induced Oxidations of Alcohols

Infrared spectra of ices containing alcohols that are known or potential interstellar molecules are examined before and after irradiation with 1 MeV protons at ~20 K. The low-temperature oxidation (hydrogen loss) of six alcohols is followed, and conclusions are drawn based on the results. The formation of reaction products is discussed in terms of the literature on the radiation chemistry of alcohols and a systematic variation in their structures. The results from these new laboratory measurements are then applied to a recent study of propargyl alcohol. Connections are drawn between known interstellar molecules, and several new reaction products in interstellar ices are predicted.

astrochemistry – infrared: ISM – ISM: molecules – ↗

The NANOGrav 12.5 Year Data Set: Monitoring Interstellar Scattering Delays

We extract interstellar scintillation parameters for pulsars observed by the NANOGrav radio pulsar timing program. Dynamic spectra for the observing epochs of each pulsar were used to obtain estimates of scintillation timescales, scintillation bandwidths, and the corresponding scattering delays using a stretching algorithm to account for frequency-dependent scaling. We were able to measure scintillation bandwidths for 28 pulsars at1500 MHz and 15 pulsars at 820 MHz. We examine scaling behavior for 17 pulsars and find power-law indices ranging from−0.7 to−3.6, though these may be biased shallow due to insufficient frequency resolution at lower frequencies. We were also able to measure scintillation timescales for six pulsars at 1500 MHz and seven pulsars at820 MHz. There is fair agreement between our scattering delay measurements and electron-density model predictions for most pulsars. We derive interstellar scattering-based transverse velocities assuming isotropic scattering and a scattering screen halfway between the pulsar and Earth. We also estimate the location of the scattering screens assuming proper motion and interstellar scattering-derived transverse velocities are equal. We find no correlations between variations in scattering delay and either variations in dispersion measure or flux density. For most pulsars for which scattering delays are measurable, we find that time-of-arrival uncertainties for a given epoch are larger than our scattering delay measurements, indicating that variable scattering delays are currently subdominant in our overall noise budget but are important for achieving precisions of tens of nanoseconds or less.

Jacob E Turner↗

An evolutionary system of mineralogy. Part II: Interstellar and solar nebula primary condensation mineralogy (>4.565 Ga)

The evolutionary system of mineralogy relies on varied physical and chemical attributes, including trace elements, isotopes, solid and fluid inclusions, and other information-rich characteristics, to understand processes of mineral formation and to place natural condensed phases in the deep-time context of planetary evolution. Part I of this system reviewed the earliest refractory phases that condense at T > 1000 K within the turbulent expanding and cooling atmospheres of highly evolved stars. Part II considers the subsequent formation of primary crystalline and amorphous phases by condensation in three distinct mineral-forming environments, each of which increased mineralogical diversity and distribution prior to the accretion of planetesimals >4.5 billion years ago. (1) Interstellar molecular solids: Varied crystalline and amorphous molecular solids containing primarily H, C, O, and N are observed to condense in cold, dense molecular clouds in the interstellar medium (10 < T < 20 K; P < 10−13 atm). With the possible exception of some nanoscale organic condensates preserved in carbonaceous meteorites, the existence of these phases is documented primarily by telescopic observations of absorption and emission spectra of interstellar molecules in radio, microwave, or infrared wavelengths. (2) Nebular and circumstellar ice: Evidence from infrared observations and laboratory experiments suggest that cubic H2O (“cubic ice”) condenses as thin crystalline mantles on oxide and silicate dust grains in cool, distant nebular and circumstellar regions where T ~100 K. (3) Primary condensed phases of the inner solar nebula: The earliest phase of nebular mineralogy saw the formation of primary refractory minerals that solidified through high-temperature condensation (1100 < T < 1800 K; 10−6 < P < 10−2 atm) in the solar nebula more than 4.565 billion years ago. These earliest mineral phases originating in our solar system formed prior to the accretion of planetesimals and are preserved in calcium-aluminum-rich inclusions, ultra-refractory inclusions, and amoeboid olivine aggregates.

Shaunna M. Morrison↗

Ultraviolet Spectropolarimetry with Polstar: Interstellar Medium Science

Continuum polarization over the UV-to-microwave range is due to dichroic extinction (or emission) by asymmetric, aligned dust grains. Scattering can also be an important source of polarization, especially at short wavelengths. Because of both grain alignment and scattering physics, the wavelength dependence of the polarization, generally, traces the size of the aligned grains. Similarly because of the differing wavelength dependencies of dichroic extinction and scattering polarization, the two can generally be reliably separated. Ultraviolet (UV) polarimetry therefore provides a unique probe of the smallest dust grains (diameter<0.09 μm ), their mineralogy and interaction with the environment. However, the current observational status of interstellar UV polarization is very poor with less than 30 lines of sight probed. With the modern, quantitative and well-tested, theory of interstellar grain alignment now available, we have the opportunity to advance the understanding of the interstellar medium (ISM) by executing a systematic study of the UV polarization in the ISM of the Milky Way and near-by galaxies. The Polstar mission will provide the sensitivity and observing time needed to carry out such a program (probing hundreds of stars in the Milky Way and dozens of stars in the LMC/SMC), addressing questions of dust composition as a function of size and location, radiation- and magnetic-field characteristics as well as unveiling the carrier of the 2175 Å extinction feature. In addition, using high-resolution UV line spectroscopy Polstar will search for and probe the alignment of, and polarization from, aligned atoms and ions - so called “Ground State Alignment”, a potentially powerful new probe of magnetic fields in the diffuse ISM.

B-G Andersson↗

Hydrogen ejection from hydrocarbons: Characterization and relevance in soot formation and interstellar chemistry

Polycyclic aromatic hydrocarbons (PAHs) play a major role in the chemistry of combustion, pyrolysis, and the interstellar medium. Production (or activation) of radical PAHs and propagation of their resulting reactions require efficient dehydrogenation, but the preferred method of hydrogen loss is not well understood. Unimolecular hydrogen ejection (i.e., direct C─H bond fission) and bimolecular radical abstraction are two main candidate pathways. We performed a computational study to characterize the role of H ejection, particularly as a driver for radical-centric hydrocarbon-growth mechanisms and particle formation. Electronic structure calculations establish that C─H bond strengths span a broad range of energies, which can be weaker than 30 kcal/mol in some C 9 and C 13 PAH radicals. At T > 1200 K, calculated thermal rates for hydrogen ejection from weak C─H bonds at zigzag sites on PAH radicals are significantly larger than typical H-abstraction rates. These results are highly relevant in the context of chain reactions of radical species and soot inception under fuel-rich combustion conditions. Furthermore, calculated microcanonical rates that include the additional internal energy released by bond formation (e.g., ring closure to yield C 9 H 9 ) yield significantly higher rates than those associated with full thermalization. These microcanonical considerations are relevant to the astrochemical processes associated with hydrocarbon growth and processing in the low-density interstellar environment.

08 HYDROGEN↗

Feasibility of Interstellar Travel

The feasibility of interstellar flight is discussed. Mathematical equations for single-stage and multistage rocket propulsion are developed; velocity data and transit times are presented. The conclusions indicate that interstellar travel is theoretically feasible by utilizing known staged nuclear-energy systems.

Interstellar Travel↗

Interstellar beamer engineering

The fundamental differences between solar sails and interstellar beam riders are presented. Design requirements and design considerations are developed for an interstellar beamer phased array of gigantic proportions of photon pushing beam riding spacecraft to significant fractions of the speed of light.

interstellar↗

NASA's Interstellar Probe Mission

NASA's Interstellar Probe will be the first spacecraft designed to explore the nearby interstellar medium and its interaction with our solar system.

Interstellar↗

Technology Gaps for Rapid Response Missions to Near-Earth Objects, Interstellar Objects, and Long-Period Comets

The last several years has seen the discovery of the first two interstellar objects, the first ever planetary defense mission, recommendation for a rapid reconnaissance planetary defense demonstration, and the continued emergence of a robust commercial small satellite industry. The present and near future also consist of emerging next-generation observatories including Vera Rubin and NEO Surveyor. These seemingly disparate events converge in the context of rapid response: a cross-cutting capability that would enable NASA and the international community to quickly discover and respond to an emerging target such as a near-Earth object (NEO), interstellar object (ISO), or long-period comet (LPC) either for rapid characterization of a potential threat, or revolutionary science that would inform early solar system formation and evolution. In late October 2022, subject matter experts gathered at the California Institute of Technology in a week-long workshop sponsored by the Keck Institute for Space Studies (KISS) to address enabling mission concepts for rapid response and key technology gaps (final report in progress). These experts concurred that the ability to respond on the order of a few months is necessary for rapid in-situ characterization of a NEO, ISO, or LPC, and that while there are several technology gaps, this capability could be realized in the near future.

Technology gaps↗

Testing theories of Gravitation with the Interstellar Probe Radio Experiment

General Relativity (GR) will soon celebrate its 110th birthday, holding up against all experimental enquiry. Nonetheless, unification theories attempting to quantize gravity, such as string theory, are gaining footing. These hypothesize additional scalar, vector, and tensor long-range fields that couple to matter (Will, 2014), introducing violations to GR. Although such violations have never been detected, it is likely that GR will not be the ultimate theory of gravity. What is certain is that gravity tests are alive and well, pushing the validity of GR to new scales and accuracies, or -potentially- suggesting alternative routes for new physics. Building upon the legacy of Voyager and Pioneer missions, which demonstrated the capability to survive in the outer reaches of the solar system, the Interstellar Probe mission concept (McNutt et al., 2022) aims to characterise our heliosphere through state-of-the-art instrumentation, opening new frontiers also for GR testing. In this work, we investigate the possibility of constraining the Nordtvedt parameter η and the mass of the graviton via the Compton wavelength λc, by simulating the processing of 10 years of radiometric data from the Interstellar Probe. Station calibration and clock synchronisation, as well as limiting spacecraft precession manoeuvres are highlighted as key strategies for obtaining high-quality estimates. In the most favourable scenario, η can be constrained to less than 1.5 · 10 -5 , reducing the uncertainty obtained via Lunar Laser Ranging (Hofmann and Müller, 2018), and a lower bound of 1.4 ‧ 10 14 km is set for λc, improving the estimates obtained from planetary ephemerides (Bernus et al., 2020) and gravitational wave detection (Abbott et al., Jun 2021). Extending ranging measurement acquisition to 20 years improves the results tenfold. This experiment interrogates fundamental physics from a unique dynamical setting, investigating possible violations of the Equivalence Principle (EP) underlying GR.

general relativity↗

Diagnostics of Magnetohydrodynamic Modes in the Interstellar Medium through Synchrotron Polarization Statistics

One of the biggest challenges in understanding magnetohydrodynamic (MHD) turbulence is identifying the plasma mode components from observational data. Previous studies on synchrotron polarization from the interstellar medium (ISM) suggest that the dominant MHD modes can be identified via statistics of Stokes parameters, which would be crucial for studying various ISM processes such as the scattering and acceleration of cosmic rays, star formation, and dynamo. In this paper, we present a numerical study of the synchrotron polarization analysis (SPA) method through systematic investigation of the statistical properties of the Stokes parameters. We derive the theoretical basis for our method from the fundamental statistics of MHD turbulence, recognizing that the projection of the MHD modes allows us to identify the modes dominating the energy fraction from synchrotron observations. Based on the discovery, we revise the SPA method using synthetic synchrotron polarization observations obtained from 3D ideal MHD simulations with a wide range of plasma parameters and driving mechanisms, and present a modified recipe for mode identification. We propose a classification criterion based on a new SPA+ fitting procedure, which allows us to distinguish between Alfvén mode and compressible/slow mode dominated turbulence. We further propose a new method to identify fast modes by analyzing the asymmetry of the SPA+ signature and establish a new asymmetry parameter to detect the presence of fast mode turbulence. Additionally, we confirm through numerical tests that the identification of the compressible and fast modes is not affected by Faraday rotation in both the emitting plasma and the foreground.

97 MATHEMATICS AND COMPUTING↗

Seismic and acoustic signals from the 2014 ‘interstellar meteor’

SUMMARY We conduct a thorough analysis of seismic and acoustic data purported to be from the so-called ‘interstellar meteor’ which entered the Earth’s atmosphere off the coast of Papua New Guinea on 2014 January 08. Previous work had suggested that this meteor may have been caused by an alien spacecraft burning up in the atmosphere. We conclude that both previously reported seismic signals are spurious—one has characteristics suggesting a local vehicular-traffic-based origin; whilst the other is statistically indistinguishable from the background noise. As such, previously reported localizations based on this data are unreliable. Analysis of acoustic data provides a best-fitting location estimate which is very far ($\sim$170 km) from the reported fireball location. Accordingly, we conclude that material recovered from the seafloor and purported to be from this event is almost certainly unrelated to it, and is likely of more mundane (non-interstellar) origin.

Geochemistry & Geophysics↗