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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1998

Experiment 5: Science and Technology of Surface Controlled Oscillations: Report on USML-2 Results

Minuscule amounts (e.g., 1 part in 10,000) of a surface-active material in a liquid can drastically affect the surface behavior of the liquid, influencing how the material flows and mixes with other liquid and solid materials. In many respects, the science of surfactants has been empirical, with trial and error dominating over the ability to predict how surfactant type and concentration influence surface behavior. A program for the modeling of surfactant behavior has been established at Yale. This program combines experimental work performed both on the ground and in space, and theoretical and numerical modeling. By levitating a drop of liquid in air, away from solid container surfaces, and by manipulating the drop with acoustic radiation forces, we have been able to establish idealized conditions for surface behavior studies. The primary experiments involve the study of the free oscillations of initially deformed drops. In STS-73, the USML-2 mission of the Space Shuttle, we performed the following measurements: 1) the oscillation of a spherical drop in its quadrupole mode; 2) the oscillation of a drop about a deformed (oblate) shape; 3) the slow static squeezing of the drop from spherical to nearly flat; and 4) the superoscillations of drops when the radiation forces maintaining the drop in a flattened state are suddenly reduced. Analytic and numerical studies have enabled us to understand the physics of these oscillations and to extract material properties such as the dynamic surface tension and the surface viscosities (shear and dilatational). The relation to ground-based studies is essential, because the knowledge and understanding gleaned from our space studies enable us to interpret ground-based data.

Apfel, Robert E.↗
NASA NTRS2015

Spinoff 2015

Topics covered include: 3D Endoscope to Boost Safety, Cut Cost of Surgery; Audio App Brings a Better Night's Sleep Liquid Cooling Technology Increases Exercise Efficiency; Algae-Derived Dietary Ingredients Nourish Animals; Space Grant Research Launches Rehabilitation Chair; Vision Trainer Teaches Focusing Techniques at Home; Aircraft Geared Architecture Reduces Fuel Cost and Noise; Ubiquitous Supercritical Wing Design Cuts Billions in Fuel Costs; Flight Controller Software Protects Lightweight Flexible Aircraft; Cabin Pressure Monitors Notify Pilots to Save Lives; Ionospheric Mapping Software Ensures Accuracy of Pilots' GPS; Water Mapping Technology Rebuilds Lives in Arid Regions; Shock Absorbers Save Structures and Lives during Earthquakes; Software Facilitates Sharing of Water Quality Data Worldwide; Underwater Adhesives Retrofit Pipelines with Advanced Sensors; Laser Imaging Video Camera Sees through Fire, Fog, Smoke; 3D Lasers Increase Efficiency, Safety of Moving Machines; Air Revitalization System Enables Excursions to the Stratosphere; Magnetic Fluids Deliver Better Speaker Sound Quality; Bioreactor Yields Extracts for Skin Cream; Private Astronaut Training Prepares Commercial Crews of Tomorrow; Activity Monitors Help Users Get Optimum Sun Exposure; LEDs Illuminate Bulbs for Better Sleep, Wake Cycles; Charged Particles Kill Pathogens and Round Up Dust; Balance Devices Train Golfers for a Consistent Swing; Landsat Imagery Enables Global Studies of Surface Trends; Ruggedized Spectrometers Are Built for Tough Jobs; Gas Conversion Systems Reclaim Fuel for Industry; Remote Sensing Technologies Mitigate Drought; Satellite Data Inform Forecasts of Crop Growth; Probes Measure Gases for Environmental Research; Cloud Computing Technologies Facilitate Earth Research; Software Cuts Homebuilding Costs, Increases Energy Efficiency; Portable Planetariums Teach Science; Schedule Analysis Software Saves Time for Project Planners; Sound Modeling Simplifies Vehicle Noise Management; Custom 3D Printers Revolutionize Space Supply Chain; Improved Calibration Shows Images' True Colors; Micromachined Parts Advance Medicine, Astrophysics, and More; Metalworking Techniques Unlock a Unique Alloy; Low-Cost Sensors Deliver Nanometer-Accurate Measurements; Electrical Monitoring Devices Save on Time and Cost; Dry Lubricant Smooths the Way for Space Travel, Industry; and Compact Vapor Chamber Cools Critical Components.

Source record↗
NASA NTRS2009

A Summary of NASA and USAF Hypergolic Propellant Related Spills And Fires

Hypergolic fluids are toxic liquids that react spontaneously and violently when they contact each other. These fluids are used in many different rocket and aircraft systems for propulsion and hydraulic power including, orbiting satellites, manned spacecraft, military aircraft, and deep space probes. Hypergolic fuels include hydrazine (N 2H4) and its derivatives including monomethylhydrazine (MMH), unsymmetrical di-methylhydrazine (UDMH), and Aerozine 50 (A-50), which is an equal mixture of N2H4 and UDMH. The oxidizer used with these fuels is usually nitrogen tetroxide (N2O4), also known as di-nitrogen tetroxide or NTO, and various blends of N2O4 with nitric oxide (NO). Several documented, unintentional hypergolic fluid spills and fires related to the Apollo Program, the Space Shuttle Program, and several other programs from approximately 1968 through the spring of 2009 have been studied for the primary purpose of extracting the lessons learned. Spill sites include KSC, JSC, WSTF, CCAFS, EAFB, McConnell AFB, and VAFB.

Nufer, B. M.↗
NASA NTRS1990

On the Response of the Special Sensor Microwave/Imager to the Marine Environment: Implications for Atmospheric Parameter Retrievals

A reasonably rigorous basis for understanding and extracting the physical information content of Special Sensor Microwave/Imager (SSM/I) satellite images of the marine environment is provided. To this end, a comprehensive algebraic parameterization is developed for the response of the SSM/I to a set of nine atmospheric and ocean surface parameters. The brightness temperature model includes a closed-form approximation to microwave radiative transfer in a non-scattering atmosphere and fitted models for surface emission and scattering based on geometric optics calculations for the roughened sea surface. The combined model is empirically tuned using suitable sets of SSM/I data and coincident surface observations. The brightness temperature model is then used to examine the sensitivity of the SSM/I to realistic variations in the scene being observed and to evaluate the theoretical maximum precision of global SSM/I retrievals of integrated water vapor, integrated cloud liquid water, and surface wind speed. A general minimum-variance method for optimally retrieving geophysical parameters from multichannel brightness temperature measurements is outlined, and several global statistical constraints of the type required by this method are computed. Finally, a unified set of efficient statistical and semi-physical algorithms is presented for obtaining fields of surface wind speed, integrated water vapor, cloud liquid water, and precipitation from SSM/I brightness temperature data. Features include: a semi-physical method for retrieving integrated cloud liquid water at 15 km resolution and with rms errors as small as approximately 0.02 kg/sq m; a 3-channel statistical algorithm for integrated water vapor which was constructed so as to have improved linear response to water vapor and reduced sensitivity to precipitation; and two complementary indices of precipitation activity (based on 37 GHz attenuation and 85 GHz scattering, respectively), each of which are relatively insensitive to variations in other environmental parameters.

Petty, Grant W.↗
DOE OSTI2025

Deep Learning Approaches for Predicting the Surface Tension of Ionic Liquids

Ionic liquids (ILs) are a novel class of solvents that have attracted significant attention due to their unique and tunable properties. Among their physiochemical characteristics, surface tension plays a critical role in various industrial applications including electrolytes, heat transfer fluids, and separation processes. However, because of the exploratory nature of IL design and the vast combinatorial space of possible anion–cation pairs, the experimental determination of these properties is often impractical, being both time-consuming and costly. To overcome these challenges, computational approaches are increasingly employed to develop accurate predictive models that can accelerate IL discovery and design. In this study, we present two deep learning (DL) models for predicting the surface tension of ILs across a broad temperature range at a constant pressure. The models use simplified molecular input line entry system, SMILES, representations of ILs to extract molecular features as inputs. Both DL models demonstrate excellent agreement with experimental data, achieving an R 2 value of 0.990 and a root-mean-square error of 0.792 mN/m. In conclusion, these results offer valuable insights for the rapid screening and rational design of ILs with tailored surface tension values.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Analysis of scintillation light dependence on Liquid Argon purity in the ICARUS detector

Previous studies have investigated the correlation between impurities concentration in Liquid Argon (LAr) and the temporal evolution of either the slow scintillation decay time or the light yield.These impurities typically consist of various molecular species. Electronegative contaminants directly affect electron drift and photon production, while other molecules, such as nitrogen (N$_{2}$), can influence LAr scintillation properties without necessarily affecting electron lifetime.Many current and future neutrino and dark-matter experiments use LAr detectors. This study aims to evaluate the measured electron lifetime in relation to the timing characteristics of the scintillation light signal in the SBN ICARUS detector at Fermi National Accelerator Laboratory. The ICARUS detector consists of two cryostats that have shown different behaviors in the measured electron lifetime over the years. In particular, this study addresses the use of data collected under varying purity conditions in the two cryostats and presents the methodology used to extract scintillation timing characteristics and their correlation with LAr purity.

Saia, C. [Catania Astrophys. Observ.] (ORCID:00090↗
NASA NTRS1996

Multi-Dimensional Measurements of Combustion Species in Flame Tube and Sector Gas Turbine Combustors

The higher temperature and pressure cycles of future aviation gas turbine combustors challenge designers to produce combustors that minimize their environmental impact while maintaining high operation efficiency. The development of low emissions combustors includes the reduction of unburned hydrocarbons, smoke, and particulates, as well as the reduction of oxides of nitrogen (NO(x)). In order to better understand and control the mechanisms that produce emissions, tools are needed to aid the development of combustor hardware. Current methods of measuring species within gas turbine combustors use extractive sampling of combustion gases to determine major species concentrations and to infer the bulk flame temperature. These methods cannot be used to measure unstable combustion products and have poor spatial and temporal resolution. The intrusive nature of gas sampling may also disturb the flow structure within a combustor. Planar laser-induced fluorescence (PLIF) is an optical technique for the measurement of combustion species. In addition to its non-intrusive nature, PLIF offers these advantages over gas sampling: high spatial resolution, high temporal resolution, the ability to measure unstable species, and the potential to measure combustion temperature. This thesis considers PLIF for in-situ visualization of combustion species as a tool for the design and evaluation of gas turbine combustor subcomponents. This work constitutes the first application of PLIF to the severe environment found in liquid-fueled, aviation gas turbine combustors. Technical and applied challenges are discussed. PLIF of OH was used to observe the flame structure within the post flame zone of a flame tube combustor, and within the flame zone of a sector combustor, for a variety of fuel injector configurations. OH was selected for measurement because it is a major combustion intermediate, playing a key role in the chemistry of combustion, and because its presence within the flame zone can serve as a qualitative marker of flame temperature. All images were taken in the environment of actual engines during flight, using actual jet fuel. The results of the PLIF study led directly to the modification of a fuel injector.

Hicks, Yolanda Royce↗
DOE OSTI2026

Status of 1eNp0π Charged-Current Electron Neutrino Cross Section on Argon in the NuMI Beam at ICARUS

The Short-Baseline Neutrino (SBN) Program is designed to probe short-baseline neutrino anomalies, including the LSND electron neutrino excess and the MiniBooNE low-energy excess. Essential to interpreting these anomalies and to the success of future experiments like DUNE, is the precise measurement of neutrino-argon interaction cross sections. The program utilizes two liquid argon time projection chamber (LArTPC) detectors: the Short-Baseline Near Detector (SBND) located 110 meters downstream from the Booster Neutrino Beam (BNB) target, and the ICARUS detector positioned 600 meters downstream. Additionally, the ICARUS detector lies off-axis to the NuMI beamline, providing a unique, high-statistics flux of electron neutrinos and sensitivity to energies that overlap with the DUNE spectrum. To analyze the data from these detectors, we have begun employing a machine-learning-based reconstruction algorithm referred to as “Scalable Particle Imaging with Neural Embeddings” (SPINE). SPINE has shown improvement in the ability to reconstruct the properties of final state particles in the detector, like the particle ID and momentum, with the potential to enhance the quality of measurements achievable within the SBN Program e.g., the resolution on kinematics used in differential cross section extraction. This poster presents progress toward measuring the electron neutrino argon interaction cross section in the 1eNp0π topology using the NuMI beam, highlighting the impact of SPINE through the ability to select signal events across a wide kinematic range without sacrificing background rejection power.

Carber, Dan [Colorado State U.] (ORCID:00090006451↗
NASA NTRS2003

Evaluation of the Spherical Flange Concept for a Rocket Engine

Due to the inherent tolerance variability of hardware, flange misalignments occur during installation of mating components for a liquid propellant rocket engine. Flange misalignments include axial, lateral, and angular offsets. If these misalignments are high, they can impart significant loads into the two mating components. These significant loads can then be a driver in the design of the propellant ducts. Such was the case for the Rocketdyne RS-83 engine design for the Space Launch Initiative Program. To address this flange misalignment issue, Marshall Space Flight Center joined with Rocketdyne to develop and test a spherical flange system that allows for misalignment, yet reduces loads imparted, and at the same time provides sufficient sealing against leakage. The flange design was tested to evaluate and compare performance parameters such as misalignment and leakage. The environmental conditions ranged from -100 to 400 degrees Fahrenheit (F) with 1000 to 4000 pounds per square inch gage (psig) pressure. The desirable design features will be extracted and synthesized into a new flange design concept. This paper will address the spherical flange design and the test results.

Nichols, Jay↗
NASA NTRS1999

Interchange for Joint Research Entitled: Miniature Laser Spectrometer for Stable Isotope Measurements

As a first step in successfully measuring carbon isotopes optically we have previously demonstrated the measurement of C-13/C-12 to a precision of 0.1% using a tunable diode laser and CO2 spectral lines in the 2300/cm spectral region. This precision of 0.1% (1 per mil) for carbon isotopes is a value sufficiently precise to provide important isotopic data of interest to astrobiologists. The precision presently attainable in gases is sufficient to permit our instrument to be used in the measurement of isotopic ratios of interest to astrobiologists as well as geologists and planetary scientists. A small stable isotope laser spectrometer with a 10 cm path gas cell was designed and constructed. The cell was integrated with a liquid nitrogen cooled tunable diode laser and indium antimonide detector for evaluation. Using the small gas cell, preliminary measurements of 13C/12C in CO2 were made employing single-beam sequential acquisitions of the required spectral data. The results indicate an accuracy of 0.1% which is sufficiently high to make meaningful measurements of martian samples. In addition, improvements in the spectrometer gas handling system have been made to markedly reduce C-13/C-12 isotopic fractionation during sample gas cell loading which we expect will lead to further improvements in precision and accuracy. An important part of making isotopic ratio measurements in solid samples using diode lasers is the conversion of the elements of interest to molecules that have absorption spectra in the mid-ir spectral range accessible by tunable diode lasers. In this project we have investigated the necessary sample preparation procedures to extract carbon, an element of astrobiological importance, from model soil compounds and to convert it to CO2, a molecule with appropriate optical absorption characteristics for reliable laser spectrometer isotopic ratio measurements of 13C/12C. We have considered calcium carbonate as a model for a component of the martian regolith, and we have formulated a simple heating protocol for extracting carbon in the form of CO2.

Becker, J. F.↗
NASA NTRSDate not supplied

TPSAS-NF1676L-13579-DND

During aerospace vehicle conceptual and preliminary design, empirical non-optimum factors are typically applied to predicted structural component weights to account for undefined manufacturing and design details. Non-optimum factors are developed here for 32 aluminum-lithium 2195 orthogrid panels comprising the liquid hydrogen tank barrel of the Space Shuttle External Tank using measured panel weights and manufacturing drawings. Minimum values for skin thickness, axial and circumferential blade stiffener thickness and spacing, and overall panel thickness are used to estimate individual panel weights. Panel non-optimum factors computed using a coarse weights model range from 1.21 to 1.77, and a refined weights model (including weld lands and skin and stiffener transition details) yields non-optimum factors of between 1.02 and 1.54. Acreage panels have an average 1.24 non-optimum factor using the coarse model, and 1.03 with the refined version. Non-optimum factors are also calculated for the aluminum-alloy gores that compose the ogive and ellipsoidal bulkheads of the Space Shuttle Super-Lightweight Tank propellant tanks. Minimum values for actual gore skin thicknesses and weld land dimensions are extracted from component production drawings, and are used to predict reference gore weights. These actual skin thicknesses are also compared to skin thicknesses predicted using classical structural mechanics and tank proof-test pressures. Both coarse and refined weights models are developed for the gores. The coarse model is based on the proof-test skin thicknesses, and the refined model uses the actual skin thicknesses and weld land details. Both models include manufacturing tolerance weight estimates. To determine the gore non-optimum factors, these reference weights are then compared to flight hardware weights reported in a mass properties database. The gore non-optimum factors computed using the coarse weights model range from 1.18 to 2.36, with an average non-optimum factor of 1.68. Application of the refined weights model yields non-optimum factors between 1.00 and 1.45, with an average non-optimum factor of 1.13. To demonstrate their utility, these calculated non-optimum factors are then used to predict more realistic (i.e., heavier) gore weights for a proposed heavy-lift launch vehicle's propellant tank bulkheads.

K Chauncey Wu↗
NASA NTRS1999

Massive Chromite in the Brenham Pallasite and the Fractionation of Cr During the Crystallization of Asteroidal Cores

Large (greater than or equal to 2 mm) chromite grains are present in IIIAB iron meteorites and in the main-group a pallasites (PMG), closely related to high-Au IIIAB irons, Pallasites seem to have formed by the intrusion of a highly evolved metallic magma from a IIIAB-like core into fragmented olivine of the overlying dunite mantle. High Cr contents are commonly encountered during the analyses of metallic samples of high-Au IIIAB irons and main-group pallasites, an indication that Cr contents were high in the intruding liquid and that Cr behaved as an incompatible element during the crystallization of the IIIAB magma, contrary to expectations based on the negative IIIAB Cr-Ni and Cr-Au trends among low-Au IIIAB irons. In a region about 10 cm across in the Brenham main-group pallasite massive chromite fills the interstices between olivine grains, the site normally occupied by metal in Brenham and other pallasites. The massive chromite may have formed as a late cumulus phase; because Fe-Ni was also crystallizing, its absence in the chromite-rich region suggests a separation associated with differences in liquid buoyancy. The coexisting chromite and olivine are zoned; in the olivine FeO is highest in pallasitic (olivine-metal) regions, lowest in rims adjacent to chromite, and intermediate in the cores of these olivines. Chromite shows the opposite zoning, with the highest FeO contents at grain edges adjacent to olivine. The observed gradients are those expected to form by Fe-Mg exchange between olivine and chromite during slow cooling at subsolidus temperatures. Compared to normal Brenham, contents of phosphoran olivine and phosphates are higher in the chromitic pallasitic region. We also report data for large-to-massive chromites present in PMG Molong and in high-Au IIIAB Bear Creek that, like Brenham, formed from a highly evolved magma. The Bear Creek chromite has a much lower Mg content than that in the pallasites, implying that, in the PMG, the Mg was extracted from the olivine during high-temperature reaction with the precipitating chromite. There are other circumstantial arguments indicating that Cr was incompatible in the metal during the crystallization of the IIIAB magma, with the concentration in die residual magma rising from an initial value of about 300 micrograms/g to a value around 700 micrograms/g when Bear Creek and Brenham were formed. We consider possible explanations for these negative Cr-Au and Cr-Ni trends and find the most probable one to be that they reflect sampling artefacts resulting from analysts avoiding visible chromite (and the commonly associated phase FeS) when choosing metal samples.

Wasson, John T.↗
NASA NTRS2017

Robust Exploration and Commercial Missions to the Moon Using LANTR Propulsion and Lunar Liquid Oxygen Derived from FeO-Rich Pyroclastic Deposits

Studies conducted by NASA and its contractors (early 1980s early 1990s) indicated a substantial benefit from using lunar-derived propellants specifically lunar-derived LO2 (LLO2) or LUNOX in a lunar space transportation system (LTS). With a LTS using LO2/LH2 chemical rockets, approx. 6 kilograms (kg) of mass in low Earth orbit (LEO) is required to place 1 kg of payload on the lunar surface (LS). Of this 6 kg, approx. 70% (4.2 kg) is propellant and 6/7th of this mass (3.6 kg) is oxygen assuming an O/H MR 6:1. Since the cost of placing a kilogram of mass on the LS is approx. 6X the cost of delivering it to LEO, the ability to produce and utilize LUNOX or lunar-derived LO2 and hydrogen (LLH2) from lunar polar ice (LPI) deposits can provide significant mission leverage. Providing LUNOX for use in fuel cells, life support systems and LO2/LH2 chemical rockets used on lunar landing vehicles (LLVs), can allow high value cargo (people, manufacturing and scientific equipment, etc.) to be transported to LEO, then to the Moon instead of bulk LO2 propellant. Oxygen is abundant in the lunar regolith (approx. 43% by mass) and can be extracted using a variety of techniques, such as hydrogen reduction of ilmenite (FeOTiO2) or FeO-rich volcanic glass (orange soil) discovered during the Apollo 17 mission to Taurus-Littrow. While considerable interest has been expressed about mining and processing LPI for rocket propellant, ground truth must first be established to quantify the physical state of the ice (e.g., its vertical thickness and areal extent, levels of soil contamination, etc.) and the deep, extremely cold (approx. 26-100 K) permanently shadowed craters where the ice resides.

Nuclear Thermal Propulsion↗
DOE OSTI2026

Comparability of Liquid Chromatography Tandem Mass Spectrometry Analysis of Dissolved Organic Matter across Laboratories

Non-targeted liquid chromatography tandem highresolution mass spectrometry (LC−MS/MS) is increasingly applied for the structure-resolved chemical analysis of dissolved organic matter (DOM). With new developments in MS instrumentation and analysis software, the approach has gained substantial momentum over the past decade. However, achieving high-quality analytical data that is reproducible and comparable across laboratories can be a bottleneck in non-targeted metabolomics and organic matter chemical analysis, especially for data reuse in repository-scale analyses. Understanding the capabilities as well as challenges of comparing LC−MS/MS data from different laboratories is necessary for inferring global trends from public data sets. To illuminate instrumentation factors that drive differences and variability, we used a standardized data analysis pipeline, including classical (CMN) and featurebased molecular networking (FBMN), to analyze data from a ring trial by 24 laboratories on identical sample sets of algal and DOM extracts that were mixed in predefined concentrations and spiked with standards. Our results showed that data sets from similar mass spectrometer types with unified instrument parameters were qualitatively comparable, resolving the same general trends and shared mass spectral features. Interlaboratory comparability was best for high-intensity features, while low-intensity features showed greater detection variability. Our analysis also highlights challenges when comparing data from instruments with different acquisition rates or operating with less standardized methods. Lastly, we provide recommendations for data integration, public data sharing, standardization, and best practices for standardized LC−MS/MS data acquisition, which will be critical for long-term time series and intercomparability of DOM chemical analyses.

DOM↗
DOE OSTI2024

High Performance Heat Pipe Power Transient Testing at SPHERE Facility

Microreactors are being researched, designed, and built at Idaho National Laboratory (INL). Microreactors are small reactors defined at less than 20MW of power. These reactor concepts are also being looked at throughout industry for various applications. An important aspect of these reactor designs is economic feasibility i.e. lower overnight capital cost. The driving factors for implementing microreactors are quick setup and takedown, minimal operators, and the ability to manufacture them readily and to fit in mid-sized containers for transport. A specific area of research to aid in successful integration of these factors within the designs is passive heat removal of the core’s thermal power. Interest in heat pipes to achieve this passive heat removal has been shown across multiple industry partners. Because of this interest, INL has developed a test facility to facilitate experimental tests for sodium filled heat pipes. INL has developed the Single Primary Heat Extraction and Removal Emulator (SPHERE) facility to run experiments on high performance, sodium filled heat pipes. As mentioned above, heat pipes are passive heat transfer devices. Radially, heat pipes are broken up into an outer wall, a small annular gap, a wick structure, and a centerline gap. They function by utilizing latent heat transfer. Heat pipes are traditionally separated into three regions, an evaporator (heat input), an adiabatic region, and finally a condenser region (heat removal). As heat is being applied to the evaporator, the working fluid undergoes a phase change to a vapor. This phase change causes a differential pressure across the axial length of the pipe driving flow down the center gap of the heat pipe. The vapor flows down past the adiabatic region to the condenser where the heat is removed. This heat removal forces the working fluid to phase change back to a liquid. The wick structure is then utilized to drive the flow back towards the evaporator by capillary forces. This backflow is aided by the annular gap. Because this heat transfer mechanism functions with latent heat transfer, the heat pipe is close to isothermal down the axial length. Heat pipes can operate under a wide range of working fluids. Considerations for these working fluids are primarily driven by operating temperatures amongst other important factors based around overall performance. Sodium filled heat pipes operate from 450°C up to 900°C. This temperature range works well for the current microreactor designs. In conjunction with this experimental capability, INL has developed a modeling software to simulate heat pipe physics within reactor cores. This modeling software is called Sockeye and functions under the established INL Multiphysics Object Oriented Simulation Environment (MOOSE). SPHERE also supports Sockeye development by providing the modeling team with experimental data on an array of setups and operating parameters to support validation efforts. A power transient experiment was performed utilizing the SPHERE facility to continue to aid with Sockeye development. The testing followed a proposed test plan to ramp up and down the temperature of the heat pipe. Sockeye models steady state heat pipe operation with high accuracy, the data provided by the power transient testing aims to assist with the validation efforts and further enhance transient modeling capability of the tool [2].

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2026

Upcycling plastic waste into polyhydroxyalkanoates with high carbon conversion via CO 2 plasma-enabled deconstruction

Plastic deconstruction into fermentable intermediates is a key step for microbial bio-upcycling into value-added products. In this study, CO 2 plasma deconstruction was used as an electrified route to convert polyethylene into oxygenated intermediates and liquid (OIL). The resulting OIL was rich in fatty acids, fatty alcohols, and hydrocarbons, making it a suitable feedstock for medium-chain-length polyhydroxyalkanoate (mcl-PHA) production by Pseudomonas putida NRRL B-14688 and Pseudomonas resinovorans NRRL B-2649. Compared with batch fermentation and monocultures, fed-batch co-cultivation markedly improved biomass formation and PHA accumulation, likely due to complementary substrate utilization, particularly hydrocarbon conversion by P. resinovorans. Using virgin polyethylene-derived OIL (Vir-OIL), the co-culture achieved 40.11% mcl-PHA content and about 18% PHA yield based on total OIL fed. More importantly, OIL produced from post-consumer single-use plastic films (PCR-OIL) was directly fermented and well supported the cell growth and PHA accumulation, achieving 38.11% PHA content and about 14.7% PHA yield. Based on emulsified OIL fractions, PHA yields for Vir-OIL and PCR-OIL were comparable (∼28%). PHA granules were extracted from PCR-OIL-grown cells with high recovery (88.25%) and purity (94.8%). Five monomers were identified in the polymer, including 3-hydroxyhexanoate (3HHx), 3-hydroxyoctanoate (3HO), 3-hydroxydecanoate (3HD), 3-hydroxydodecanoate (3HDD), and 3-hydroxytetradecanoate (3HTD), with 3HO (44.28%) and 3HD (40.60%) as the dominant units. The polymer exhibited moderate molecular weight and narrow dispersity (M n = 65.4 kDa, M w = 92.1 kDa, Đ = 1.40) and low crystallinity (T m ≈ 76.6 °C, X c ≈ 15.5%). These characteristics indicate elastomer-like behavior, making the material suitable for flexible applications such as films, coatings, adhesives, and blend modifiers. Overall, this study establishes a CO 2 plasma-assisted route for generating fermentable polyethylene-derived intermediates and demonstrates that fed-batch co-culture fermentation can effectively funnel plastic-derived carbon into mcl-PHA.

42 ENGINEERING↗
DOE OSTI2025

Understanding and Harnessing the Robustness of Undomesticated Yarrowia lipolytica Strains for Biosynthesis of Designer Bioesters (Final Report)

This project seeks to elucidate and harness the exceptional robustness of novel and undomesticated Y. lipolytica isolates, which were identified from a genetic diversity screening for compatibility with bioenergy development. Bioenergy-relevant isolates were further developed as microbial platforms for efficient conversion of undetoxified biomass hydrolysates into designer bio-esters continuously recovered by solvent extraction. The project has three major goals. Goal 1. Elucidate and enhance the endogenous metabolism of Y. lipolytica for superior growth, sugar utilization, and lipid accumulation in undetoxified biomass hydrolysates under hypoxic conditions. Goal 2. Understand and enhance the underlying mechanism of exceptional tolerance of Y. lipolytica to organic solvents. Goal 3. Elucidate and rewire endogenous metabolism of the most robust Y. lipolytica strains for effective conversion of accumulating lipids to designer bio-esters. Significant progress has been made toward completing all research goals. We elucidated and optimized the robustness of Y. lipolytica by utilizing mixed C5 and C6 sugars in switchgrass hydrolysates (SGH) for lipid production (Aim 1). We conducted extensive omics analysis to investigate how genetic diversity among Yarrowia strains, derived from natural isolates or developed through adaptive laboratory evolution, influences lipid production when utilizing SGH. In Aim 2, novel mechanisms and underlying genetics were discovered that enabled Yarrowia strains to thrive in cultures containing high ionic liquid (IL) concentrations. Amongst other novel findings, it was found that sterols strengthened cell membranes to confer IL toxicity resistance, specifically via increased ergosterol content upon exposure to IL. In Aim 3, mechanistic studies elucidated how Y. lipolytica utilized intracellular lipids and alkanes/alkenes, leading to our discovery of novel enzymes and pathways for making short-chain esters. Most notably, thermostable chloramphenicol transferases were repurposed to function as alcohol acetyltransferases in Y. lipolytica, as well as the Gram-negative and Gram-positive bacteria Escherichia coli and thermophile Clostridium thermocellum, respectively.

09 BIOMASS FUELS↗
NASA NTRS2009

Life in Ice: Implications to Astrobiology

During the 2008 Tawani International Expedition Schirmacher Oasis/Lake Untersee Antarctica Expedition, living and instantly motile bacteria were found in freshly thawed meltwater from ice of the Schirmacher Oasis Lakes, the Anuchin Glacier ice and samples of the that perennial ice sheet above Lake Untersee. This phenomenon of living bacteria encased in ice had previously been observed in the 32,000 year old ice of the Fox Tunnel. The bacteria found in this ice included the strain FTR1T which was isolated and published as valid new species (Carnobacterium pleistocenium) the first validly published living Pleistocene organism still alive today. Living bacteria were also extracted from ancient ice cores from Vostok, Antarctica. The discovery that many strains of bacteria are able to survive and remain alive while frozen in ice sheets for long periods of time may have direct relevance to Astrobiology. The abundance of viable bacteria in the ice sheets of Antarctica suggests that the presence of live bacteria in ice is common, rather than an isolated phenomenon. This paper will discuss the results of recent studies at NSSTC of bacteria cryopreserved in ice. This paper advances the hypothesis that cryopreserved cells, and perhaps even viable bacterial cells, may exist today--frozen in the water-ice of lunar craters, the Polar Caps or craters of Mars; or in the permafrost of Mars; ice and rocks of comets or water bearing asteroids; or in the frozen crusts of the icy moons of Jupiter and Saturn. The existence of bacterial life in ice suggests that it may not be necessary to drill through a thick ice crust to reach liquid water seas deep beneath the icy crusts of Europa, Ganymede and Enceladus. The presence of viable bacteria in the ice of the Earth s Polar Caps suggests that the possibility that cryo-panspermia (i.e., the trans-planetary transfer of microbial life by impact ejection/spallation of bacteria-rich polar ice masses) deserves serious consideration and study as a possible natural phenomenon of the solar system that may have played a profoundly important role in the Origin of Life on Earth and the Distribution of Life in the Cosmos. The paper concludes with a consideration of the protective properties of ice by absorption of UV-B, UV-C, h-rays, gamma-rays and the high energy proton environment of the Jupiter Radiation Belt. A proposed instrument that may provide additional data on the potential survivability of microbial extremophiles encased in ice and subjected to the simulated space environment will be briefly described.

Hoover, Richard B.↗