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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 523 records · Page 29
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Magnetostrictive Ultrasonic Waveguide Transducer for In-Pile Thermometry

Real-time and reliable temperature measurement on nuclear fuels is crucial for the safe operation of existing pressurized-water reactors and future advanced nuclear reactors. Magnetostrictive materials deform when subjected to a magnetic field or exhibit magnetization variation when stressed. Here, based on these properties, this study prototyped an ultrasonic thermometer (UT) consisting of a magnetostrictive waveguide, a dc coil providing appropriate magnetic biasing, and an ac coil generating an acoustic impulse and detecting the resulting acoustic echoes. By tracking the time of flight between the excitation pulse and the echoes, the UT can potentially detect nuclear fuel cladding temperature from a long distance. In this study, magnetostrictive iron–gallium alloys, or Galfenol, were selected as the waveguide due to their large magnetostriction, superior temperature survivability, excellent radiation resilience, and high mechanical robustness. A multiphysics finite-element model considering electrical, magnetic, and mechanical dynamics in the magnetostrictive UT was then developed. The model exhibited an error of 0.24% in time-of-flight simulation and, therefore, enabled computer-aided design and guided signal processing. Between room temperature and 120 °C, the new Galfenol-based UT exhibits a linear sensitivity of 162.8×10 ₋6 °C ₋1 , which is 51.7% higher than a previous magnetostrictive UT based on iron–cobalt–vanadium alloys.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2022

Mesoporous MoO 2 thin films for high rate Li + storage: Effect of crystallinity and porous structure

MoO 2 has attracted much recent attention as a high capacity energy storage material. While much of the current work on MoO 2 has been focused on the high capacity four-electron reduction, this reaction is limited to slow charging process due to the large volume change and phase transitions involved. In this study we focus on one-electron insertion reactions and demonstrate that ordered mesoporous thin films of MoO 2 can show signatures of pseudocapacitive charge storage. Mesoporous MoO 2 (mp-MoO 2 ) thin films were treated at different temperatures between 350 and 700 °C to explore the role of crystallinity and nanoscale structure on charging dynamics. The porosity and pore size decreased while the crystallinity and grain size increased as the calcination temperature increased. Materials processed at 600 °C showed the best electrochemical performance due to an optimized combination of high crystallinity and small grain size. These materials could be charged and discharged in 24 s while still achieving a Li + storage capacity of 158 mAh/g. While such thin film systems do not constitute a practical energy storage device, the work here provides structural design parameters for the production of future bulk nanoporous materials.

25 ENERGY STORAGE↗
DOE OSTI2023

Nanopinhole Passivating Contact Si Solar Cells Fabricated with Metal-Assisted Chemical Etching

Monocrystalline Si (c-Si) solar cells with passivating contacts based on doped polycrystalline Si (poly-Si) on ≈2.0 nm silicon oxide (SiO x ) require >1000 °C thermal processing to create conducting pinholes in the SiO x layer. However, this high thermal budget can induce bulk defects in the Czochralski c-Si wafers used as the cell absorber layer. We demonstrate that pinholes can instead be created using metal-assisted chemical etching on planar or textured morphologies, at room temperature. This wet process creates up to 200 nm wide conducting pinholes that are directly observed with transmission electron and atomic force microscopies. High-performance hole-selective poly-Si/SiN y /SiO x and electron-selective poly-Si/SiO x passivating contacts are fabricated and implemented in laboratory-scale solar cells. This process development significantly broadens the range of passivation layer materials, their thicknesses, and surface morphologies, which enables the design of poly-Si contacts with superior passivating quality.

14 SOLAR ENERGY↗
DOE OSTI2024

Material analysis of metal hydrides for bulk hydrogen storage

The United States Department of Energy (DOE) Hydrogen Storage Engineering Center of Excellence (HSECoE), 2009–2014, was established to evaluate the viability of material-based hydrogen storage for light duty vehicles. The HSECoE concluded that there were no metal hydrides that simultaneously met the DOE targets for gravimetric and volumetric capacity, and rate of onboard refueling. However, it was noted by the DOE that potential applications existed for stationary hydrogen storage systems. An application of particular interest is using a metal-hydride to store a hydrogen supply for fuel cell backup power to a 5 MWe data center. A generalized numerical model that coupled mass and energy conservation, chemical kinetics and thermodynamics was developed to simulate the discharge process for a given metal-hydride. The model was applied to an interstitial and a complex metal-hydride. In conclusion, it was found that the interstitial metal-hydride, which is discharged by a pressure swing is preferrable in a practical sense to the complex metal-hydride, which requires a temperature swing discharge process.

08 HYDROGEN↗
DOE OSTI2024

A Century of Reforestation Reduced Anthropogenic Warming in the Eastern United States

Abstract Restoring and preserving the world's forests are promising natural pathways to mitigate some aspects of climate change. In addition to regulating atmospheric carbon dioxide concentrations, forests modify surface and near‐surface air temperatures through biophysical processes. In the eastern United States (EUS), widespread reforestation during the 20th century coincided with an anomalous lack of warming, raising questions about reforestation's contribution to local cooling and climate mitigation. Using new cross‐scale approaches and multiple independent sources of data, we uncovered links between reforestation and the response of both surface and air temperature in the EUS. Ground‐ and satellite‐based observations showed that EUS forests cool the land surface by 1–2°C annually compared to nearby grasslands and croplands, with the strongest cooling effect during midday in the growing season, when cooling is 2–5°C. Young forests (20–40 years) have the strongest cooling effect on surface temperature. Surface cooling extends to the near‐surface air, with forests reducing midday air temperature by up to 1°C compared to nearby non‐forests. Analyses of historical land cover and air temperature trends showed that the cooling benefits of reforestation extend across the landscape. Locations surrounded by reforestation were up to 1°C cooler than neighboring locations that did not undergo land cover change, and areas dominated by regrowing forests were associated with cooling temperature trends in much of the EUS. Our work indicates reforestation contributed to the historically slow pace of warming in the EUS, underscoring reforestation's potential as a local climate adaptation strategy in temperate regions.

Environmental Sciences & Ecology↗
DOE OSTI2023

Substrate Effects When Using Photons to Make Perovskite Solar Cells

To shorten annealing time and minimize substrate heating, flash lamps that deliver short, intense light pulses, commonly called photonic curing, are used to replace thermal annealing using hot plates or ovens. This method is different from equilibrium heating in that the radiant energy is selectively absorbed by the film. The high-intensity light pulses produce a high peak temperature in the film. Because most processes follow Arrhenius behavior, reaching high temperatures allow chemical reactions/phase transformations to occur in a short time, significantly reducing the processing time. Often the results are non-intuitive. We will present fabricating flexible halide perovskite solar cells (PSCs) on indium tin oxide (ITO) coated Willow glass. The effect of ITO transmittance on the photonic curing of nickel nitrate sol-gel precursors into nickel oxide to fabricate hole transport layer and consequently the performance of PSCs. Unexpectedly, ITO samples processed by photonic curing show improved optical and electrical properties.

14 SOLAR ENERGY↗
DOE OSTI2024

Removal and Deactivation of Bond Sodium from Fast Reactor Blanket Materials

The disposition of sodium-bonded spent nuclear fuel and blanket materials in a repository is complicated by the presence of sodium metal that is used as a thermal bond between the uranium metal fuel and blanket slugs and their cladding. The concern is that the metallic sodium could react with water, producing explosive hydrogen gas, or could exhibit a pyrophoric character. Thus, experimental studies were performed to investigate and demonstrate the removal and deactivation of bond sodium from blanket material in a dry environment. Specifically, bond sodium was removed from unirradiated Fermi-1 blanket elements and an assembly via a melt-drain-evaporate process using elevated temperature and reduced pressure. The effectiveness of sodium metal removal from the blanket materials and their associated cladding was =99.9998%, based on post-test quantitative analyses. The separated sodium metal was collected and subsequently deactivated by reacting it in a molten state with a controlled addition of ammonium chloride particles atop a molten salt medium. In this process sodium chloride is formed and assimilates into the salt pool. The subsequent deactivation of the bond sodium produced a solid ingot of sodium chloride, potassium chloride, lithium chloride, and cesium chloride that was devoid of sodium metal based on post-test analyses of the salt product. Both the sodium removal and deactivation operations were conducted within a dry inert atmosphere enclosure. The results of this study substantiate a path forward for the disposition of sodium-bonded blanket materials, including 34 metric tons heavy metal in irradiated Fermi-1 blanket material currently stored at Idaho National Laboratory.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2021

Efficiency and mechanisms of Sb(III/V) removal by Fe-modified biochars using X-ray absorption spectroscopy

Fe-modified biochars (FeBC) are effective antimony (Sb) removal materials; however, the removal mechanisms require further investigation. In this study, aqueous Sb(III) and Sb(V) removal by FeBC (300, 600, and 900 °C) was evaluated, with the adsorption mechanisms investigated using X-ray absorption spectroscopy (XAS). Screening results (based on removal efficiencies) using different types of FeBC indicated the 900 °C FeCl3- modified biochar (FeCl3BC900) achieved the best Sb(III/V) removal performance. The kinetics of the Sb(III/V) removal process were best fitted by a pseudo-second-order model. Additionally, the isothermal results were described by Langmuir and Redlich-Peterson models. Aqueous analysis and X-ray absorption near-edge structure data fitting indicated Sb(III) was oxidized to Sb(V) in the Sb(III)-spiked system, and the oxidation extent increased with increasing pyrolysis temperature. The oxidation process rapidly occurred in both the solution and biochar. No Sb(V) was reduced to Sb(III) in the Sb(V)-spiked system. The XAS results of the isothermal experiment indicated the oxidation capacity of FeCl3BC900 was limited for high initial Sb(III) concentrations. The SbFe1 and Sb-Fe2 bonding distances were 3.05–3.10 and 3.47–3.54 Å, respectively, indicating inner-sphere complexes were formed during the Sb(III/V) removal processes. The Sb(III/V) removal mechanisms included electrostatic adsorption, inner-sphere complexes, and coprecipitation. Oxidation was also involved in Sb(III) removal.

Antimony↗
DOE OSTI2023

Deposition-controlled phase separation in CuNb metallic alloys

Vapor co-deposited metal nanocomposites with immiscible components have shown to have several superior properties including mechanical performance, radiation tolerance, and enhanced functionalities. The morphology and structural design of these nanocomposites are important in determining the expression of these properties. The conditions used to deposit thin film nanocomposites are the governing factors in determining the final nanostructure. In this work, we link the effects of process gas pressure, substrate temperature, and sputtering target power on resultant Cu/Nb thin film nanostructures. Here, we find that for films with equiatomic phase fractions of Cu and Nb, inhomogeneous precipitate segregation dominated the structure at lower substrate temperature depositions while higher temperatures distributed the Cu and Nb phases more uniformly. Increasing process gas pressure during deposition lead to a spatially homogeneous, nanocrystalline structure of Cu/Nb. In situ annealing of this sample shows that the phase separated morphology of the two immiscible materials depends on the initial composition. Finally, compositions of Cu and Nb that were highly disparate lead to interface segregation of the minority phase. The morphological evolution observed in the Cu/Nb system is compatible with modified structural zone models for immiscible thin film systems.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Room-Temperature Eutectic Synthesis for Upcycling of Cathode Materials

Ni-rich LiNixMnyCo1−x−yO2 (NMC) materials have been adopted in a range of applications, including electric vehicles. The recycled NMC material from a spent cell would be much more valuable if it could be upgraded to a Ni-rich, more energy-dense version of the material. This work demonstrates a simple, inexpensive, and facile method to upcycle LiNi1/3Mn1/3Co1/3O2 (NMC111, 160 mAh∙g−1), a cathode used in early generations of electric vehicle batteries, to LiNi0.8Mn0.1Co0.1O2 (NMC811, 190 mAh∙g−1), a more energy-dense cathode material. In this study, a preliminary investigation into a room-temperature eutectic synthesis of NMC811 is performed using NMC111, LiOH, and nickel nitrate as precursors. The synthesized material showed the desired crystal structure and stoichiometry, though the cycle life and Li diffusion coefficient need improvement when compared to commercially available NMC811. This study demonstrates an interesting proof of concept of the room-temperature eutectic synthesis process for LIB cathodes and could be improved by tuning the synthesis conditions.

lithium-ion battery↗
DOE OSTI2025

Impact of El Niño‐Southern Oscillation and Madden‐Julian Oscillation on the US Puget Sound Regional Hydroclimate

El Niño-Southern Oscillation (ENSO) and Madden-Julian Oscillation (MJO) are two major modes of climate variability with global hydroclimate impacts. However, their impacts often depend on the local climate and geography, resulting in large regional differences. In this study, we examined the connection of ENSO and MJO to the hydroclimate conditions and extremes in the Puget Sound (PS) basin located in the US Pacific Northwest coast. The results indicate that ENSO significantly modulates the cold season temperature and temperature-mediated hydrologic processes. El Niño cold seasons feature less snow accumulation and intensified surface runoff, even if the precipitation amount is similar to La Niña cold seasons. Therefore, El Niño causes more snow drought (in the form of compound dry and warm snow drought) and shifts the surface runoff seasonality by reducing runoff in the subsequent warm season. MJO phases 6–7 trigger more extreme precipitation, temperature, snowmelt, and runoff in the PS region at 0–9–day lags, and such connections are robust regardless of how the ENSO signals are removed. Meanwhile, MJO modulates large-scale extreme weather systems (e.g., atmospheric rivers) with significant enhancement during phases 6–7. ENSO impacts have intensified in the 2001–2020 period, whereas MJO impacts showed some phase shift in this period. This study reveals ENSO and MJO phases 6–7 as useful predictors of the PS hydroclimate anomalies/extremes at seasonal and daily scales, respectively. Utilizing these findings holds the potential to improve regional water resources prediction and management.

ENSO↗
DOE OSTI2021

Simulation of lithium transport using the BOUT++ framework

A numerical model that calculates the collisional interactions between the lithium atoms from a lithium pellet and the background plasmas has been upgraded. The ion density ($N_t$), electron temperature ($T_e$), ion temperature ($T_i$) and parallel ion velocity ($V_{∥, i}$) are used to characterize the background plasmas. The lithium atom density ($N^{a}_{Li}$) and parallel velocity ($V_{∥,a}$) of lithium atoms evolve with time. For each lithium ion, the density ($N_{Li^{n+}}$), temperature ($T_{Li^{n+}}$) and parallel velocity ($V_{∥, Li^{n+}}$) are self-consistently calculated. A C-mod lower single null equilibrium is used to generate the grid for the BOUT++ simulation. The lithium atoms can be fully ionized to $Li^{3+}$ in ~2 μs. The rapid radial and poloidal expansion of the lithium ions are found in the simulation. After the collision interaction process, the electron temperature rapidly decreases at the pellet location; then, it rapidly poloidally expands, and the temperature at the pellet location starts to recover. The electron pressure increases at the pellet location despite the decrease in electron temperature because of the extra electrons from the lithium ionization. The ion pressure profile decreases in the pellet location due to the decrease in ion temperature.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2026

Influence of Transition Metal Ion Contaminants on the Performance of Amine-Based Solid Sorbents in Direct Air Capture

Amine-functionalized solid sorbents are a class of sorbent materials proposed for direct air capture (DAC) of CO 2 , yet their long-term performance is susceptible to degradation under realistic operating conditions. Many amines are not thermodynamically stable in air, and amine sorbents oxidize while in use during DAC temperature swing adsorption processes. In this study, we investigate the role of transition metal ion contaminants, specifically Cu 2+ , Fe 2+ , and Ni 2+ , on the oxidative degradation of poly(ethylenimine) (PEI)-impregnated SBA-15 sorbents. By introducing metal ions via different modes mimicking both synthesis-related impurities and impurities derived from environmental exposure, we systematically evaluate sorbent stability after exposure to dry air at an elevated temperature. Thermogravimetric CO 2 uptake measurements reveal that even trace levels of Cu and Fe (as low as ∼4 ppm) can lead to measurable sorbent deactivation after oxidative aging, despite negligible loss in the performance of the control samples. In situ infrared, UV–vis, and X-ray photoelectron spectroscopies indicate that these metals catalyze radical-driven oxidation pathways, altering the chemical structure of the sorbent and accelerating degradation. Our findings underscore the need to account for trace metal contamination during DAC sorbent synthesis and deployment and highlight the importance of environmental contamination pathways.

CO2 capture↗
DOE OSTI2021

Physical Properties of Candidate X-ray Detector Material Rb 4 Ag 2 BiBr 9

Recently, metal halide perovskites have emerged as promising semiconductor candidates for sensitive X-ray photon detection due to their suitable band gap energies, excellent charge transport properties, and low material cost afforded by their low-temperature solution-processing preparation. Furthermore, we report an improved methodology for single crystal growth and thermal and electrical properties of a two-dimensional (2D) layered halide material Rb 4 Ag 2 BiBr 9 , which has been identified as a potential candidate for X-ray radiation detection applications. The measured heat capacity for Rb 4 Ag 2 BiBr 9 implies that there are no structural phase transitions upon cooling. Temperature dependence of thermal transport measurements further suggests remarkably low thermal conductivities of Rb 4 Ag 2 BiBr 9 that are comparable to the lowest reported in literature. The bulk crystal resistivity is determined to be 2.59 × 10 9 Ω·cm from the current–voltage (I–V) curve. Density of trap states is estimated to be ~10 10 cm –3 using the space-charge-limited-current measurements. The fabricated Rb 4 Ag 2 BiBr 9 -based X-ray detector shows good operational stability with no apparent current drift, which may be ascribed to the 2D crystal structure of Rb 4 Ag 2 BiBr 9 . Finally, by varying the X-ray tube current to change the corresponding dose rate, the Rb4Ag2BiBr9 X-ray detector sensitivity is determined to be 222.03 μC Gy –1 cm –2 (at an electric field of E = 24 V/mm).

36 MATERIALS SCIENCE↗
DOE OSTI2023

Excitation-Dependent High-Lying Excitonic Exchange via Interlayer Energy Transfer from Lower - to - Higher Bandgap 2D Material

High light absorption (~15%) and strong photoluminescence (PL) emission in monolayer (1L) transition metal dichalcogenides (TMDs) make them ideal candidates for optoelectronic device applications. Competing interlayer charge transfer (CT) and energy transfer (ET) processes control the photocarrier relaxation pathways in TMD heterostructures (HSs). In TMDs, long-distance ET can survive up to several tens of nm, unlike the CT process. Our experiment shows that an efficient ET occurs from the 1Ls WSe 2 -to-MoS 2 with an interlayer hexagonal boron nitride (hBN), due to the resonant overlapping of the high-lying excitonic states between the two TMDs, resulting in enhanced HS MoS 2 PL emission. This type of unconventional ET from the lower-to-higher optical bandgap material is not typical in the TMD HSs. With increasing temperature, the ET process becomes weaker due to the increased electron–phonon scattering, destroying the enhanced MoS 2 emission. Our work provides new insight into the long-distance ET process and its effect on the photocarrier relaxation pathways.

2D material↗
DOE OSTI2026

ARM Radiosondes for SNPP/JPSS Validation Field Campaign Report

This field campaign extension has been a coordinated effort involving the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) User Facility, the University of Wisconsin at Madison, and the Joint Polar Satellite System (JPSS) project to validate NOAA Unique Combined Atmospheric Processing System (NUCAPS) temperature and moisture sounding products from the Cross-track Infrared Sounder (CrIS) and the Advanced Technology Microwave Sounder (ATMS) instruments on board the NOAA-20 and NOAA-21 satellite platforms. In this arrangement, funding for radiosondes and balloons was provided by the JPSS project to ARM. These radiosondes were launched coincident with NOAA-20 and NOAA-21 satellite overpasses at the ARM field sites at Eastern North Atlantic (ENA), North Slope Alaska (NSA), and Southern Great Plains (SGP). Combined with other ARM data, an assessment of the radiosonde data quality was performed and post-processing corrections applied. The dedicated radiosondes were integrated into the NOAA Products Validation System (NPROVS+), which collocated the radiosondes with satellite products (NOAA, National Aeronautics and Space Administration [NASA], European Organisation for the Exploitation of Meteorological Satellites [EUMETSAT], Geostationary Operational Environmental Satellite [GOES], Constellation Observing System for Meteorology, Ionosphere, and Climate [COSMIC]) and numerical weather prediction (NWP) forecasts for use in product assessment and algorithm development. This work is a part of the NOAA-20 and NOAA-21 satellite retrieval validation efforts and provides critical accuracy assessments of the temperature and water vapor soundings.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Low‐Temperature Synthesis of Stable CaZn 2 P 2 Zintl Phosphide Thin Films as Candidate Top Absorbers

Abstract The development of tandem photovoltaics and photoelectrochemical solar cells requires new absorber materials with bandgaps in the range of ≈1.5–2.3 eV, for use in the top cell paired with a narrower‐gap bottom cell. An outstanding challenge is finding materials with suitable optoelectronic and defect properties, good operational stability, and synthesis conditions that preserve underlying device layers. This study demonstrates the Zintl phosphide compound CaZn 2 P 2 as a compelling candidate semiconductor for these applications. Phase‐pure, ≈500 nm‐thick CaZn 2 P 2 thin films are prepared using a scalable reactive sputter deposition process at growth temperatures as low as 100 °C, which is desirable for device integration. Ultraviolet‐visible spectroscopy shows that CaZn 2 P 2 films exhibit an optical absorptivity of ≈10 4 cm −1 at ≈1.95 eV direct bandgap. Room‐temperature photoluminescence (PL) measurements show near‐band‐edge optical emission, and time‐resolved microwave conductivity (TRMC) measurements indicate a photoexcited carrier lifetime of ≈30 ns. CaZn 2 P 2 is highly stable in both ambient conditions and moisture, as evidenced by PL and TRMC measurements. Experimental data are supported by first‐principles calculations, which indicate the absence of low‐formation‐energy, deep intrinsic defects. Overall, this study shall motivate future work integrating this potential top cell absorber material into tandem solar cells.

14 SOLAR ENERGY↗
DOE OSTI2025

Design Assessment of Brayton Cycles for Combined Heat and Power from Nuclear Power Plants

Brayton cycles (BCs) are gaining renewed interest for use in high-temperature nuclear reactors for power production. This study explores the potential of nuclear Brayton systems in industrial combined heat and power (CHP) production. After a review of the historical deployment and technical development of BC systems for nuclear and cogeneration applications several BCs in CHP configurations are assessed when applied to representative high-temperature reactor types. The analysis emphasizes process heat delivery options, electrical efficiency, and component performance for the case of a direct cycle—Helium BC in a high temperature gas reactor, and an open-air Brayton cycle with a high temperature gas reactor. The results highlight thermodynamic trade-offs in cogeneration operation, particularly in recuperated configurations, and compare BC-based CHP with conventional Rankine cycle (RC) performance. Key findings suggest Helium BCs offer viable CHP performance primarily at lower process heat temperatures, with open air cycles being less efficient. The work also demonstrates trade-off between CHP performance and power production performance with a detailed comparison to where steam RC has better performance. The work is designed to be used as a reference work when cogeneration is proposed from high temperature reactors alongside the use of BCs.

22 - GENERAL STUDIES OF NUCLEAR REACTORS↗