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At least 523 records · Page 29

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NASA NTRS1991

Hydrogen reduction mechanisms of ilmenite between 823 and 1353 K

In situ gravimetric measurements and microscopic examinations were used to determine the mechanisms of oxygen removal from synthetic ilmenite disks between 823 and 1353 K. Under a hydrogen atmosphere, iron was observed to form a layer of low porosity on the surface of samples early in the reduction. This created diffusion limitations for hydrogen to the reaction front and for the escape of water vapor. A shrinking core reduction model, modified to include the growth of this iron film, was capable of predicting the conversion-time relationships of ilmenite samples. An activation energy of 43.2 +/- 2.6 kcal/gmole was determined to be representative of reaction control over the temperature range 823-1023 K.

Briggs, R. A.↗

NASA NTRS1991

Coupled rotor-flexible fuselage vibration reduction using open loop higher harmonic control

A fundamental study of vibration prediction and vibration reduction in helicopters using active controls was performed. The nonlinear equations of motion for a coupled rotor/flexible fuselage system have been derived using computer algebra on a special purpose symbolic computer facility. The trim state and vibratory response of the helicopter are obtained in a single pass by applying the harmonic balance technique and simultaneously satisfying the trim and the vibratory response of the helicopter for all rotor and fuselage degrees of freedom. The influence of the fuselage flexibility on the vibratory response is studied. It is shown that the conventional single frequency higher harmonic control is capable of reducing either the hub loads or only the fuselage vibrations but not both simultaneously. It is demonstrated that for simultaneous reduction of hub shears and fuselae vibrations a new scheme called multiple higher harmonic control is required.

Papavassiliou, I.↗

NASA NTRS1991

New plant and controller order reduction results with weighted balancing

A frequency-response error analysis for frequency-weighted internally balanced (FWIB) truncation is extended and an exact error bound for a case of order reduction by one state is presented. An approximate error bound for a general case of order reduction by more than one state, assuming that only small controllability-observability measures are truncated, is considered. FWIB residualization is presented, and it is shown that a frequency-response error analysis yields results similar to those found for FWIB truncation. It is concluded that FWIB truncation and residualization can be used in a coordinated manner consistent with classical truncation and residualization in order to obtain accuracy higher than that possible from either technique used alone.

Newman, Brett↗

NASA NTRS1991

Transformation products of submicron-sized aluminum-substituted magnetite: Color and reductant solubility

Magnetite, when present as fine particles, is soluble in acid ammonium oxalate (pH equals 3). However, the commonly used extractant for free iron oxides (i.e., citrate dithionite-bicarbonate (CDB) is not very effective in dissolving magnetite in soils and geologic materials. Upon oxidation, magnetite transforms to maghemite; at elevated temperatures, maghemite inverts to hematite. This transformation causes a change in color from black to red and may affect the reductant solubility as well. The objectives here were to examine the color and reflectance spectral characteristics of products during the transformation of magnetite to maghemite to hematite and to study the effect of Al-substitution in magnetite on the above process. Reductant solubility of Al-substituted magnetite, maghemite, and hematite was also studied. In summary, the transformation of magnetite to maghemite was accompanied by a change in color from black to red because of the oxidation of Fe2(+) to Fe3(+). The phase change maghemite to hematite had a relatively minor effect on the color and the reflectance spectra.

Golden, D. C.↗

NASA NTRS1992

Laboratory for Engineering Man/Machine Systems (LEMS): System identification, model reduction and deconvolution filtering using Fourier based modulating signals and high order statistics

Several important problems in the fields of signal processing and model identification, such as system structure identification, frequency response determination, high order model reduction, high resolution frequency analysis, deconvolution filtering, and etc. Each of these topics involves a wide range of applications and has received considerable attention. Using the Fourier based sinusoidal modulating signals, it is shown that a discrete autoregressive model can be constructed for the least squares identification of continuous systems. Some identification algorithms are presented for both SISO and MIMO systems frequency response determination using only transient data. Also, several new schemes for model reduction were developed. Based upon the complex sinusoidal modulating signals, a parametric least squares algorithm for high resolution frequency estimation is proposed. Numerical examples show that the proposed algorithm gives better performance than the usual. Also, the problem was studied of deconvolution and parameter identification of a general noncausal nonminimum phase ARMA system driven by non-Gaussian stationary random processes. Algorithms are introduced for inverse cumulant estimation, both in the frequency domain via the FFT algorithms and in the domain via the least squares algorithm.

Pan, Jianqiang↗

NASA NTRS1991

The entropy reduction engine: Integrating planning, scheduling, and control

The Entropy Reduction Engine, an architecture for the integration of planning, scheduling, and control, is described. The architecture is motivated, presented, and analyzed in terms of its different components; namely, problem reduction, temporal projection, and situated control rule execution. Experience with this architecture has motivated the recent integration of learning. The learning methods are described along with their impact on architecture performance.

Drummond, Mark↗

NASA NTRS1992

Optimal design of compact spur gear reductions

The optimal design of compact spur gear reductions includes the selection of bearing and shaft proportions in addition to gear mesh parameters. Designs for single mesh spur gear reductions are based on optimization of system life, system volume, and system weight including gears, support shafts, and the four bearings. The overall optimization allows component properties to interact, yielding the best composite design. A modified feasible directions search algorithm directs the optimization through a continuous design space. Interpolated polynomials expand the discrete bearing properties and proportions into continuous variables for optimization. After finding the continuous optimum, the designer can analyze near optimal designs for comparison and selection. Design examples show the influence of the bearings on the optimal configurations.

Savage, M.↗

NASA NTRS1992

The O2 reduction at the IFC modified O2 fuel cell electrode

The International Fuel Corporation (IFC) state of the art (SOA) O2 electrode (Au-10 percent Pt electrocatalyst by weight) is currently being used in the alkaline H2-O2 fuel cell in the NASA Space Shuttle. Recently, IFC modified O2 electrode, as a possible replacement for the SOA electrode. In the present study, O2 reduction data were obtained for the modified electrode at temperatures between 23.3 and 91.7 C. BET measurements gave an electrode BET surface area of about 2070 sq. cm/sq. cm of geometric surface area. The Tafel data could be fitted to two straight line regions. The slope for the lower region, designated as the 0.04 V/decade region, was temperature dependent, and the transfer coefficient was about 1.5. The 'apparent' energy of activation for this region was about 19 kcal/mol. An O2 reduction mechanism for this 0.04 region is presented. In the upper region, designated as the 0.08 V/decade region, diffusion may be the controlling process. Tafel data are presented to illustrate the increase in performance with increasing temperature.

Fielder, William L.↗

NASA NTRS1991

Reinterpretation of reduction potential measurements done by linear sweep voltammetry in silicate melts

The equilibrium concentrations of Ni between silicate melt and Pt were determined experimentally as a function of oxygen fugacity. The results demonstrate that metallic species derived in linear sweep voltammetry experiments in silicate melts are diffusing into Pt electrodes and not into the melt, as was concluded by previoius studies. This requires reinterpretation of previous linear sweep voltammetry results and recalculation and correction of reported reduction potentials. This paper reports these corrected reduction potentials. Also reported are the activity coefficients for Ni in synthetic basalt and diopsidic melts and for Co in diopsidic melt.

Colson, R. O.↗

NASA NTRS1991

Significant long-term reduction in n-channel MESFET subthreshold leakage using ammonium-sulfide surface treated gates

Ammonium-sulfide (NH4)2S treated gates have been employed in the fabrication of GaAs MESFETs that exhibit a remarkable reduction in subthreshold leakage current. A greater than 100-fold reduction in drain current minimum is observed due to a decrease in Schottky gate leakage. The electrical characteristics have remained stable for over a year during undesiccated storage at room temperature, despite the absence of passivation layers.

Neudeck, P. G.↗

NASA NTRS1991

Hub and pylon fairing integration for helicopter drag reduction

The results of testing hub and pylon fairings mounted on a one-fifth scale helicopter with the goal of reducing parasite drag are presented. Lift, drag, and pitching moment, as well as side force and yawing moment, were measured. The primary objective of the test was to validate the drag reduction capability of integrated hub and pylon configurations in the aerodynamic environment produced by a rotating hub in forward flight. In addition to the baseline helicopter without fairings, three hub fairings and three pylon fairings were tested in various combinations. The three hub fairings tested reflect two different conceptual design approaches to implementing an integrated fairing configuration on an actual aircraft. The design philosophy is discussed in detail and comparisons are made between the wind tunnel models and potential full-scale prototypes. The data show that model drag can be reduced by as much as 20.8 percent by combining a small hub fairing with circular arc upper and flat lower surfaces and a nontapered 34-percent thick pylon fairing. Aerodynamic effects caused by the fairings, which may have a significant impact on static longitudinal and directional stability, were observed. The results support previous research which showed that the greatest reduction in model drag is achieved if the hub and pylon fairings are integrated with minimum gap between the two.

Martin, D. M.↗

NASA NTRS1991

Experimental investigation of helicopter vibration reduction using rotor blade aeroelastic tailoring

A wind tunnel investigation has been conducted to parametrically investigate the effect of blade nonstructural mass on helicopter fixed- and rotating-system vibratory loads. The data were obtained using Mach- and aeroelastically-scaled model rotor blades which allowed for the addition of concentrated nonstructural masses at multiple points along the blade radius. Testing was conducted for advance ratios ranging from 0.10 to 0.35 for ten blade mass configurations. Three thrust levels were obtained at representative full-scale shaft angles for each configuration. Results indicate that proper placement of blade nonstructural mass can provide reductions in fixed-system vibratory loads, but that correct mass placement and the loads reduction realized are dependent upon flight condition. The data base obtained with this investigation provides a comprehensive set of fixed-system shears and moments, blade moment, and blade flap and lag response. The data set is well suited for use in the correlation and development of advanced rotorcraft analyses.

Wilbur, Matthew L.↗

NASA NTRS1991

Reduction of chemical reaction models

An attempt is made to reconcile the different terminologies pertaining to reduction of chemical reaction models. The approaches considered include global modeling, response modeling, detailed reduction, chemical lumping, and statistical lumping. The advantages and drawbacks of each of these methods are pointed out.

Frenklach, Michael↗

NASA NTRS1991

Krylov model reduction algorithm for undamped structural dynamics systems

Krylov vectors furnish an efficient basis for eigenvalue analysis and model reduction of structural dynamics systems. The reduced-order model obtained by the present Krylov model-reduction algorithm for an undamped structural-dynamics system is found to match low-frequency moments. The transformed system equation in Krylov coordinates reflects the structure of a tandem system.

Craig, Roy R., Jr.↗

NASA NTRS1991

Detailed reduction of reaction mechanisms for flame modeling

A method for reduction of detailed chemical reaction mechanisms, introduced earlier for ignition system, was extended to laminar premixed flames. The reduction is based on testing the reaction and reaction-enthalpy rates of the 'full' reaction mechanism using a zero-dimensional model with the flame temperature profile as a constraint. The technique is demonstrated with numerical tests performed on the mechanism of methane combustion.

Wang, Hai↗

NASA NTRS1992

Ultrasonic evaluation of oxygen content, modulus, and microstructure changes in YBa2Cu3O(7-x) occurring during oxidation and reduction

Ultrasonic velocity measurement techniques were used to evaluate the effects of oxidation and reduction on the elastic properties, global microstructure and oxygen content of the YBa2Cu3O(7-x) ceramic superconductor for samples ranging from 70 to 90 pct of theoretical density. Bulk density, velocity, and elastic modulus generally increased with increasing oxygen content upon oxidation, and this behavior was reversible. Velocity image patterns were similar after oxidation and reduction treatments for a 90 pct. dense sample, although the velocity value at any given point on the sample was changed following the treatments. The unchanging pattern correlated with destructive measurements showing that the spatial pore distribution (fraction and size) was not measurably altered after the treatments. Changes in superconducting behavior, crystal structure, and grain structure were observed consistent with changes in oxygen content.

Roth, Don J.↗

NASA NTRS1992

Model reduction for systems with integrators

The reduction algorithm for systems with integrators is derived. The algorithm is based on balancing the antigrammians and has the same computational effectiveness as the regular balancing procedure. It was applied to the reduction of the NASA Deep Space Network antenna model. As a result, the 90-state model has been reduced to a 27-state model, which preserves the full-model properties.

Gawronski, Wodek↗

NASA NTRS1991

BVI impulsive noise reduction by higher harmonic pitch control - Results of a scaled model rotor experiment in the DNW

Results are presented of a model rotor acoustics test performed to examine the benefit of higher harmonic control (HHC) of blade pitch to reduce blade-vortex interaction (BVI) impulsive noise. A dynamically scaled, four-bladed, rigid rotor model, a 40-percent replica of the B0-105 main rotor, was tested in the German Dutch Wind Tunnel. Noise characteristics and noise directivity patterns as well as vibratory loads were measured and used to demonstrate the changes when different HHC schedules were applied. Dramatic changes of the acoustic signatures and the noise radiation directivity with the HHC phase variations are found. Compared to the baseline conditions (without HHC), significant mid-frequency noise reductions of locally 6 dB are obtained for low-speed descent conditions where GVI is most intense. For other rotor operating conditions with less intense BVI there is less or no benefit from the use of HHC. LF noise and vibratory loads, especially at optimum noise reduction control settings, are found to increase.

Splettstoesser, Wolf R.↗