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At least 523 records · Page 29

Relative rate constants for the reactions of OH with methane and methyl chloroform

Atmospheric lifetimes of methane and methyl chloroform are largely determined by the rates of their reactions with hydroxyl radical. The relative lifetimes for this loss path are inversely proportional to the ratio of the corresponding rate coefficients. The relative rate constants were measured in a slow-flow, temperature-controlled photochemical reactor, and were based on rates of disappearance of the parent compounds as measured by FTIR spectroscopy. The temperature range was 277-356 K. Hydroxyl radicals were generated by 254 nm photolysis of O3 in the presence of water vapor. The preferred Arrhenius expression for the results is k(CH3CCl3)/k(CH4) = 0.62 exp (291/T), corresponding to a value of 1.65 at 298 K and 1.77 at 277 K. The respective uncertainties are 5 and 7 percent.

Demore, W. B.↗

The JPL Field Emission Spectrometer

The Jet Propulsion Laboratory (JPL) Field Emission Spectrometer (FES) was built by Designs and Prototypes based on a set of functional requirements supplied by JPL. The instrument has a spectral resolution of 6 wavenumbers (wn) and can acquire spectra from either the Mid Infrared (3-5 mu m) or the Thermal Infrared (8-12 pm) depending on whether the InSb or HgCdTe detector is installed respectively. The instrument consists of an optical head system unit and battery. The optical head which is tripod mounted includes the interferometer and detector dewar assembly. Wavelength calibration of the interferometer is achieved using a Helium-Neon laser diode. The dewar needs replenishing with liquid Nitrogen approximately every four hours. The system unit includes the controls for operation and the computer used for acquiring viewing and processing spectra. Radiometric calibration is achieved with an external temperature-controlled blackbody that mounts on the fore-optics of the instrument. The blackbody can be set at 5 C increments between 10 and 55 C. The instrument is compact and weighs about 33 kg. Both the wavelength calibration and radiometric calibration of the instrument have been evaluated. The wavelength calibration was checked by comparison of the position of water features in a spectrum of the sky with their position in the output from a high resolution atmospheric model. The results indicatethat the features in the sky spectrum are within 6-8 wn of their position ill the model spectrum. The radiometric calibration was checked by first calibrating the instrument using the external blackbody supplied with the instrument and then measuring the radiance from another external blackbody at a series of temperatures. The temperatures of these radiance spectra were then recovered by inventing Planck's law and the recovered temperatures compared lo the measured blackbody temperature. These results indicate that radiometric calibration is good to 0.5 C over the range of temperatures 10 to 55 C. The results also indicate that the instrument drifts slowly over time and should be recalibrated every 20 to 30 minutes in the field to ensure good radiometric fidelity. The instrument has now been extensively tested in the field in the United States and Australia. These in situ field measurements are being used to validate emissivity spectra recovered from the Thermal Infrared Multispectral Scanner (TIMS) and also the Australian CO2 Laser. The availability of in situ measurements is proving crucial to validation of the spectra derived from the airborne instruments since many natural surfaces cannot be easily transported back to the laboratory.

Hook, Simon J.↗

A modular suite of hardware enabling spaceflight cell culture research

BioServe Space Technologies, a NASA Research Partnership Center (RPC), has developed and operated various middeck payloads launched on 23 shuttle missions since 1991 in support of commercial space biotechnology projects. Modular cell culture systems are contained within the Commercial Generic Bioprocessing Apparatus (CGBA) suite of flight-qualified hardware, compatible with Space Shuttle, SPACEHAB, Spacelab and International Space Station (ISS) EXPRESS Rack interfaces. As part of the CGBA family, the Isothermal Containment Module (ICM) incubator provides thermal control, data acquisition and experiment manipulation capabilities, including accelerometer launch detection for automated activation and thermal profiling for culture incubation and sample preservation. The ICM can accommodate up to 8 individually controlled temperature zones. Command and telemetry capabilities allow real-time downlink of data and video permitting remote payload operation and ground control synchronization. Individual cell culture experiments can be accommodated in a variety of devices ranging from 'microgravity test tubes' or standard 100 mm Petri dishes, to complex, fed-batch bioreactors with automated culture feeding, waste removal and multiple sample draws. Up to 3 levels of containment can be achieved for chemical fixative addition, and passive gas exchange can be provided through hydrophobic membranes. Many additional options exist for designing customized hardware depending on specific science requirements.

manned↗

Loop Heat Pipe Transient Behavior Using Heat Source Temperature for Set Point Control with Thermoelectric Converter on Reservoir

The LHP operating temperature is governed by the saturation temperature of its reservoir. Controlling the reservoir saturation temperature is commonly done by cold biasing the reservoir and using electrical heaters to provide the required control power. With this method, the loop operating temperature can be controlled within 0.5K or better. However, because the thermal resistance that exists between the heat source and the LHP evaporator, the heat source temperature will vary with its heat output even if the LHP operating temperature is kept constant. Since maintaining a constant heat source temperature is of most interest, a question often raised is whether the heat source temperature can be used for LHP set point temperature control. A test program with a miniature LHP was carried out to investigate the effects on the LHP operation when the control temperature sensor was placed on the heat source instead of the reservoir. In these tests, the LHP reservoir was cold-biased and was heated by a control heater. Test results show that it was feasible to use the heat source temperature for feedback control of the LHP operation. In particular, when a thermoelectric converter was used as the reservoir control heater, the heat source temperature could be maintained within a tight range using a proportional-integral-derivative or on/off control algorithm. Moreover, because the TEC could provide both heating and cooling to the reservoir, temperature oscillations during fast transients such as loop startup could be eliminated or substantially reduced when compared to using an electrical heater as the control heater.

Ku, Jentung↗

Temperature‐Dependent Crystallization in Two‐Step Perovskite Deposition Revealed by In Situ GIWAXS and Machine Learning‐Guided Analysis

The performance and stability of perovskite solar cells are strongly governed by the crystallization behavior of their active layer. In two-step sequential deposition, early-stage film formation plays a decisive role in determining final phase purity and device quality. Guided by a data-driven analysis of nearly 39 000 devices in the FAIR perovskite database, we identified solvent-mediated quenching and thermal processing as key variables affecting power conversion efficiency (PCE), particularly in two-step fabrication. Here, to investigate these effects in real time, we designed and implemented a custom-built, temperature-controlled spin-coating system, enabling precise thermal modulation during precursor deposition. Using this platform, we performed in situ GIWAXS measurements to study the crystallization dynamics of FA 0.5 MA 0.5 PbI 3 films over a temperature range of 30°C–90°C. Our results reveal a non-monotonic relationship between spin-coating temperature and α-phase formation, governed by the interplay between precursor interdiffusion, PbI 2 crystallinity, and δ-phase suppression. The custom thermal control enabled us to isolate and quantify these competing effects during the earliest stages of film formation, providing mechanistic insight into how spin-coating temperature governs both phase purity and kinetic pathways in two-step perovskite systems. Temperature-dependent SEM and photovoltaic device measurements further demonstrate that early-stage crystallization pathways directly translate into differences in morphology, charge-transport continuity, and device performance. These findings inform targeted strategies for optimizing deposition protocols to balance rapid nucleation, phase stability, and device performance.

Saadawy, Ahmed [King Fahd University of Petroleum ↗

Data Assimilation Experiments using Quality Controlled AIRS Version 5 Temperature Soundings

The AIRS Science Team Version 5 retrieval algorithm has been finalized and is now operational at the Goddard DAAC in the processing (and reprocessing) of all AlRS data. Version 5 contains accurate case-by-case error estimates for most derived products, which are also used for quality control. We have conducted forecast impact experiments assimilating AlRS quality controlled temperature profiles using the NASA GEOS-5 data assimilation system, consisting of the NCEP GSI analysis coupled with the NASA FVGCM. Assimilation of quality controlled temperature profiles resulted in significantly improved forecast skill in both the Northern Hemisphere and Southern Hemisphere Extra-Tropics, compared to that obtained from analyses obtained when all data used operationally by NCEP except for AlRS data is assimilated. Experiments using different Quality Control thresholds for assimilation of AlRS temperature retrievals showed that a medium quality control threshold performed better than a tighter threshold, which provided better overall sounding accuracy; or a looser threshold, which provided better spatial coverage of accepted soundings. We are conducting more experiments to further optimize this balance of spatial coverage and sounding accuracy from the data assimilation perspective. In all cases, temperature soundings were assimilated well below cloud level in partially cloudy cases. The positive impact of assimilating AlRS derived atmospheric temperatures all but vanished when only AIRS stratospheric temperatures were assimilated. Forecast skill resulting from assimilation of AlRS radiances uncontaminated by clouds, instead of AlRS temperature soundings, was only slightly better than that resulting from assimilation of only stratospheric AlRS temperatures. This reduction in forecast skill is most likely the result of significant loss of tropospheric information when only AIRS radiances unaffected by clouds are used in the data assimilation process.

Susskind, Joel↗

Compact Dual-Mode Microwave Antenna

Compact dual-mode antenna, 3.66 cm wide by 1.83 cm thick is used both for heating and thermographic detection of tumors in cancer research. Temperature sensor operates independently or simultaneously with heater. Antenna includes 1.6-GHz transmitter and 4.76-GHz receiver. Strip heater between antennas controls temperature of device. Maximum power output is 25 W.

Carr, K. L.↗

The Lick Observatory charge-coupled device /CCD/ and controller

A description is given of a flexible microprocessor-based controller for charge-coupled device two-dimensional detectors. It is noted that the controller can operate under manual control or as a slave to a remote computer linked by coaxial cable. The system is discussed, together with data taken at the telescope and in the laboratory. The flexibility of the controller derives from its modular form and from the use of a programmable 8-bit microprocessor to control and sequence the electronic logic. The electronic circuits for such functions as signal processing, clock sequencing, voltage level adjustment, and temperature control are on small individual plug-in cards, making future improvements and changes simple. The software of the microprocessor is stored in erasable, programmable, read-only memory. Among the limitations of the controller is a scan speed of roughly 35 microsec per pixel.

Robinson, L. B.↗

Manufacturing Diamond Under Very High Pressure

A process for manufacturing bulk diamond has been made practical by the invention of the High Pressure and Temperature Apparatus capable of applying the combination of very high temperature and high pressure needed to melt carbon in a sufficiently large volume. The apparatus includes a reaction cell wherein a controlled static pressure as high as 20 GPa and a controlled temperature as high as 5,000 C can be maintained.

Voronov, Oleg↗

Infrared Images of Boundary Layer Transition on the D8 Transport Configuration in the LaRC 14- by 22-Foot Subsonic Tunnel

Grit, trip tape, or trip dots are routinely applied on the leading-edge regions of the fuselage, wings, tails or nacelles of wind tunnel models to trip the flow from laminar to turbulent. The thickness of the model's boundary layer is calculated for nominal conditions in the wind tunnel test to determine the effective size of the trip dots, but the flow over the model may not transition as intended for runs with different flow conditions. Temperature gradients measured with an infrared camera can be used to detect laminar to turbulent boundary layer transition on a wind tunnel model. This non-intrusive technique was used in the NASA Langley 14- by 22-Foot Subsonic Tunnel to visualize the behavior of the flow over a D8 transport configuration model. As the flow through the wind tunnel either increased to or decreased from the run conditions, a sufficient temperature difference existed between the air and the model to visualize the transition location (due to different heat transfer rates through the laminar and the turbulent boundary layers) for several runs in this test. Transition phenomena were visible without active temperature control in the atmospheric wind tunnel, whether the air was cooler than the model or vice-versa. However, when the temperature of the model relative to the air was purposely changed, the ability to detect transition in the infrared images was enhanced. Flow characteristics such as a wing root horseshoe vortex or the presence of fore-body vortical flows also were observed in the infrared images. The images of flow features obtained for this study demonstrate the usefulness of current infrared technology in subsonic wind tunnel tests.

Mason, Michelle L.↗

Causes and Effects of AIRS Optics Temperature Cycles

In addition to the expected orbital thermal cycle, geophysical conditions with high thermal and reflected upwelling infrared (IR) drive measurable changes in the AIRS instrument with a period of 24 hours. Especially hot and bright scenes are important, with about 30% of the variability driven by thermal IR and 70% by reflected IR. We show how these cycles manifest in the instrument telemetry for temperatures and gain and with careful analysis can even be detected in spectral shifts.Thermal cycles are an unavoidable feature of instruments observing upwelling radiances from Earth, because the signal inherently carries varying amounts of energy into the instrument. Temperature control of the optical bench, on-board calibrator blackbody, and Focal Plane Array (FPA) in AIRS reduce the impacts of temperature variability to extremely small levels. This combined with good on-board telemetry of the temperatures and including temperature variability in our calibration algorithm has resulted in an instrument that achieves ‘climate quality’ measurements. Careful instrument and algorithm design allows us to characterize and document the impact of temperature variability and limit the effects to negligible levels, helping the instrument meet important climate-quality criteria specified in Ohring 2005

Overoye, Kenneth↗

Conceptual Design of Neutron Sensor Qualification Device

The Advanced Sensors and Instrumentation Program at Idaho National Laboratory has been formulating strategies to qualify sensors for use in nuclear environments, particularly in irradiation experiments and advanced reactors. When qualifying neutron sensors for use in high-temperature environments, the wide range of neutron flux levels and representative energy spectra presents significant challenges. This paper discusses the development of the Neutron Sensor Qualification Device (NQD), which is designed to test neutron sensors in high temperature controlled environments with known neutron spectra, addressing the spatial and spectral complexities of neutron fluxes in reactor cores. The proposed NQD will be situated in the exposure room at the Armed Forces Radiobiology Research Institute, thus affording a unique capability to expose sensors to high neutron and gamma fluxes. To achieve thermal control, the device will utilize a radiation-hardened tube furnace, accommodating multiple sensors and neutron activation dosimetry wires. Titanium, iron, and cobalt dosimeter wires are chosen from the American Society for Testing and Materials and International Reactor Dosimetry and Fusion File libraries as references for providing energy-dependent fluence measurements. The design ensures precise sensor positioning to minimize mutual shielding and flux perturbation, which are evaluated via Monte Carlo N particle Transport Code (MCNP) simulations. These simulations have informed the development of guidelines on sensor placement within the NQD. The NQD is essential to the qualification of neutron sensors for advanced reactor technologies. It enables controlled testing of a statistically significant number of sensors, thereby supporting assessments of sensor performance across various neutron flux levels and temperatures. This paper highlights the detailed planning for the NQD prototype, along with its inaugural irradiation (scheduled for fiscal year [FY] 2025). The results from this initial testing will be fundamental in evaluating the device’s performance and establishing measurement uncertainty for in-pile neutron sensor measurements.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

A Reinforcement Learning Approach to Augment Conventional PID Control in Nuclear Power Plant Transient Operation

The ability of nuclear reactors to operate their power conversion cycles more flexibly will enhance their value to energy grids with variable pricing. Current nuclear control systems are typically classical controllers that are often based on proportional-integral-derivative (PID) control. This paper presents a method of augmenting the existing PID control for difficult transient operations in nuclear power plants using a reinforcement learning–derived feedforward signal applied in real time. The agents, which are trained on a test thermal load-following problem, are designed to improve steam generator outlet temperature control for a range of fast load-following scenarios covering ramp rates from 9%/min to 15%/min. Several reinforcement learning algorithms were initially investigated for the training of the feedforward agents with deep Q-learning (DQN) and proximal policy optimization (PPO) networks, which were found to be the most promising. The DQN controllers utilize discrete actions, giving them a better disturbance rejection at steady state but inconsistent response to initial temperature deviations. In contrast, PPO-trained agents, which take continuous actions except for a dead zone around zero, were shown to have the best combination of high disturbance rejection at steady state and good tracking of the desired temperature value. The ability of the PPO agent was also examined, with the average time of decision making found to be on the order of 1 ms. The fault properties of the controller under the loss of the reinforcement learning agent feedforward signal were also examined. The controller showed strong performance in situations of “no-signal” faults. but was less good at handling “stuck-at” faults, where the feedforward signal remains at a set value. In both cases, however, the PID was able to successfully maintain stability, eventually returning the system to a steady state. It is hoped that this work will allow for the proposed control architecture to be examined for more difficult control problems such that it may eventually be used to adapt existing nuclear plants for more aggressive load-following on grids of the future.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Space Station Biological Research Project Habitat: Incubator

Developed as part of the suite of Space Station Biological Research Project (SSBRP) hardware to support research aboard the International Space Station (ISS), the Incubator is a temperature-controlled chamber, for conducting life science research with small animal, plant and microbial specimens. The Incubator is designed for use only on the ISS and is transported to/from the ISS, unpowered and without specimens, in the Multi-Purpose Logistics Module (MPLM) of the Shuttle. The Incubator interfaces with the three SSBRP Host Systems; the Habitat Holding Racks (HHR), the Life Sciences Glovebox (LSG) and the 2.5 m Centrifuge Rotor (CR), providing investigators with the ability to conduct research in microgravity and at variable gravity levels of up to 2-g. The temperature within the Specimen Chamber can be controlled between 4 and 45 C. Cabin air is recirculated within the Specimen Chamber and can be exchanged with the ISS cabin at a rate of approximately equal 50 cc/min. The humidity of the Specimen Chamber is monitored. The Specimen Chamber has a usable volume of approximately equal 19 liters and contains two (2) connectors at 28v dc, (60W) for science equipment; 5 dedicated thermometers for science; ports to support analog and digital signals from experiment unique sensors or other equipment; an Ethernet port; and a video port. It is currently manifested for UF-3 and will be launched integrated within the first SSBRP Habitat Holding Rack.

Nakamura, G. J.↗

Evaluation of a spacecraft nitrogen generator

An experiment was completed to demonstrate that low ammonia concentrations in the product nitrogen stream are possible using the staging concept. Mixtures of nitrogen, hydrogen and ammonia were fed into a temperature controlled packed bed ammonia dissociator. An ammonia concentration of 1.03% in the feed stream was reduced to less than 50 ppm at temperatures greater than or equal to 777K. The actual inlet ammonia concentration to the final nitrogen generation module ammonia dissociation stage was only 0.09%.

Marshall, R. D.↗

Reactor for simulation and acceleration of solar ultraviolet damage

An environmental test chamber providing acceleration of UV radiation and precise temperature control (+ or -)1 C was designed, constructed and tested. This chamber allows acceleration of solar ultraviolet up to 30 suns while maintaining temperature of the absorbing surface at 30 C - 60 C. This test chamber utilizes a filtered medium pressure mercury arc as the source of radiation, and a combination of selenium radiometer and silicon radiometer to monitor solar ultraviolet (295-340 nm) and total radiant power output, respectively. Details of design and construction and operational procedures are presented along with typical test data.

Laue, E.↗

Numerical investigation of the thermal stratification in cryogenic tanks subjected to wall heat flux

The flow pattern and thermal stratification of a cryogenic cylindrical tank are numerically studied. The tank sidewall is subjected to either a uniform heat-flux or two discrete levels of uniform heat-flux at the upper and lower halves of the tank wall. The tank bottom is kept at a constant temperature controlled by the heat exchanger of a thermodynamic vent system. The tank pressure is also assumed constant resulting in a constant saturation temperature at the interface which is higher than the tank bottom temperature. The effects of vapor motion and vapor superheat on the mass and heat transfer processes at the interface are assumed negligible such that the calculations of liquid region can be decoupled from the vapor region. Dimensionless steady-state conservation equations are solved by a finite-difference method. The effects of modified Rayleigh number, Prandtl number, tank aspect ratio, wall heat-flux parameter, and wall heat-flux distribution on the liquid velocity and temperature fields are investigated. Also, their effects on the rate of heat transfer through the interface and the tank bottom are examined.

Lin, Chin-Shun↗

Numerical investigation of the thermal stratification in cryogenic tanks subjected to wall heat flux

The flow pattern and thermal stratification of a cryogenic cylindrical tank are numerically studied. The tank sidewall is subjected to either a uniform heat-flux or two discrete levels of uniform heat-flux at the upper and lower halves of the tank wall. The tank bottom is kept at a constant temperature controlled by the heat exchanger of a thermodynamic vent system. The tank pressure is also assumed constant resulting in a constant saturation temperature at the interface which is higher than the tank bottom temperature. The effects of vapor motion and vapor superheat on the mass and heat transfer processes at the interface are assumed negligible such that the calculations of liquid region can be decoupled from the vapor region. Dimensionless steady-state conservation equations are solved by a finite-difference method. The effects of modified Rayleigh number, Prandtl number, tank aspect ratio, wall heat-flux parameter, and wall heat-flux distribution on the liquid velocity and temperature fields are investigated. Also, their effects on the rate of heat transfer through the interface and the tank bottom are examined.

Lin, Chin-Shun↗