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Marshall Space Flight Center Materials and Processes Laboratory

Marshall?s Materials and Processes Laboratory has been a core capability for NASA for over fifty years. MSFC has a proven heritage and recognized expertise in materials and manufacturing that are essential to enable and sustain space exploration. Marshall provides a "systems-wise" capability for applied research, flight hardware development, and sustaining engineering. Our history of leadership and achievements in materials, manufacturing, and flight experiments includes Apollo, Skylab, Mir, Spacelab, Shuttle (Space Shuttle Main Engine, External Tank, Reusable Solid Rocket Motor, and Solid Rocket Booster), Hubble, Chandra, and the International Space Station. MSFC?s National Center for Advanced Manufacturing, NCAM, facilitates major M&P advanced manufacturing partnership activities with academia, industry and other local, state and federal government agencies. The Materials and Processes Laborato ry has principal competencies in metals, composites, ceramics, additive manufacturing, materials and process modeling and simulation, space environmental effects, non-destructive evaluation, and fracture and failure analysis provide products ranging from materials research in space to fully integrated solutions for large complex systems challenges. Marshall?s materials research, development and manufacturing capabilities assure that NASA and National missions have access to cutting-edge, cost-effective engineering design and production options that are frugal in using design margins and are verified as safe and reliable. These are all critical factors in both future mission success and affordability.

Tramel, Terri L.↗

Dynamic Responses of the Earth's Outer Core to Assimilation of Observed Geomagnetic Secular Variation

Assimilation of surface geomagnetic observations and geodynamo models has advanced very quickly in recent years. However, compared to advanced data assimilation systems in meteorology, geomagnetic data assimilation (GDAS) is still in an early stage. Among many challenges ranging from data to models is the disparity between the short observation records and the long time scales of the core dynamics. To better utilize available observational information, we have made an effort in this study to directly assimilate the Gauss coefficients of both the core field and its secular variation (SV) obtained via global geomagnetic field modeling, aiming at understanding the dynamical responses of the core fluid to these additional observational constraints. Our studies show that the SV assimilation helps significantly to shorten the dynamo model spin-up process. The flow beneath the core-mantle boundary (CMB) responds significantly to the observed field and its SV. The strongest responses occur in the relatively small scale flow (of the degrees L is approx. 30 in spherical harmonic expansions). This part of the flow includes the axisymmetric toroidal flow (of order m = 0) and non-axisymmetric poloidal flow with m (is) greater than 5. These responses can be used to better understand the core flow and, in particular, to improve accuracies of predicting geomagnetic variability in future.

secular variation↗

Dynamic cache bypassing

A processing system fills a memory access request for data from a processor core by bypassing a cache when a write congestion condition is detected, and when transferring the data to the cache would cause eviction of a dirty cache line. The cache is bypassed by transferring the requested data to the processor core or to a different cache. Accordingly, the processing system can temporarily bypass the cache storing the dirty cache line when filling a memory access request, thereby avoiding the eviction and write back to main memory of a dirty cache line when a write congestion condition exists.

97 MATHEMATICS AND COMPUTING↗

WHONDRS 2016 Sediment Organic Matter Characterization Data from Streams across HJ Andrews Experimental Forest, Oregon

This dataset supports a broader synoptic effort to map morphological, hydrological, chemical, and biological conditions across a fifth-order mountain stream network. Samples were generated through a collaborative synoptic sampling effort in 2016. The dataset provides sediment Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FTICR-MS) from 60 sites across the HJ Andrews Experimental Forest, Oregon (https://andrewsforest.oregonstate.edu). Related data were collected as part of the event and were published separately in collaboration with other team members. The data are available at http://www.hydroshare.org/resource/ea6c0832885a46c3939e7bb22e48e754 and are described within https://doi.org/10.5194/essd-11-1567-2019 (Ward et al., 2019). The hydroshare data package contains processed FTICR-MS data from the samples included in this data package. The data were processed via Formultitude (previously called Formularity; https://github.com/PNNL-Comp-Mass-Spec/Formultitude). However, we have re-processed the data using Core-MS and included it in this data package. Additional related data collected in 2025 from a similar effort can be found at https://data.ess-dive.lbl.gov/datasets/doi:10.15485/3023310 and http://www.hydroshare.org/resource/b274c4a234bf4b12b7cb8a54a696c629. For details on how to navigate data packages generated by this project, see https://data.ess-dive.lbl.gov/portals/PNNLRiverCorridorSFA/About. In addition to a readme, this data package also includes a file-level metadata (FLMD) file that describes each file and a data dictionary (DD) that describes all column/row headers and variable definitions. This dataset is comprised of (1) a folder of sample data; (2) data dictionary; (3) file-level metadata; (4); (5) coordinates; and (6) readme. The sample data subfolder contains 12 Tesla (12T) FTICR-MS data. This folder contains the processed data and three subfolders, one containing the .xml files, one containing the CoreMS output files, and the other containing instructions and scripts for processing the files in CoreMS (https://github.com/EMSL-Computing/CoreMS). All files are .csv, .pdf, .R, .xml, .Rmd, .py, .cal, or .json.

Biogeochemistry↗

Large Eddy Simulation (LES) of Particle-Laden Temporal Mixing Layers

High-fidelity models of plume-regolith interaction are difficult to develop because of the widely disparate flow conditions that exist in this process. The gas in the core of a rocket plume can often be modeled as a time-dependent, high-temperature, turbulent, reacting continuum flow. However, due to the vacuum conditions on the lunar surface, the mean molecular path in the outer parts of the plume is too long for the continuum assumption to remain valid. Molecular methods are better suited to model this region of the flow. Finally, granular and multiphase flow models must be employed to describe the dust and debris that are displaced from the surface, as well as how a crater is formed in the regolith. At present, standard commercial CFD (computational fluid dynamics) software is not capable of coupling each of these flow regimes to provide an accurate representation of this flow process, necessitating the development of custom software. This software solves the fluid-flow-governing equations in an Eulerian framework, coupled with the particle transport equations that are solved in a Lagrangian framework. It uses a fourth-order explicit Runge-Kutta scheme for temporal integration, an eighth-order central finite differencing scheme for spatial discretization. The non-linear terms in the governing equations are recast in cubic skew symmetric form to reduce aliasing error. The second derivative viscous terms are computed using eighth-order narrow stencils that provide better diffusion for the highest resolved wave numbers. A fourth-order Lagrange interpolation procedure is used to obtain gas-phase variable values at the particle locations.

Bellan, Josette↗

A Comprehensive Plan for the Long-Term Calibration and Validation of Oceanic Biogeochemical Satellite Data

The primary objective of this planning document is to establish a long-term capability and validating oceanic biogeochemical satellite data. It is a pragmatic solution to a practical problem based primarily o the lessons learned from prior satellite missions. All of the plan's elements are seen to be interdependent, so a horizontal organizational scheme is anticipated wherein the overall leadership comes from the NASA Ocean Biology and Biogeochemistry (OBB) Program Manager and the entire enterprise is split into two components of equal sature: calibration and validation plus satellite data processing. The detailed elements of the activity are based on the basic tasks of the two main components plus the current objectives of the Carbon Cycle and Ecosystems Roadmap. The former is distinguished by an internal core set of responsibilities and the latter is facilitated through an external connecting-core ring of competed or contracted activities. The core elements for the calibration and validation component include a) publish protocols and performance metrics; b) verify uncertainty budgets; c) manage the development and evaluation of instrumentation; and d) coordinate international partnerships. The core elements for the satellite data processing component are e) process and reprocess multisensor data; f) acquire, distribute, and archive data products; and g) implement new data products. Both components have shared responsibilities for initializing and temporally monitoring satellite calibration. Connecting-core elements include (but are not restricted to) atmospheric correction and characterization, standards and traceability, instrument and analysis round robins, field campaigns and vicarious calibration sites, in situ database, bio-optical algorithm (and product) validation, satellite characterization and vicarious calibration, and image processing software. The plan also includes an accountability process, creating a Calibration and Validation Team (to help manage the activity), and a discussion of issues associated with the plan's scientific focus.

Hooker, Stanford B.↗

Multi-Layer RF Tissue Phantoms for Mimicking a Human Core

This work presents the design recipe, fabrication process and characterization of tissue-simulating materials, configured as a physical model to mimic the electrical and some physical properties of an abdominal cavity. The complete three layer design is called the human core model (HCM). To our knowledge, presented is the first hybrid skin-muscle phantom developed to mimic the electrical properties of the intervening tissue layers of an abdominal cavity within the frequency band of 1 GHz 2 GHz, a band of interest for human body sensing due to its deep detection depth. To complete the model, a liquid blood phantom was also developed and characterized in this frequency band. The phantoms were characterized with respect to complex dielectric constant using the Agilent 85070E dielectric probe kit, and the results compared to the Gabriel model, which is used as the standard for human tissue characterization. Since the tissue impedance is an important parameter for characterizing on-body sensors and near field antenna performance, the impedance of the phantoms were also calculated and presented in the analysis.

Bonds, Quenton↗

Earth's water reservoirs in a changing climate

Progress towards achieving a quantitative understanding of the exchanges of water between Earth's main water reservoirs is reviewed with emphasis on advances accrued from the latest advances in Earth Observation from space. These exchanges of water between the reservoirs are a result of processes that are at the core of important physical Earth-system feedbacks, which fundamentally control the response of Earth's climate to the greenhouse gas forcing it is now experiencing, and are therefore vital to understanding the future evolution of Earth's climate. The changing nature of global mean sea level (GMSL) is the context for discussion of these exchanges. Different sources of satellite observations that are used to quantify ice mass loss and water storage over continents, how water can be tracked to its source using water isotope information and how the waters in different reservoirs influence the fluxes of water between reservoirs are described. The profound influence of Earth's hydrological cycle, including human influences on it, on the rate of GMSL rise is emphasized. The many intricate ways water cycle processes influence water exchanges between reservoirs and thus sea-level rise, including disproportionate influences by the tiniest water reservoirs, are emphasized.

54 ENVIRONMENTAL SCIENCES↗

Fluor Idaho's Technical and Programmatic Approach That Resolved the Problems with the Integrated Waste Treatment Unit - 19290

The Integrated Waste Treatment Unit (IWTU) is a facility designed to treat approximately 900,000 gallons of radioactive liquid waste, referred to as Sodium Bearing Waste (SBW). IWTU is a Fluidized Bed Steam Reforming process that will be used to treat the SBW to produce a granular sodium carbonate and sodium aluminate product. The product is planned to be managed as remote handled transuranic waste. Construction of the IWTU was completed in 2011 and Critical Decision 4 was achieved in 2012 with the expectation that the treatment of the SBW would be completed in 2012. However, process instabilities and equipment problems prevented the safe and reliable operation of the facility. All of the nonradiological tests of the IWTU had to be stopped prematurely because each time the IWTU was operated, the process would become unstable within a few days of initiating the operation. The instabilities were associated with the primary fluidized bed reaction vessel, the Denitration Mineralization Reformer (DMR). The instabilities included difficulties maintaining fluidization conditions and scale formation within the DMR. Design inadequacies and equipment reliability problems in other parts of the facility also hampered the testing the IWTU. The U.S. Department of Energy (DOE) awarded the Idaho Clean-up contract to Fluor Idaho (Fluor) in 2016. To resolve the issues with the IWTU, Fluor assembled a dedicated team to develop the technical and programmatic strategy to resolve the issues with the IWTU and get it operational. Fluor's approach has successfully resolved the primary issues with the IWTU. As a result of modifications of equipment and operating strategies implemented by Fluor, the core part of the IWTU process now works reliably when processing simulated Sodium Bearing Waste over a wide range of operating conditions. This paper describes Fluor's approach and summarize key steps in the process to resolve the issues with the IWTU. Fluor has used strong fundamentals including a first principles approach and unique program management techniques to solve the technical problems with the IWTU. The successful approach has provided renewed confidence in the IWTU process enabling the troubled project to move forward. Important factors in the success of the project include using a dedicated project team separate from the IWTU line organization, a Technical Review Group, the Chemistry Team and a diverse set of supporting contractors and National Laboratories. Fluor typically used multiple means to validate solutions before testing them in the IWTU. Fluor's successful full-scale demonstration runs of the IWTU confirm the process will reliably produce a compliant, treated waste product over a wide range of operating conditions.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Impact of the Latest 22 Ne+ α Reaction Rates on Nucleosynthesis in Massive Stars and Galactic Chemical Evolution

In massive stars (initial mass of ≳9 M ⊙ ), the weak s- (slow neutron capture) process produces elements between Fe and Zr, enriching the Galaxy with these elements through core-collapse supernova explosions. The weak s-process nucleosynthesis is driven by neutrons produced in the 22 Ne(α, n) 25 Mg reaction during convective He core and C shell burning. The yields of heavy elements thus depend on the 22 Ne(α, n) 25 Mg and the competitive 22 Ne(α, γ) 26 Mg reaction rates, which are dominated by several narrow-resonance reactions. While the accuracy of these rates has been under debate for decades, recent experimental efforts, including ours, drastically reduced these uncertainties. In this work, we use a set of 280 massive star nucleosynthesis models calculated using different 22 Ne(α, n) 25 Mg and 22 Ne(α, γ) 26 Mg rates and a galactic chemical evolution (GCE) study to probe their impact on the weak s-process elemental abundances in the Galaxy. The GCE was computed with the OMEGA+ code, using the new sets of stellar yields with different 22 Ne+α rates. From GCE, we find that these rates are causing up to 0.45 dex of variations in the [Cu/Fe], [Ga/Fe], and [Ge/Fe] ratios predicted at solar metallicity. The greatest impact on the stellar nucleosynthesis and GCE results derives from uncertainties in the (α, n) strength (ωγ (α,n) ) of the E x = 11.32 MeV resonance. We show that variations observed in the GCE calculations for weak s-process elements become negligibly smaller than dispersions found in observations once the ωγ (α,n) is accurately determined within the uncertainty of 10%–20% (typically reported experimental errors for the resonance) in future nuclear physics experiments.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Multi-Layer RF Tissue Phantoms for Mimicking a Human Core

This work presents the design recipe, fabrication process and characterization of tissue-simulating materials, configured as a physical model to mimic the electrical and some physical properties of an abdominal cavity. The complete three-layer design is called the human core model (HCM) see Fig. 1. To our knowledge, presented is the first hybrid skin-muscle phantom developed to mimic the electrical properties of the intervening tissue layers of an abdominal cavity within the frequency band of 1 GHz - 2 GHz, a band of interest for human body sensing due to its deep detection depth.

Biomedical Microwave Sensing↗

An Approach to Improved Credibility of CFD Simulations for Rocket Injector Design

Computational fluid dynamics (CFD) has the potential to improve the historical rocket injector design process by simulating the sensitivity of performance and injector-driven thermal environments to. the details of the injector geometry and key operational parameters. Methodical verification and validation efforts on a range of coaxial injector elements have shown the current production CFD capability must be improved in order to quantitatively impact the injector design process.. This paper documents the status of an effort to understand and compare the predictive capabilities and resource requirements of a range of CFD methodologies on a set of model problem injectors. Preliminary results from a steady Reynolds-Average Navier-Stokes (RANS), an unsteady Reynolds-Average Navier Stokes (URANS) and three different Large Eddy Simulation (LES) techniques used to model a single element coaxial injector using gaseous oxygen and gaseous hydrogen propellants are presented. Initial observations are made comparing instantaneous results, corresponding time-averaged and steady-state solutions in the near -injector flow field. Significant differences in the flow fields exist, as expected, and are discussed. An important preliminary result is the identification of a fundamental mixing mechanism, accounted for by URANS and LES, but missing in the steady BANS methodology. Since propellant mixing is the core injector function, this mixing process may prove to have a profound effect on the ability to more correctly simulate injector performance and resulting thermal environments. Issues important to unifying the basis for future comparison such as solution initialization, required run time and grid resolution are addressed.

Tucker, Paul K.↗

Evaluating Core Quality for a Mars Sample Return Mission

Sample return missions, including the proposed Mars Sample Return (MSR) mission, propose to collect core samples from scientifically valuable sites on Mars. These core samples would undergo extreme forces during the drilling process, and during the reentry process if the EEV (Earth Entry Vehicle) performed a hard landing on Earth. Because of the foreseen damage to the stratigraphy of the cores, it is important to evaluate each core for rock quality. However, because no core sample return mission has yet been conducted to another planetary body, it remains unclear as to how to assess the cores for rock quality. In this report, we describe the development of a metric designed to quantitatively assess the mechanical quality of any rock cores returned from Mars (or other planetary bodies). We report on the process by which we tested the metric on core samples of Mars analogue materials, and the effectiveness of the core assessment metric (CAM) in assessing rock core quality before and after the cores were subjected to shocking (g forces representative of an EEV landing).

Mars samples↗

Gamma Rays as a Signature of r -process Producing Supernovae: Remnants and Future Galactic Explosions

We consider the question of whether core-collapse supernovae (CCSNe) can produce rapid neutron capture process (r-process) elements and how future MeV gamma-ray observations could address this. Rare types of CCSNe characterized by substantial magnetic fields and rotation, known as magnetorotational supernovae (MR-SNe), are theoretically predicted to produce these elements, although direct observational evidence is lacking. We suggest that this critical question be addressed through the study of some of the 11 CCSN remnants located within 10 kpc, as well as through the detection of gamma-ray emission from a future Galactic supernova. We use a two-dimensional MR-SN model to estimate the expected gamma flux stemming from nuclear decays in the range of a few tens of keV to a few MeV. Our results indicate that an observation of 126 Sn ( 126 Sb) in a remnant stands out as a signature of an r-process-producing supernova. Since the neutron-rich conditions that lead to the production of the r-process could also enhance the production of 60 Fe, the detection of substantial 60 Fe ( 60 Co) would be indicative of favorable conditions for the r-process. In the case of a future supernova explosion, when the evolution of the spectrum is studied over 10 days to a few years, a rich picture emerges. At various epochs, the second peak r-process isotopes such as 125 Sn, 131 I, 132 Te, 132 I, and 140 La produce signals that are not obscured by the gamma emission from explosive burning products and electron–positron annihilation. The weak r-process isotopes 95 Nb, 103 Ru, and 106 Rh also have periods of prominence.

Gamma-rays↗

Investigation of the neoclassical ambipolar electric field in ion-root plasmas on W7-X

The role of the radial electric field in high-performance ion-root plasmas on Wendelstein 7-X (W7-X) is examined and compared with neoclassical predictions herein. The W7-X stellarator is the world’s first large-scale optimized stellarator. One of the important targets chosen for optimization during the W7-X design process was the reduction of core neoclassical heat transport. This optimization was targeted for reactor-relevant high-density plasmas with $T_e ≈ T_i$ in which the neoclassical ambipolar radial electric field is expected to be negative throughout the plasmas core. Measurements of the core radial electric field $(E_r)$ have confirmed that ion-root conditions (negative $(E_r)$ in the plasma core) have been achieved in W7-X with high-density plasmas and central ECRH. These measured $(E_r)$ profiles agree well with the neoclassical ambipolar $(E_r)$ predicted by the code SFINCS . This good agreement provides confidence in the validity of neoclassical calculations in high-density ion-root conditions, and enables initial studies on the role of neoclassical transport in the optimized high-density regime of W7-X. Profile measurements of electron temperature $(T_e)$, ion temperature $(T_i)$ and electron density $(n_e)$ along with approximations for the average value of $Z$ eff have been used as inputs to the sfincs code to calculate the ambipolar $E_r$ profile along with neoclassical ion and electron energy flux profiles $(Q$ NCi , $Q$ NCe $)$. Finally the total experimental energy input to the plasma from ECRH heating has been compared to the neoclassical energy fluxes to provide a first estimate for the fraction of transport that can be attributed to neoclassical processes in reactorrelevant high-density ion-root conditions.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Computers in Spaceflight: the NASA Experience

This book examines the computer systems used in actual spaceflight or in close support of it. Computer systems used in administration and in aeronautical and other research not directly related to spaceflight are ignored. Each chapter deals with either a specific program, such as Gemini or Apollo onboard computers, or a closely related set of systems, such as launch processing or mission control.. A glossary of computer terms is included.

assembly language↗

Geomagnetic Variability and Predictability

The Earth's magnetic field varies on time scales from seconds to millions of years. These variations can be measured directly by ground observatories and satellites, and indirectly through laboratories. They are from different electromagnetic processes in magnetosphere and ionosphere (external), ocean and crust (surface), and deep in the Earth's fluid outer core (internal). Of the measured magnetic signals, 95% is from the core, and is called the core field, or internal field. Variation of the core field, often called the geomagnetic secular variation (SV), is the manifestation of the magnetohydrodynamic processes in the core. Therefore, SV provides rich information on the core dynamical state that is then critical for understanding the geophysical mechanisms of the SV, the core-mantle interactions, and contribution of mass transport inside the core on Earth's gravity variation. Traditionally, the core state is probed via two independent methodologies: core flow inversion from the observed SV, and pure numerical dynamo simulation. The former is driven by observations, but does not include necessary interactions among physical variables; the latter is dynamically consistent, but is not constrained by any observation. Therefore, both are very limited in providing appropriate estimates of the core state. To avoid these limitations, a new approach, geomagnetic data assimilation, appears recently. In this approach, simulation results (model forecasts) are constantly corrected with observations, the corrected solutions (analysis), are then used as the initial conditions to make more accurate forecasts of future. Recent studies have demonstrated successfully that assimilation solutions are different from those of free running models. These new solutions are better estimates of the core state, and have been used to provide accurate prediction of SV for the period from 2010 to 2015. This prediction is part of the IGRF field model for international community applications.

Kuang, Weijia↗

Calibration of MAMBA and CRUD Sources Using Full-Core CTF+MAMBA

This report outlines a process for the deterministic calibration of MAMBA using the computational toolkit Dakota. The tools and processes for deterministic calibration have been built and are laid out in this report. While completing this milestone, issues emerged with MAMBA that resulted in delays. The consequences for these difficulties to the calibration process are briefly discussed. The report concludes with an outline of a path forward for Bayesian calibration. The Bayesian calibration will be performed next year. This process was laid out by Benjamin Collins, Robert Salko, and Adam Hetzler.

42 ENGINEERING↗