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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 523 records · Page 29
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NASA NTRS2016

Design of Superconducting Gravity Gradiometer Cryogenic System for Mars Mission

Measurement of a planets gravity field provides fundamental information about the planets mass properties. The static gravity field reveals information about the internal structure of the planet, including crustal density variations that provide information on the planets geological history and evolution. The time variations of gravity result from the movement of mass inside the planet, on the surface, and in the atmosphere. NASA is interested in a Superconducting Gravity Gradiometer (SGG) with which to measure the gravity field of a planet from orbit. An SGG instrument is under development with the NASA PICASSO program, which will be able to resolve the Mars static gravity field to degree 200 in spherical harmonics, and the time-varying field on a monthly basis to degree 20 from a 255 x 320 km orbit. The SGG has a precision two orders of magnitude better than the electrostatic gravity gradiometer that was used on the ESAs GOCE mission. The SGG operates at the superconducting temperature lower than 6 K. This study developed a cryogenic thermal system to maintain the SGG at the design temperature in Mars orbit. The system includes fixed radiation shields, a low thermal conductivity support structure and a two-stage cryocooler. The fixed radiation shields use double aluminized polyimide to emit heat from the warm spacecraft into the deep space. The support structure uses carbon fiber reinforced plastic, which has low thermal conductivity at cryogenic temperature and very high stress. The low vibration cryocooler has two stages, of which the high temperature stage operates at 65 K and the low temperature stage works at 6 K, and the heat rejection radiator works at 300 K. The study also designed a second option with a 4-K adiabatic demagnetization refrigerator (ADR) and two-stage 10-K turbo-Brayton cooler.

Li, X.↗
NASA NTRS2024

In-depth Analysis of LISA Pathfinder Performance Results: Time Evolution, Noise Projection, Physical Models, and Implications for LISA

We present an in-depth analysis of the LISA Pathfinder differential acceleration performance over the entire course of its science operations, spanning approximately 500 days. We find: (1) The evolution of the Brownian noise that dominates the acceleration amplitude spectral density (ASD), for frequencies f≳1 mHz, is consistent with the decaying pressure due to the outgassing of a single gaseous species. (2) Between f=36 μHz and 1 mHz, the acceleration ASD shows a 1/f tail in excess of the Brownian noise of almost constant amplitude, with ≃20% fluctuations over a period of a few days, with no particular time pattern over the course of the mission. (3) At the lowest considered frequency of f=18 μHz, the ASD significantly deviates from the 1/f behavior, because of temperature fluctuations that appear to modulate a quasistatic pressure gradient, sustained by the asymmetries of the outgassing pattern. We also present the results of a projection of the observed acceleration noise on the potential sources for which we had either a direct correlation measurement or a quantitative estimate from dedicated experiments. These sources account for approximately 40% of the noise power in the 1/f tail. Finally, we analyze the possible sources of the remaining unexplained fraction and identify the possible measures that may be taken to keep those under control in LISA.

M Armano↗
NASA NTRS2012

Measuring the Redshift Dependence of The Cosmic Microwave Background Monopole Temperature With Planck Data

We study the capability of Planck data to constrain deviations of the cosmic microwave background (CMB) blackbody temperature from adiabatic evolution using the thermal Sunyaev-Zeldovich anisotropy induced by clusters of galaxies. We consider two types of data sets depending on how the cosmological signal is removed: using a CMB template or using the 217 GHz map. We apply two different statistical estimators, based on the ratio of temperature anisotropies at two different frequencies and on a fit to the spectral variation of the cluster signal with frequency. The ratio method is biased if CMB residuals with amplitude approximately 1 microK or larger are present in the data, while residuals are not so critical for the fit method. To test for systematics, we construct a template from clusters drawn from a hydro-simulation included in the pre-launch Planck Sky Model. We demonstrate that, using a proprietary catalog of X-ray-selected clusters with measured redshifts, electron densities, and X-ray temperatures, we can constrain deviations of adiabatic evolution, measured by the parameter α in the redshift scaling T (z) = T0(1 + z)(sup 1−alpha), with an accuracy of sigma(sub alpha) = 0.011 in the most optimal case and with sigma alpha = 0.018 for a less optimal case. These results represent a factor of 2-3 improvement over similar measurements carried out using quasar spectral lines and a factor 6-20 with respect to earlier results using smaller cluster samples.

cosmic background radiation↗
NASA NTRSDate not supplied

Does Chirality Influence the Stability of Amino Acid –Cu Complexes in the Salt-Induced Peptide Formation Reaction? Insights from Density Functional Theory Calculations

The polymerization of amino acids into peptides and ultimately proteins is critical to evolution of life. Ribosomally-synthesized proteins are homochiral, composed entirely of L-amino acids. Abiotic syntheses of amino acids, however, produce racemic mixtures(equal amounts of L and D enantiomers), meaning that the pool of monomers available for abiotic protein synthesis would be racemic or nearly so. There are no prebiotically plausible mechanisms known to yield homochiral peptides from racemic pools of amino acids. While some mechanisms capable of producing or amplifying enantiomeric excesses have been observed, these excesses are small or not applicable to all biologically relevant amino acids. As a result, a prebiotically-feasible mechanism to create enantiopure pools of amino acids has not been identified. However, it is not clear that these enantio-enriched or enantiopure pools are necessary to produce homochiral peptides. Steric and electronic effects, or a combination of both, may influence how different enantiomers interact with each other, potentially leading to homochiral peptides from racemic mixtures. Here, we use density functional theory (DFT) calculations to assess the stability of homochiral and heterochiral reactive complexes produced during polymerization via the salt-induced peptide formation (SIPF) reaction. Experimental studies of the SIPF reaction have shown that it enables the formation of peptides under diverse environmental conditions, making it a plausible pathway to peptide formation on early Earth. In the SIPF reaction, NaCl acts as a condensation reagent while a divalent metal cation, primarily Cu2+, facilitates polymerization by complexing and activating amino acids forming a monochlorocuprate complex. To assess if hetero-or homochiral monochlorocuprate complexes were energetically favored, we compared the stability of LL, DD, and LD enantiomers of Cu2+–(alanine)2and Cu2+–(valine) 2 complexes. Gaussian 09 density DFT energy-minimization calculations were made for each Cu –amino acid complex in the cis and trans configuration. Models were energy minimized using the BH and HLYP/6-31++G(d,p) level of theory and free energies were compared to determine the most stable configuration.

A C Fox↗
NASA NTRS1990

Radial evolution of solar wind thermal electron distributions due to expansion and collisions

ISEE 3 electron observations near 1 AU show that the solar wind thermal electron temperature anisotropy, T(parallel)/T(perpendicular), is typically 1.0 to 1.5, with densest distributions most nearly isotropic, but is sometimes much higher when density is low. For a small observational subset characterized by high density and low bulk speed, T(perpendicular) can exceed T(parallel). Based on these and other observations, a simple model is proposed for radial evolution of thermal electrons in a structureless solar wind under the influence of Coulomb collisions and geometric expansion in a spiral interplanetary magnetic field. The model, which satisfactorily explains the 1 AU observations, shows that the evolution of electron temperature and T(parallel)/T(perpendicular) is controlled by plasma density, flow speed, and initial temperature, with density the most important factor. The model makes predictions for radial distances other than 1 AU and for high solar latitudes.

Phillips, J. L.↗
NASA NTRS1993

Neutral hydrogen at the present epoch: A constraint on the evolution of high redshift systems

Damped Lyman-alpha and metal absorption lines in the spectra of quasars indicate the presence of intervening gas-rich systems at high redshift (z greater than 2). These systems have characteristic size scales, velocity dispersions, and neutral hydrogen column densities (N(H1)) similar to present day spirals and are thus thought to be their progenitors. Constraints on galaxy evolution can be derived by comparing the H1 properties of high redshift systems to the present galaxy population. Good observational statistics on high redshift absorbers specify the number of these systems along the line of sight as a function of N(H1), the column density of neutral hydrogen per absorber. Similar statistics for nearby (z = 0) galaxies of which spirals are the only gas-rich systems that provide a significant cross-section for the interception of light from quasars is derived.

Rao, Sandhya↗
DOE OSTI2024

Heat transfer and transport property contrast effects on the compressible Rayleigh-Taylor instability

In extreme environments, the Rayleigh-Taylor instability (RTI) may occur under large variations in density and temperature and with fluid transport properties strongly dependent on temperature. Direct numerical simulations of the 3D fully compressible RTI are conducted, examining the idealized configuration of a hotter, less dense fluid pushing against a colder, denser fluid. Various temperature ratios and transport property configurations are explored to examine how heat conduction, large variations in transport properties, and sudden changes in transport properties can affect the evolution of the mixing layer. Nonuniform fluid expansion and contraction induced by heat transfer can significantly affect local density differences and overall instability growth, causing profile asymmetries about the initial interface for flow and mixing statistics. The departures from classical self-similar development of the instability along with misalignment between regions of mixing and regions of most intense turbulent activity caused by both heat transfer and transport property contrasts are examined. After sudden changes in fluid transport properties, which may occur as a result of rapid heating (e.g., in inertial confinement fusion), the flow quickly responds and begins to relax towards quasi-self-similar late-time evolution. For many dynamical quantities such as vorticity and dissipation, this late-time evolution resembles that of the configuration that already started with the final transport property magnitudes, suggesting that these quantities depend only on the transport properties and not on past flow history, provided that the density field distributions for the flows remain similar. On the other hand, the mixing evolution after the transport property change is unique, implying that both property magnitudes and previous history are impactful on the mixing. In conclusion, these simulations demonstrate how various temperature-related effects are extremely important to consider in compressible RTI flows with large temperature variations.

42 ENGINEERING↗
NASA NTRS1977

Clusters of galaxies

Observational properties of clusters of galaxies and some theoretical interpretations are reviewed. The major subjects of the review include catalogs of clusters, the static properties of rich clusters, cluster dynamics, X-ray emission from clusters of galaxies, and cluster radio emission. Observed static properties discussed are: richness, classification schemes, galactic content, cD galaxies, density profiles, sizes, and the optical luminosity function. Several characteristic time scales of clusters of galaxies are examined along with mass segregation, the dynamical evolution of clusters, cluster masses, mass-to-light ratios, the missing-mass problem, and the mean galactic and cluster mass densities in the universe. The main characteristics of clusters that contain X-ray emission are summarized, emphasizing the relation of the X-ray emission to optical properties. The most important properties of cluster radio emission are outlined, the relation of this emission to the other cluster properties studied is indicated, and evidence suggesting the influence of an intracluster gas on the radio galaxies and their relativistic electrons is noted.

Bahcall, N. A.↗
NASA NTRS1978

Diagrammatic analysis of the density operator for nonlinear optical calculations Pulsed and CW responses

In the present paper a diagrammatic analysis of the density operator for the evaluation of nonlinear optical quantities is considered. The present approach extends earlier diagrammatic analysis by treating the time evolution of both the wave function and its complex conjugate. Time-ordered graphs result, each of which corresponds to a term in the density matrix. Examples involving the third-order susceptibility are discussed for both monochromatic and pulse excitation. In particular coherent rotational transient birefringence is discussed. The diagrams provide a convenient means by which nonlinear optical processes can be precisely defined and the susceptibility readily evaluated.

Yee, T. K.↗
NASA NTRS1992

Contradictory clues as to the origin of the Martian moons

The meager available information that is pertinent to the origin and evolution of the Martian satellites is contradictory. The known physical properties of the Martian moons (density, albedo, color and spectral reflectivity) are similar to those of many C-type asteroids, the dark 'carbonaceous' objects abundant in the outer belt but scarce near Mars; thus this line of physical evidence suggests that Phobos and Deimos are captured bodies. In contrast, calculated histories of orbital evolution due to tides in the planet and in the satellites indicate that these small craggy moons originated on nearly circular, uninclined orbits not far from their current positions; hence dynamicists prefer an origin in circum-Martian orbit. Ways are described in which these apparently contradictory viewpoints may be reconciled, although a definitive answer to the origin of the Martian satellites will almost surely have to await in situ measurements.

Burns, Joseph A.↗
DOE OSTI2024

Dynamical friction in dark matter superfluids: The evolution of black hole binaries

Abstract The theory of superfluid dark matter is characterized by self-interacting sub-eV particles that thermalize and condense to form a superfluid core in galaxies. Massive black holes at the center of galaxies, however, modify the dark matter distribution and result in a density enhancement in their vicinity known as dark matter spikes. The presence of these spikes affects the evolution of binary systems by modifying their gravitational wave emission and inducing dynamical friction effects on the orbiting bodies. In this work, we assess the role of dynamical friction for bodies moving through a superfluid core enhanced by a central massive black hole. As a first step, we compute the dynamical friction force experienced by bodies moving in a circular orbit. Then, we estimate the gravitational wave dephasing of the binary, showing that the effect of the superfluid drag force is beyond the reach of space-based experiments like LISA, contrarily to collisionless dark matter, therefore providing an opportunity to distinguish these dark matter models.

Astronomy & Astrophysics↗
NASA NTRS2011

Enthalpy-Based Thermal Evolution of Loops: II. Improvements to the Model

This paper further develops the zero-dimensional (0D) hydrodynamic coronal loop model "Enthalpy-based Thermal Evolution of Loops" (EBTEL) originally proposed by Klimchuk et al (2008), which studies the plasma response to evolving coronal heating. It has typically been applied to impulsive heating events. The basis of EBTEL is the modelling of mass exchange between the corona and transition region and chromosphere in response to heating variations, with the key parameter being the ratio of transition region to coronal radiation. We develop new models for this parameter that now include gravitational stratification and a physically motivated approach to radiative cooling. A number of examples are presented, including nanoflares in short and long loops, and a small flare. It is found that while the evolution of the loop temperature is rather insensitive to the details of the model, accurate tracking of the density requires the inclusion of our new features. In particular, we are able to now obtain highly over-dense loops in the late cooling phase and decreases to the coronal density arising due to stratification. The 0D results are compared to a 1D hydro code (Hydrad). The agreement is acceptable, with the exception of the flare case where some versions of Hydrad can give significantly lower densities. This is attributed to the method used to model the chromosphere in a flare. EBTEL is suitable for general use as a tool for (a) quick-look results of loop evolution in response to a given heating function and (b) situations where the modelling of hundreds or thousands of elemental loops is needed. A single run takes a few seconds on a contemporary laptop.

Cargill, P. J.↗
NASA NTRS1993

Thermal inertia and radar reflectivity of the Martian north polar ERG: Low-density aggregates

The north polar layered deposits on Mars appear to be the source of the dark material that comprises the north polar erg. The physical properties and chemical composition of the erg material therefore have important implications for the origin and evolution of the Martian layered deposits. Viking bistatic radar and infrared thermal mapping (IRTM) data indicate that the bulk density of the erg material is lower than that of the average Martian surface. These data are consistent with hypotheses involving formation of filamentary sublimation residue (FSR) particles from erosion of the layered deposits. The color and albedo of the erg and of the layered deposits, and the presence of magnetic material on Mars, suggest that the dark material is composed of low-density aggregates of magnetic dust grains, perhaps similar to FSR particles created in laboratory experiments.

Herkenhoff, K. E.↗
DOE OSTI2025

Off-Equilibrium Reactivity of Boron-Enriched Metal Diboride Surfaces in Electroreduction Conditions

Boron-based materials, featuring B-dependent reactivity and diverse phases, are emerging as promising catalyst systems. However, the catalytic mechanism on many borides remains poorly understood due to complex surface reconstructions under reaction conditions. Here, we investigate the MoB 2 surface in conditions of hydrogen evolution reaction in acidic media, using grand canonical global optimization, grand canonical density functional theory, ab initio molecular dynamics, free energy surface sampling, and an analytical model for electrochemical barrier evaluation. We propose a boron-enrichment strategy to tune the surface reactivity of the hexagonal face of MoB 2 . We reveal the dynamic nature of the B-enriched surface under H coverage and kinetic trapping of the system in the metastable regime with an extensive examination of the deactivation pathways. The metastable center B site on B-enriched surfaces, featuring buckled-up configuration and a usual relaxation effect, is found to be highly active toward HER via the Volmer–Heyrovsky mechanism. In conclusion, this work demonstrates how off-equilibrium behaviors can arise from the interplay between adsorbate coverage and surface reconstruction on a seemingly simple surface, and we present a theoretical framework and computational workflows to address these behaviors, along with other realistic complexities, in kinetics simulations.

Adsorption↗
NASA NTRS1995

The Hubble Space Telescope quasar absorption line key project. v. redshift evolution of lyman limit absorption in the spectra of a large sample of quasars

Using a sample of 119 QSOs, containing objects we have selected having previously available high quality ground-based and IUE spectral observations, together with Hubble Space Telescope (HST) observations of 26 QSOs from Bahcall et al. (1993, 1995) and Impey et al. (1995) and new optical observations of 41 objects by Steidel & Sargent (1995), we study the redshift evolution of Lyman limit absorption systems (LLSs; tau greater than 1.0) over the reshift range 0.32 less than or equal to z(sub LLS) less than or equal to 4.11. The HST observations significantly improve the determination of the low redshift (0.4 less than or equal to z(sub LLS) less than or equal to 1.4) distribution. We find the effect which may have been responsible for the apparent strong evolution at a(sub LLS) greater than or equal to 2.5 found by Lanzetta (1991), which led him to consider a broken, not single power law as a better description of the redshift distribution of LLSs. After removing objects which may bias our sample, leaving a total of 169 QSOs, we find the distribution is well described by a single power law, and obtain for the number density as a function of redshift the form N(z) = N(sub 0)(1 + z)(exp gamma) with gamma = 1.50 =/- 0.39 and N(sub 0) = 0.25(sup -0.10)(sub +0.17), consistent with a constant comoving density of absorbers in a Firedmann universe with q(sub 0) = 0 but indicating evolution if q(sub 0) = 1/2.

Stengler-Larrea, Erik A.↗
DOE OSTI2025

Establishing defect-property relationships for 2D-nanomaterials (Final technical report)

Studies of new families of two-dimensional nanomaterials (2DNMs) have established that they possess unique properties that diverge from those of their bulk counterparts. This project aimed to determine how tolerant 2DNMs are to extreme photon and particle fluxes and to identify the mechanisms governing their radiation response. Early work indicated that graphene is not as representative of other 2DNMs as previously assumed; however, the origin of this difference remained unclear. To address these knowledge gaps, this project investigated the physical processes occurring at multiple length scales in transition metal dichalcogenides (TMDs) and quantified their structural stability and property evolution under far-from-equilibrium conditions. In-situ and ex-situ ion and electron irradiations were performed to directly control and monitor defect formation in TMDs. Complementary density functional theory (DFT) and molecular dynamics (MD) simulations were employed to elucidate the mechanisms of defect generation and evolution. The outcomes of this work established mechanistic understanding of irradiation-induced defect formation in 2DNMs, quantified the radiation tolerance of TMDs, and built a fundamental knowledge base for correlating defect structures with material properties. Collectively, these results provide new insights into the stability of low-dimensional materials in extreme environments and enable the predictive design of radiation-tolerant 2DNMs.

2D materials↗
NASA NTRS1993

A representation for the turbulent mass flux contribution to Reynolds-stress and two-equation closures for compressible turbulence

The turbulent mass flux, or equivalently the fluctuating Favre velocity mean, appears in the first and second moment equations of compressible kappa-epsilon and Reynolds stress closures. Mathematically it is the difference between the unweighted and density-weighted averages of the velocity field and is therefore a measure of the effects of compressibility through variations in density. It appears to be fundamental to an inhomogeneous compressible turbulence, in which it characterizes the effects of the mean density gradients, in the same way the anisotropy tensor characterizes the effects of the mean velocity gradients. An evolution equation for the turbulent mass flux is derived. A truncation of this equation produces an algebraic expression for the mass flux. The mass flux is found to be proportional to the mean density gradients with a tensor eddy-viscosity that depends on both the mean deformation and the Reynolds stresses. The model is tested in a wall bounded DNS at Mach 4.5 with notable results.

Ristorcelli, J. R.↗