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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 523 records · Page 29
All sourcesNASA NTRSDOE OSTI
NASA NTRS2003

The Feasibility of Using a Galvanic Cell Array for Corrosion Detection and Solution Monitoring

An initial investigation into the response of the individual galvanic couples was conducted using potentiodynamic polarization measurements of solutions under conditions of varying corrosivity. It is hypothesized that the differing electrodes may provide a means to further investigate the corrosive nature of the analyte through genetic algorithms and pattern recognition techniques. The robust design of the electrochemical sensor makes its utilization in space exploration particularly attractive. Since the electrodes are fired on a ceramic substrate at 900 C, they may be one of the most rugged sensors available for the anticipated usage.

Kolody, Mark↗
NASA NTRS1996

Array of micro-machined mass energy micro-filters for charged particles

An energy filter for charged particles includes a stack of micro-machined wafers including plural apertures passing through the stack of wafers, focusing electrodes bounding charged particle paths through the apertures, an entrance orifice to each of the plural apertures and an exit orifice from each of the plural apertures and apparatus for biasing the focusing electrodes with an electrostatic potential corresponding to an energy pass band of the filter.

Stalder, Roland E.↗
DOE OSTI2015

Understanding Charge Transfer in Carbon Nanotube–Fullerene Bulk Heterojunctions

Semiconducting single-walled carbon nanotube/fullerene bulk heterojunctions exhibit unique optoelectronic properties highly suitable for flexible, efficient, and robust photovoltaics and photodetectors. We investigate charge-transfer dynamics in inverted devices featuring a polyethylenimine-coated ZnO nanowire array infiltrated with these blends and find that trap-assisted recombination dominates transport within the blend and at the active layer/nanowire interface. We find that electrode modifiers suppress this recombination, leading to high performance.

36 MATERIALS SCIENCE↗
NASA NTRS1989

Gray-Scale Processing For Tracking Of Welds

Digital analysis of video-image-processing system contributes to automation of weld-seam tracking. Makes no contact with seam. Small television camera views seam just ahead of point currently being welded. Arc provides illumination. Periodically frame grabber digitizes video image and stores in computer memory as gray-scale values. Seam located by analyzing Hough-transform arrays of derivatives of digitally-filtered image data. Information on location and orientation of seam used as feedback by welding robot to correct deviations of electrode from seam as welding continues.

Gutow, David A.↗
NASA NTRS2004

Miniaturized multiplex label-free electronic chip for rapid nucleic acid analysis based on carbon nanotube nanoelectrode arrays

BACKGROUND: Reducing cost and time is the major concern in clinical diagnostics, particularly in molecular diagnostics. Miniaturization technologies have been recognized as promising solutions to provide low-cost microchips for diagnostics. With the recent advancement in nanotechnologies, it is possible to further improve detection sensitivity and simplify sample preparation by incorporating nanoscale elements in diagnostics devices. A fusion of micro- and nanotechnologies with biology has great potential for the development of low-cost disposable chips for rapid molecular analysis that can be carried out with simple handheld devices. APPROACH: Vertically aligned multiwalled carbon nanotubes (MWNTs) are fabricated on predeposited microelectrode pads and encapsulated in SiO2 dielectrics with only the very end exposed at the surface to form an inlaid nanoelectrode array (NEA). The NEA is used to collect the electrochemical signal associated with the target molecules binding to the probe molecules, which are covalently attached to the end of the MWNTs. CONTENT: A 3 x 3 microelectrode array is presented to demonstrate the miniaturization and multiplexing capability. A randomly distributed MWNT NEA is fabricated on each microelectrode pad. Selective functionalization of the MWNT end with a specific oligonucleotide probe and passivation of the SiO2 surface with ethylene glycol moieties are discussed. Ru(bpy)2+ -mediator-amplified guanine oxidation is used to directly measure the electrochemical signal associated with target molecules. SUMMARY: The discussed MWNT NEAs have ultrahigh sensitivity in direct electrochemical detection of guanine bases in the nucleic acid target. Fewer than approximately 1000 target nucleic acid molecules can be measured with a single microelectrode pad of approximately 20 x 20 microm2, which approaches the detection limit of laser scanners in fluorescence-based DNA microarray techniques. MWNT NEAs can be easily integrated with microelectronic circuitry and microfluidics for development of a fully automated system for rapid molecular analysis with minimum cost.

Carbon↗
DOE OSTI2020

Enhanced Rate Capability of Ion‐Accessible Ti 3 C 2 T x ‐NbN Hybrid Electrodes

Abstract Although 2D Ti 3 C 2 T x is a good candidate for supercapacitors, the restacking of nanosheets hinders the ion transport significantly at high scan rates, especially under practical mass loading (>10 mg cm −2 ) and thickness (tens of microns). Here, Ti 3 C 2 T x ‐NbN hybrid film is designed by self‐assembling Ti 3 C 2 T x with 2D arrays of NbN nanocrystals. Working as an interlayer spacer of Ti 3 C 2 T x , NbN facilitates the ion penetration through its 2D porous structure; even at extremely high scan rates. The hybrid film shows a thickness‐independent rate performance (almost the same rate capabilities from 2 to 20 000 mV s −1 ) for 3 and 50 µm thick electrodes. Even a 109 µm thick Ti 3 C 2 T x ‐NbN electrode shows a better rate performance than 25 µm thick pure Ti 3 C 2 T x electrodes. This method may pave a way to controlling ion transport in electrodes composed of 2D conductive materials, which have potential applications in high‐rate energy storage and beyond.

Wang, Hao↗
DOE OSTI2013

Manipulation of the magnetron orbit of a positron cloud in a Penning trap

We describe a simple and versatile method to manipulate the amplitude of the magnetron orbit of ions stored in a Penning trap, applied here to a cloud of low energy positrons. By applying a pulsed voltage to a split electrode in the trap, which is normally used for rotating wall compression of the particles, the size of the magnetron orbit can be changed at will. The modified orbit has been shown to be stable for many magnetron periods. The technique could find use in applications which require off-axis ejection of particles, for instance in the filling of arrays of traps for multicell positron storage.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS2005

CdZnTe Image Detectors for Hard-X-Ray Telescopes

Arrays of CdZnTe photodetectors and associated electronic circuitry have been built and tested in a continuing effort to develop focal-plane image sensor systems for hard-x-ray telescopes. Each array contains 24 by 44 pixels at a pitch of 498 m. The detector designs are optimized to obtain low power demand with high spectral resolution in the photon- energy range of 5 to 100 keV. More precisely, each detector array is a hybrid of a CdZnTe photodetector array and an application-specific integrated circuit (ASIC) containing an array of amplifiers in the same pixel pattern as that of the detectors. The array is fabricated on a single crystal of CdZnTe having dimensions of 23.6 by 12.9 by 2 mm. The detector-array cathode is a monolithic platinum contact. On the anode plane, the contact metal is patterned into the aforementioned pixel array, surrounded by a guard ring that is 1 mm wide on three sides and is 0.1 mm wide on the fourth side so that two such detector arrays can be placed side-by-side to form a roughly square sensor area with minimal dead area between them. Figure 1 shows two anode patterns. One pattern features larger pixel anode contacts, with a 30-m gap between them. The other pattern features smaller pixel anode contacts plus a contact for a shaping electrode in the form of a grid that separates all the pixels. In operation, the grid is held at a potential intermediate between the cathode and anode potentials to steer electric charges toward the anode in order to reduce the loss of charges in the inter-anode gaps. The CdZnTe photodetector array is mechanically and electrically connected to the ASIC (see Figure 2), either by use of indium bump bonds or by use of conductive epoxy bumps on the CdZnTe array joined to gold bumps on the ASIC. Hence, the output of each pixel detector is fed to its own amplifier chain.

Chen, C. M. Hubert↗
NASA NTRS2004

Fabrication of MEMS-Based Microshutter Arrays for Optical Transmission Selection

A MEMS-based programmable aperture mask is under development at the NASA Goddard Space Flight Center. Termed the Microshutter (u-shutter) Array, the device will be used to control the transmission of light, with both high efficiency and contrast, to a multi-object spectrometer on the James Webb Space Telescope. Fabrication of the p-shutter array employs several novel designs and processing techniques. The current generation of micro-shutters consists of 128x64 pixel arrays with unit cell dimensions of 100x200 microns. Shutters are patterned in silicon nitride and sit on a 100 micron silicon frame that is DRIE etched below each shutter. The front and back sides of the device are shown. A magnetic cobalt-iron alloy patterned on top of the shutter allows it to be actuated 90 degrees out-of-plane, into the frame, by an external magnetic field. An electrode on the shutter and a vertical electrode on the sidewall of the frame, approximately 90pm deep, allow them to be electrostatically latched in their rotated position. The vertical electrode is deposited and patterned on the backside of the frame in a single step using a directionally controlled evaporation. Individual addressing of shutters for electrostatic latching is accomplished via a crosspoint addressing scheme, with no on-chip active components. A portion of an array with shutters in the open, latched, and closed positions is shown. Light loss at shutter edges is minimized by an overhanging aluminum light-shield that is anchored to the frame. A photoresist sacrificial layer is used to raise the light-shield up and over the 2 micron gap that surrounds each pixel. After completion, arrays are subjected to life cycle, environmental and optical testing. Fabricated devices have survived 10(exp 6) actuation cycles at both room and cryogenic temperatures and a 14g rms launch-simulation test. Optical testing has shown contrast measurements between open and closed shutters up to 10000:1.

Lynch, Bernard A.↗
DOE OSTI2018

Electrochemical Applications of Microphase-Separated Block Copolymer Thin Films

In this work, we discuss electrochemical applications of electrode-supported thin films derived from microphase-separated block copolymers (BCPs). In contrast to conventional homopolymers used for electrode modification, BCPs afford periodic nanoscale structures (microdomains) of uniform dimensions (5-100 nm) and predictable morphologies, which can be controlled by adjusting the lengths of individual homopolymer segments. BCPs usable for electrochemical applications consist of two or more segments that form solute-permeable, redox-active or etchable microdomains and a chemically inert matrix. The resulting microdomains afford nanoscale molecular/charge transport pathways toward the underlying electrode, whereas the matrix serves as a scaffold to improve film stability in a solution. In conclusion, these polymeric thin films provide a unique means for fabricating nanowire arrays via template-based electrochemical synthesis, designing electrochemical sensors with unique selectivity, and constructing electrochemically-tunable functional materials.

36 MATERIALS SCIENCE↗
DOE OSTI2014

Calculating electronic tunnel currents in networks of disordered irregularly shaped nanoparticles by mapping networks to arrays of parallel nonlinear resistors

We have shown both theoretically and experimentally that tunnel currents in networks of disordered irregularly shaped nanoparticles (NPs) can be calculated by considering the networks as arrays of parallel nonlinear resistors. Each resistor is described by a one-dimensional or a two-dimensional array of equal size nanoparticles that the tunnel junction gaps between nanoparticles in each resistor is assumed to be equal. The number of tunnel junctions between two contact electrodes and the tunnel junction gaps between nanoparticles are found to be functions of Coulomb blockade energies. In addition, the tunnel barriers between nanoparticles were considered to be tilted at high voltages. Furthermore, the role of thermal expansion coefficient of the tunnel junction gaps on the tunnel current is taken into account. The model calculations fit very well to the experimental data of a network of disordered gold nanoparticles, a forest of multi-wall carbon nanotubes, and a network of few-layer graphene nanoplates over a wide temperature range (5-300 K) at low and high DC bias voltages (0.001 mV–50 V). Our investigations indicate, although electron cotunneling in networks of disordered irregularly shaped NPs may occur, non-Arrhenius behavior at low temperatures cannot be described by the cotunneling model due to size distribution in the networks and irregular shape of nanoparticles. Non-Arrhenius behavior of the samples at zero bias voltage limit was attributed to the disorder in the samples. Unlike the electron cotunneling model, we found that the crossover from Arrhenius to non-Arrhenius behavior occurs at two temperatures, one at a high temperature and the other at a low temperature.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
NASA NTRS2004

Ultrasensitive Label-free Electronic Chip for DNA Analysis Using Carbon Nanotube Nanoelectrode Arrays

There is a strong need for faster, cheaper, and simpler methods for nucleic acid analysis in today s clinical tests. Nanotechnologies can potentially provide solutions to these requirements by integrating nanomaterials with biofunctionalities. Dramatic improvement in the sensitivity and multiplexing can be achieved through the high-degree miniaturization. Here, we present our study in the development of an ultrasensitive label-free electronic chip for DNA/RNA analysis based on carbon nanotube nanoelectrode arrays. A reliable nanoelectrode array based on vertically aligned multi-walled carbon nanotubes (MWNTs) embedded in a SiO2 matrix is fabricated using a bottom-up approach. Characteristic nanoelectrode behavior is observed with a low-density MWNT nanoelectrode array in measuring both the bulk and surface immobilized redox species. The open-end of MWNTs are found to present similar properties as graphite edge-plane electrodes, with a wide potential window, flexible chemical functionalities, and good biocompatibility. A BRCA1 related oligonucleotide probe with 18 bases is covalently functionalized at the open ends of the MWNTs and specifically hybridized with an oligonucleotide target as well as a PCR amplicon. The guanine bases in the target molecules are employed as the signal moieties for the electrochemical measurements. Ru(bpy)3(2+) mediator is used to further amplify the guanine oxidation signal. This technique has been employed for direct electrochemical detection of label-free PCR amplicon through specific hybridization with the BRCAl probe. The detection limit is estimated to be less than approximately 1000 DNA molecules, approaching the limit of the sensitivity by laser-based fluorescence techniques in DNA microarray. This system provides a general electronic platform for rapid molecular diagnostics in applications requiring ultrahigh sensitivity, high-degree of miniaturization, simple sample preparation, and low- cost operation.

Li, Jun↗
NASA NTRS2012

Radiation Shielding System Using a Composite of Carbon Nanotubes Loaded with Electropolymers

Single-wall carbon nanotubes (SWCNTs) coated with a hydrogen-rich, electrically conducting polymer such as polyethylene, receive and dissipate a portion of incoming radiation pulse energy to electrical signals that are transmitted along the CNT axes, and are received at energy-dissipating terminals. In this innovation, an array of highly aligned nanowires is grown using a strong electric field or another suitable orientation procedure. Polyethylene (PE), polymethymlethacrylate (PMMA), or other electrically conducting polymer is spin-coated onto the SWCNTs with an average thickness of a few hundred nanometers to a few tenths of micrometers to form a PE/SWCNT composite. Alternatively, the polymer is spin-coated onto the nanowire array or an anodized alumina membrane (AAM) to form a PE/metal core shell structure, or PE can be electropolymerized using the SWCNTs or the metal nanowires as an electrode to form a PE/SWCNT core shell structure. The core shell structures can be extruded as anisotropic fibers. A monomer can be polymerized in the presence of SWCNTs to form highly cross-linked PE/SWCNT films. Alternatively, Pb colloid solution can be impregnated into a three-dimensional PE/SWCNT nanostructure to form a PW/SWCNT/Pb composite structure. A face-centered cubic (FCC) arrangement provides up to 12 interconnection channels connected to each core, with transverse channel dimensions up to 20 nm, with adequate mechanical compressive strength, and with an associated electrical conductivity of around 3 Seimens/cm for currents ranging from 0.01 to 10 mA. This threedimensional nanostructure is used as a host material to house appropriate radiation shielding material such as hydrogen- rich polymer/CNT structures, metal nanoparticles, and nanowires. Thicknesses of this material required to attenuate 10 percent, 50 percent, and 90 percent of an incident beam (gamma, X-ray, ultraviolet, neutron, proton, and electron) at energies in the range of 0 440 MeV are being determined, for example, by measuring fluence rate reduction. For example, a radiation field arrives first at an exposed surface of the innovation and produces an associated first electric field within the metal-like fingers of the three-dimensional nanostructure. This field is intensified near the exposed tips of the fingers, and this intensified field generates an intensified second electric field near the adjacent exposed tips of the coated CNSs. This generates an associated electrical current in the CNSs, and the associated electropolymer coating. The current is received by the second substrate transport component and is transported to the dissipation mechanism located contiguously to the second substrate.

McKay, Chris↗
DOE OSTI2012

P25 niblet-like coated on large void space TiO{sub 2} nanotubes arrays for high-rate charge-collection and improved photoconversion efficiency

A niblet-like P25-coated large void space TiO{sub 2} nanotubes arrays (PCTs) has been synthesized by decorating P25 nanoparticles on a rapidly-synthesized large void space TiO{sub 2} nanotube arrays (LTAs) with an appropriate hydrothermal treatment approach in a Teflon-lined stainless steel autoclave. Some key factors and probable synthetic mechanisms have been investigated to obtain an optimal route. Exhilaratingly, the as-synthesized PCTs and LTAs show impressive morphologies, structures and very large void space. And the most important is that, compared with LTAs, the decorated PCTs demonstrates significantly improved dye loading and high-rate charge-collection capability and thus leads to a more than double of the solar cell efficiency than that of LTAs (from 1.46% of LTAs to 3.00% of PCTs under simulated AM 1.5 conditions in our case). - Graphical abstract: The top view and cross-section SEM images of obtained electrode materials (LTAs and PCTs), with the schematic diagram (on the right) showing the kinetic advantages of the PCTs in charge collection and transmission. Highlights: Black-Right-Pointing-Pointer A large void space TiO{sub 2} nanotubes arrays (LTAs) was fabricated in not more than 12 h. Black-Right-Pointing-Pointer A niblet-like P25-coated void space TiO{sub 2} nanotubes arrays (PCTs) has been synthesized based on the LTAs. Black-Right-Pointing-Pointer Some key factors, probable synthetic mechanisms and optimal synthetic route are investigated. Black-Right-Pointing-Pointer The PCTs and LTAs show impressive morphologies, structures and greatly improved dye loading capability. Black-Right-Pointing-Pointer The PCTs shows enhanced charge-collection and light scattering properties and double solar cell efficiency.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2019

Synergistic Doping and Intercalation: Realizing Deep Phase Modulation on MoS 2 Arrays for High-Efficiency Hydrogen Evolution Reaction

A synergistic N doping plus PO 4 3- intercalation strategy is used to induce high conversion (ca. 41%) of 2H-MoS 2 into 1T-MoS, which is much higher than single N doping (ca. 28 %) or single PO 4 3- intercalation ca. 10%). A scattering mechanism is proposed to illustrate the synergistic phase transformation from the 2H to the 1T phase, which was confirmed by synchrotron radiation and.spherical aberration TEM. To further enhance reaction kindies, the designed (N, PO 4 3- )-MoS 2 nanosheds are combined with conductive vertical graphene (VG) skeleton forming binder-free arrays fir high efficiencyhydrogen evolution reaction (HER). Owing 10 the decreased band gap, lower d-band censer, and smaller hydrogen adsorption/desorption energy, the designed (NPO 4 3- )-MoSJVG electrode shows excellent HER perfor mance with a lower Tafel slope and overpotential than N-MoS 2 /VG, PO 4 3- -MoS 2 /VG counterparts, and other Mo-base catalysts in the literature.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1981

Radiatively coupled thermionic power system concept

It is shown that thermionic converters at moderate emitter temperatures of about 1600 K can be designed for a radiatively coupled 100 kWe device. A nuclear reactor is a primary heat source, with heat pipes extracting heat from the reactor and distributing it over a large surface opposite an array of thermionic energy converters. The radiative heat transfer across the vacuum gap heats up the thermionic emitters, and excess heat from the converters is radiated from the collector electrodes to the vacuum of space; the heat transfer is controlled by the energy density to be transferred, and by the temperature differential between the heat source and the heat receiver. It is concluded that this system achieves isolation of power converter modules from the heat source, elimination of additional radiators, and reduction of converter dimensions.

Shimada, K.↗