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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 523 records · Page 29
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

Near-ultraviolet scattering properties of Jupiter

Voyager 2 photometric observations of Jupiter at four phase angles between 20 and 80 deg and at various illumination angles are used to determine the altitude distribution and scattering properties of the material responsible for Jupiter's low geometric albedo at 2400 A. Center-to-limb measurements at midlatitudes indicate that most of the absorbing material lies deeper than 100 mbar, while the latitudinal distribution of stratospheric absorbers suggests that energy deposition from the magnetosphere is important in the formation of the absorbers. Scattering properties of model atmospheres containing three distinct aerosol size distributions are examined, and an upper limit to the column abundance of particles larger than the 0.05 micron radius in the north tropical zone and equatorial belt are derived. Rayleigh scattering fits the variation of intensity with phase angles between 20 and 80 deg better than any of the considered particle phase functions, although the Rayleigh scattering from the top 100 mbar obscures effects due to scattering from deeper absorbing particles.

West, R. A.↗
DOE OSTI2024

Competing itinerant and local spin interactions in kagome metal FeGe

The combination of a geometrically frustrated lattice, and similar energy scales between degrees of freedom endows two-dimensional Kagome metals with a rich array of quantum phases and renders them ideal for studying strong electron correlations and band topology. The Kagome metal, FeGe is a noted example of this, exhibiting A-type collinear antiferromagnetic (AFM) order at T N ≈ 400 K, then establishes a charge density wave (CDW) phase coupled with AFM ordered moment below T CDW ≈ 110 K, and finally forms a c-axis double cone AFM structure around T Canting ≈ 60 K. Here we use neutron scattering to demonstrate the presence of gapless incommensurate spin excitations associated with the double cone AFM structure of FeGe at temperatures well above T Canting and T CDW that merge into gapped commensurate spin waves from the A-type AFM order. Commensurate spin waves follow the Bose factor and fit the Heisenberg Hamiltonian, while the incommensurate spin excitations, emerging below T N where AFM order is commensurate, start to deviate from the Bose factor around T CDW , and peaks at T Canting . This is consistent with a critical scattering of a second order magnetic phase transition with decreasing temperature. By comparing these results with density functional theory calculations, we conclude that the incommensurate magnetic structure arises from the nested Fermi surfaces of itinerant electrons and the formation of a spin density wave order.

36 MATERIALS SCIENCE↗
DOE OSTI2024

A discretized representation for Monte Carlo simulation of deformed semiflexible chains

In this study, we present a novel orientation discretization approach based on the rhombic triacontahedron for Monte Carlo simulations of semiflexible polymer chains, aiming at enhancing structural analysis through rheo-small-angle scattering (rheo-SAS). Our approach provides a more accurate representation of the geometric features of semiflexible chains under deformation, surpassing the capabilities of traditional lattice structures. Validation against the Kratky–Porod chain system demonstrated superior consistency, underscoring its potential to significantly improve the precision of uncovering geometric details from rheo-SAS data. Further, this approach opens new avenues for investigating the conformations of semiflexible polymers and mechanically induced phase transitions in more complex polymer structures, offering deeper insights into their behavior under various conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

75 Years of Drift: The changing meaning of phasor [History]

The origin of what electrical engineers call a phasor diagram is explored, and traced to a treatise by William Thomson (later Lord Kelvin) and Peter Tait. The diagram was mechanical in origin, and gave a geometrical way to visualize and calculate the interactions of sinusoidal motions. Originally, the words radius vector were used in association with the diagram. Later authors used vector. As work on electromagnetic fields expanded, the word phasor was introduced to replace it. That change came about as a result of a deliberate effort (in 1944) to have a clear and unambiguous term of art. Since then, the meaning of the word has changed, and the geometrical interpretation has fallen out of favor. Unfortunately, clarity and unambiguity have suffered as a result. Newer meanings are examined. The measurement of phase angle in the electric power system is described. An Appendix on the work of Steinmetz shows that he did not favor the phasor representation.

Vector, Phasor, Phasor Measurement Unit↗
NASA NTRS1975

M-DAS: System for multispectral data analysis

M-DAS is a ground data processing system designed for analysis of multispectral data. M-DAS operates on multispectral data from LANDSAT, S-192, M2S and other sources in CCT form. Interactive training by operator-investigators using a variable cursor on a color display was used to derive optimum processing coefficients and data on cluster separability. An advanced multivariate normal-maximum likelihood processing algorithm was used to produce output in various formats: color-coded film images, geometrically corrected map overlays, moving displays of scene sections, coverage tabulations and categorized CCTs. The analysis procedure for M-DAS involves three phases: (1) screening and training, (2) analysis of training data to compute performance predictions and processing coefficients, and (3) processing of multichannel input data into categorized results. Typical M-DAS applications involve iteration between each of these phases. A series of photographs of the M-DAS display are used to illustrate M-DAS operation.

Johnson, R. H.↗
NASA NTRS1977

Multiple scattering in reflection nebulae. IV - The multiplicity of scattering

The characteristics of higher order scattering in plane-parallel reflection nebulae of finite optical thickness have been examined. Measured both by the mean number of scatterings and the effective multiplicity, the importance of multiple scattering in such systems varies strongly with position as well as direction, and the effects cannot be taken into account by simple corrections only. It is found that the amount of higher order scattering is relatively insensitive to the shape of the phase function over a wide range of asymmetries, while the dependence of multiplicity on particle albedo, optical thickness of the nebula, and other geometrical factors is as expected. Pronounced asymmetries in the surface brightness distribution of strongly tilted plane-parallel nebulae are explained by different radial variations of the effective multiplicity along opposite radii on the projected nebular face.

Witt, A. N.↗
NASA NTRS1984

STAEBL: Structural tailoring of engine blades, phase 2

The Structural Tailoring of Engine Blades (STAEBL) program was initiated at NASA Lewis Research Center in 1980 to introduce optimal structural tailoring into the design process for aircraft gas turbine engine blades. The standard procedure for blade design is highly iterative with the engineer directly providing most of the decisions that control the design process. The goal of the STAEBL program has been to develop an automated approach to generate structurally optimal blade designs. The program has evolved as a three-phase effort with the developmental work being performed contractually by Pratt & Whitney Aircraft. Phase 1 was intended as a proof of concept in which two fan blades were structurally tailored to meet a full set of structural design constraints while minimizing DOC+I (direct operating cost plus interest) for a representative aircraft. This phase was successfully completed and was reported in reference 1 and 2. Phase 2 has recently been completed and is the basis for this discussion. During this phase, three tasks were accomplished: (1) a nonproprietary structural tailoring computer code was developed; (2) a dedicated approximate finite-element analysis was developed; and (3) an approximate large-deflection analysis was developed to assess local foreign object damage. Phase 3 is just beginning and is designed to incorporated aerodynamic analyses directly into the structural tailoring system in order to relax current geometric constraints.

Hirschbein, M. S.↗
NASA NTRS1996

Multipath analysis diffraction calculations

This report describes extensions of the Kirchhoff diffraction equation to higher edge terms and discusses their suitability to model diffraction multipath effects of a small satellite structure. When receiving signals, at a satellite, from the Global Positioning System (GPS), reflected signals from the satellite structure result in multipath errors in the determination of the satellite position. Multipath error can be caused by diffraction of the reflected signals and a method of calculating this diffraction is required when using a facet model of the satellite. Several aspects of the Kirchhoff equation are discussed and numerical examples, in the near and far fields, are shown. The vector form of the extended Kirchhoff equation, by adding the Larmor-Tedone and Kottler edge terms, is given as a mathematical model in an appendix. The Kirchhoff equation was investigated as being easily implemented and of good accuracy in the basic form, especially in phase determination. The basic Kirchhoff can be extended for higher accuracy if desired. A brief discussion of the method of moments and the geometric theory of diffraction is included, but seems to offer no clear advantage in implementation over the Kirchhoff for facet models.

Statham, Richard B.↗
NASA NTRS2003

Acquisition, Tracking, and Pointing Using Earth Thermal Images for Deep Space Optical Communications

The feasibility of using long wavelength Earth thermal (infrared) images for telescope tracking/pointing application. for both Deep Space Free- pace Optical Communications has been investigated and is reported her. The advantage of this technology rests on using full Earth images in this band, which yield more accurate estimates of geometric centroids than that of Earth images in the visible band. Another major advantage is that these images are nearly independent of Earth phase angle. The results of the study show that at a Mars range, with currently available sensors, a noise equivalent angle of 10 to 150 nanoradians and a bias error of better than 80 nanoradians can be obtained. This enables precise pointing of the optical communications beam for high data rate links.

free-space optical communication↗
DOE OSTI2023

Geometrically frustrated interactions drive structural complexity in amorphous calcium carbonate

Amorphous calcium carbonate is an important precursor for biomineralization in marine organisms. Key outstanding problems include understanding the structure of amorphous calcium carbonate and rationalizing its metastability as an amorphous phase. Here we report high-quality atomistic models of amorphous calcium carbonate generated using state-of-the-art interatomic potentials to help guide fits to X-ray total scattering data. Exploiting a recently developed inversion approach, we extract from these models the effective Ca∙∙∙Ca interaction potential governing the structure. This potential contains minima at two competing distances, corresponding to the two different ways that carbonate ions bridge Ca 2+ -ion pairs. We reveal an unexpected mapping to the Lennard-Jones–Gauss model normally studied in the context of computational soft matter. The empirical model parameters for amorphous calcium carbonate take values known to promote structural complexity. We thus show that both the complex structure and its resilience to crystallization are actually encoded in the geometrically frustrated effective interactions between Ca 2+ ions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Determining the Oxygen Stoichiometry of Cobaltite Thin Films

Transition metal oxides (TMO) are promising materials to realize low-power neuromorphic devices. Their physical properties critically depend on their oxygen vacancy concentrations, whose experimental determination remains a challenging task. Here we focus on cobaltites, in particular La 1-x Sr x CoO 3-d (LSCO), and we present a strategy to identify fingerprints of oxygen vacancies in X-ray absorption (XA) spectra. Using a combination of experiment and theory, we show that the variation of the oxygen vacancy concentration in the perovskite phase of LSCO is correlated with the change of the relative peak positions of the O K-edge XA spectra. Furthermore, we also identify an additional geometrical fingerprint that captures both the changes of the Co-O bond length and Co-O-Co bond angle in the material due to the presence of oxygen vacancies. Finally, we predict the oxygen vacancy concentration of experimental samples and show how the resistivity of the oxide material may be tuned as a function of the defect concentration present in the system.

36 MATERIALS SCIENCE↗
DOE OSTI2021

On-chip non-Hermitian optical parametric amplifiers with a large bandwidth

Recently, our groups have introduced the notion of optical parametric amplification based on non-Hermitian phase matching wherein the incorporation of loss can lead to gain in this nonlinear optical process. Previous simulation results using second-order nonlinear optical coupled-mode theory have demonstrated the potential of this technique as an alternative to the stringent phase-matching condition, which is often difficult to achieve in semiconductor platforms. Here we fortify this notion for the case of third-order nonlinearity by considering parametric amplification in silicon nanowires and illustrate the feasibility of these devices by employing rigorous finite-difference time-domain analysis using realistic materials and geometric parameters. Particularly, we demonstrate that by systematic control of the optical loss of the idler in a four-wave mixing process, we can achieve efficient unidirectional energy conversion from the pump to the signal component even when the typical phase-matching condition is violated. Importantly, our simulations show that a signal gain of ∼ <#comment/> 9 d B for a waveguide length of a few millimeters is possible over a large bandwidth of several hundreds of nanometers ( ∼ <#comment/> 600 n m ). This bandwidth is nearly 2 orders of magnitude larger than what can be achieved in the conventional silicon-photonics-based four-wave mixing process.

Ahmed, Asif (ORCID:0000000152234392)↗
DOE OSTI2025

SOC Microstructural Property Estimator

This pre-trained ML model is a tool that uses basic compositional parameters for porous solid oxide cell (SOC) electrodes - the phase fractions and mean particle/pore diameters – as inputs and uses them to estimate additional electrochemical performance parameters: active (i.e., connected) TPB density, all tortuosity factors, and phase pair specific interfacial areas. The electrode is assumed to be composed of two solid phases and a pore phase. The property calculations are performed using neural network regression models trained on a large bank of synthetic electrode microstructural data that NETL has generated using the program DREAM3D (that bank is also hosted on EDX: https://edx.netl.doe.gov/dataset/soc-synthetic-microstructure-bank). This means the generated parameters are based on training from actual measured properties from 3D microstructures, not estimated from geometric simplifications. This tool was developed and is intended to replace percolation theory calculations in models that use hypothetical electrode properties. An example use case would be running SOC performance simulations across a parametric sweep of electrode designs (e.g., varying phase fractions and particle sizes) and assessing how it impacts the electrochemical performance of the SOC. Within the parameter space of the training data (statistics of that parameter space is provided in the readme file), this model achieves sub-5% mean absolute percent errors, an order of magnitude less error than percolation theory across the same parameter space. However, be aware that this tool was developed with parametric simulations in mind, and users are encouraged to assess accuracy for their own specific use case rather than taking accuracy metrics at face value. More info, including a usage guide, is in the included readme file. This tool should be cited with the DOI number provided.

Electrode Microstructure↗
DOE OSTI2023

Effective permeability of an immiscible fluid in porous media determined from its geometric state

Based on the phenomenological extension of Darcy's law, two-fluid flow is dependent on a relative permeability function of saturation only that is process or path dependent with an underlying dependency on pore structure and wettability. For applications (fuel cells to underground CO 2 storage), it is imperative to determine the effective phase permeability relationships where the traditional approach is based on the inverse modeling of time-consuming experiments. The underlying reason is that the fundamental upscaling step from pore to Darcy scale, which links the pore structure of the porous medium to the continuum hydraulic conductivities, is not solved. Herein, we develop an artificial neural network (ANN) that relies on fundamental geometrical relationships to determine the mechanical energy dissipation during creeping immiscible two-fluid flow. Finally, the developed ANN is based on a prescribed set of state variables based on physical insights that predict the effective permeability of 4500 unseen pore-scale geometrical states with R 2 = 0.98.

42 ENGINEERING↗
DOE OSTI2022

High entropy alloys with hexagonal close-packed structure derived from thin film combinatorial approach

A thin film combinatorial synthesis approach was utilized to develop a compositional and structural library for the OsRuWCo alloy system. The survey of this alloy space produced 24 unique compositions and their corresponding crystal structures, which represent a phase map where amorphous and single-phase hexagonal close-packed alloys were identified. Based on the identification of a promising candidate film region, a new high entropy alloy based on OsRuWCo, but with non-equiatomic composition, was synthesized in bulk form. The alloy exhibited a single-phase hexagonal close-packed structure in the as-cast state. Three derivatives from this system were also developed by considering the heat of mixing, atomic size, and binary solubility. These new alloys are based on OsRuWCoIr and OsRuWCoFe, both of which exhibit single-phase hexagonal close-packed as-cast structures, as determined by X-ray diffraction and electron microscopy. Additionally, this large compositional space was utilized to evaluate conventional parameters that describe high entropy alloys (ΔS mix , ΔH mix , Ω, δ, and VEC), and these were found to elucidate the criteria for solid solution formation in this system. Additionally, trends illustrating the evolution from amorphous to crystalline phases are demonstrated and discussed. It is concluded that in this particular case, the dominant factors promoting crystallinity are thermodynamic or electronic, rather than geometric.

36 MATERIALS SCIENCE↗
NASA NTRS1977

Structure and dynamics of a solar flare - X-ray and XUV observations

Results are presented for an analysis of X-ray and XUV emission from the solar flare that occurred on September 5, 1973. X-ray emission was monitored by ionization chambers aboard the Solrad 9 satellite, and the XUV emission in the wavelength range 170-345 A was recorded by a slitless objective-grating spectroheliograph on Skylab. The physical parameters of the flare plasma, including temperature, density, volume, and magnetic-field configuration, are evaluated. A geometrical loop model is used to determine the volumes of the various emitting regions. The structure of the flare in the rise and decay phases is examined in detail, and conclusions about the effect of various dynamic processes in the flare plasma are made. A major finding is that continued energy release is required well into the flare decay phase. In the rise phase, energy is apparently released only along a small portion of a loop, and in the decay phase apparently throughout most of its length.

Dere, K. P.↗
NASA NTRS1978

Planetary isophotes as a clue to aerosol characteristics. II - Observations of Venus from spacecraft

Contrary to published reports, the limb-darkening observed by Mariner 10 is consistent with the sulfuric-acid aerosol scattering that explains the polarization and spectroscopic features of Venus. A combination of both geometric and photometric systematic errors explains the previously reported discrepancy. Although the aerosol model cannot be distinguished from isotropic scattering at the Mariner 10 phase angle, Venera 9 data at larger phases clearly favor the aerosol model. There is no evidence for isotropic scattering in the clouds of Venus.

Young, A. T.↗
NASA NTRS1979

On the wavelength dependence of the effects of turbulence on average refraction angles in occultations by planetary atmospheres

The dependence of the effects of planetary atmospheric turbulence on radio or optical wavelength in occultation experiments is discussed, and the analysis of Hubbard and Jokipii (1977) is criticized. It is argued that in deriving a necessary condition for the applicability of their method, Hubbard and Jokipii neglect a factor proportional to the square of the ratio of atmospheric or local Fresnel zone radius and the inner scale of turbulence, and fail to establish sufficient conditions, thereby omitting the square of the ratio of atmospheric scale height and the local Fresnel zone radius. The total discrepancy is said to mean that the results correspond to geometrical optics instead of wave optics, as claimed, thus being inapplicable in a dicussion of wavelength dependence. Calculations based on geometrical optics show that the bias in the average bending angle depends on the wavelength in the same way as does the bias in phase path caused by turbulence in a homogeneous atmosphere. Hubbard and Jokipii comment that the criterion of Haugstad and Eshleman is incorrect and show that there is a large wave optical domain where the results are independent of wavelength.

Haugstad, B. S.↗