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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 523 records · Page 29
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

In situ formation of pseudohalide anions induced by humid air and light passivates formamidinium‐based halide perovskites

Abstract Metal halide perovskites based on formamidinium (FA), or FA‐rich compositions have shown great promise for high‐performance photovoltaics. A deeper understanding of the impact of ambient conditions (e.g., moisture, oxygen, and illumination) on the possible reactions of FA‐based perovskite films and their processing sensitivities has become critical for further advances toward commercialization. Herein, we investigate reactions that take place on the surface of the FA 0.7 Cs 0.3 , mixed Br/I wide bandgap perovskite thin films in the presence of humid air and ambient illumination. The treatment forms a surface layer containing O, OH, and N‐based anions. We propose the latter originates from formamidine trapped at the perovskite/oxide interface reacting further to cyanide and/or formamidinate—an understudied class of pseudohalides that bind to Pb. Optimized treatment conditions improve photoluminescence quantum yield owing to both reduced surface recombination velocity and increased bulk carrier lifetime. The corresponding perovskite solar cells also exhibit improved performance. Identifying these reactions opens possibilities for better utilizing cyanide and amidinate ligands, species that may be expected during vapor processing of FA‐based perovskites. Our work also provides new insights into the self‐healing or self‐passivating of MA‐free perovskite compositions where FA and iodide damage could be partially offset by advantageous reaction byproducts. image

14 SOLAR ENERGY↗
NASA NTRS1978

CELFE: Coupled Eulerian-Lagrangian Finite Element program for high velocity impact. Part 1: Theory and formulation

A 3-D finite element program capable of simulating the dynamic behavior in the vicinity of the impact point, together with predicting the dynamic response in the remaining part of the structural component subjected to high velocity impact is discussed. The finite algorithm is formulated in a general moving coordinate system. In the vicinity of the impact point contained by a moving failure front, the relative velocity of the coordinate system will approach the material particle velocity. The dynamic behavior inside the region is described by Eulerian formulation based on a hydroelasto-viscoplastic model. The failure front which can be regarded as the boundary of the impact zone is described by a transition layer. The layer changes the representation from the Eulerian mode to the Lagrangian mode outside the failure front by varying the relative velocity of the coordinate system to zero. The dynamic response in the remaining part of the structure described by the Lagrangian formulation is treated using advanced structural analysis. An interfacing algorithm for coupling CELFE with NASTRAN is constructed to provide computational capabilities for large structures.

Lee, C. H.↗
NASA NTRS1981

Instability of baroclinic flows with horizontal shear along topography

The stability of baroclinic flows with horizontal shear over sloping topography is analyzed with special emphasis on the structure and energetics of the unstable perturbations. The study is conducted by using a linearized two-layer quasi-geostrophic channel model for different topography profiles and distributions of the basic velocity field. Interactions between the two fluid layers and the energy conversions by the unstable perturbations are described. It is found that topography sloping as (opposed to) the fluid interface contributes to enhance the perturbation amplitude in the upper (lower) layer relative to the lower (upper) layer. The results for bottom topography with differing characteristics across the flow indicate pronounced localized effects on the energy conversions over the slopes and the meridional scale of the perturbations in the lower layer.

Mechoso, C. R.↗
NASA NTRS1984

Detection of shocked atomic gas in the Kleinmann-Low nebula

The 63 micrometer (3)p(1)-(3)P(2) fine structure line emission of neutral atomic oxygen at the center of the Orion nebula with a resolution of 30" is presented. There are three main emission peaks. One is associated with the region of strongest thermal radio continuum radiation close to the Trapezium cluster, and probably arises at the interface between the HII region and the dense Orion molecular cloud. The other two line emission peaks, associated with the Kleinmann Low nebula, are similar in both distribution and velocity to those of the 2 micrometer S(1) line of molecular hydrogen and of the high velocity wings of rotational CO emission. The OI emission from the KL nebula can be produced in the shocked gas associated with the mass outflows in this region and is an important coolant of the shocked gas.

Werner, M.↗
NASA NTRS1989

Ground-based measurements of O 1D and the H2O production rate from comets

High spectral resolution 6300.3 A line profiles of Comet Halley are modeled to determine the relative contributions to the emission that can be expected from the distant O 1D daughters produced by photodissociation H2O, CO2, and CO. The results are compared with profiles measured with a single etalon Fabry-Perot interferometer interfaced with a 0.4-m telescopre. To accurately calculate Q O 1D using the 6300.3 A intensity, the line profile must be known. It is shown that the outflow velocity of the parent molecules from the nucleus can be determined using the interferometer profiles.

Kerr, R. B.↗
NASA NTRS1993

Theory and operation of a three-gate time-of-flight velocity analyzer

Theoretical considerations and test results are presented for a new-type velocity analyzer for incident fast neutral particles, positive ions, and negative ions. Velocity analysis is carried out by means of a pulsed, three-gate time-of-flight (TOF) technique capable of eliminating alias velocities (harmonics) to sixth order. In addition the design and operation are presented of a four-element ion lens system, with small spherical and chromatic aberrations, suitable for interfacing a large-diameter ion beam from the TOF section with a subsequent mass analyzer.

Martus, K. E.↗
NASA NTRS1993

Ultrasonic assessment of interfacial oxidation damage in ceramic matrix composites

A new approach to characterizing oxidation damage in ceramic matrix composites using ultrasonic techniques is proposed. In this approach, the elastic constants of the composite are determined nondestructively by measuring the angular dependence of both longitudinal and transverse wave velocities. A micromechanical model for composites with anisotropic constituents is used to find the anisotropic properties of an effective fiber, which is a combination of the fiber and the interface. Interfacial properties are extracted from the properties of this effective fiber by analyzing the difference between effective and actual fiber properties. Unidirectional /0/28 SiC/Si3N4 composites with 30 percent fiber volume fraction and 30 percent matrix porosity are used. The samples are exposed in a flowing oxygen environment at elevated temperatures, up to 1400 C, for 100 hours and then measured by ultrasonic methods at room temperature. The Young's modulus in the fiber direction of the sample oxidized at 600 C decreased significantly but it was unchanged for samples oxidized at temperatures above 1200 C. The transverse moduli obtained from ultrasonic measurements decrease continuously up to 1200 C. The shear stiffnesses show behavior similar to the transverse moduli. The effective elastic moduli of the interfacial carbon coating are determined from the experimental data, and their change due to thermal oxidation is discussed.

Chu, Y. C.↗
NASA NTRS2003

Hot Gas in Planetary Nebulae

It was successfully obtained the FUSE spectra of all targets awarded. The analysis of the spectra has been a complex task due to the superposition of the P-Cygni profile from the wind of the central star and absorption components from low ionization and molecular species in the nebular shell. In six of the eight targets there are narrow O VI absorption components that may arise from the interface layer between the hot (l0(exp 6) K) interior gas and the surrounding warm (l0(exp 4) K) dense nebular shell. To better determine whether these narrow O VI absorption lines arise from the interface region we have obtained ground-based high-dispersion spectroscopic observations of the central star and nebula to pin-point the precise line-of-sight velocity of the nebular emission lines. The comparison between these optical spectra with the far-UV spectra obtained with FUSE is complete. The analysis shows that in most cases the narrow O VI absorption components have velocities slightly redshifted from the emission lines which arise from the approaching side of the nebular shell. Preliminary results have been published in two papers.

Gruendl, Robert A.↗
DOE OSTI2024

Topological Signature of Stratospheric Poincaré-Gravity Waves

The rotation of Earth breaks time-reversal and reflection symmetries in an opposite sense north and south of the equator, leading to a topological origin for certain atmospheric and oceanic equatorial waves. Away from the equator, the rotating shallow-water and stably stratified primitive equations exhibit Poincaré inertia–gravity waves that have nontrivial topology as evidenced by their strict superinertial time scale and a phase singularity in frequency–wavevector space. This nontrivial topology then predicts, via the principle of bulk-interface correspondence, the existence of two equatorial waves along the equatorial interface, the Kelvin and Yanai waves. To directly test the nontrivial topology of Poincaré-gravity waves in observations, we examine ERA5 data and study cross correlations between the wind velocity and geopotential height of the midlatitude stratosphere at the 50 hPa height. We find the predicted vortex and antivortex in the relative phase of the geopotential height and velocity at the high frequencies of the waves. By contrast, lower-frequency planetary waves are found to have trivial topology also as expected from theory. These results demonstrate a new way to understand stratospheric waves and provide a new qualitative tool to investigate waves in other components of the climate system.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1968

Large-amplitude inviscid fluid motion in an accelerating container

Study of dynamic behavior of the liquid-vapor interface of an inviscid fluid in an accelerating cylindrical container includes an analytical-numerical method for determining large amplitude motion. The method is based on the expansion of the velocity potential in a series of harmonic functions with time dependent coefficients.

Perko, L. M.↗
NASA NTRS1981

Laser velocimeter (autocovariance) buffer interface

A laser velocimeter (autocovariance) buffer interface (LVABI) was developed to serve as the interface between three laser velocimeter high speed burst counters and a minicomputer. A functional description is presented of the instrument and its unique features which allow the studies of flow velocity vector analysis, turbulence power spectra, and conditional sampling of other phenomena. Typical applications of the laser velocimeter using the LVABI are presented to illustrate its various capabilities.

Clemmons, J. I., Jr.↗
NASA NTRS1988

Growth of needle-shaped crystals in the presence of convection

The motion of the freezing front between a needle-shaped crystal and a supercooled liquid is analyzed for situations where there is forced convection aligned with the crystal axis. It is shown that in the absence of capillary effects the shape of the crystal-melt interface is a paraboloid of revolution, similar to that found in situations where diffusion is the sole heat-transfer mechanism. A relation between the supercooling, the product of tip velocity and tip radius, and the strength of the flow is derived which reduces to the well-known Ivantsov theory in the absence of convection.

Saville, D. A.↗
NASA NTRS1993

Dynamic gas temperature measurements using a personal computer for data acquisition and reduction

This report describes a dynamic gas temperature measurement system. It has frequency response to 1000 Hz, and can be used to measure temperatures in hot, high pressure, high velocity flows. A personal computer is used for collecting and processing data, which results in a much shorter wait for results than previously. The data collection process and the user interface are described in detail. The changes made in transporting the software from a mainframe to a personal computer are described in appendices, as is the overall theory of operation.

Fralick, Gustave C.↗
NASA NTRS2011

Geodetic Strain Analysis Tool

A geodetic software analysis tool enables the user to analyze 2D crustal strain from geodetic ground motion, and create models of crustal deformation using a graphical interface. Users can use any geodetic measurements of ground motion and derive the 2D crustal strain interactively. This software also provides a forward-modeling tool that calculates a geodetic velocity and strain field for a given fault model, and lets the user compare the modeled strain field with the strain field obtained from the user s data. Users may change parameters on-the-fly and obtain a real-time recalculation of the resulting strain field. Four data products are computed: maximum shear, dilatation, shear angle, and principal components. The current view and data dependencies are processed first. The remaining data products and views are then computed in a round-robin fashion to anticipate view changes. When an analysis or display parameter is changed, the affected data products and views are invalidated and progressively re-displayed as available. This software is designed to facilitate the derivation of the strain fields from the GPS and strain meter data that sample it to facilitate the understanding of the strengths and weaknesses of the strain field derivation from continuous GPS (CGPS) and other geodetic data from a variety of tectonic settings, to converge on the "best practices" strain derivation strategy for the Solid Earth Science ESDR System (SESES) project given the CGPS station distribution in the western U.S., and to provide SESES users with a scientific and educational tool to explore the strain field on their own with user-defined parameters.

Kedar, Sharon↗
NASA NTRS2019

Numerical Study of Lander Engine Plume Impingement on the Surface of Europa

Plume exhaust from lander engines would be of concern when landing on the surface of Europa since it could have detrimental effects on both the landing surface and powered descent vehicle. The plume could also entrain particles and redirect them up toward the landing vehicle, as well as erode and contaminate the surface where science would be conducted. In this work, a numerical methodology is developed and validated to conduct a first-order assessment of individual engine plumes of a potential Europa Lander vehicle. Computational Fluid Dynamics (CFD) is used to solve the flow field inside and immediately downstream of the nozzle, while the Direct Simulation Monte Carlo (DSMC) method is applied further downstream where the flow becomes rarefied. An interface between the two domains is defined where macroscopic flow data is passed from the CFD domain to the DSMC domain, establishing a one-way coupling. Plume pressure and velocity fields, as well as ground heating, pressure and density flux profiles, are obtained at altitudes from 25 m down to 10 m, spanning the final stages of landing. The codes and methodologies used in this study are successfully validated with simulations conducted by Morris et al. of the Apollo Lunar Module Descent Engine (LMDE) exhaust plume impinging onto the lunar surface.

Lam, Rebekah↗
NASA NTRS2019

Numerical study of lander engine plume impingement on the surface off Europa

Plume exhaust from lander engines would be of concern when landing on the surface of Europa since it could have detrimental effects on both the landing surface and powered descent vehicle. The plume could also entrain particles and redirect them up toward the landing vehicle, as well as erode and contaminate the surface where science would be conducted. In this work, a numerical methodology is developed and validated to conduct a first-order assessment of individual engine plumes of a potential Europa Lander vehicle. Computational Fluid Dynamics (CFD) is used to solve the flow field inside and immediately downstream of the nozzle, while the Direct Simulation Monte Carlo (DSMC) method is applied further downstream where the flow becomes rarefied. An interface between the two domains is defined where macroscopic flow data is passed from the CFD domain to the DSMC domain, establishing a one-way coupling. Plume pressure and velocity fields, as well as ground heating, pressure and density flux profiles, are obtained at altitudes from 25 m down to 10 m, spanning the final stages of landing. The codes and methodologies used in this study are successfully validated with simulations conducted by Morris et al. [1-3] of the Apollo Lunar Module Descent Engine (LMDE) exhaust plume impinging onto the lunar surface.

Hoey, William↗
DOE OSTI2025

Assessment of metadynamic recrystallization in single copper particle impacts by focused ion beam tomography

We study single Cu-on-Cu impacts relevant to cold spray deposition and quantitatively analyze the metadynamic recrystallization (mDRX) that takes place after the impact by virtue of lingering impact adiabatic heat. Unlike prior studies, the current full 3D tomographic analysis of the mDRX volume shows that mDRX is extremely common in such impacts, although it is often missed when examining 2D sections. We also report an unexpected trend: there is a “sour spot” for mDRX at velocities about 20–40 % above the velocity for particle adhesion. This non-monotonic trend is contrary to the expectations based on increasing adiabatic heating with velocity. With a schematic model, we show that the trend can be explained on the basis of heat transfer: cooling of the heat-affected region is limited by transport through the bonded regions at the particle-substrate interface. Thus, bonding has a prominent role in the heat dissipation process and the best bonded particles most rapidly bulk quench, avoiding mDRX. Here, the developed semi-empirical model aligns with the experimental findings and may help inform microstructural evolution during cold spray and post-spray processing.

FIB-SEM tomography↗
DOE OSTI2021

Enhanced electro-osmosis in propylene carbonate salt solutions

Properties of solid–liquid interfaces and surface charge characteristics mediate ionic and molecular transport through porous systems, affecting many processes such as separations. Herein, we report experiments designed to probe the electrochemical properties of solid–liquid interfaces using a model system of a single polyethylene terephthalate (PET) pore in contact with aqueous and propylene carbonate solutions of LiClO 4 . First, the existence and polarity of surface charges were inferred from current–voltage curves recorded when a pore was placed in contact with a LiClO4 concentration gradient. Second, the electro-osmotic transport of uncharged polystyrene particles through the PET pore provided information on the polarity and the magnitude of the pore walls’ zeta potential. Our experiments show that the PET pores become effectively positively charged when in contact with LiClO 4 solutions in propylene carbonate, even though in aqueous LiClO 4 , the same pores are negatively charged. Additionally, the electro-osmotic velocity of the particles revealed a significantly higher magnitude of the positive zeta potential of the pores in propylene carbonate compared to the magnitude of the negative zeta potential in water. The presented methods of probing the properties of solid–liquid interfaces are expected to be applicable to a wide variety of solid and liquid systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗