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At least 523 records · Page 29

High-Voltage, Asymmetric-Waveform Generator

The shapes of waveforms generated by commercially available analytical separation devices, such as some types of mass spectrometers and differential mobility spectrometers are, in general, inadequate and result in resolution degradation in output spectra. A waveform generator was designed that would be able to circumvent these shortcomings. It is capable of generating an asymmetric waveform, having a peak amplitude as large as 2 kV and frequency of several megahertz, which can be applied to a capacitive load. In the original intended application, the capacitive load would consist of the drift plates in a differential-mobility spectrometer. The main advantage to be gained by developing the proposed generator is that the shape of the waveform is made nearly optimum for various analytical devices requiring asymmetric-waveform such as differential-mobility spectrometers. In addition, this waveform generator could easily be adjusted to modify the waveform in accordance with changed operational requirements for differential-mobility spectrometers. The capacitive nature of the load is an important consideration in the design of the proposed waveform generator. For example, the design provision for shaping the output waveform is based partly on the principle that (1) the potential (V) on a capacitor is given by V=q/C, where C is the capacitance and q is the charge stored in the capacitor; and, hence (2) the rate of increase or decrease of the potential is similarly proportional to the charging or discharging current. The proposed waveform generator would comprise four functional blocks: a sine-wave generator, a buffer, a voltage shifter, and a high-voltage switch (see Figure 1). The sine-wave generator would include a pair of operational amplifiers in a feedback configuration, the parameters of which would be chosen to obtain a sinusoidal timing signal of the desired frequency. The buffer would introduce a slight delay (approximately equal to 20 ns) but would otherwise leave the fundamental timing signal unchanged. The buffered timing signal would be fed as input to the level shifter. The output of the level shifter would serve as a timing and control signal for the high-voltage switch, causing the switch to alternately be (1) opened, allowing the capacitive load to be charged from a high-voltage DC power supply; then (2) closed to discharge the capacitive load to ground. Hence, the output waveform would closely approximate a series of exponential charging and discharging curves (see Figure 2).

Beegle, Luther W.↗

Analysis of the Hermite spectrum in plasma turbulence

The properties of the Hermite spectrum associated with the linear drift-kinetic equation—as used in studies of gyrokinetic turbulence—are examined. A rigorous uniform asymptotic expression is derived for the steady-state spectrum with a Lenard-Bernstein collision operator. It is found that the spectrum is partitioned into three regions whose boundaries are determined by the ratio of the collision frequency ν to the parallel transit frequency kvth. In the regime of small Hermite index, n, with n ≲ (ν/kv th ) 2/3 , collisions play no role, and the free energy decays like n –1/2 due to phase mixing. In the previously unexplored large-n regime, n ≥ (ν/kv th ) 2 , collisions are dominant, and the decay of the free energy spectrum is extremely steep, falling off like (n/e) –n . Most of the free energy is dissipated in the intermediate regime, (ν/kv th ) 2/3 ≲ n << (ν/kv th ) 2 , where the asymptotic spectrum is in close agreement with the exponentially decaying “continuization” estimate. Furthermore, our analysis shows that collisions act as a singular perturbation, giving rise to the intermediate regime, where collisions are significantly altering the spectrum well inside the general large-n asymptotic region.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Control of a heterogeneous two-server exponential queueing system

A dynamic control policy known as 'threshold queueing' is defined for scheduling customers from a Poisson source on a set of two exponential servers with dissimilar service rates. The slower server is invoked in response to instantaneous system loading as measured by the length of the queue of waiting customers. In a threshold queueing policy, a specific queue length is identified as a 'threshold,' beyond which the slower server is invoked. The slower server remains busy until it completes service on a customer and the queue length is less than its invocation threshold. Markov chain analysis is employed to analyze the performance of the threshold queueing policy and to develop optimality criteria. It is shown that probabilistic control is suboptimal to minimize the mean number of customers in the system. An approximation to the optimum policy is analyzed which is computationally simple and suffices for most operational applications.

Larsen, R. L.↗

Using airborne and DESIS imaging spectroscopy to map plant diversity across the largest contiguous tract of tallgrass prairie on earth

Grassland ecosystems are under threat globally, primarily due to land-use and land-cover changes that have adversely affected their biodiversity. Given the negative ecological impacts of biodiversity loss in grasslands, there is an urgent need for developing an operational biodiversity monitoring system that functions in these ecosystems. In this paper, we assessed the capability of airborne and spaceborne imaging spectroscopy (also known as hyperspectral imaging) to capture plant α-diversity in a large naturally-assembled grassland while considering the impact of common management practices, specifically prescribed fire. We collected a robust in-situ plant diversity data set, including species composition and percent cover from 2500 sampling points with different burn ages, from recently-burned to transitional and pre-prescribed fire at the Joseph H. Williams Tallgrass Prairie Preserve in Oklahoma, USA. We expressed in-situ plant α-diversity using the first three Hill numbers, including species richness (number of observed species in a plant community), exponential Shannon entropy index (hereafter Shannon diversity; effective number of common species, where species are weighed proportional to their percent cover), and inverse Simpson concentration index (hereafter Simpson diversity; effective number of dominant species, where more weight is given to dominant species) at four different plot sizes, including 60 m × 60 m, 120 m × 120 m, 180 m × 180 m, and 240 m × 240 m. We collected full-range airborne hyperspectral data with fine spatial resolution (1 m) and visible and near-infrared spaceborne hyperspectral data from DESIS sensor with coarse spatial resolution (30 m), and used the spectral diversity hypothesis—i.e., that the variability in spectral data is largely driven by plant diversity—to estimate α-diversity remotely. In recently-burned plots and those at the transitional stage, both airborne and spaceborne data were capable of capturing Simpson diversity—a metric that calculates the effective number of dominant species by emphasizing abundant species and discounting rare species—but not species richness or Shannon diversity. Further, neither airborne nor spaceborne hyperspectral data sets were capable of capturing plant α-diversity of 60 m × 60 m or 120 m × 120 m plots. Based on these results, three main findings emerged: (1) management practices influence grassland biodiversity patterns that can be remotely detected, (2) both fine- and coarse-resolution remotely-sensed data can detect the effective number of dominant species (e.g., Simpson diversity), and (3) attention should be given to site-specific plant diversity field data collection to appropriately interpret remote sensing results. Findings of this study indicate the feasibility of estimating Simpson diversity in naturally-assembled grasslands using forthcoming spaceborne imagers such as National Aeronautics and Space Administration's Surface Biology and Geology mission.

Hamed Gholizadeh↗

A riming‐dependent parameterization of scattering by snowflakes using the self‐similar Rayleigh–Gans approximation

Abstract Riming is a key process of precipitation formation in ice‐containing clouds, but quantifying riming from observations is challenging, limiting our ability to evaluate the riming process in numerical weather models. One challenge for radar observations is that riming changes both the physical properties (mass, area cross‐section) and scattering properties of ice particles. These changes need to be implemented consistently as a function of riming in radar forward operators, which are required for retrievals and model evaluation in observation space. In this study, mass–size, cross‐section area–size, and backscattering cross‐section relations are developed as a function of the normalized rime mass for aggregates composed of various monomer types (columns, dendrites, needles, plates, and rosettes). The proposed framework allows us to simulate scattering properties of aggregated ice particles consistently as a function of riming in retrievals and radar forward operators. The parameterizations are developed from a large data set of simulated rimed aggregates of different sizes and monomer crystal types. The backscattering cross‐section parameterization (the “riming‐dependent parameterization”) is evaluated for radar frequencies of 35.6 and 94.0 GHz and is based on the Self‐Similar Rayleigh–Gans approximation (SSRGA), which is increasingly used to calculate microwave scattering of ice crystals and snowflakes. Compared with parameterizations from the literature that do not consider riming, the riming‐dependent parameterization leads to significantly smaller biases in terms of backscattering cross‐section. When using the particle masses and scattering properties of the individual particles simulated by the aggregation and riming model as a reference, the bias of our parameterization is below 1 dB when integrating over an exponential particle size distribution with sizes from 0.1–10 mm.

54 ENVIRONMENTAL SCIENCES↗

Regime-specific Cloud Vertical Overlap Characteristics from Radar and Lidar Observations at the ARM sites

Climate and numerical weather prediction models require assumptions to represent the vertical distribution of subgrid-scale clouds, which have radiative transfer implications. In this study, nearly 25 years of ground-based radar and lidar observations of vertical cloud profiles at the Atmospheric Radiation Measurement Program (ARM) Southern Great Plains (SGP) site are utilized to derive cloud vertical overlap characteristics from the Cloud Type (CLDTYPE) data product. Here, the cloud vertical overlap characteristics are further separated by cloud regime by considering seven cloud types (i.e., low cloud, congestus, deep convection, altocumulus, altostratus, cirrostratus, and cirrus) as well as periods of shallow cumulus. The decorrelation length scale (i.e., exponential transition from maximum to random overlap with layer separation) is found to vary by cloud regime, ranging between 0.04 km for cirrostratus paired with cirrus to 4.58 km for low cloud paired with cirrus at SGP. Cloud vertical overlap characteristics are also considered for other ARM sites including the Tropical Western Pacific (TWP), North Slope of Alaska (NSA), and Eastern North Atlantic (ENA) sites amongst other shorter term ARM deployments globally. The decorrelation length scale ranged globally from 1.03 km in the Arctic Ocean to 3.06 km in Manacapuru, Brazil. Globally, the decorrelation length scale by cloud regime exhibited similarities (e.g., for cirrus paired with cirrus) and differences (e.g., congestus paired with cirrus). The results could help inform development of cloud vertical overlap assumptions within operational numerical weather prediction models and potentially improve prediction of radiative fluxes for weather, climate, and renewable energy forecasting.

54 ENVIRONMENTAL SCIENCES↗

Spatial variability of outgoing longwave radiation

Data from the Earth Radiation Budget Experiment scanning radiometer aboard the NOAA-9 operational meteorological satellite are used to investigate the spatial variability of Outgoing Longwave Radiation (OLR). Daily and monthly radiation maps at 2.5 deg latitude-longitude scale are used as a basis for the study. The regions of greatest variability are in the tropics and subtropics. Storm tracks such as the South Pacific convergence zone appear as regions of high OLR variability. Spatial spectra in longitude show two regimes of OLR. At large scales (wavenumbers less than 6), the spatial spectrum is flat. For wavenumbers greater than 10, the spectra decrease as wavenumber to the -3 power. The spatial spectrum of daily anomalies from the mean is a strong function of latitude and season, with interesting features. Correlations of daily anomalies from the monthly mean decrease exponentially in latitude but have a damped-wave structure in longitude. The spatial variability of the daily maps, as measured by degree variance, have 10 times the power at degree 24 than the monthly maps, but at scales between 1 and 10, the degree variance is practically the same for daily as for monthly.

Smith, G. Louis↗

OceanWATERS Lander Robotic Arm Operation

Ocean Worlds Autonomy Testbed for Exploration Research and Simulation (OceanWATERS) is an open-source simulator for developing onboard autonomy software for robotic exploration of ocean worlds, such as Europa, Enceladus, and Titan, built on the Robot Operating System (ROS) and Gazebo simulation environment. Inevitable ground communication delays increase demand for a high degree of autonomy during excavation, collection and transfer of samples to scientific instruments for in-situ analysis. This paper offers a detailed discussion of the robotic arm design and operation for such autonomous surface exploration, taking as reference the Europa Lander mission. The lander arm, which is designed primarily to acquire icy surface and subsurface samples within the arm’s workspace, is a 6-degree-of-freedom manipulator with two end effectors: a sample excavation tool and a trenching end-effector. The robotic arm’s modes and operations can be summarized as follows: stowed arm, intended as the lander arm default configuration characterized by zero-power consumption; un-stowed arm, target arm configuration after its first deployment; selection and deployment of the end-effector to use next; guarded move, to detect ground level at the desired trenching location; drill ice using the grinder; dig trench at a particular location using the scoop; deliver sample to the sample transfer dock; discard redundant samples. The motion planning tool used for the lander arm is MoveIt, a ROS package. MoveIt uses sampling-based planning and collision checking libraries to determine safe paths. The Rapidly Exploring Random Trees* (RRT*) has been chosen as default planning algorithm as it provides optimal plans with an exponential speed and is guaranteed to find a solution, if feasible solutions exist. Furthermore, this work quantifies and discusses the energy requirements for excavating and collecting samples. In OceanWATERS, force feedback from the terrain, which influences the arm dynamics, is modelled using a discrete element method (DEM) simulation. The DEM and Gazebo software run in parallel and communicate through a co-simulation plugin. This paper presents an analysis and comparison of three DEM open source software (YADE, ESyS-Particle, Project Chrono) for implementation in OceanWATERS and motivates the choice of YADE as most suitable candidate.

Damiana Catanoso↗

An energy-dependent electro-thermal response model of CUORE cryogenic calorimeter

The Cryogenic Underground Observatory for Rare Events (CUORE) is the most sensitive experiment searching for neutrinoless double-beta decay (0νββ) in 130 Te. CUORE uses a cryogenic array of 988 TeO 2 calorimeters operated at ~10 mK with a total mass of 741 kg. To further increase the sensitivity, the detector response must be well understood. Here, we present a non-linear thermal model for the CUORE experiment on a detector-by-detector basis. We have examined both equilibrium and dynamic electro-thermal models of detectors by numerically fitting non-linear differential equations to the detector data of a subset of CUORE channels which are well characterized and representative of all channels. Further, we demonstrate that the hot-electron effect and electric-field dependence of resistance in NTD-Ge thermistors alone are inadequate to describe our detectors' energy-dependent pulse shapes. We introduce an empirical second-order correction factor in the exponential temperature dependence of the thermistor, which produces excellent agreement with energy-dependent pulse shape data up to 6 MeV. We also present a noise analysis using the fitted thermal parameters and show that the intrinsic thermal noise is negligible compared to the observed noise for our detectors.

47 OTHER INSTRUMENTATION↗

Analysis of hematite attrition in a grid jet apparatus

Particulate attrition is of interest for novel carbon-capture processes such as chemical looping combustion because the makeup cost of oxygen carrier is a significant portion of operating cost. As such, models to study and predict attrition of various oxygen carriers in fluidized bed systems are being developed. One of the regions of concern in fluidized bed systems is the high-velocity jet region near gas distributors in a fluid bed. This work studies the attrition of hematite particles using a modified ASTM apparatus to measure the particle size distribution throughout the experiment. Bed weight and gas velocity were varied. Hematite particles above the corresponding threshold value had a severe variation of particle size distributions which decreased with time. Weight fractions of the sieves over time were fit to a linear, time-variant population balance model to offer insight into particle attrition. The first-order rate constant was modified as a decaying exponential.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Integration of Total-Sky Imager Data with a Physics-Based Smart Persistence Model for Intra-Hour Forecasting of Solar Radiation

Short-term solar forecasting models based solely on global horizontal irradiance (GHI) measurements are often unable to discriminate the forecasting of the factors affecting GHI from those that can be precisely computed by atmospheric models. Our previous study introduced a Physics-based Smart Persistence model for Intra-hour forecasting of solar radiation (PSPI) that decomposed the forecasting of GHI into the computation of extraterrestrial solar radiation and solar zenith angle and the forecasting of cloud albedo and cloud fraction. The extraterrestrial solar radiation and solar zenith angle were accurately computed by the Solar Position Algorithm (SPA) developed at the National Renewable Energy Laboratory (NREL). A cloud retrieval technique was used to estimate cloud albedo and cloud fraction from surface-based observations of GHI. With the assumption of persistent cloud structures, the cloud albedo and cloud fraction were predicted for future time steps using a two-stream approximation and a 5-minute exponential weighted moving average, respectively. The model evaluation indicated the estimation and forecast of cloud fraction mostly contributed to the uncertainty of the PSPI though it overcame the persistence and smart persistence models in all forecast time horizons between 5 and 60 minutes. This study aims to enhance the PSPI by ingesting surface-based observations of cloud fraction from a total sky imager (TSI). The estimation and forecast of cloud albedo is correspondingly improved by utilizing the cloud fraction observations and thus leads to more accurate GHI forecast. Various time-series analysis methods are also investigated on the forecasting of cloud fraction and cloud albedo for further improving the GHI forecast. These improvements are valuable for many applications, such as forecasting energy use for buildings, grid operations, and ultimately bringing down the cost of solar energy.

14 SOLAR ENERGY↗

First subleading power resummation for event shapes

We derive and analytically solve renormalization group (RG) equations of gauge invariant non-local Wilson line operators which resum logarithms for event shape observables τ at subleading power in the τ « 1 expansion. These equations involve a class of universal jet and soft functions arising through operator mixing, which we call θ-jet and θ-soft functions. An illustrative example involving these operators is introduced which captures the generic features of subleading power resummation, allowing us to derive the structure of the RG to all orders in αs, and provide field theory definitions of all ingredients. As a simple application, we use this to obtain an analytic leading logarithmic result for the subleading power resummed thrust spectrum for H → gg in pure glue QCD. This resummation determines the nature of the double logarithmic series at subleading power, which we find is still governed by the cusp anomalous dimension. We check our result by performing an analytic calculation up to O(α$3\atop{s}$). Consistency of the subleading power RG relates subleading power anomalous dimensions, constrains the form of the θ-soft and θ-jet functions, and implies an exponentiation of higher order loop corrections in the subleading power collinear limit. Our results provide a path for carrying out systematic resummation at subleading power for collider observables.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Iterative quantum optimization of spin glass problems with rapidly oscillating transverse fields

In this work, we introduce a new iterative quantum algorithm, called Iterative Symphonic Tunneling for Satisfiability problems (IST-SAT), which solves quantum spin glass optimization problems using high-frequency oscillating transverse fields. IST-SAT operates as a sequence of iterations, in which bitstrings returned from one iteration are used to set spin-dependent phases in oscillating transverse fields in the next iteration. Over several iterations, the novel mechanism of the algorithm steers the system toward the problem ground state. We benchmark IST-SAT on sets of hard MAX-3-XORSAT problem instances with exact state vector simulation, and report polynomial speedups over Trotterized adiabatic quantum computation and the best known semi-greedy classical algorithm. When IST-SAT is seeded with a sufficiently good initial approximation, the algorithm converges to exact solution(s) in a polynomial number of iterations. Our numerical results identify a critical Hamming radius, or quality of initial approximation, where the time-to-solution crosses from exponential to polynomial scaling in problem size. This work proposes IST-SAT a new quantum algorithm, which improves upon solutions obtained from initial classical or quantum optimization algorithms. The steering mechanism we introduce through IST-SAT presents a new path toward achieving quantum advantage in optimization.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Scattering in black hole backgrounds and higher-spin amplitudes. Part II

We continue to investigate correspondences between, on the one hand, scattering amplitudes for massive higher-spin particles and gravitons in appropriate quantum-to-classical limits, and on the other hand, classical gravitational interactions of spinning black holes according to general relativity. We first construct an ansatz for a gravitational Compton amplitude, at tree level, constrained only by locality, crossing symmetry, unitarity and consistency with the linearized-Kerr 3-point amplitude, to all orders in the black hole’s spin. We then explore the extent to which a unique classical Compton amplitude can be identified by comparing with the results of the classical process of scattering long-wavelength gravitational waves off an exact Kerr black hole, determined by appropriate solutions of the Teukolsky equation. Up to fourth order in spin, we find complete agreement with a previously conjectured exponential form of the tree-level Compton amplitude. At higher orders, we extract tree-level contributions from the Teukolsky amplitude by an analytic continuation from a physical (a/GM < 1) to a particle-like (a/GM > 1) regime. Up to the sixth order in spin, we identify a unique conservative part of the amplitude which is insensitive both to the choice of boundary conditions at the black hole horizon and to branch choices in the analytic continuation. The remainder of the amplitude is determined modulo an overall sign from a branch choice, with the sign flipping under exchanging purely ingoing and purely outgoing boundary conditions at the horizon. Along the way, we make contact with novel applications of massive spinor-helicity variables pertaining to their relation to EFT operators and (spinning) partial amplitudes.

79 ASTRONOMY AND ASTROPHYSICS↗

Advancing the science and impact of blockchain technology at Oak Ridge National Laboratory

Over the last decade, blockchain technology has experienced unprecedented growth from its humble beginnings as the decentralized currency Bitcoin in 2009 to a $500 billion industry today with applications including decentralized cloud computing, peer-to-peer lending, governance, social media, cybersecurity and the development of decentralized, trustless smart contracts and applications. Although it has not yet reached maturity, the blockchain technology industry (sometimes hailed as the “Web 3.0”) is experiencing exponential growth and adoption: new projects and partnerships are announced almost daily, and top research institutions are beginning to develop novel initiatives in this space. In this white paper, I will outline a vision for the future of blockchain technology at Oak Ridge National Laboratory (ORNL). Specifically, I will (1) introduce the fundamental concepts of blockchain technology and provide a survey of the current state-of-the-art, (2) identify the wide-ranging applications that blockchain technology can have across groups, divisions, and directorates at ORNL, (3) summarize the newly initiated programs in blockchain technology at ORNL’s core partnership universities that may lead to future collaboration opportunities, (4) suggest critical ways that blockchain technology can advance ORNL’s strategic objectives for excellence in science and technology, laboratory operations, and community engagement, and (5) outline the most likely funding strategies to support new blockchain initiatives and partnerships at the Lab. Finally, I will propose a vision for the future of a Blockchain Institute at ORNL.

97 MATHEMATICS AND COMPUTING↗

Fault-tolerant resource comparison of qudit and qubit encodings for diagonal quadratic operators

Finite local Hilbert-space truncations arise naturally in quantum simulations of lattice field theories and motivate qudit encodings, but their fault-tolerant advantage over qubit encodings remains unclear. We compare the non-Clifford cost of implementing quadratic diagonal evolutions, exemplified by 𝑈 = 𝑒$^{−𝑖⁢𝑡⁢𝜙^2_𝑥}$ in a uniform field-amplitude discretization of a real scalar field, using either one logical 𝑑-level qudit or 𝑛 𝑏 = ⌈log 2⁡ 𝑑⌉ logical qubits. We analyze two standard settings: product-formula simulation and linear combination of unitaries (LCU) per block encoding, taking the resource metric to be the number of non-Clifford gates after synthesis into a discrete logical gate set. Because tight synthesis bounds for general single-qudit rotations are not known, we express the qudit constructions in terms of embedded two-level SU⁡(2) rotations and derive explicit finite-𝑑 break-even conditions for their synthesis cost; these serve as compiler targets for when qudit encodings can outperform the qubit baseline. Within the constructive models studied here, product-formula implementations would require an exponentially stronger per-primitive synthesis advantage for qudits to win asymptotically, while in the LCU setting the qubit encoding is asymptotically cheaper in 𝑑. Nevertheless, the finite-𝑑 threshold analysis identifies low-dimensional regions in which qudits can yield meaningful constant-factor savings, particularly for LCU-based implementations. As a secondary analysis of the LCU construction, we use an idealized negligible-overhead qubit-qudit code-switching model to give an absolute 𝑇-count comparison and reinterpret the savings as an allowable per-switch overhead budget.

Godwood, Samuel [Univ. of Liverpool (United Kingdo↗

Verification of 5D continuum gyrokinetic code COGENT: Studies of kinetic drift wave instability

COGENT (Continuum Gyrokinetic Edge New Technology) is a kinetic plasma simulation code that is being developed by the edge simulation laboratory (ESL) collaboration. The original version of the code has been developed in a 4D phase space (2D configuration space and 2D velocity space) to address kinetic plasma phenomena in a complex magnetic field geometry including the core, magnetic separatrix, and scrape-off layer regions. This paper is focused on extending the original 4D phase space to a 5D phase space (3D2V) to address full kinetic turbulences in a tokamak edge region. Here, we report on the current status of 5D COGENT, which presently operates in a shear-less, simple slab geometry. As a verification study, we use the problems of collision-less drift wave instability (universal instability) including its modification in the presence of collisional effects. The simulation model includes the gyrokinetic equations for ion and electron species coupled to the long-wavelength limit of the gyro-Poisson equation. Collisional effects are represented by the Krook collision model. Linear analytical results for the drift mode growth rate and real frequency are recovered, and the non-linear stage is modelled and analysed as well. In addition, extensive 5D runs have been performed to address the effects of the drift wave instability on blob/filamentary structures characteristic of a tokamak edge. Finally, a helical-shaped potential perturbation is observed to grow exponentially in time while spinning around the filament axis with electron drift frequency.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Structural dynamics of first-order phase transition in giant magnetocaloric La(Fe,Si) 13 : The free energy landscape

Maximizing the performance of magnetic refrigerators and thermomagnetic energy harvesters is imperative for their successful implementation and can be done by maximizing their operation frequency. One of the features delimiting the frequency and efficiency of such devices is the phase transition kinetics of their magnetocaloric/thermomagnetic active material. While previous studies have described the magnetic component governing the kinetics of the magnetovolume phase transition in La(Fe,Si) 13 giant magnetocaloric materials, a comprehensive description of its structural component has yet to be explored. In this study, in situ synchrotron X-ray diffraction is employed to describe the structural changes upon magnetic field application/removal. Long magnetic field dependent relaxation times up to a few hundred seconds are observed after the driving field is paused. The phase transition is found to be highly asymmetric upon magnetic field cycling due to the different Gibbs energy landscapes and the absence of an energy barrier upon field removal. An exponential relationship is found between the energy barriers and the relaxation times, suggesting the process is governed by a non-thermal activation over an energy barrier process. Such fundamental knowledge on first-order phase transition kinetics suggests pathways for materials optimization and smarter design of magnetic field cycling in real-life devices.

36 MATERIALS SCIENCE↗