Search NASA⌕ Search

SEARCH · Search NASA

Results for “surface functionalization”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 523 records · Page 29
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

Laser surface fusion of plasma sprayed ceramic turbine seals

The thermal shock resistance of a ceramic layer is improved. An improved abradable lining that is deposited on a shroud forming a gas path seal in turbomachinery is emphasized. Improved thermal shock resistance of a shroud is effective through the deliberate introduction of 'benign' cracks. These are microcracks which will not propagate appreciably upon exposure to the thermal shock environment in which a turbine seal must function. Laser surface fusion treatment is used to introduce these microcracks. The ceramic surface is laser scanned to form a continuous dense layer. As this cools and solidifies, shrinkage results in the formation of a very fine crack network. The presence of this deliberately introduced fine crack network precludes the formation of a catastrophic crack during thermal shock exposure.

Wisander, D. W.↗
NASA NTRS2010

Excitation of Crossflow Instabilities in a Swept Wing Boundary Layer

The problem of crossflow receptivity is considered in the context of a canonical 3D boundary layer (viz., the swept Hiemenz boundary layer) and a swept airfoil used recently in the SWIFT flight experiment performed at Texas A&M University. First, Hiemenz flow is used to analyze localized receptivity due to a spanwise periodic array of small amplitude roughness elements, with the goal of quantifying the effects of array size and location. Excitation of crossflow modes via nonlocalized but deterministic distribution of surface nonuniformity is also considered and contrasted with roughness induced acoustic excitation of Tollmien-Schlichting waves. Finally, roughness measurements on the SWIFT model are used to model the effects of random, spatially distributed roughness of sufficiently small amplitude with the eventual goal of enabling predictions of initial crossflow disturbance amplitudes as functions of surface roughness parameters.

Carpenter, Mark H.↗
DOE OSTI2020

DFT modelling of explicit solid–solid interfaces in batteries: methods and challenges

Density Functional Theory (DFT) calculations of electrode material properties in high energy density storage devices like lithium batteries have been standard practice for decades. By contrast, DFT modelling of explicit interfaces in batteries arguably lacks universally adopted methodology and needs further conceptual development. In this paper, we focus on solid–solid interfaces, which are ubiquitous not just in all-solid state batteries; liquid-electrolyte-based batteries often rely on thin, solid passivating films on electrode surfaces to function. We use metal anode calculations to illustrate that explicit interface models are critical for elucidating contact potentials, electric fields at interfaces, and kinetic stability with respect to parasitic reactions. The examples emphasize three key challenges: (1) the “dirty” nature of most battery electrode surfaces; (2) voltage calibration and control; and (3) the fact that interfacial structures are governed by kinetics, not thermodynamics. To meet these challenges, developing new computational techniques and importing insights from other electrochemical disciplines will be beneficial.

25 ENERGY STORAGE↗
NASA NTRS2001

On the Definition of Surface Potentials for Finite-Difference Operators

For a class of linear constant-coefficient finite-difference operators of the second order, we introduce the concepts similar to those of conventional single- and double-layer potentials for differential operators. The discrete potentials are defined completely independently of any notion related to the approximation of the continuous potentials on the grid. We rather use all approach based on differentiating, and then inverting the differentiation of a function with surface discontinuity of a particular kind, which is the most general way of introducing surface potentials in the theory of distributions. The resulting finite-difference "surface" potentials appear to be solutions of the corresponding continuous potentials. Primarily, this pertains to the possibility of representing a given solution to the homogeneous equation on the domain as a variety of surface potentials, with the density defined on the domain's boundary. At the same time the discrete surface potentials can be interpreted as one specific realization of the generalized potentials of Calderon's type, and consequently, their approximation properties can be studied independently in the framework of the difference potentials method by Ryaben'kii. The motivation for introducing and analyzing the discrete surface potentials was provided by the problems of active shielding and control of sound, in which the aforementioned source terms that drive the potentials are interpreted as the acoustic control sources that cancel out the unwanted noise on a predetermined region of interest.

Tsynkov, S. V.↗
NASA NTRS2018

Applying Machine Learning to Jet Noise Prediction

This presentation summarizes the application of machine learning to jet noise data in an effort to predict the resulting noise from the interaction between a jet and a hard surface. The Aero-Acoustic Propulsion Laboratory at the NASA Glenn Research Center has acquired the noise resulting from the interaction between a jet and metal plate over a range of surface placements (e.g. plate lengths and positions) and a range of jet flow configurations. For each configuration, the noise was measured at 24 observer locations via a microphone array centered around the jet nozzle. An artificial neural network developed with Keras and TensorFlow was trained on the data to predict an 88-band spectrum as a function of surface placement, jet conditions, and observer location. Analysis of the machine learning models provide insight into which experimental parameters contribute more to the noise and which parameters could potentially be removed entirely to simplify future experiments. Preliminary results will be discussed and presented via a live demonstration of the software, which outputs a sound spectrum in real-time with user-inputted jet-surface configurations.

Dowdall, Jonny↗
NASA NTRS1973

Plotting program for aerodynamic lifting surface theory

A description of and users manual for a USA FORTRAN IV computer program which plots the planform and control points of a wing are presented. The program also plots some of the configuration data such as the aspect ratio. The planform data is stored on a disc file which is created by a geometry program. This program, the geometry program, and several other programs are used together in the analysis of lifting, thin wings in steady, subsonic flow according to a kernel function lifting surface theory.

Medan, R. T.↗
DOE OSTI2021

Active mechanisorption driven by pumping cassettes

Pumping macrocycles onto surfaces Numerous chemical processes, ranging from water purification to catalysis, involve sorption of small molecules onto surfaces. Typically, spontaneous attractive interactions favor the binding event. Feng et al . report a mechanisorption process that requires redox manipulations to pump macrocycles from bulk solution onto axles immobilized on a metal-organic framework. The resulting rotaxanes store energy through nonequilibrium charge concentration in their mechanical bonds. Ultimately, the technique could also prove useful for actively partitioning compounds with particular functionality between surface and bulk environments. —JSY

Science & Technology - Other Topics↗
NASA NTRS2002

Test and Analysis Capabilities of the Space Environment Effects Team at Marshall Space Flight Center

Marshall Space Flight Center has developed world-class space environmental effects testing facilities to simulate the space environment. The combined environmental effects test system exposes temperature-controlled samples to simultaneous protons, high- and low-energy electrons, vacuum ultraviolet (VUV) radiation, and near-ultraviolet (NUV) radiation. Separate chambers for studying the effects of NUV and VUV at elevated temperatures are also available. The Atomic Oxygen Beam Facility exposes samples to atomic oxygen of 5 eV energy to simulate low-Earth orbit (LEO). The LEO space plasma simulators are used to study current collection to biased spacecraft surfaces, arcing from insulators and electrical conductivity of materials. Plasma propulsion techniques are analyzed using the Marshall magnetic mirror system. The micro light gas gun simulates micrometeoroid and space debris impacts. Candidate materials and hardware for spacecraft can be evaluated for durability in the space environment with a variety of analytical techniques. Mass, solar absorptance, infrared emittance, transmission, reflectance, bidirectional reflectance distribution function, and surface morphology characterization can be performed. The data from the space environmental effects testing facilities, combined with analytical results from flight experiments, enable the Environmental Effects Group to determine optimum materials for use on spacecraft.

Finckenor, M. M.↗
NASA NTRS1977

Secondary-electron-emission properties of conducting surfaces with application to multistage depressed collectors for microwave amplifiers

To improve the efficiency of high power microwave tubes, low secondary electron yield electrode surface for use in depressed collectors are needed. The secondary emission characteristics of a number of materials were investigated. The materials studied were beryllium, carbon (soot and pyrolytic graphite), copper, titanium carbide, and tantalum. Both total secondary yield delta and relative reflected primary yield were measured. These measurements were made in conjunction with Auger spectroscopy so that the secondary emission characteristics could be determined as a function of surface contamination or purity. The results show that low atomic weight elements, such as beryllium and carbon, have the lowest reflected primary yield and that roughening the surface of an electrode can markedly decrease secondary yield both for delta and reflected primaries. All factors considered, a roughened pyrolytic graphite surface showed the greatest potential for use as an electrode surface in depressed collectors.

Forman, R.↗
NASA NTRS2010

Examination of Scanning Electron Microscope and Computed Tomography Images of PICA

Micrographs of PICA (Phenolic Impregnated Carbon Ablator) taken using a Scanning Electron Microscope (SEM) and 3D images taken with a Computed Tomography (CT) system are examined. PICA is a carbon fiber based composite (Fiberform ) with a phenolic polymer matrix. The micrographs are taken at different surface depths and at different magnifications in a sample after arc jet testing and show different levels of oxidative removal of the charred matrix (Figs 1 though 13). CT scans, courtesy of Xradia, Inc. of Concord CA, were captured for samples of virgin PICA, charred PICA and raw Fiberform (Fig. 14). We use these images to calculate the thermal conductivity (TC) of these materials using correlation function (CF) methods. CF methods give a mathematical description of how one material is embedded in another and is thus ideally suited for modeling composites like PICA. We will evaluate how the TC of the materials changes as a function of surface depth. This work is in collaboration with ETH-Zurich, which has expertise in high temperature materials and TC modeling (including CF methods).

Lawson, John W.↗
NASA NTRS1975

The effect of intermediate-scale motions on line formation

The problem of LTE and non-LTE line formation in the presence of nonthermal velocity fields with geometric scales between the microscopic and macroscopic limits is investigated in the cases of periodic sinusoidal and sawtooth waves. For a fixed source function (the LTE case), it is shown that time-averaged line profiles progress smoothly from the microscopic to the macroscopic limits as the geometric scale of the motions increases, that the sinusoidal motions produce symmetric time-averaged profiles, and that the sawtooth motions cause a redshift. In several idealized non-LTE cases, it is found that intermediate-scale velocity fields can significantly increase the surface source functions and line-core intensities. Calculations are made for a two-level atom in an isothermal atmosphere for a range of velocity scales and non-LTE coupling parameters and also for a two-level atom and a four-level representation of Na I line formation in the Harvard-Smithsonian Reference Atmosphere (1971) solar model. It is found that intermediate-scale velocity fields in the solar atmosphere could explain the central intensities of the Na I D lines and other strong absorption lines without invoking previously suggested high electron densities.

Shine, R. A.↗
NASA NTRS1984

Origin of the Greenland Ice Sheet

A climate model resolving the seasonal cycle and the two horizontal dimensions was developed and applied to several problems of current interest. Models of this type are useful when for various reasons a general circulation model experiment is not warranted or not feasible. For example, in cases where the signal to natural variability is small it may be advantageous to first consider such a statistical dynamical model because extremely long runs may be necessary in the application. In this case the simpler statistical dynamical model serves as a pilot study device. The model developed is a thermodynamic model whose solution yields the equilibrium seasonal cycle for the surface temperature field over the globe. The model is essentially a statement of the conservation of heat energy for individual columns of the earth atmosphere system. Various terms such as the infrared radiation flux to space are parameterized with earth radiation budget data from satellites such as Nimbus 6. The primary agent modulating the seasonal cycle amplitude is the heat capacity per unit area which is a strong function of surface type -- ocean surface can store 60 times more heat per unit time than land. By adjusting its few empirical parameters the model can be brought into remarkable agreement with the observed seasonal cycle. The model is then very useful for looking at the dependence of the seasonal cycle of the temperature on such externally defined variables as the Earth's orbital elements (eccentricity, tilt, precession of equinoxes) or the configuration of land-sea geography which can be changed by continental drift.

North, G. R.↗
DOE OSTI2026

Subseasonal Tropical Convection Characteristics in the Energy Exascale Earth System Model Version 2

Accurate simulation of subseasonal tropical moist convection remains a key challenge for Earth system models. The difficulties stem from the reliance of cumulus cloud processes on model parameterizations and the need to represent the multiscale nature of interactions among clouds, radiation, moisture, circulation, and surface energy fluxes. Equatorial convection drives circulation anomalies that can affect weather patterns and extremes globally, motivating efforts to better understand and simulate these tropical disturbances. Here, a detailed review of subseasonal tropical convective behavior as simulated in the Energy Exascale Earth System Model version 2 (E3SMv2) is presented, with comparison to its predecessor version 1 (E3SMv1) and reference data sets. Model structural changes to the deep convective trigger function and surface fluxes, along with parametric tuning of the cloud and microphysics schemes, together result in an improved depiction of organized tropical convection across scales. In particular, E3SMv2 exhibits a more realistic Madden‐Julian oscillation (MJO) and low‐frequency Kelvin waves—owing to a sharper time mean equatorial meridional moisture gradient and improved convection‐circulation coupling —as well as a better depiction of MJO Northern Hemisphere teleconnections. Despite these improvements, subseasonal precipitation variance continues to be strongly underestimated in E3SMv2. Use of a cloud plume model also reveals that the coupling between daily averaged tropical precipitation and lower tropospheric instability in E3SM is inconsistent with observations, a bias that could potentially impact the simulation of intraseasonal disturbances.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1986

Mars vehicle TCS and aerobrake TPS

General design approach, some problems and technology needs for a Mars vehicle manned module Thermal Control System (TCS) and aerobrake Thermal Protection System (TPS) are discussed. The design approach of the TCS will be similar to that of the space station. Mars atmospheric dust storms are identified as an unknown that will impact the design of the Mars landing vehicle and base facility. New technology may be needed for thermal control surfaces to functionally survive the dust storms. The TPS for the Mars aerocapture vehicle will be subject to marginal stagnation heating rates for conjunction class missions and very high heating rates for opposition class missions. New technology TPS materials or an ablative heat shield will be required for the high stagnation heating rate trajectories. No significantly new technology is needed for the manned modules that do not descent to the Mars surface.

Comer, G.↗
NASA NTRS1986

Color constancy - A method for recovering surface spectral reflectance

An algorithm has been developed for estimating the surface reflectance functions of objects in a scene with incomplete knowledge of the spectral power distribution of the ambient light. An image processing system employing this algorithm can assign colors that are constant despite changes in the lighting of the scene; this capability is essential to correct color rendering in photography, TV, and in the construction of artificial visual systems for robotics. Attention is given to the way in which constraints on lights and surfaces in the environment make color-constancy possible for a visual system, and the algorithm's implications for human color vision are discussed.

Maloney, L. T.↗
DOE OSTI2023

Thiol–ene Click Chemistry Incorporates Hydroxyl Functionality on Polycyclooctene to Tune Properties

Polyolefins compose the majority of plastic waste, but conventional mechanical recycling degrades their properties, thereby reducing their value. We report the functionalization of a model for dehydrogenated polyethylene, polycyclooctene (PCOE), with thiol–ene click chemistry to install pendant hydroxyl ethyl thioethers. Functionalization of PCOE using mercaptoethanol via thiol–ene click chemistry yielded functionalization between 1.4 and 22.9% based on ethylene monomeric units. Reactions were well-controlled by varying the reagent stoichiometry and reaction time. Crystallinity and melting temperature decreased, and glass transition temperature increased with greater functionalization. Contact angle measurements reveal an increase in surface polarity with functionalization. Here, comparisons with poly(ethylene-co-vinyl alcohol) (EVOH) show comparable surface polarity at similar levels of alcohol functionalization. At 12% functionalization, the ultimate shear stress (USS) of functionalized PCOE in an adhesive configuration is 4.10 ± 0.48 MPa, comparable to EVOH. At >12% functionalization, the failure mode changed from adhesive to mixed adhesive–cohesive, and the USS decreased.

36 MATERIALS SCIENCE↗
DOE OSTI2022

What can surface wind observations tell us about interannual variation in wind energy output?

The past decade of wind power growth was supported by capacity factor improvements and associated cost reductions. But are higher capacity factors a technology success story or, as suggested by recent research, has the influence of technology been overstated by ignoring positive surface wind speed trends? The answer could influence estimates of wind energy's cost and even future deployment rates. We find that US surface wind speed observations imply a 2.6% improvement in capacity factors from 2010 to 2019. Yet newer vintages of wind plants have recorded capacity factors that are ~25% larger than plants built close to 2010. It follows that technological factors and improved site quality, not higher wind speeds, drove most of the improvement in capacity factors. Additionally, we match hundreds of meteorological stations to nearby (< 25 km) wind plants and compare annual estimated generation, based on a function of surface wind speed observations, to annual recorded generation. Researchers rely on this publicly available surface data because measurements co-located with wind plants are generally considered proprietary. Our analysis addresses a research gap: interannual variation in observed surface wind speeds is rarely compared to observed data at wind plant locations and turbine heights. We find that despite its common use for this purpose, generation estimates based on publicly available surface observational data provide a poor proxy for interannual variability in recorded wind generation. These findings suggest that caution is generally needed when researchers use surface wind speed measurements to investigate long-term wind energy trends.

17 WIND ENERGY↗
NASA NTRS2024

Post-Synthetic Modification of Yttria-Stabilized Zirconia Aerogels with Silica Coatings for Enhanced Thermal Stability

Maintaining high surface area and porosity at high temperatures is important when considering aerogels for use in thermal management systems. The mesoporous structure of aerogels results in extremely low thermal conductivity, making them lightweight, high performance insulating materials. Maintaining these properties requires innovative routes to suppress sintering and pore collapse as use temperatures rise. The current work aims to improve the pore structure stability of yttria-stabilized zirconia aerogels by the addition of a SiO 2 coating. The functionalization of surface hydroxyl groups by the addition of SiO 2 is hypothesized to mitigate condensation reactions, which are a driving force for shrinkage and pore structure collapse. Zirconia aerogels with 0, 10 and 30 mol% yttria (YO 1.5 ) additions were coated in a tetraethyl orthosilicate (TEOS) solution and exposed to temperatures up to 1200°C. Crystal structure, pore structure, and aerogel morphology were investigated to understand changes in aerogel thermal stability. The SiO 2 coating exhibited a greater influence on pore stability over yttria concentration, with specific surface area of the coated aerogels being twice that of the uncoated aerogels up to 1000°C. However, the presence of the SiO 2 coating promoted rapid sintering and densification at 1200°C, establishing an upper use temperature for SiO 2 and a need to develop other coating chemistries.

aerogel↗