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At least 523 records · Page 29

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NASA NTRS1993

Water in Earth's mantle: Hydrogen analysis of mantle olivine, pyroxenes and garnet using the SIMS

Hydrogen (or water) in the Earth's interior plays a key role in the evolution and dynamics of the planet. However, the abundance and the existence form of the hydrogen have scarcely been clear in practice. Hydrogen in the mantle was incorporated in the interior during the formation of the Earth. The incorporated hydrogen was hardly possible to concentrate locally inside the Earth considering its high mobility and high reactivity. The hydrogen, preferably, could be distributed homogeneously over the mantle and the core by the subsequent physical and chemical processes. Therefore, hydrogen in the mantle could be present in the form of trace hydrogen in nominally anhydrous mantle minerals. The hydrogen and the other trace elements in mantle olivines, orthopyroxenes, clinopyroxenes, and garnets were determined using secondary ion mass spectrometry (SIMS) for elucidating (1) the exact hydrogen contents, (2) the correlation between the hydrogen and the other trace elements, (3) the dependence of the hydrogen contents on the depth, and (4) the dependence of the whole rock water contents on the depth.

Kurosawa, Masanori↗

NASA NTRS2024

Percolative Sulfide Core Formation in Oxidized Meteorite Parent Bodies

Most models of planetary differentiation involve the formation of metallic cores during or after extensive silicate melting, but some volatile-rich reservoirs in the protoplanetary disk did not accrete substantial amounts of Fe,Ni-metal. Instead, their potential core-forming assemblages were dominated by Fe,Ni-sulfides and oxides due to high ƒ O 2 and ƒ S 2 . Derivative melts from these assemblages may have been capable of percolative migration leading to core formation prior to silicate melting. However, no direct evidence for this process has been reported in meteoritic literature. Similarly, while many iron meteorites are thought to represent cores of their respective parent bodies, no direct evidence for Fe,Ni-sulfide/oxide cores have been reported to-date. The most promising potential for such evidence may be found in the anomalous noble metal trace element proportions of restitic oxidized primitive achondrites (i.e., brachinites, log ƒ O 2 ~IW-1), which are similar to those found in sulfides of Rumuruti-type chondrites (RCs) that contain only trace amounts of Fe,Ni-metal at log ƒ O 2 ≥ IW-1. This work addresses the following outstanding questions: (1) Are molten sulfides in oxidized meteorite assemblages capable of percolative melt migration? (2) How is this process recorded in the noble metal (i.e., siderophile/chalcophile) trace element geochemistry of relevant meteorites? (3) Did O,S-rich meteorite parent bodies form sulfide cores?

S. D. Crossley↗

NASA NTRS2006

Pyroxenes in Martian meteorites as petrogenetic indicators

Pyroxenes in Martian meteorites are important recorders of petrogenetic processes. Understanding the details of pyroxene major and minor element compositional variations can provide important insights into those processes. A combination of careful petrographic analysis of natural samples and experimental crystallization studies can lead to better understanding of the processes that gave rise to these samples on Mars. In addition, experimentally determined major, minor and trace element partition coefficients are important for using natural pyroxenes to estimate the compositions of the melts from which they crystallized and the oxidation conditions that prevailed during crystallization. We will report on minor element (Al, Ti, Cr) zoning in nakhlite pyroxenes and in synthetic pyroxenes that we have grown for the purposes of determining pyroxene/melt partition coefficients for Sr and REE. The natural pyroxenes have patchy Al zoning that, by analogy with our experimental pyroxenes, we interpret as sector zoning. The irregular patchy nature of the zoning is probably the result of the vagaries of growth kinetics and local environment during crystal growth. More slowly cooled nakhlites have the most distinct bimodal zoning, with one mode having Al2O3 around 0.5-0.6 wt%, and the other around 0.9 %. Average Al content increases with increasing cooling rate. This feature is puzzling, since the cumulus pyroxenes were almost certainly present at the time of eruption. Al and Ti are strongly correlated, but Cr is completely decoupled from those elements. The synthetic pyroxenes are distinctly sector zoned in Al and Ti, and the sector-to-sector variation in Al within a single crystal has important effects on trace element partition coefficients. Trivalent REE are strongly correlated with Al, while divalent elements (Sr, Eu+2) show a significantly weaker correlation. For example, as the Al2O3 content varies from 0.3 to 0.6 wt % from one sector to another, D(Gd) increases by approx.80% while D(Sr) and D(Eu) only increase by 20-30% at oxygen fugacities near IW. The different Al dependency of D for trivalent REE vs. divalent Eu and Sr considerably complicates the calibration of the Eu oxybarometer.

McKay, Gordon↗

NASA NTRS1986

Antarctic and non-Antarctic meteorites form different populations

The trace element differences between Victoria Land H5 chondrites and non-Antarctic H5 chondrites are studied. The focus on common meteorites was stimulated by Antarctic and non-Antarctic differences in meteorite types and in the trace element contents of congeners of rare type. Thirteen elements were analyzed by neutron activation analysis with radiochemical separation, and eight differed significantly. Eliminating test biasing and the possibility of compositional difference due to Antarctic weathering of the 300,000 year-old (on the average) Victoria Land falls, it is concluded that the two sets of chondrites differ due to extraterrestrial causes. The three possibilities discussed, differences in sample population, physical properties, orbital characteristics, and meteoroid flux with time, are all seen as problematic.

Dennison, J. E.↗

NASA NTRS1990

Solutions to problems of weathering in Antarctic eucrites

Neutron activation analysis was performed for major and trace elements on a suite of eucrites from both Antarctic and non-Antarctic sources. The chemistry was examined to see if there was an easy way to distinguish Antarctic eucrites that had been disturbed in their trace elements systematics from those that had normal abundances relative to non-Antarctic eucrites. There was no simple correlation found, and identifying the disturbed meteorites still remains a problem. In addition, a set of mineral separates from an eucrite were analyzed. The results showed no abnormalities in the chemistry and provides a possible way to use Antarctic eucrites that were disturbed in modelling of the eucrite parent body.

Strait, Melissa M.↗

DOE OSTI2019

Effects of industrial disturbances on biodiversity of carrion-associated beetles

Energy production systems such as nuclear reactors and coal-burning power plants produce a multitude of waste contaminants including radionuclides, trace elements, and heavy metals. Among invertebrates, much of the effort to understand the impact of these contaminants has focused in aquatic environments, while relatively less attention has been on terrestrial communities. In this work, we investigated the effects of trace element and radionuclide contamination on assemblages of beetles that are drawn to vertebrate carrion. Samples were collected from riparian sites at the Savannah River Site in South Carolina to compare trap catches (i.e., measure of relative abundance) of beetles and species diversity along a habitat gradient (0–300 m) away from an aquatic habitat and between uncontaminated and contaminated sites. We collected 17,800 carrion-associated beetles representing 112 species in nine families, which were classified as either scavenger or predatory beetles. Beetle catches and species diversity were generally higher at contaminated than uncontaminated sites. These trends were likely driven by scavenger species, which showed similar patterns between sites, whereas patterns of catches and species diversity were variable between sites for predatory beetles. Species compositions of contaminated and uncontaminated sites were generally distinct, however habitat edges appeared to substantially affect beetle assemblages. Overall, our study suggests carrion beetle assemblages are sensitive to edge effects and may exhibit variable responses to the presence of anthropogenic contaminants or disturbances associated with energy production systems. Such results reflect the inherent variability among individual beetle species, populations, and communities to local environmental conditions, and underscores the need for multi-taxa approach in environmental impact assessments.

59 BASIC BIOLOGICAL SCIENCES↗

NASA NTRS1981

Hotspots, basalts, and the evolution of the mantle

It is noted that the trace element concentration patterns of continental and ocean island basalts and of mid-ocean ridge basalts are complementary. Estimates of the relative sizes of the source regions for these fundamentally different basalt types can be arrived at from the trace element enrichment-depletion patterns. Their combined volume occupies the greater part of the mantle above the 670 km discontinuity. It is pointed out that the source regions separated as a result of early mantle differentiation and crystal fractionation from the resulting melt. The mid-ocean ridge basalts source evolved from an eclogite cumulate that gave up its late-stage enriched fluids at various times to the shallower mantle and continental crust. The mid-ocean ridge basalts source is rich in garnet and clinopyroxene, while the continental and ocean island basalt source is a garnet peridotite that has experienced secondary enrichment. These relationships are found to be consistent with the evolution of a terrestrial magma ocean.

Anderson, D. L.↗

NASA NTRS1983

Nickel-iron spherules in tektites - Non-meteoritic in origin

The concentrations of several diagnostic trace elements were determined in two comparatively large NiFe spherules extracted from tektites. The purpose of the study was to obtain some clues about the chemistry of the projectile that is presumed responsible for the formation of these tektites. However, the trace element pattern is distinctly terrestrial implying that the spherules are the result of in-situ reduction of the host rock and are not meteoritic in origin.

Ganapathy, R.↗

DOE OSTI2020

Distribution of rare earth elements in fly ash derived from the combustion of Illinois Basin coals

This study examined rare earth element (REE) trends for Illinois Basin coal-sourced fly ashes, with the goal of understanding the elemental composition and resource potential for various fly ash fractions. Illinois Basin coals have a high volatile C through A bituminous rank with a moderate ash content (slightly>12% ash (dry basis)), about 3% sulfur, and, in general, lower concentrations of hazardous and other trace elements than many Central Appalachian coals. Fly ash from the combustion of Illinois Basin coals tends to have a high Fe 2 O 3 content owing to the amount of pyrite in the feed coals. The rare earth element (REE) concentrations in Illinois Basin coal-sourced fly ashes are less than that for fly ashes from the combustion of Central Appalachian coals. The Upper continental crust-corrected fly ashes show an H-type enrichment, a positive Eu N /Eu N * , and, in some cases, a sharp Gd peak. For comparison, a suite of fly ashes from the combustion of a blend of eastern Kentucky coals had an H-type enrichment, a positive Eu N /Eu N * , but only a minimal Gd peak. In contrast, fly ash from the combustion of the Fire Clay coal, a REE-rich coal, had a negative Eu N /Eu N * and a sharp Gd peak. Finally, these results highlight the importance of feed coal composition on trace element contents of respective combustion fly ash fractions and also the unique REE enrichment patterns of the Illinois Basin fly ashes relative to the better studied fly ashes of eastern Kentucky and Central Appalachia.

01 COAL, LIGNITE, AND PEAT↗

NASA NTRS1984

Petrogenesis of the SNC (shergottites, nakhlites, chassignites) meteorites - Implications for their origin from a large dynamic planet, possibly Mars

Comprehensive chemical data are presented on the shergottites Shergotty, Zagami, Allan Hills (ALHA) 77005, and the new member Elephant Moraine (EETA) 79001 using results of sequential instrumental and radiochemical neutron activation analysis. The close relationship of the Antarctic shergotites indicates that ALHA 77005 is a residual source produced by incongruent melting of a source similar in bulk composition to EETA 79001A and that EETA 79001B and the interstitial phases in EETA 79001A are the melts produced by such melting episodes. The large ion lithophile LIL) trace element abundanced of the shergottites require variable but extensive degrees of nomodal melting of isotopically constrained parent sources. The SNG sources are consistent with their derivation by extensive fractionation of a primitive magma initially produced from a source having chondritic refractory LIL trace element abundances. Petrogenetic and age relationships among SNC meteorites suggest a single complex-provenance on a dynamic planet not unlike earth, probably Mars.

Smith, M. R.↗

NASA NTRS1992

Proceedings of Lunar and Planetary Science, Volume 22; Conference, Houston, TX, Mar. 18-22, 1991

Various papers on lunar and planetary science are presented. Individual topics addressed include: analysis of Phobos Mission Gamma ray spectra from Mars, comparison of volcanic and modified landforms from Tharsis Montes on Mars, polygenetic origin of Hrad Vallis region of Mars, new evidence of lacustrine basins on Mars, flood surge through the Lunae Planum Outflow Complex on Mars, interpretation of canyon materials and flood sources on Kasei Valles on Mars, geochemistry of Manson Impact structure rocks, micrometer-sized glass spheres in Apollo 16 soil 61181, isotopic abundances in Pesyanoe of solar-type xenon, mineralogy of 12 large 'chondritic' interplanetary dust particles. Also discussed are: trace elements in chondritic stratospheric particles, evolution of isotopic signatures in lunar regolith nitrogen, pyroclastic deposits on the western limb of the moon, origin of picritic green glass magmas by polybaric fractional fusion, origin of yellow glasses associated with Apollo 15 KREEP basalt fragments, trace elements in 59 mostly highland moon rocks, mineralization on the moon, relation between diogenite cumulates and eucrite magmas.

Ryder, Graham↗

NASA NTRS1975

Meteoritic material in four terrestrial meteorite craters

In the reported studies of meteoritic material on the moon an attempt was made to characterize the nature of the projectile from the abundance pattern of certain diagnostic trace elements, such as Ir, Re, Ni, Au, Ge, Sb, and Bi. Analyses were conducted of 47 samples from 4 terrestrial meteorite craters. The main object in the investigation was to show that the nature of the projectile could be reliably inferred from the trace-element pattern of the ejecta. In this connection material was analyzed from two terrestrial craters where the projectile itself was known. A second objective was to characterize the projectile at two craters where no discrete meteoritic fragments had been found.

Morgan, J. W.↗

NASA NTRS1974

Meteoritic material on the moon

Micrometeorites, ancient planetesimal debris from the early intense bombardment, and debris of recent, crater-forming projectiles are discussed and their amounts and compositions have been determined from trace element studies. The micrometeorite component is uniformly distrubuted over the entire lunar surface, but is seen most clearly in mare soils whereas, the ancient component is seen in highland breccias and soils. A few properties of the basin-forming objects are inferred from the trace element data. An attempt is made to reconstruct the bombardment history of the moon from the observation that only basin-forming objects fell on the moon after crustal differentiation. The apparent half-life of basin-forming bodies is close to the calculated value for earth-crossing planetesimals. It is shown that a gap in radiometric ages is expected between the Imbrium and Nectaris impacts, because all 7 basins formed in this interval lie on the farside or east limb.

Morgan, J. W.↗

NASA NTRS2013

The Petrology and Geochemistry of Feldspathic Granulitic Breccia NWA 3163: Implications for the Lunar Crust

Lunar meteorites are crucial to understand the Moon s geological history because, being samples of the lunar crust that have been ejected by random impact events, they potentially originate from areas outside the small regions of the lunar surface sampled by the Apollo and Luna missions. The Apollo and Luna sample sites are contained within the Procellarum KREEP Terrain (PKT, Jolliff et al., 2000), where KREEP refers to potassium, rare earth element, and phosphorus-rich lithologies. The KREEP-rich rocks in the PKT are thought to be derived from late-stage residual liquids after approx.95-99% crystallization of a lunar magma ocean (LMO). These are understood to represent late-stage liquids which were enriched in incompatible trace elements (ITE) relative to older rocks (Snyder et al., 1992). As a consequence, the PKT is a significant reservoir for Th and KREEP. However, the majority of the lunar surface is likely to be significantly more depleted in ITE (84%, Jolliff et al., 2000). Lunar meteorites that are low in KREEP and Th may thus sample regions distinct from the PKT and are therefore a valuable source of information regarding the composition of KREEP-poor lunar crust. Northwest Africa (NWA) 3163 is a thermally metamorphosed ferroan, feldspathic, granulitic breccia composed of igneous clasts with a bulk anorthositic, noritic bulk composition. It is relatively mafic (approx.5.8 wt.% FeO; approx.5 wt.% MgO) and has some of the lowest concentrations of ITEs (17ppm Ba) compared to the feldspathic lunar meteorite (FLM) and Apollo sample suites (Hudgins et al., 2011). Localized plagioclase melting and incipient melting of mafic minerals require localized peak shock pressures in excess of 45 GPa (Chen and El Goresy, 2000; Hiesinger and Head, 2006). NWA 3163, and paired samples NWA 4481 and 4883, have previously been interpreted to represent an annealed micro-breccia which was produced by burial metamorphism at depth in the ancient lunar crust (Fernandes et al., 2009). This is in contrast to the interpretation of Hudgins et al. (2009) where NWA 3163 was interpreted to have formed through contact metamorphism. To further constrain its origin, we examine the petrogenesis of NWA 3163 with a particular emphasis on in-situ measurement of trace elements within constituent minerals, Sm-Nd and Rb-Sr isotopic systematics on separated mineral fractions and petrogenetic modeling.

McLeod, C. L.↗

NASA NTRS1983

Chemical characteristics and origin of H chondrite regolith breccias

Petrologic data and contents of Ag, Bi, Cd, Co, Cs, Ga, In, Rb, Se, Te, Tl and Zn-trace elements spanning the volatility/mobility range-in light and dark portions of H chondrite regolith breccias and L chondrite fragmental breccias are reported. The chemical/petrologic characteristics of H chondrite regolith breccias differ from those of nonbrecciated chondrites or fragmental breccias. Petrologic characteristics and at least some trace element contents of H chondrite regolith breccias reflect primary processes; contents of the most volatile/mobile elements may reflect either primary or secondary processing, possibly within layered H chondrite parent object(s). Chemical/petrologic differences existed in different regions of the parent(s). Regoligh formation and gardening and meteoroid compaction were not so severe as to alter compositions markedly.

Lipschutz, M. E.↗

NASA NTRS2006

Geochemistry of Pallasite Olivines and the Origin of Main-Group Pallasites

Main-group pallasites (PMG) are mixtures of iron-nickel metal and magnesian olivine thought to have been formed at the core-mantle boundary of an asteroid [1]. Some have anomalous metal compositions (PMG-am) and a few have atypically ferroan olivines (PMG-as) [2]. PMG metal is consistent with an origin as a late fractionate of the IIIAB iron core [2]. Most PMG olivines have very similar Fe/Mg ratios, likely due to subsolidus redox reaction with the metal [3]. In contrast, minor and trace elements show substantial variation, which may be explained by either: (i) PMG were formed at a range of depths in the parent asteroid; the element variations reflect variations in igneous evolution with depth, (ii) the pallasite parent asteroid was chemically heterogeneous; the heterogeneity partially survived igneous processing, or (iii) PMG represent the core-mantle boundaries of several distinct parent asteroids [4, 5]. We have continued doing major, minor and trace elements by EMPA and INAA on a wider suite of PMG olivines, and have begun doing precise oxygen isotope analyses to test these hypotheses. Manganese is homologous with Fe(2+), and can be used to distinguish between magmatic and redox processes as causes for Fe/Mg variations. PMG olivines have a range in molar 1000*Mn/Mg of 2.3-4.6 indicating substantial igneous fractionation in olivines with very similar Fe/Mg (0.138-0.148). The Mg-Mn-Fe distributions can be explained by a fractional crystallization-reduction model; higher Mn/Mg ratios reflect more evolved olivines while Fe/Mg is buffered by redox reactions with the metal. There is a positive association between Mn/Mg and Sc content that is consistent with igneous fractionation. However, most PMG olivines fall within a narrow Mn/Mg range (3.0-3.6), but these show a substantial range in Sc (1.00-2.29 micro-g/g). Assuming fractional crystallization, this Sc range could have resulted from approx.65% crystallization of an ultramafic magma. This is inconsistent with formation at the core-mantle boundary of a single asteroid [4]. One alternative is that the PMG are fragments of several asteroids, and these could have had different initial Sc contents, Mn/Mg and differences in igneous history. Our preliminary O isotope data and those of [6, 7] do not support this, although the coverage of PMG olivines is incomplete. The PMG-as Springwater is not easily fit in any scenario. Its olivine has among the highest Mn/Mg suggesting it is one of the most evolved, but the lowest Sc content suggesting it is the least evolved. The O isotopic composition of Springwater olivine is the same as that of other PMG. Thus there is no indication that it represents a distinct parent asteroid. Our preliminary O isotopic data favor a single PMG parent asteroid. In this case, the olivines are more likely melt-residues, and that the parent asteroid was initially heterogeneous in chemical, but not isotopic, composition.

Mittlefehldt, D. W.↗

NASA NTRS1993

An H chondrite stream - Identification and confirmation

Fall data indicate that a significant, elongate cluster of co-orbital H chondrite falls in May between 1855 and 1895 (H Cluster 1) records encounters with two or three closely spaced and probably related meteoroid stream components, each of which was met near its perihelion. Although meteorites included in the cluster vary widely in petrographic type, shock facies, and Ne-21 exposure age, they have a distinct labile trace element signature that confirms a common thermal history and, thus, a common source region within an H chondrite parent body. Hence, meteorites selected by one criterion (fall parameters) as distinguishable from all other H chondrites, are distinguished from them by another completely different criterion (contents of labile trace elements).

Dodd, Robert T.↗

NASA NTRS1977

The Apollo 17 'melt sheet' - Chemistry, age and Rb/Sr systematics

Major, minor, and trace-element compositions, age data, and Rb/Sr systematics of Apollo 17 boulders have been compiled, and additional analyses performed on a norite breccia clast (77215) included in the Apollo 17, Station 7 boulder. The Apollo 17 boulders are found to be identical or nearly so in major, minor, and trace-element composition, suggesting that they all originated as an impact melt analogous to melt sheets found in larger terrestrial craters. The matrix dates (Ar-40/Ar-39) and Rb/Sr systematics available suggest that this impact melt formed by a single impact about 4 billion years ago. This impact excavated, shocked, brecciated, and melted norites, norite cumulates, and possibly anorthositic gabbros and dunites about 4.4 billion years old. The impact was likely a major one, possibly the Serenitatis basin-forming event.

Winzer, S. R.↗