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Investigations on microstructure, mechanical properties and abrasion resistance of 4wt%Cr-2wt%Mn-2wt%Cu-Fe-B alloy

Highlights: • The microstructure mainly consists of martensite and boride (M{sub 2}B) in the as-cast and heat treated Fe-B alloys, and the M{sub 2}B presents 3D-skeleton continuous-distribution. • After heat treatment, the nucleation and precipitation of secondary borocarbide M{sub 23}(C, B){sub 6} probably take place in an in situ manner within martensite. • The matrix hardness and bulk hardness of Fe-B alloy decrease after heat treatment, this is attributed to the decreasing of B/C concentration of matrix caused by the precipitation of M{sub 23}(C, B){sub 6}. • During the two-body wear process, the wear mechanism of Fe-B alloy is microcutting; with decreasing of hardness of Fe-B alloy, the abrasion resistance of Fe-B alloy decreases, i.e. the heat treatment will decrease the abrasion resistance of Fe-B alloy. - Abstract: The microstructure, mechanical properties and abrasion resistance of Fe-B alloy with 4wt%Cr-2wt%Mn-2wt%Cu addition have been systematically investigated. The results show that the microstructures mainly consist of martensite and boride (M{sub 2}B) in the as-cast and heat treated Fe-B alloys; after heat treatment, the morphology and volume fraction of the M{sub 2}B have little change, meanwhile the nucleation and precipitation of secondary borocarbide M{sub 23}(C, B){sub 6} probably take place in an in situ manner within martensite. Moreover, the M{sub 2}B is identified as chemical formula of Fe{sub 2.04}Cr{sub 0.11}Mn{sub 0.07}(B, C) reflecting body-centred tetragonal (bct) structure, and the secondary borocarbide M{sub 23}(B, C){sub 6} has the stoichiometry of Fe{sub 18.84}Cr{sub 2.84}Mn{sub 0.57}(B, C){sub 6} with face-centred cubic (fcc) structure. After heat treatment, the matrix hardness and bulk hardness of Fe-B alloy decrease owing to the decreasing of B/C concentration of matrix caused by the precipitation of M{sub 23}(C, B){sub 6}, while the fracture toughness of Fe-B alloy increases. Meanwhile, the heat treatment will decrease the wear resistance of Fe-B alloy, i.e. the wear resistance of Fe-B alloy would decrease with reduction of the matrix hardness.

36 MATERIALS SCIENCE↗

Wear in particle based CSP systems from particle abrasion and attrition at high temperature

High temperature particle-based receivers offer distinct advantages over conventional molten salt receivers due to their ability to achieve temperatures above 700 ºC, direct absorption of solar energy as they fall through a beam of concentrated sunlight, and the relative ease of storage (and retrieval using a secondary working fluid) in insulated storage tanks. The use of particles, however, also raises concerns with material degradation from the flow of hot or cold particles through discharge hoppers or along the inner receiver surfaces and other system components (e.g. tubes, valves etc.), depending on operating mode of the receiver. The flow of particles over surfaces may result in loss of material from abrasive wear, impact erosion from impingement under gravitational fall and particle attrition as particles fall and move on top of each other. In the present study, the performance of candidate materials and particles were evaluated through a series of abrasion erosion and particle attrition experiments at room temperature as well as at 800 °C. Candidate materials were subject to abrasive wear from particles at low particle to material velocities inside a resistance heated kiln, and analyzed for changes in mass and surface morphology using cross-sectional scanning electron microscopy (SEM) and energy dispersive x-ray spectroscopy (EDS) tests. The wear rate for different specimens was noted to be largely driven by the strength of chromia scales built on the specimens from exposure to high temperature. Particle attrition measurements explored the susceptibility of particles to breakdown from particle to particle interaction and the generation of fines from this process. At the low velocities expected in particle based CSP plants, the particles tested exhibited near negligible breakdown. However, changes in the particle hardness at 800 ºC resulted in a significantly higher particle breakdown to sizes <40 microns raising potential environmental concerns. In addition to particle breakdown, it was also noted that the sample had oxides from the stainless steel test setup mixed in with the particles. Similar oxides can be expected to turn up in the utility scale particle based CSP plants as well. The presence of oxide was also noted to affect the solar absorptivity of the mixture compared to a clean initial specimen, potentially resulting in a change in the overall efficiency of the CSP plant.

14 SOLAR ENERGY↗

Abrasion wear at high temperature in particle receiver type Concentrating Solar Power Systems

The use of solid particles as a heat transfer fluid in receivers for concentrating solar powerplants has garnered much attention in the past decade. Particles are not only stable at temperatures above 700 °C but are also able to absorb solar energy directly, which gives them a distinct advantage over conventional molten salts. The use of particles can, however, cause material degradation from the flow of hot or cold particles through discharge hoppers or along the inner receiver surfaces and other system components (e.g. tubes, valves etc.), depending on operating mode of the receiver. Stainless steel alloy 316, nickel-based alloy Inconel® 740H®, Haynes 230, and a 60% alumina, low-cement refractory castable from Allied Mineral Products were tested for wear from first-of-a-kind high-temperature low-velocity abrasion-erosion experiments. The tests are designed to simulate potential conditions in Generation 3 falling particle Concentrating Solar Power (CSP) systems. Simultaneous experiments were conducted at room temperature as well to draw comparison on the role of temperature on abrasion wear rates. It was noted that the abrasion wear rate in candidate materials was driven by the oxidation resistance of the material. The findings from these experiments will be used to determine life-time of critical components in particle receiver concentrated solar powerplants.

14 SOLAR ENERGY↗

Optical-model abrasion cross sections for high-energy heavy ions

Within the context of eikonal scattering theory, a generalized optical model potential approximation to the nucleus-nucleus multiple scattering series is used in an abrasion-ablation collision model to predict abrasion cross sections for relativistic projectile heavy ions. Unlike the optical limit of Glauber theory, which cannot be used for very light nuclei, the abrasion formalism is valid for any projectile target combination at any incident kinetic energy for which eikonal scattering theory can be utilized. Results are compared with experimental results and predictions from Glauber theory.

Townsend, L. W.↗

An abrasion-ablation model description of galactic heavy-ion fragmentation

The fragmentation of high-energy galactic heavy ions by nuclear interactions with arbitrary target nuclei is described within the context of a simple abrasion-ablation fragmentation model. The abrasion part of the theory utilizes a quantum-mechanical formalism based upon an optical model potential approximation to the exact nucleus-nucleus multiple-scattering series. Nuclear charge distributions of the excited prefragments are calculated using either a hypergeometric distribution or a method based upon the zero-point oscillations of the giant dipole resonance. The excitation energy of the prefragment is estimated from the geometric clean-cut abrasion-ablation model. The decay probabilities for the various particle emission channels, in the ablation stage of the fragmentation, are obtained from the EVAP-4 Monte Carlo computer program. Elemental production cross sections for 1.88-GeV/nucleon iron colliding with carbon, silver, and lead targets are calculated and compared with experimental data and with the predictions from the semiempirical relations of Silberberg and Tsao.

Townsend, L. W.↗

Aeolian abrasion on Venus: Preliminary results from the Venus simulator

The role of atmospheric pressure on aeolian abrasion was examined in the Venus Simulator with a constant temperature of 737 K. Both the rock target and the impactor were fine-grained basalt. The impactor was a 3 mm diameter angular particle chosen to represent a size of material that is entrainable by the dense Venusian atmosphere and potentially abrasive by virtue of its mass. It was projected at the target 10 to the 5 power times at a velocity of 0.7 m/s. The impactor showed a weight loss of approximately 1.2 x 10 to the -9 power gm per impact with the attrition occurring only at the edges. Results from scanning electron microscope analysis, profilometry, and weight measurement are summarized. It is concluded that particles can incur abrasion at Venusian temperatures even with low impact velocities expected for Venus.

Marshall, J. R.↗

Plasma-polymerized coating for polycarbonate: Single-layer, abrasion resistant, and antireflection

Plasma-polymerized vinyl trimethoxy silane films were deposited on transparent polycarbonate substrates. The adherent, clear films protected the substrates from abrasion and also served as antireflection coatings. Post-treatment of the vinyl trimethoxy silane films in an oxygen glow discharge further improved their abrasion resistance. The coatings were characterized by elemental analysis of the bulk, ESCA analysis of the surface, transmission, thickness, abrasion resistance, haze, and adhesion. This patented process is currently used by the world's largest manufacturers of non-prescription sunglasses to protect the plastic glasses from scratching and thereby to increase their useful lifetime.

Wydeven, Theodore↗

Target correlation effects on neutron-nucleus total, absorption, and abrasion cross sections

Second order optical model solutions to the elastic scattering amplitude were used to evaluate total, absorption, and abrasion cross sections for neutron nucleus scattering. Improved agreement with experimental data for total and absorption cross sections is found when compared with first order (coherent approximation) solutions, especially below several hundred MeV. At higher energies, the first and second order solutions are similar. There are also large differences in abrasion cross section calculations; these differences indicate a crucial role for cluster knockout in the abrasion step.

Cucinotta, Francis A.↗

Abrasion-ablation model for neutron production in heavy ion reactions

In heavy ion reactions, neutron production at forward angles is observed to occur with a Gaussian shape that is centered near the beam energy and extends to energies well above that of the beam. This paper presents an abrasion-ablation model for making quantitative predictions of the neutron spectrum. To describe neutrons produced from the abrasion step of the reaction where the projectile and target overlap, the authors use the Glauber model and include effects of final-state interactions. They then use the prefragment mass distribution from abrasion with a statistical evaporation model to estimate the neutron spectrum resulting from ablation. Measurements of neutron production from Ne and Nb beams are compared with calculations, and good agreement is found.

Cucinotta, Francis A.↗

Photodetector Development for the Wheel Abrasion Experiment on the Sojourner Microrover of the Mars Pathfinder Mission

On-board the Mars Pathfinder spacecraft, launched in December of 1996, is a small roving vehicle named Sojourner. On Sojourner is an experiment to determine the abrasive characteristics of the Martian surface, called the Wheel Abrasion Experiment (WAE). The experiment works as follows: one of the wheels of the rover has a strip of black anodized aluminum bonded to the tread. The aluminum strip has thin coatings of aluminum, nickel and platinum deposited in patches. There are five (5) patches or samples of each metal, and the patches range in thickness from 200 A to 1000 A. The different metals were chosen for their differing hardness and their environmental stability. As the wheel is spun in the Martian soil, the thin patches of metal are abraded away, exposing the black anodization. The abrasion is monitored by measuring the amount of light reflected off of the samples. A photodetector was developed for this purpose, and that is the subject of this paper.

Wilt, David M.↗

High Resolution Laser Scanning Techniques for Rock Abrasion and Texture Analyses on Mars and Earth

Aeolian abrasion is operative in many arid locations on Earth and is probably the dominant rock erosion process in the current Martian environment. Therefore, understanding the controlling parameters and rates of aeolian abrasion provides 1) insight into the stability of rocks on planetary surfaces and the environments under which the rocks abrade, and 2) a link between ventifact (a rock abraded by windblown particles) morphology and: a) abrasion conditions, b) possible ancient environments under which the rocks were abraded, and c) rock properties. promising and we plan further investigations in the wind tunnel and field. Our intent here is to discuss the basic technique, initial results, and upcoming plans.

Bridges, N. T.↗

Abrasion-ablation model for neutron production in heavy ion collisions

In intermediate energy nucleus-nucleus collisions, neutron production at forward angles is observed to occur with a Gaussian shape that is centered near the beam energy and extends to energies well above that of the beam. This paper presents an abrasion-ablation model for making quantitative predictions of the neutron spectrum. To describe neutrons produced from the abrasion step of the reaction where the projectile and target overlap, we use the Glauber model and include effects of final-state interactions. We then use the prefragment mass distribution from abrasion with a statistical evaporation model to estimate the neutron spectrum resulting from ablation. Measurements of neutron production from Ne and Nb beams are compared with calculations, and good agreement is found.

NASA Discipline Radiation Health↗

Trajectories and energy transfer of saltating particles onto rock surfaces : application to abrasion and ventifact formation on Earth and Mars

The interaction between saltating sand grains and rock surfaces is assessed to gauge relative abrasion potential as a function of rock shape, wind speed, grain size, and planetary environment. Many kinetic energy height profiles for impacts exhibit a distinctive increase, or kink, a few centimeters above the surface, consistent with previous field, wind tunnel, and theoretical investigations. The height of the kink observed in natural and wind tunnel settings is greater than predictions by a factor of 2 or more, probably because of enhanced bouncing off hard ground surfaces. Rebounded grains increase the effective flux and relative kinetic energy for intermediate slope angles. Whether abrasion occurs, as opposed to simple grain impact with little or no mass lost from the rock, depends on whether the grain kinetic energy (EG) exceeds a critical value (EC), as well as the flux of grains with energies above EC. The magnitude of abrasion and the shape change of the rock over time depends on this flux and the value of EG > EC. Considering the potential range of particle sizes and wind speeds, the predicted kinetic energies of saltating sand hitting rocks overlap on Earth and Mars. However, when limited to the most likely grain sizes and threshold conditions, our results agree with previous work and show that kinetic energies are about an order of magnitude greater on Mars.

planet sufraces↗

Abrasion of Candidate Spacesuit Fabrics by Simulated Lunar Dust

A protocol has been developed that produced the type of lunar soil abrasion damage observed on Apollo spacesuits. This protocol was then applied to four materials (Kevlar(Registered TradeMark), Vectran(Registered TradeMark), Orthofabric, and Tyvek(Registered TradeMark)) that are candidates for advanced spacesuits. Three of the four new candidate fabrics (all but Vectran(Registered TradeMark)) were effective at keeping the dust from penetrating to layers beneath. In the cases of Kevlar(Registered TradeMark) and Orthofabric this was accomplished by the addition of a silicone layer. In the case of Tyvek , the paper structure was dense enough to block dust transport. The least abrasive damage was suffered by the Tyvek(Registered TradeMark). This was thought to be due in large part to its non-woven paper structure. The woven structures were all abraded where the top of the weave was struck by the abrasive. Of these, the Orthofabric suffered the least wear, with both Vectran(Registered TradeMark) and Kevlar(Registered TradeMark) suffering considerably more extensive filament breakage.

Gaier, James R.↗

Abrasion of Candidate Spacesuit Fabrics by Simulated Lunar Dust

A protocol has been developed that produced the type of lunar soil abrasion damage observed on Apollo spacesuits. This protocol was then applied to four materials (Kevlar (DuPont), Vectran (Kuraray Co., Ltd.), Orthofabric, and Tyvek (DuPont)) that are candidates for advanced spacesuits. Three of the four new candidate fabrics (all but Vectran) were effective at keeping the dust from penetrating to layers beneath. In the cases of Kevlar and Orthofabric this was accomplished by the addition of a silicone layer. In the case of Tyvek, the paper structure was dense enough to block dust transport. The least abrasive damage was suffered by the Tyvek. This was thought to be due in large part to its non-woven paper structure. The woven structures were all abraded where the top of the weave was struck by the abrasive. Of these, the Orthofabric suffered the least wear, with both Vectran and Kevlar suffering considerably more extensive filament breakage.

Gaier, James R.↗

Standardization of a Volumetric Displacement Measurement for Two-Body Abrasion Scratch Test Data Analysis

A limitation has been identified in the existing test standards used for making controlled, two-body abrasion scratch measurements based solely on the width of the resultant score on the surface of the material. A new, more robust method is proposed for analyzing a surface scratch that takes into account the full three-dimensional profile of the displaced material. To accomplish this, a set of four volume- displacement metrics was systematically defined by normalizing the overall surface profile to denote statistically the area of relevance, termed the Zone of Interaction. From this baseline, depth of the trough and height of the plowed material are factored into the overall deformation assessment. Proof-of-concept data were collected and analyzed to demonstrate the performance of this proposed methodology. This technique takes advantage of advanced imaging capabilities that allow resolution of the scratched surface to be quantified in greater detail than was previously achievable. When reviewing existing data analysis techniques for conducting two-body abrasive scratch tests, it was found that the ASTM International Standard G 171 specified a generic metric based only on visually determined scratch width as a way to compare abraded materials. A limitation to this method was identified in that the scratch width is based on optical surface measurements, manually defined by approximating the boundaries, but does not consider the three-dimensional volume of material that was displaced. With large, potentially irregular deformations occurring on softer materials, it becomes unclear where to systematically determine the scratch width. Specifically, surface scratches on different samples may look the same from a top view, resulting in an identical scratch width measurement, but may vary in actual penetration depth and/or plowing deformation. Therefore, two different scratch profiles would be measured as having identical abrasion properties, although they differ significantly.

Street, K. W. Jr.↗

Simplified Abrasion Test Methodology for Candidate EVA Glove Lay-Ups

During the Apollo Program, space suit outer‐layer fabrics were badly abraded after performing just a few extravehicular activities (EVAs). For example, the Apollo 12 commander reported abrasive wear on the boots that penetrated the outer‐layer fabric into the thermal protection layers after less than 8 hrs of surface operations. Current plans for the exploration planetary space suits require the space suits to support hundreds of hours of EVA on a lunar or Martian surface, creating a challenge for space suit designers to utilize materials advances made over the last 40 years and improve on the space suit fabrics used in the Apollo Program. Over the past 25 years the NASA Johnson Space Center Crew and Thermal Systems Division has focused on tumble testing as means of simulating wear on the outer layer of the space suit fabric. Most recently, in 2009, testing was performed on 4 different candidate outer layers to gather baseline data for future use in design of planetary space suit outer layers. In support of the High Performance EVA Glove Element of the Next Generation Life Support Project, testing a new configuration was recently attempted in which require 10% of the fabric per replicate of that need in 2009. The smaller fabric samples allowed for reduced per sample cost and flexibility to test small samples from manufacturers without the overhead to have a production run completed. Data collected from this iteration was compared to that taken in 2009 to validate the new test method. In addition the method also evaluated the fabrics and fabric layups used in a prototype thermal micrometeoroid garment (TMG) developed for EVA gloves under the NASA High Performance EVA Glove Project. This paper provides a review of previous abrasion studies on space suit fabrics, details methodologies used for abrasion testing in this particular study, results of the validation study, and results of the TMG testing.

Rabel, Emily↗

Weatherable solar reflector with high abrasion resistance

Described herein are solar reflectors which provide a low cost reflector construction that has a unique set of attributes: high solar reflectance, abrasion resistance, UV stability, mechanical integrity, and flexibility. The abrasion resistance is enabled through incorporation of an abrasion-resistant coating into a polymer film metal mirror construction. Methods of using the solar reflectors in solar concentrating applications are also provided.

14 SOLAR ENERGY↗