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41 records · Page 3

Evaluation of Four Ground-based Retrievals of Cloud Droplet Number Concentration in Marine Stratocumulus with Aircraft In Situ Measurements

Cloud droplet number concentration (N d ) is crucial for understanding aerosol-cloud interactions (ACI) and associated radiative effects. We present evaluations of four ground-based N d retrievals based on comprehensive datasets from the Atmospheric Radiation Measurements (ARM) Aerosol and Cloud Experiments in the Eastern North Atlantic (ACE-ENA) field campaign. The N d retrieval methods use ARM ENA observatory ground-based remote sensing observations from a Micropulse lidar, Raman lidar, cloud radar, and the ARM NDROP Value-added Product (VAP), all of which also retrieve cloud effective radius (r e ). The retrievals are compared against aircraft measurements from the Fast-Cloud Droplet Probe (FCDP) and the Cloud and Aerosol Spectrometer (CAS) obtained from low-level marine boundary layer clouds on 12 flight days during summer and winter seasons. Additionally, the in situ measurements are used to validate the assumptions and characterizations used in the retrieval algorithms. Statistical comparisons of the probability distribution function (PDF) of the N d and cloud r e retrievals with aircraft measurements demonstrate that these retrievals align well with in situ measurements for overcast clouds, but they may substantially differ for broken clouds or clouds with low liquid water path (LWP). The retrievals are applied to four years of ground-based remote sensing measurements of overcast marine boundary layer clouds at the ARM ENA observatory to find that N d (r e ) values exhibit seasonal variations, with higher (lower) values during the summer season and lower (higher) values during the winter season. The ensemble of various retrievals using different measurements and retrieval algorithms such as those in this paper can help to quantify N d retrieval uncertainties and identify reliable N d retrieval scenarios. Of the retrieval methods, we recommend using the using the Micropulse lidar-based method given its good agreement with in situ measurements, it has less sensitivity to issues arising from precipitation and low cloud LWP/optical depth, and it has broad applicability by functioning for both day and nighttime conditions.

54 ENVIRONMENTAL SCIENCES↗

EASTERN NORTH ATLANTIC (ENA) CONDENSATION PARTICLE COUNTER (CPC) with the AEROSOL MASK (ENA-AM) for the YEAR 2017

The Eastern North Atlantic (ENA) central facility is periodically affected by episodes of local aerosols. High-concentration aerosol events associated with potential local aerosol sources are sampled by the Concentration Particle Counter (CPC) and can be observed in the high-time-resolution data. In an effort to remove aerosol data that is not regionally representative from the CPC data, an aerosol mask (ENA-AM) has been previously developed and validated during the ACE-ENA campaing (Gallo et al., 2020). The ENA-AM is a standard deviation algorithm based on the statistically different behavior of adjacent data points used to determine periods when the measurements are impacted by local aerosols. This file contain one-minute time resolution submicron aerosol particle concentration datasets from the CPC for the year 2017, and the corresponding ENA-AM datasets to remove datapoints affected by local aerosol sources.

54 ENVIRONMENTAL SCIENCES↗

EASTERN NORTH ATLANTIC (ENA) CONDENSATION PARTICLE COUNTER (CPC) with the AEROSOL MASK (ENA-AM) for the YEAR 2018

The Eastern North Atlantic (ENA) central facility is periodically affected by episodes of local aerosols. High-concentration aerosol events associated with potential local aerosol sources are sampled by the Concentration Particle Counter (CPC) and can be observed in the high-time-resolution data. In an effort to remove aerosol data that is not regionally representative from the CPC data, an aerosol mask (ENA-AM) has been previously developed and validated during the ACE-ENA campaing (Gallo et al., 2020). The ENA-AM is a standard deviation algorithm based on the statistically different behavior of adjacent data points used to determine periods when the measurements are impacted by local aerosols. This file contain one-minute time resolution submicron aerosol particle concentration datasets from the CPC for the year 2018, and the corresponding ENA-AM datasets to remove datapoints affected by local aerosol sources.

54 ENVIRONMENTAL SCIENCES↗

EASTERN NORTH ATLANTIC (ENA) CONDENSATION PARTICLE COUNTER (CPC) with the AEROSOL MASK (ENA-AM) for the YEAR 2016

The Eastern North Atlantic (ENA) central facility is periodically affected by episodes of local aerosols. High-concentration aerosol events associated with potential local aerosol sources are sampled by the concentration particle counter (CPC) and can be observed in the high-time-resolution data. In an effort to remove aerosol data that is not regionally representative from the CPC data, an aerosol mask (ENA-AM) has been previously developed and validated during the ACE-ENA campaign (Gallo et al. 2020). The ENA-AM is a standard deviation algorithm based on the statistically different behavior of adjacent data points used to determine periods when the measurements are impacted by local aerosols. This file contains one-minute-time-resolution submicron aerosol particle concentration data sets from the CPC for the year 2016, and the corresponding ENA-AM data sets to remove data points affected by local aerosol sources.

54 ENVIRONMENTAL SCIENCES↗

Observed Relationships Between Cloud Droplet Effective Radius and Biogenic Gas Concentrations in Summertime Marine Stratocumulus Over the Eastern North Atlantic

Abstract Biogenic gases are a prominent component of the summertime marine boundary layer (MBL) over the Eastern North Atlantic. One of these gases, dimethyl sulfide (DMS), can produce sulfate cloud condensation nuclei (CCN) that, in theory, can brighten clouds through photolysis, and produces a reaction product, methane sulfonic acid (MSA). It is also possible that DMS can interact with sea‐salt or other marine aerosols changing their CCN activation spectrum, which could also modify cloud microphysical structure. Data collected aboard the G1 aircraft during the Aerosol Cloud Experiment Eastern North Atlantic (ACE‐ENA) in well‐mixed and decoupled marine boundary layers (MBLs) were used to examine relationships between the cloud droplet effective radii, , and the concentrations of DMS and MSA in constant cloud liquid water content (LWC) bins. A weak but statistically significant negative correlation was observed between CCN concentration and in most LWC bins, regardless of the source of the CCN, while a weak but statistically significant positive correlation between and DMS was observed. No correlation between the cloud droplet number concentration and DMS was found. The presence of MSA indicated that DMS‐to‐sulfate photolysis was likely occurring, but data sparsity prevented a statistically significant conclusion regarding the relationship between MSA and . Data sparsity in decoupled conditions also prevented statistically significant conclusions. To properly address biogenic gas impacts on cloud microphysics, it is recommended that aircraft data be supplemented by long‐term biogenic gas measurements at the surface in marine locations with appropriate remote and in‐situ cloud sensing capabilities, and the analysis limited to well‐mixed MBL's.

54 ENVIRONMENTAL SCIENCES↗