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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
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NASA NTRSDate not supplied

Observing of Pre-earthquake Transients Features in Atmosphere-ionosphere Associated with January 2020 Caribbean Earthquakes

Several significant earthquakes occurred in the Caribbean during January 2020. The first earthquake with M = 6.4 occurred on January 7 off the southern coast of Puerto Rico. An earthquake of M7.7occurred in the Caribbean Sea on January 28, 2020, around 19:10 UT on the island of Jamaica. After3 hours (21:55), another M 6.1 earthquake (NEIC / USGS) occurred in the Caribbean. We analyzed, retrospectively, four different atmosphere/ionosphere physical parameters of during the time of these earthquakes namely: (i) the lower atmosphere chemical potential (ACP); (ii) outgoing earth radiation (OLR) at the TOA; (iii) GPS/TEC and; (iv) the very-low-frequency (VLF/LF) signals. We found that at the beginning of January 2020, a rapid increase in satellite measurements of the earth’s atmosphere radiation was recorded, an anomaly appeared over Puerto Rico on January 6 (1 day before the M6.4), and the maxim anomaly appeared eastward from January 20 (eight days before theM7.7). The increases in ACP on January 20-23 were measured near the epicentral area of the M7.7event and coincided with the OLR anomaly. For the VLF analysis, we used the amplitude data of the NAU signal (signal frequency 40.75 kHz), which was received at Chapman University in Orange, California. The length of the signal propagation path from the transmitter to the receiver was about 5300 km. A significant decrease in signal amplitude, exceeding the level of two standard deviations, was observed before the January 7 earthquake (M = 6.4) off the coast of Puerto Rico. A more significant anomaly in the VLF signal was observed before the M7.7 earthquake on January 28. The pre-earthquake nature of the signals in the atmosphere and ionosphere was revealed by simultaneous analysis of satellite, GPS/TEC, and VLF/LF observations. They suggest that they follow a general temporal-spatial evolution pattern, which has been previously observed globally.

D Ouzounov↗
NASA NTRSDate not supplied

Tropical Tropospheric Ozone Trends (1990 to 2022): A Re-evaluation Based on SHADOZ and IAGOS Profiles and TOMS/OMI Columns

Changes in tropical tropospheric ozone (TTO) are of importance because this region spans roughly a third of the Earth and portions of it are experiencing variability in trends of ozone precursors (CO, NO x , CH 4 and nonmethane hydrocarbons) associated with economic growth and fires. In addition to ozone changes affecting radiative forcing, tropical ozone is an important source of the OH radical and thus, the oxidizing capacity of the planet (Thompson, 1992). Recent studies examining TTO trends satellite and in-situ observations over the past ~25 years include: Thompson et al., JGR, 2021; Gaudel et al., ACP, 2023; Stauffer et al., ACP, 2023. The results show considerable regional and seasonal variability in TTO trends and sensitivity to data selection, frequency, and statistical method used. The satellite data vary most widely in method, time period and reliability. Here we revisit trends for the 1990-2022 period with the best-characterized buv-based satellite products that span that period (derived from TOMS and OMI, Ziemke et al., 2019). The satellite-based trends are compared to trends based on in-situ data from the Southern Hemisphere Additional Ozonesondes (SHADOZ) network (1998-2022), measurements from selected pre-SHADOZ and IAGOS commercial aircraft data (Gaudel et al., 2023). Among sensitivities examined are the dependence of ozone trends on start and end years, impacts of ENSO events and the COVID-19 perturbation to emissions. Two statistical methods are used, quantile regression (QR) and multiple linear regression (MLR). Trends of total TTO, ozone segments in the boundary layer (to ~700 hPa), and free troposphere (700-300 hPa) are compared.

ozone, OMI, tropospheric ozone, SHADOZ↗
NASA NTRSDate not supplied

Integration of Fatigue R-Curve Effects into VCCT for Durability Predictions, Part 1: Buckled Composite Single-Stringer Stiffened Panels

Composite structures have become popular in modern aircraft because they help reduce weight and increase durability. In addition, hat-stiffened panels provide the stability that the airframe skin needs. However, they can be subject to delamination in the post-buckling regime. Progressive damage analysis (PDA) methods can help predict interlaminar and intralaminar failure events. Many aircraft structures are subject to cyclic loading in the post-buckling regime. Hence, fatigue life prediction becomes essential for design and sustainment purposes. Under the NASA Advanced Composites Project (ACP), composite panels stiffened with single hat-stringers were subject to a cyclic loading sequence from a pre-buckling state to a post-buckling state. This test campaign aimed to provide damage initiation and growth data for three initial damage scenarios: nominally pristine, initial Teflon inserts representing manufacturing defects, and impact-induced damage. This work uses the Abaqus FEA Virtual Crack Closure Technique (VCCT), capabilities enhanced through a novel empirical method integrating fatigue R-curve effects (different from R-ratio) into the Paris Law via user-defined subroutine to simulate the fatigue response of the panels with single hat-stringers. The analysis predictions were within 5% of the test results using this novel method.

single hat↗
NASA NTRSDate not supplied

Integration of Fatigue R-Curve Effects into VCCT for Durability Predictions, Part 2: Buckled Composite Multi-Stringer Stiffened Panels

Composite structures with hat-stiffened panels have gained traction in modern aircraft because they help reduce weight, increase durability, and provide stability to airframe skins. For weight reduction, skins should be designed to operate in the post-buckling regime. This causes possible interlaminar and intralaminar failure. However, composite panels stiffened with multiple hat-stringers are subject to cyclic loading even in the post-buckling regime. Under the NASA Advanced Composites Project (ACP), composite panels with multiple hatstringers were subject to a cyclic loading sequence from a pre-buckling state to a post-buckling state. This effort aimed to predict interlaminar failure for cyclic compression loading with pre-existent impact-induced damage. This work uses the Abaqus FEA Virtual Crack Closure Technique (VCCT), capabilities enhanced through an empirical method to integrate fatigue R-curve effects (different from R-ratio) into the Paris Law via user-defined subroutine to simulate the fatigue response o

ACP↗
DOE OSTI2026

Metabolic engineering strategies for producing decanoic acid and related oleochemicals: 1-decanol, 2-nonanone, and poly(3-hydroxydecanoate) in Escherichia coli

Medium-chain (mc-) oleochemicals are an important class of renewable chemicals with broad industrial applications; however, their sustainable microbial production remains challenging. In this study, we developed a versatile metabolic engineering and fed-batch strategy to produce C 10 -oleochemicals in Escherichia coli. Central to this approach is an engineered mc-acyl-ACP thioesterase Cl FatB3-tr-D10S with C 10 species accounting for around 70% of the total fatty acids produced. To expand product diversity, we established a decanoyl-CoA pool through co-expression of fadD, enabling downstream conversion into multiple product classes. Through pathway tuning, enzyme bioprospecting, strain engineering and fermentation optimization strategies, we demonstrated selective production of 1-decanol, 2-nonanone and poly(3-hydroxydecanoate) (C 10 -PHA). Production of decanoic acid and 1-decanol were achieved by optimizing expression of Cl fatB3-tr-D10S and, Mt fadD6 and Ma acr, respectively. Leveraging β-oxidation enabled the production of β-ketoacyl-CoA intermediates, which were converted to 2-nonanone via heterologous Mlu fadE, Vf fadB and Ps fadM expression. Additionally, expression of phaJ2 and phaC2 facilitated the conversion of decanoyl-CoA pool into C 10 -PHA homopolymer. Altogether, this work demonstrates a versatile and tunable platform for medium-chain oleochemical production.

1-Decanol↗
DOE OSTI2026

Engineering an Extremely Hybrid PKS for Adipic Acid Production

Polyketide synthases (PKSs) are modular enzymes with exceptional potential as biocatalysts for producing non-native compounds. Here, we report the first PKS-based pathway for adipic acid (AA), an industrial monomer for nylon production, by engineering one of the most extensively hybridized PKS systems to date. Using a retrobiosynthetic approach, we identified EtnB, a succinyl-CoA-loading module that uniquely retains the terminal carboxyl group, enabling access to dicarboxylic polyketide products, rarely produced by canonical PKSs. EtnB was coupled to a fully reducing extension module through an engineered communication linker, which improved ACP–KS interactions, enhanced titers, and demonstrated selective succinyl-CoA loading in vivo . This construct integrates genes from five organisms─with domains from seven PKS modules joined across six non-natural junctions─and functions in both Escherichia coli and Pseudomonas putida . Additional engineering that included AT domain exchanges, optimization of extender unit supply, and host strain metabolic rewiring further increased AA production. Together, this work demonstrates that highly chimeric PKSs can be rendered functional through rational design, expands the PKS toolkit with a carboxyl-retaining loading module, and establishes a versatile platform for engineering diacids and other noncanonical products through PKS pathways.

biomanufacturing↗
DOE OSTI2025

Data for Metabolic Engineering of β-Oxidation to Leverage Thioesterases for Production of 2-Heptanone, 2-Nonanone, and 2-Undecanone

Medium-chain length methyl ketones are potential blending fuels due to their cetane numbers and low melting temperatures. Biomanufacturing offers the potential to produce these molecules from renewable resources such as lignocellulosic biomass. In this work, we designed and tested metabolic pathways in Escherichia coli to specifically produce 2-heptanone, 2-nonanone and 2-undecanone. We achieved substantial production of each ketone by introducing chain-length specific acyl-ACP thioesterases, blocking the β-oxidation cycle at an advantageous reaction, and introducing active β-ketoacyl-CoA thioesterases. Using a bioprospecting approach, we identified 15 homologs of E. coli β-ketoacyl-CoA thioesterase (FadM) and evaluated the in vivo activity of each against various chain length substrates. The FadM variant from Providencia sneebia produced the most 2-heptanone, 2-nonanone, and 2-undecanone, suggesting it has the highest activity on the corresponding β-ketoacyl-CoA substrates. We tested enzyme variants, including acyl-CoA oxidases, thiolases, and bi-functional 3-hydroxyacyl-CoA dehydratases to maximize conversion of fatty acids to β-keto acyl-CoAs for 2-heptanone, 2-nonanone, and 2-undecanone production. In order to address the issue of product loss during fermentation, we applied a 20% (v/v) dodecane layer in the bioreactor and built an external water cooling condenser connecting to the bioreactor heat-transferring condenser coupling to the condenser. Using these modifications, we were able to generate up to 4.4 g/L total medium-chain length methyl ketones.

Metabolic Engineering↗
DOE OSTI2025

Plutonium Oxidation State Distribution in the Presence of WIPP-Relevant Organics and Iron Corrosion Products

The oxidation state and solubility of plutonium (Pu) in high ionic strength synthetic WIPP (Waste Isolation Pilot Plant) brines as a function of pC H+ in the presence and absence of WIPP-relevant organic ligands (EDTA [Ethylenediaminetetraacetic acid], oxalate, citrate, acetate) and iron corrosion products (magnetite and metallic iron) at 𝑇 = 23 ± 2 ∘C was thoroughly studied by long-term batch solubility experiments (between approximately 800-1,100 days) from an undersaturation approach. The oxidation state of Pu in the WIPP environment has been a topic of interest since the initial Compliance Certification Application (CCA). This study aims to investigate the solubility of Pu under the expected WIPP conditions and to determine the oxidation state of the solid phase that will control the solubility. One of the most important results of this study is that the Pu oxidation state was analyzed both from the surface area of the corrosion products and in the precipitated solid. The analysis of the Pu oxidation state on the surface of the iron mineral from the ongoing undersaturated experiments is more relevant to the performance assessment of nuclear waste disposal than short term batch (plutonium-iron phase) experiments. The X-ray Absorption Near-Edge Spectroscopy (XANES) analysis showed that Pu oxidation state is different on the metal surface and in the precipitated solid. Pu(III) is the dominant oxidation state in the metallic iron (Fe 0 ) system in the presence and absence of organics. Pu(IV) is the dominant oxidation state in the magnetite system in the presence and absence of organics. Also, organics stabilize Pu(IV) in the magnetite system. Analysis of Pu in the precipitated solid by Extended X-ray Absorption Fine Structure (EXAFS) analysis showed that Pu formed an inner-sphere complex with iron with minor amounts of PuO 2 present. X-ray diffraction (XRD) results indicate that metallic iron and magnetite did not oxidize in three years in the alkaline and high ionic strength system. Under these conditions (8 < pC H+ < 10 at T = (22 ± 2) °C under nitrogen atmosphere, the solubility of Pu changes by up to three orders of magnitude (10 -5 and 10 -8 M). The spread in solubility is highest at pC H+ = 9. Pu(III) and Pu(IV) showed different solubility behavior in the synthetic WIPP brine. A summary of the data collected in this report will be submitted to Sandia National Laboratories as part of a parameter update report which will outline the changes to the OXSTAT parameter for the 2026 Compliance Recertification Application (CRA-2026). The experiments performed were done according to the U.S. Department of Energy (DOE) approved Test Plan entitled “Effects of Radiolysis, Organic Complexation, and Redox Conditions on the Speciation and Oxidation State Distribution of Pu(III/IV)” (LCO-ACP-25). All data reported were obtained under the Los Alamos National Laboratory-Carlsbad Office (LANL-CO) Quality Assurance Program, which is compliant with the DOE Carlsbad Field Office, Quality Assurance Program Document (CBFO/QAPD).

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2025

Monitored Natural Attenuation (MNA) Assessment for the Chemicals, Metals, and Pesticides (CMP) Pits Operable Unit (OU) and the Pen Branch Wetland

In October 2024, Savannah River National Laboratory (SRNL) was tasked to conduct an independent review of groundwater data and assess the monitored natural attenuation (MNA) performance related to the Chemicals, Metals, and Pesticides (CMP) Pits Operable Unit (OU) located in the central portion of the Savannah River Site (SRS). The SRNL assessment of MNA entailed an independent analysis of groundwater concentration data, groundwater elevation data, available surface water concentration data, soil concentration data, and relevant historical geological characterization logs for the CMP Pits OU. Historical data tables and records were obtained from both the Savannah River Nuclear Solutions - Area Completion Projects (SRNS&#x2;ACP) team and South Carolina State University (SCSU) and condensed into new data sets by the SRNL project team for more targeted analysis of MNA performance characteristics. All data pertaining to groundwater concentration, surface water concentration, and groundwater elevation were restricted to collection dates after any known active remediation for the CMP OU.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Humate Amendment Injection Viability Testing – Supplementary Batch Mixture and Soil Column Studies

Groundwater in the Lost Lake Aquifer Zone (LLAZ) in the Southern Sector of the M-Area Hazardous Waste management Facility (HWMF) is contaminated with chlorinated ethenes, including trichloroethylene (TCE) and tetrachloroethylene (PCE). Treatment of contaminated groundwater with humic acid is being evaluated as a potential corrective action for these volatile organic compounds (VOCs) in the LLAZ in Southern Sector (SRNS, 2019). Pilot scale injections of Huma-K brand humic acid for groundwater treatment were previously performed in M-Area between 2017 and 2020 (Amidon, 2023). Groundwater was extracted from the Lost Lake Aquifer Zone (LLAZ), then a solution of humate was mixed with recovered groundwater and subsequently re-injected into the same aquifer unit. Operations of the historical humate pilot testing were discontinued in 2020 due to COVID-19 restrictions, low injection rates, and recirculation fluid spillage. No further field scale or laboratory research to investigate humate amended groundwater injection was performed at the SRS until 2024. At the request of Area Completion Projects (ACP), the Savannah River National Laboratory (SRNL) performed supplementary testing to help determine the viability of further injection of humate as a remedial option for VOCs within the LLAZ in the Southern Sector of the M-Area HWMF.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2025

Biologically Influenced Transport of the +3 Actinide Oxidation State from the WIPP Environment, Using Neodymium as an Analog

This report provides an update to a previously issued report on the bioassociation of the +3 actinide analog, neodymium, with Waste Isolation Pilot Plant (WIPP) microbial isolates (LCO ACP-32, Biologically Influenced Transport of the +3 Actinide Oxidation State from the WIPP Environment, Using Neodymium as an Analog ). Results contribute to updates for the biocolloid parameters for the 2026 Compliance Recertification Application (CRA-2026).

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2025

Synthesis of aerosol-cloud interactions over the southeast Atlantic throughout the seasonal cycle (Final Technical Report)

An analysis of the aerosol compositional, physical and optical datasets towards understanding why the single‐scattering‐albedo of smoke is so much lower over the southeast Atlantic than elsewhere, in particular the northern hemisphere. This includes data from the complementary NASA ORACLES aircraft campaign, which sampled closer to the African coast. The first analysis resulting from this prong of research was published earlier this year (Dobracki et al., 2023, ACP) and focused more on the free-tropospheric biomass burning aerosol (BBA). We primarily attributed the low SSA to a high number/mass fraction of black carbon, ranging from 15 to 40% of the total aerosol. We are further able to use other literature, the modified combustion efficiency, and the black carbon and carbon monoxide values to highlight a common source in dry, flame-efficient burning conditions of grasses. Condensation and coagulation of smaller aerosol particles onto the larger black carbon aerosols can also increased the SSA as the aerosol ages from 4 to 5 days. A comparison to data gathered over Ascension Island during the UK CLARIFY aircraft campaign indicates an organic aerosol loss relative to black carbon of about 50%. This is high compared to findings from other campaigns.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1973

Integrated thruster assembly program

The program is reported which has provided technology for a long life, high performing, integrated ACPS thruster assembly suitable for use in 100 typical flights of a space shuttle vehicle over a ten year period. The four integrated thruster assemblies (ITA) fabricated consisted of: propellant injector; a capacitive discharge, air gap torch type igniter assembly; fast response igniter and main propellant valves; and a combined regen-dump film cooled chamber. These flightweight 6672 N (1500 lb) thruster assemblies employed GH2/GO2 as propellants at a chamber pressure of 207 N/sq cm (300 psia). Test data were obtained on thrusted performance, thermal and hydraulic characteristics, dynamic response in pulsing, and cycle life. One thruster was fired in excess of 42,000 times.

Source record↗
NASA NTRS1979

Isoelectric focusing of proteins and peptides

Egg-white solution was chosen as the reference solution in order to assess the effects of operational parameters (voltage, flow rate, ampholine pH range and concentration, and protein concentration) of the RIEF apparatus on protein resolution. Topics of discussion include: (1) comparison of RIEF apparatus to conventional IEF techniques (column and PAG) with respect to resolution and throughput; (2) peptide and protein separation (AHF, Thymosin - Fraction 5, vasoactive peptide, L-asparaginase and ACP); and (3) detection of peptides - dansyl derivatives of amino acids and peptides, post-focusing fluorescent labeling of amino acids, peptides and proteins, and ampholine extraction from focused gels.

Egen, N.↗
NASA NTRS1995

Analytical pyrolysis experiments of Titan aerosol analogues in preparation for the Cassini Huygens mission

Comparative pyrolysis mass spectrometric data of Titan aerosol analogs, called 'tholins', are presented. The Titan tholins were produced in the laboratory at Cornell by irradiation of simulated Titan atmospheres with high energy electrons in plasma discharge. Mass-spectrometry measurements were performed at FOM of the solid phase of various tholins by Curie-point pyrolysis Gas-Chromatography/Mass-Spectrometry (GCMS) and by temperature resolved in-source Pyrolysis Mass-Spectrometry to reveal the composition and evolution temperature of the dissociation products. The results presented here are used to further define the ACP (Aerosol Collector Pyrolyser)-GCMS experiment and provide a basis for modelling of aerosol composition on Titan and for the iterpretation of Titan atmosphere data from the Huygens probe in the future.

Ehrenfreund, P.↗
NASA NTRS2001

Miniaturized Wilkinson Power Dividers Utilizing Capacitive Loading

This letter reports the miniaturization of a planar Wilkinson power divider by capacitive loading of the quarter wave transmission lines employed in conventional Wilkinson power dividers. Reduction of the transmission line segments from lambda/4 to between lambda/5 and lambda/12 are reported here. The input and output lines at the three ports and the lines comprising the divider itself are coplanar waveguide (CPW) and asymmetric coplanar stripline (ACPS), respectively. The 10 GHZ power dividers are fabricated on high resistivity silicon (HRS) and alumina wafers. These miniaturized dividers are 74% smaller than conventional Wilkinson power dividers, and have a return loss better than +30 dB and an insertion loss less than 0.55 dB. Design equations and a discussion about the effect of parasitic reactance on the isolation are presented for the first time.

Scardelletti, Maximilian C.↗
NASA NTRS2004

Modeling of Spacecraft Advanced Chemical Propulsion Systems

This paper outlines the development of the Advanced Chemical Propulsion System (ACPS) model for Earth and Space Storable propellants. This model was developed by the System Technology Operation of SAIC-Huntsville for the NASA MSFC In-Space Propulsion Project Office. Each subsystem of the model is described. Selected model results will also be shown to demonstrate the model's ability to evaluate technology changes in chemical propulsion systems.

Benfield, Michael P. J.↗
NASA NTRS2004

The Cassini-Huygens Mission: Exo/Astro/Cosmobiological Perspectives

One of the main objectives of the Cassini-Huygens mission is to explore Titan in great detail and to study in particular the many exobiological aspects of Titan, this exotic world which presents so many analogies with our planet. The Cassini orbiter and the Huygens probe, in a complementary way, will systematically study the many chemical and physical aspects of the different parts of what can be called the "geofluid" of Titan. Many of the twelve instruments of the Cassini orbiter and most of the six instruments of the Huygens probe will provide much information of crucial importance for our knowledge of the complexity of Titan's organic chemistry. This is particularly the case with the GC-M4S and ACP experiments which will provide the first in situ chemical (including isotopic and molecular) analyses of the gas and aerosol phases of Titan's atmosphere. Indeed, because of the presence of a dense atmosphere, mainly made of N2 with noticeable fraction of CH4, and of an environment very rich in organics, and of many couplings involved in the various parts of its geofluid, in spite of low temperatures and the absence of liquid water, Titan is a reference for studying prebiotic chemistry on a planetary scale. Many programs have recently been developed to study in detail Titan's chemistry, in direct connection with the Cassini-Huygens mission. They include new observations, development of photochemical models, laboratory determination of IR and UV spectra of organics of interest for Titan's atmosphere, and experimental studies, such as laboratory simulation of Titan's gas and aerosol organic chemistry. The paper will review the exobiological aspects of Titan. It will also present some of the new data concerning Titan s organic chemistry that have been obtained through the several possible approaches and discuss the exobiological implication of the potential scientific return of the Cassini-Huygens mission.

Raulin, F.↗