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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

Alkali metal vapors - Laser spectroscopy and applications

The paper examines the rapidly expanding use of lasers for spectroscopic studies of alkali metal vapors. Since the alkali metals (lithium, sodium, potassium, rubidium and cesium) are theoretically simple ('visible hydrogen'), readily ionized, and strongly interacting with laser light, they represent ideal systems for quantitative understanding of microscopic interconversion mechanisms between photon (e.g., solar or laser), chemical, electrical and thermal energy. The possible implications of such understanding for a wide variety of practical applications (sodium lamps, thermionic converters, magnetohydrodynamic devices, new lasers, 'lithium waterfall' inertial confinement fusion reactors, etc.) are also discussed.

Stwalley, W. C.↗

Alkali metal carbon dioxide electrochemical system for energy storage and/or conversion of carbon dioxide to oxygen

An alkali metal, such as lithium, is the anodic reactant; carbon dioxide or a mixture of carbon dioxide and carbon monoxide is the cathodic reactant; and carbonate of the alkali metal is the electrolyte in an electrochemical cell for the storage and delivery of electrical energy. Additionally, alkali metal-carbon dioxide battery systems include a plurality of such electrochemical cells. Gold is a preferred catalyst for reducing the carbon dioxide at the cathode. The fuel cell of the invention produces electrochemical energy through the use of an anodic reactant which is extremely energetic and light, and a cathodic reactant which can be extracted from its environment and therefore exacts no transportation penalty. The invention is, therefore, especially useful in extraterrestrial environments.

Hagedorn, Norman H.↗

High power density performance of WPt and WRh electrodes in the alkali metal thermoelectric converter

The properties of the alkali metal thermoelectric converter (AMTEC) are discussed together with those of an efficient AMTEC electrode. Three groups of electrodes were prepared and tested for their performance as AMTEC electrodes, including WPt-T3, WRh-B1, and WRh-B2. The best electrodes of both WPt and WRh types typically exhibited low porosity, and thickness greater than 0.8 micron, which indicated that transport in these electrodes does not occur by a purely free-molecular flow mode. The observed values of the exchange current were found to be within the range of those observed for oxide-free Mo electrodes under similar conditions.

Williams, R. M.↗

Alkali Metal Rankine Cycle Boiler Technology Challenges and Some Potential Solutions for Space Nuclear Power and Propulsion Applications

Alkali metal boilers are of interest for application to future space Rankine cycle power conversion systems. Significant progress on such boilers was accomplished in the 1960's and early 1970's, but development was not continued to operational systems since NASA's plans for future space missions were drastically curtailed in the early 1970's. In particular, piloted Mars missions were indefinitely deferred. With the announcement of the Space Exploration Initiative (SEI) in July 1989 by President Bush, interest was rekindled in challenging space missions and, consequently in space nuclear power and propulsion. Nuclear electric propulsion (NEP) and nuclear thermal propulsion (NTP) were proposed for interplanetary space vehicles, particularly for Mars missions. The potassium Rankine power conversion cycle became of interest to provide electric power for NEP vehicles and for 'dual-mode' NTP vehicles, where the same reactor could be used directly for propulsion and (with an additional coolant loop) for power. Although the boiler is not a major contributor to system mass, it is of critical importance because of its interaction with the rest of the power conversion system; it can cause problems for other components such as excess liquid droplets entering the turbine, thereby reducing its life, or more critically, it can drive instabilities-some severe enough to cause system failure. Funding for the SEI and its associated technology program from 1990 to 1993 was not sufficient to support significant new work on Rankine cycle boilers for space applications. In Fiscal Year 1994, funding for these challenging missions and technologies has again been curtailed, and planning for the future is very uncertain. The purpose of this paper is to review the technologies developed in the 1960's and 1970's in the light of the recent SEI applications. In this way, future Rankine cycle boiler programs may be conducted most efficiently. This report is aimed at evaluating alkali metal boiler technology for space Rankine cycle systems. Research is summarized on the problems of flow stability, liquid carryover, pressure drop and heat transfer, and on potential solutions developed, primarily those developed by the NASA Lewis Research Center in the 1960's and early 1970's.

Stone, James R.↗

Development of processes for the production of solar grade silicon from halides and alkali metals

High temperature reactions of silicon halides with alkali metals for the production of solar grade silicon in volume at low cost were studied. Experiments were performed to evaluate product separation and collection processes, measure heat release parameters for scaling purposes, determine the effects of reactants and/or products on materials of reactor construction, and make preliminary engineering and economic analyses of a scaled-up process.

Dickson, C. R.↗

The effect of different alkali metal hydroxides on nickel electrode life

An accelerated cycle-life test (100-percent depth of discharge) of a sintered-type Ni electrode has been carried out in a flooded cell containing different alkali metal hydroxide electrolytes such as LiOH, NaOH, KOH, RbOH, and CsOH. Decrease in Ni electrode capacity with cycling was reduced as the radius of the alkali metal ions, with possible exception of CsOH.

Lim, H. S.↗