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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

Effect of Negative Ions on the Conductivity of the Titan Atmosphere

In an earlier paper, Borucki et al (1987) calculated the electrical conductivity and electrical charge on aerosols in Titan's atmosphere due to the ionization by galactic cosmic rays and electron precipitation from Saturn's magnetosphere. The lower atmosphere was predicted to be substantially more conducting than the atmospheres of Earth and Venus because of the high concentration of free electrons. The prediction of a high conductivity is based on the lack of electrophillic species which form negative ions with low mobility and which reduce the number of free electrons. At that time, no molecular species capable of forming negative ions in concentrations sufficient to perturb the atmospheric conductivity were identified. Recently, E. Bakes and her colleagues have been investigating the formation of nitrogenous macromolecules using quantum mechanical methods. Their calculations indicate that the molecules will be highly electrophillic and are likely to be present in the atmosphere at mixing ratios of order 10(exp -7). This mixing ratio is sufficiently large that a substantial reduction in the conductivity is expected at altitudes below 100 km. Revision of the atmospheric model to accommodate the presence of negative ions and to increase the fidelity of the modeling will be described.

Borucki, W. J.

Huygens/ASI plasma wave analyzer capabilities for aerosol measurement

The capabilities of the Huygens Atmospheric Structure Instrument (HASI) are described. These include measurement of atmospheric electrical conductivity by the plasma wave analyzer. How measurement of the atmospheric conductivity can lead to an estimate or the total surface area of the aerosols as a function of altitude is outlined. It is concluded that since the ASI is designed to measure the electrical conductivity as well as the pressure and temperature as a function of altitude, its results should provide a useful check on other instruments that are designed to measure the abundance of aerosols in a limited range of sizes.

Borucki, William J.

Controls on the CO2 seasonal cycle

Surface pressure measurement performed by the Viking landers show substantial variations in pressure on seasonal timescales that are characterized by two local minima and two local maxima. These variations have widely been attributed to the seasonal condensation and sublimation of CO2 in the two polar regions. It has been somewhat of a surprise that the amplitude of the minimum and maximum that is dominated by the CO2 cycle in the north was much weaker than the corresponding amplitude of the south-dominated extrema. Another surprise was that the seasonal pressure cycle during years 2 and 3 of the Viking mission was so similar to that for year 1, despite the occurrence of two global dust storms during year 1 and none during years 2 and 3. An energy balance model that incorporates dynamical factors from general circulation model (GCM) runs in which the atmospheric dust opacity and seasonal date were systematically varied was used to model the observed seasonal pressure variations. The energy balance takes account of the following processes in determining the rates of CO2 condensation and sublimation at each longitudinal and latitudinal grid point: solar radiation, infrared radiation from the atmosphere and surface, subsurface heat conduction, and atmospheric heat advection. Condensation rates are calculated both at the surface and in the atmosphere. In addition, the energy balance model also incorporates information from the GCM runs on seasonal redistribution of surface pressure across the globe. Estimates of surface temperature of the seasonal CO2 caps were used to define the infrared radiative losses from the seasonal polar caps. The seasonal pressure variations measured at the Viking lander sites were closely reproduced.

Pollack, J. B.

Measurements of the vertical atmospheric electric field and of the electrical conductivity with stratospheric balloons

Measurements of the atmospheric (vertical) electric field with balloons in the stratosphere are reported. The atmospheric electrical conductivity is also measured and the current density inferred. The average vertical current shows the expected variation with universal time and is also seen to be influenced by external (magnetospheric) electric fields.

Iversen, I. B.

Analysis of satellite-derived ozone and water vapor measurements

Research under this grant has involved analyses of satellite-derived measurements of water vapor and total ozone. Upper tropospheric water vapor data from the Nimbus 7 temperature-humidity infrared radiometer (THIR) 6.7 micron channel were analyzed by Fourier transformation to provide wavenumber spectra for a case of an upper level system over Europe. The power law spectrum for horizontal scales from 60 to several hundred km suggests that when convective cloud energy sources are not present, the enstrophy-cascading process (with variance proportional to the minus three power of wavenumber) may hold to much smaller scales than previously thought. Several investigations of the middle atmosphere (stratosphere and mesosphere) were also conducted. Slow atmospheric oscillations with periods of 1-2 months were investigated in total ozone measurements and in ionospheric data. Using one-point correlation maps and total ozone mapping spectrometer (TOMS) data, strong statistical evidence was found for the planetary-scale oscillations at these periods. A dipole-like pattern in the tropical equatorial Indian ocean-western Pacific region was documented, along with wavetrain-like patterns emanating into the extratropics. While attempting to follow the oscillations upward above stratosphere, oscillations were studied in ionospheric data (D-region radio wave absorption, in the upper mesosphere, around 80-90 km altitude). Cross-spectral analyses with solar flux data revealed that much of the observed 1-2 month variance in the ionospheric D-region was well correlated to solar variations. Further research has involved investigations of the photochemical lifetime of greenhouse gases methane and nitrous oxide. Using Nimbus 7 satellite data, a new analysis technique was employed to determine the lifetime of these gases in situ in the upper stratosphere. The lifetimes are found to be in good agreement with theoretical estimates.

Stanford, John L.

Elucidating Processes Controlling Arctic Atmospheric Aerosol Sources, Aging, and Mixing States (Final Report)

Atmospheric aerosols play critical roles in the Earth’s energy budget, directly by scattering or absorbing solar and terrestrial radiation and indirectly by serving as seeds (nuclei) for cloud droplet and ice crystal formation and by depositing on snow and ice surface, thereby changing the surface albedo. These effects are dependent on aerosol particle size and chemical composition and impact the hydrological cycle as well. This project provided single-particle size and chemical composition measurements across the entire annual cycle in the high Arctic and in the Alaskan Arctic during fall – winter, addressing the most significant gaps in Arctic aerosol observational data. These needs were based on recent rapid sea ice loss across the entire Arctic, as well as the major annual delays in sea ice freeze-up during fall in the Chukchi Sea and increased wintertime sea ice fracturing in the Beaufort Sea, both off the North Slope of Alaska. Two DOE Atmospheric Radiation Measurement (ARM) field campaigns were conducted for atmospheric aerosol sampling. The Aerosols during the Polar Utqiagvik Night (APUN – ‘snow on ground’ in Iñupiaq) ARM field campaign at Utqagivik, Alaska was conducted from Oct. 28 – Dec. 22, 2018. Aerosol sizing instrumentation and a single-particle mass spectrometer were successfully deployed for size-resolved number concentration measurements and measurements of individual particle size and chemical composition, respectively. These results show the influence of locally-produced sea spray aerosol, with high cloud-forming potential, due to delayed sea ice freeze-up in the fall. During the 2019‐2020 international Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition, daily atmospheric aerosol particles were collected aboard the German icebreaker Polarstern in the Central Arctic from Nov. 2019 – Oct. 2020. Sea salt aerosol and marine organics were observed year-round during MOSAiC with varying morphologies and sources. These findings are important because most Arctic models do not include a sea spray aerosol source, despite this source increasing with declining sea ice extent. In addition to collecting new samples and data, this project also conducted further analysis of previously collected single-particle chemical composition measurements within the North Slope of Alaska oil fields and at Utqiaġvik, AK, during Aug. – Sep. 2015 and 2016 field campaigns. This work resulted in the discovery of chemical reactions of oil field combustion emissions occurring within fog droplets across the North Slope of Alaska and forming secondary aerosol, showing the impact of Arctic oil field emissions beyond black carbon aerosol and greenhouse gases. In addition, the distribution of chemical species across the aerosol population within the oil fields was quantified, using these data and a previously development framework. We also presented the first ambient evidence of the collision of two atmospheric particles resulting in formation of an organic-coated ammonium sulfate particle of marine origin, which has implications for cloud formation with declining sea ice extent. Overall, this project has elucidated connections between seawater biogeochemistry, resource extraction activities, atmospheric composition, clouds, and the energy budget of the Arctic region. The results of this project are expected to improve weather and sea ice forecasting for security and development in the Arctic and beyond.

54 ENVIRONMENTAL SCIENCES

An experimental and chemical kinetic modeling study of 4-butoxyheptane combustion

Here, the combustion kinetics of a novel oxygenated bioblendstock for diesel, 4-butoxyheptane (4-BH), was investigated experimentally using a flow reactor and a heated, high-pressure shock tube. The flow reactor experiments employed oxygen as the oxidizer and helium as the diluent with oxidation conducted at atmospheric pressure and 10 bar for temperatures from 400 to 1000 K at 20-K intervals. The fuel, oxidizer, and diluent flow rates were varied at different temperatures to maintain a constant initial fuel mole fraction of 1000 ppm, with stoichiometric equivalence ratio, and a residence time of 2.0 s. The reacted gas was fed to two separate GC systems that could qualitatively and quantitatively detect product species. Additionally, real fuel-air ignition delay time (IDT) data were collected using a heated, high-pressure shock-tube facility. Fuel lean (φ = 0.5) and stoichiometric (φ = 1.0) mixtures were investigated at 10 atm as well as at 30 atm for the fuel lean case for temperatures between 847 and 1259 K. A detailed chemical kinetics mechanism was developed to model the product distribution from the flow reactor and IDTs from the shock tube. The proposed model was able to predict the double NTC behavior in flow reactor experiments reasonably well. Model predictions at low temperatures were observed to be highly sensitive to the rate constants of ketohydroperoxide (KHP) decomposition in the case of the OOH group in α position which were modeled based on existing literature studies on ethers. It was noted that in the absence of theoretical or experimental studies, the rate constants for KHP decomposition used in the literature were empirically set. Additional studies are required to address the gap in model prediction obtained in this study and to reduce the uncertainty in kinetics models for ether oxidation. Predicted product concentrations and IDTs showed some quantitative agreement with experimental data, but the overall reactivity of the IDTs is underpredicted. Additionally, significant deviation is observed for the IDT results at 10 atm for the stoichiometric case with minor deviations for the other cases. The reaction pathways to the missing products were then further analyzed theoretically through quantum-mechanical calculations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH

Electrical Charging of Aerosols and Conductivity of Titan's Atmosphere

We have used recent data on graphitic cloud particles in the atmosphere of Titan to compute the electrical charging of the particles (radii ranging from 0.01 microns to 0.26 microns). The charging on the nightside was rather similar to that obtained earlier except that charge distributions on the particles are now computed and recently obtained cloud particle sizes and density distributions were employed. The negative charge on particles of 0.26 microns peaked at 9 at 150 km altitude. The computations were repeated for the dayside with the addition of photoelectron emission by the particles as a result of the absorption of solar UV radiation. Particles (except the very smallest) now became positively charged with particles of radius 0.26 microns being charged up to +47. Next, very small particles (radii approx. 3 x 10 (sup -4) microns) of polycyclic aromatic hydrocarbons (PAHs) were introduced and treated as sources of negative ions since they could be either neutral or carry one negative charge. Moreover, they are mobile so that they had to be treated like molecular size negative ions although much more massive. They had the effect of substantially reducing the electron densities in the altitude range 190 to 310 km to values less than the negative PAH densities and increasing the peak electron charge on the larger particles. Particles of radius 0.26 microns bore peak charges of approx. +47 at altitudes of approx. 250 km. The simulated effect of PAHs on the nightside proved to be much less pronounced; at the peak negative PAH density, it was less than the electron density. The physics governing these results will be discussed.

Borucki, W. J.

Energy balance and plume dynamics in Triton's lower atmosphere

The present study of the thermal balance-affecting relationships among Triton lower atmosphere thermal conduction, eddy mixing, condensation, and radiative heating indicates that, while the temperature gradient is negative in the lower atmosphere, it becomes positive at higher altitudes due to the downward conduction of ionospheric heat. This temperature profile is essentially consistent with radio-occultation experiment data; the geyser-like plumes observed by Voyager suggest that the Trioton atmosphere's convective and conductive regions join near 10-km altitude, and that the values inferred for the eddy diffusion and heat-transport coefficients indicate a profile reminiscent of the earth's.

Yelle, Roger V.

Predictions of the electrical conductivity and charging of the aerosols in Titan's atmosphere

Computational results are given for Titan atmosphere aerosol electrical conductivity and charge at altitudes up to 400 km, together with a consideration of ionization from such sources as galactic cosmic rays and electron precipitation from the Saturnian magnetosphere. Predicted conductivity shows the existence of substantial electron concentrations up to the Titan surface. At altitudes of more than 100 km, and aerosol concentrations greater than 10/cu cm, electron/positive ion-recombination is found to be controlled by the recombination of the aerosols' surfaces rather than by the gas-kinetic recombination rate.

Borucki, W. J.

Martian thermal boundary layers: Subhourly variations induced by radiative-conductive heat transfer within the dust-laden atmosphere-ground system

Radiative-conductive heat transfer has been investigated for the ground-atmosphere system of the planet Mars. The basic goal was the quantitative determination of time dependent vertical distributions of temperature and static stability for Southern-Hemispheric summer season and middle and polar latitudes, for both dust-free and dust-laden atmospheric conditions. The numerical algorithm which models at high spatial and temporal resolution the thermal energy transports in the dual ground-atmosphere system, is based on solution of the applicable heating rate equation, including radiative and molecular-conductive heat transport terms. The two subsystems are coupled by an internal thermal boundary condition applied at the ground-atmosphere interface level. Initial data and input parameters are based on Mariner 4, 6, 7, and 9 measurements and the JPL Mars Scientific Model. Numerical experiments were run for dust-free and dust-laden conditions in the midlatitudes, as well as ice-free and ice-covered polar regions. Representative results and their interpretation are presented. Finally, the theoretical framework of the generalized problem with nonconservative Mie scattering and explicit thermal-convective heat transfer is formulated, and applicable solution algorithms are outlined.

Pallmann, A. J.

Outer atmospheric research - One tether capability

One specific tether application of far-reaching promise would be to conduct outer atmospheric research by using a tethered subsatellite deployed downward from an orbiting 'mother' craft such as the Shuttle Orbiter. This capability would gather scientific and engineering/technology information about the outer atmosphere, primarily from 150 km down to perhaps 90 km. This paper presents current determinations of specific user needs, tether capabilities, and technological and program requirements to fulfill this application of tethers in space.

Anderson, John L.

Atmospheric Escape from Magnetized Rocky Exoplanets

Recent Kepler and TESS observations discovered many rocky exoplanets in habitable zones around active main-sequence stars. The upper atmospheres of exoplanets are subject to two important energy sources derived from their host stars. First, the stellar photon flux in the X-ray and XUV bands ionizes and heats the upper atmosphere, driving atmospheric heating, affecting the conductance, and enhancing atmospheric escape. Second, the stellar wind’s interaction with the exoplanet’s intrinsic magnetic field transfers energy to the atmosphere through field aligned currents and Poynting flux. That energy is dissipated in the high latitude cusp and auroral regions through Joule heating which can inflate the atmosphere and also enhance the atmospheric escape rate. This presentation will discuss recent advances in modeling these energy inputs and their consequences for exoplanetary habitability. Also, I will discuss the development of a new model, the (exo) PLANETary Ionosphere-Thermosphere Tool for Research (PLANET-ITTR) and some early results from it.

William Danchi