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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Conjecture on superrotation in planetary atmospheres - A diffusion model with mixing length theory

The component of rigid shell superrotation on Venus is discussed in the context of comparative planetary atmospheres. A simplified, heuristic analysis, utilizing mixed length theory to describe the small scale nonlinear advections of energy and angular momentum, thereby providing a closure of the dynamic system, is presented, on the basis of which a crude estimate of zonal velocity is made. The rigid shell (global average) component on Venus was calculated to be 105 m/sec.

Mayr, H. G.↗
DOE OSTI2021

Magnetic and dielectric property control in the multivalent nanoscale perovskite Eu 0.5 Ba 0.5 TiO 3

We report nanoscale Eu 0.5 Ba 0.5 TiO 3 , a multiferroic in the bulk and candidate in the search to quantify the electric dipole moment of the electron. Eu 0.5 Ba 0.5 TiO 3 , in the form of nanoparticles and other nanostructures is interesting for nanocomposite integration, biomedical imaging and fundamental research, based upon the prospect of polarizability, f-orbital magnetism and tunable optical/radio luminescence. We developed a [non-hydrolytic]sol–[H 2 O-activated]gel route, derived from in-house metallic Ba (s) /Eu (s) alkoxide precursors and Ti{(OCH(CH 3 ) 2 } 4 . Two distinct nanoscale compounds of Ba:Ti:Eu with the parent perovskite crystal structure were produced, with variable dielectric, magnetic and optical properties, based on altering the oxidizing/reducing conditions. Eu 0.5 Ba 0.5 TiO 3 prepared under air/O 2 atmospheres produced a spherical core–shell nanostructure (30–35 nm), with perovskite Eu 0.5 Ba 0.5 TiO 3 nanocrystal core-insulating oxide shell layer (~3 nm), presumed a pre-pyrochlore layer abundant with Eu 3+ . Fluorescence spectroscopy shows a high intensity 5 D 0 → 7 F 2 transition at 622 nm and strong red fluorescence. The core/shell structure demonstrated excellent capacitive properties: assembly into dielectric thin films gave low conductivity (2133 GΩ mm -1 ) and an extremely stable, low loss permittivity of ε eff ~25 over a wide frequency range (tan δ < 0.01, 100 kHz–2 MHz). Eu 0.5 Ba 0.5 TiO 3 prepared under H 2 /argon produced more irregular shaped nanocrystals (20–25) nm, with a thin film permittivity around 4 times greater ( ε eff 101, tan δ < 0.05, 10 kHz–2 MHz, σ ~59.54 kΩ mm -1 ). Field-cooled magnetization values of 0.025 emu g -1 for EBTO-Air and 0.84 emu g -1 for EBTO-Argon were observed. X-ray photoelectron spectroscopy analysis reveals a complex interplay of Eu II/III /Ti III/IV configurations which contribute to the observed ferroic and fluorescence behavior.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
NASA NTRS1992

The cometary contribution to prebiotic chemistry

The chemical composition of cometary nuclei is examined to estimate the potential contribution of volatiles to the prebiotic earth from cometary collisions. Observations of cometary nuclei are reviewed to describe the chemical evolution of the objects and their theoretical potential for affecting the terrestrial environment. Specific attention is given to the plausibility of the single-impact formation of the earth-moon system, and experiments are proposed for testing the present theories. It is proposed that significant contributions of biogenic elements such as C, H, N, O, P, and S resulted from these nuclei colliding with the earth. Observations of the solar atmosphere and of the circumstellar shells of C-rich stars indicate that compounds such as CO, C2, and H2O were not pyrolyzed as a result of collision events. The compounds are theorized to have established the foundation for the abiotic synthesis of key biochemical molecules.

Oro, J.↗
NASA NTRS2009

NESC Review of the 8-Foot High Temperature Tunnel (HTT) Oxygen Storage Pressure Vessel Inspection Requirements

The 8-Foot HTT (refer to Figure 4.0-1) is used to conduct tests of air-breathing hypersonic propulsion systems at Mach numbers 4, 5, and 7. Methane, Air, and LOX are mixed and burned in a combustor to produce test gas stream containing 21 percent by volume oxygen. The NESC was requested by the NASA LaRC Executive Safety Council to review the rationale for a proposed change to the recertification requirements, specifically the internal inspection requirements, of the 8-Foot HTT LOX Run Tank and LOX Storage Tank. The Run Tank is an 8,000 gallon cryogenic tank used to provide LOX to the tunnel during operations, and is pressured during the tunnel run to 2,250 pounds per square inch gage (psig). The Storage Tank is a 25,000 gallon cryogenic tank used to store LOX at slightly above atmospheric pressure as a external shell, with space between the shells maintained under vacuum conditions.

Gilbert, Michael↗
NASA NTRS1976

Exospheric density measurements from the drag-free satellite Triad

The Triad satellite is maintained within 1 mm of its proof mass (a small metal ball) in a purely gravitational orbit, using a drag-free control system, named Discos, as the disturbance compensation system. The Discos proof mass is surrounded by an outer shell which holds fuel tanks and cold gas jets. The shell shields the proof mass from such nongravitational forces as radiation pressure, atmospheric drag, and micrometeorite impact. Whenever these forces displace the outer shell relative to the proof mass, an error signal is generated by a capacitive bridge sensor, and the satellite is propelled by gas jets to remain centered on the proof mass when the error reaches 1 mm. Local atmospheric densities near 800 km were measured, using ball position data, and the observed accelerations were corrected for the effects of solar radiation pressure. The measured densities reveal a greater dependence on latitude than that indicated by balloon satellites, and also a dependence on longitude. Only a small dependence on Kp, however, was observed in the region where the measurements were made.

Moe, K.↗
DOE OSTI2023

Observing the onset of pressure-driven K-shell delocalization

The gravitational pressure in many astrophysical objects exceeds one gigabar (one billion atmospheres), creating extreme conditions where the distance between nuclei approaches the size of the K shell. This close proximity modifies these tightly bound states and, above a certain pressure, drives them into a delocalized state. Both processes substantially affect the equation of state and radiation transport and, therefore, the structure and evolution of these objects. Still, our understanding of this transition is far from satisfactory and experimental data are sparse. Here, in this work, we report on experiments that create and diagnose matter at pressures exceeding three gigabars at the National Ignition Facility where 184 laser beams imploded a beryllium shell. Bright X-ray flashes enable precision radiography and X-ray Thomson scattering that reveal both the macroscopic conditions and the microscopic states. The data show clear signs of quantum-degenerate electrons in states reaching 30 times compression, and a temperature of around two million kelvins. At the most extreme conditions, we observe strongly reduced elastic scattering, which mainly originates from K-shell electrons. We attribute this reduction to the onset of delocalization of the remaining K-shell electron. With this interpretation, the ion charge inferred from the scattering data agrees well with ab initio simulations, but it is significantly higher than widely used analytical models predict.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1985

A mixed pseudospectral/finite difference method for a thermally driven fluid in a nonuniform gravitational field

A numerical study of the steady, axisymmetric flow in a heated, rotating spherical shell is conducted to model the Atmospheric General Circulation Experiment (AGCE) proposed to run aboard a later shuttle mission. The AGCE will consist of concentric rotating spheres confining a dielectric fluid. By imposing a dielectric field across the fluid a radial body force will be created. The numerical solution technique is based on the incompressible Navier-Stokes equations. In the method a pseudospectral technique is based on the incompressible Navier-Stokes equations. In the method a pseudospectral technique is used in the latitudinal direction, and a second-order accurate finite difference scheme discretizes time and radial derivatives. This paper discusses the development and performance of this numerical scheme for the AGCE which has been modelled in the past only by pure FD formulations. In addition, previous models have not investigated the effect of using a dielectric force to simulate terrestrial gravity. The effect of this dielectric force on the flow field is investigated as well as a parameter study of varying rotation rates and boundary temperatures. Among the effects noted are the production of larger velocities and enhanced reversals of radial temperature gradients for a body force generated by the electric field.

Macaraeg, M. G.↗
NASA NTRS1985

A mixed pseudospectral/finite difference method for a thermally driven fluid in a nonuniform gravitational field

A numerical study of the steady, axisymmetric flow in a heated, rotating spherical shell is conducted to model the Atmospheric General Circulation Experiment (AGCE) proposed to run aboard a later Shuttle mission. The AGCE will consist of concentric rotating spheres confining a dielectric fluid. By imposing a dielectric field across the fluid a radial body force will be created. The numerical solution technique is based on the incompressible Navier-Stokes equations. In the method a pseudospectral technique is used in the latitudinal direction, and a second-order accurate finite difference scheme discretizes time and radial derivatives. This paper discusses the development and performance of this numerical scheme for the AGCE which has been modeled in the past only by pure FD formulations. In addition, previous models have not investigated the effect of using a dielectric force to simulate terrestrial gravity. The effect of this dielectric force on the flow field is investigated as well as a parameter study of varying rotation rates and boundary temperatures. Among the effects noted are the production of larger velocities and enhanced reversals of radial temperature gradients for a body force generated by the electric field.

Macaraeg, M. G.↗
NASA NTRS2002

Outbursts In Symbiotic Binaries (FUSE 2000)

During the past year, we made good progress on analysis of FUSE observations of the symbiotic binary Z And. For background, Z And is a binary system composed of a red giant and a hot component of unknown status. The orbital period is roughly 750 days. The hot component undergoes large-scale eruptions every 10-20 yr. An outburst began several years ago, triggering this FUSE opportunity. First, we obtained an excellent set of ground-based optical data in support, of the FUSE observations. We used FAST, a high throughput low resolution spectrograph on the 1.5-m telescope at Mt. Hopkins, Arizona. A 300 g/ mm grating blazed at 4750 A, a 3 in. slit, and a thinned Loral 512 x 2688 CCD gave us spectra covering 3800-7500 A at a resolution of 6 A. The wavelength solution for each spectrum has a probable error of +/- 0.5 A or better. Most of the resulting spectra have moderate signal-to-noise, S/.N approx. greater than 30 per pixel. The time coverage for these spectra is excellent. Typically, we acquired spectra every 1-2 nights during dark runs at Mt. Hopkins. These data cover most of the rise and all of the decline of the recent outburst. The spectra show a wealth of emission lines, including H I, He I, He II, [Fe V11], and the Raman scattering bands at 6830 A and 7088 A. The Raman bands and other high ionization features vary considerably throughout the outburst. These features will enable us to correlate variations in the FUSE spectra with variations in the optical spectra. Second, we began an analysis of FUSE spectra of Z And. We have carefully examined the spectra, identifying real features and defects. We have identified and measured fluxes for all strong emission lines, including the O VI doublet at 1032 A and 1038 A. These and several other strong emission lines display pronounced P Cygni absorption components indicative of outgrowing gas. We will attempt to correlate these velocities with similar profiles observed on optical spectra. The line velocities - together with line variations - will yield physical parameters for the expanding shell of gas in the outer atmosphere of the hot component. We also worked on several diagnostic tools, including upgrades to photoionization programs developed by the PI and others. We plan to use these tools to derive electron densities and temperatures front intercombination and forbidden lines observed on optical and FUSE spectra. Preliminary results indicate a large electron density, n(sub e) is greater than or = 10(exp 10)/cc and a modest electron temperature, T(sub e) approx. 20,000 K. We see no evidence for shocked gas as observed in some other symbiotics. However, we have yet to include several important lines of [Fe VII] and [Ne V] in the analysis. Inclusion of these lines will yield an improved estimate of the electron temperature in the gas. Finally, we have one additional FUSE spectrum planned for acquisition during this cycle. These data will provide important information concerning the state of the system farther along in its decline. Once we have this spectrum in hand, we plan to complete our analysis and publish our results.

Kenyon, Scott J.↗
DOE OSTI2021

Energetics and kinetics of various cyano radical hydrogen abstractions

The cyano radical (CN) is an abundant, open-shell molecule found in a variety of environments, including the atmosphere, the interstellar medium and combustion processes. In these environments, it often reacts with small, closed-shell molecules via hydrogen abstraction. Both carbon and nitrogen atoms of the cyano radical are reactive sites, however the carbon is more reactive with reaction barrier heights generally between 2–15 kcal mol -1 lower than those of the analogous nitrogen. The CN + HX → HCN/HNC + X, with X = H, CH 3 , NH 2 , OH, F, SiH 3 , PH 2 , SH, Cl, C 2 H, CN reactions have been studied at a high-level of theory, including CCSD(T)-F12a. Finally, kinetics were obtained over the 100–1000 K temperature range, showing excellent agreement with those rate constants that have been determined experimentally.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Probing radical–molecule interactions with a second generation energy decomposition analysis of DFT calculations using absolutely localized molecular orbitals

Intermolecular interactions between radicals and closed-shell molecules are ubiquitous in chemical processes, ranging from the benchtop to the atmosphere and extraterrestrial space. While energy decomposition analysis (EDA) schemes for closed-shell molecules can be generalized for studying radical–molecule interactions, they face challenges arising from the unique characteristics of the electronic structure of open-shell species. In this work, we introduce additional steps that are necessary for the proper treatment of radical–molecule interactions to our previously developed unrestricted Absolutely Localized Molecular Orbital (uALMO)-EDA based on density functional theory calculations. A “polarize-then-depolarize” (PtD) scheme is used to remove arbitrariness in the definition of the frozen wavefunction, rendering the ALMO-EDA results independent of the orientation of the unpaired electron obtained from isolated fragment calculations. The contribution of radical rehybridization to polarization energies is evaluated. It is also valuable to monitor the wavefunction stability of each intermediate state, as well as their associated spin density profiles, to ensure the EDA results correspond to a desired electronic state. The examples suggest that this second generation uALMO-EDA is a useful tool for furthering one's understanding of both energetic and property changes associated with radical–molecule interactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2017

Mathematical Modeling of Electrodynamics Near the Surface of Earth and Planetary Water Worlds

An interesting feature of planetary bodies with hydrospheres is the presence of an electrically conducting shell near the global surface. This conducting shell may typically lie between relatively insulating rock, ice, or atmosphere, creating a strong constraint on the flow of large-scale electric currents. All or parts of the shell may be in fluid motion relative to main components of the rotating planetary magnetic field (as well as the magnetic fields due to external bodies), creating motionally-induced electric currents that would not otherwise be present. As such, one may expect distinguishing features in the types of electrodynamic processes that occur, as well as an opportunity for imposing specialized mathematical methods that efficiently address this class of application. The purpose of this paper is to present and discuss such specialized methods. Specifically, thin-shell approximations for both the electrodynamics and fluid dynamics are combined to derive simplified mathematical formulations describing the behavior of these electric currents as well as their associated electric and magnetic fields. These simplified formulae allow analytical solutions featuring distinct aspects of the thin-shell electrodynamics in idealized cases. A highly efficient numerical method is also presented that is useful for calculations under inhomogeneous parameter distributions. Finally, the advantages as well as limitations in using this mathematical approach are evaluated. This evaluation is presented primarily for the generic case of bodies with water worlds or other thin spherical conducting shells. More specific discussion is given for the case of Earth, but also Europa and other satellites with suspected oceans.

Tyler, Robert H.↗
DOE OSTI2021

Advanced nanoscale characterization of aluminum nanoparticles with modified surface morphology via atmospheric helium and carbon monoxide plasmas

Aluminum nanoparticles (nAl) have the potential as energetic additives in explosive/propellant formulations. Scalable methodologies must be pursued to mitigate the inactive amorphous alumina shell surrounding the active aluminum (Al) core with modified surface morphology and chemistry for increased combustion effects. This work explores the feasibility of making reactive core/shell nAl with thinned oxide shells and modified surface coatings via a two-step atmospheric plasma surface treatment process in a custom dielectric barrier discharge plasma reactor. The commercial nAl of nominal average size similar to 40-60nm was first treated with helium (He) followed by He/carbon monoxide (CO) plasmas for different durations. The resultant samples were characterized via high-resolution transmission electron microscopy (HRTEM) and Fourier transform IR (FTIR) spectra. HRTEM images revealed sporadic patchy gamma -alumina deposits on particle surfaces and in gaps among particles for all samples, suggesting the non-uniform plasma effects of the He/CO glow. Nanoscale chemical analyses via scanning transmission electron microscopy elemental mapping and x-ray energy dispersive spectroscopy were further performed. Although no carbon-associated structure appeared in electron energy loss spectroscopy (EELS) spectra, the presence of carbonaceous materials was confirmed as a thin dispersive layer evenly distributed on the nAl surface suggesting either its amorphous nature or is present at a level insufficient to generate satisfactory EELS spectra. The trend of intensity profiles for key elements acquired by drawing lines across a single particle on the elemental maps confirmed that carbonaceous materials only existed on the surface and they were most likely carboxylates that increased with increased He/CO treatment duration, as evident by FTIR results. Finally, this work demonstrated the success of atmospheric plasma-treated reactive nAl with comprehensively characterized surface features via advanced microscopy and spectroscopy.

36 MATERIALS SCIENCE↗
NASA NTRS1974

Interactive design of large end rings on stiffened conical shells using composites

Design study methods and results for a composite reinforced base ring for the conical aeroshell structure of the planetary lander vehicle for Project Viking, an unmanned mission to Mars, are presented. The aeroshell is a ring and stringer-stiffened conical shell structure having a half angle of 70 degrees with a large base ring mounted at the outer edge of the cone and a large pay-load ring in the interior with many smaller rings spaced along the inside shell surface. The purpose of the structure is to develop the aerodynamic drag required to decelerate the lander in the Mars atmosphere to facilitiate a soft landing. The design of a shell structure of this complexity requires the use of the latest technology available in a large general-purpose shell buckling program. The large general-purpose non-linear shell buckling program (BOSOR 2) which was used for this purpose is described.

Davis, R. C.↗
NASA NTRS1979

IUE spectra of the massive close binary V382 Cygni

The massive close binary, V382 Cyg, was observed with the low-dispersion spectrograph on the IUE satellite. The dereddened spectrum can be reasonably represented by a 40,000-K model atmosphere. The spectra show interstellar, photospheric, and shell absorption blends and one shell emission feature. From one of the shell absorptions, it is possible to calculate a limiting systemic mass loss rate of about 0.00004 solar mass/yr.

Koch, R. H.↗
NASA NTRS1985

Lightning-induced electron precipitation from the magnetosphere

Precipitation of radiation belt particles induced by whistlers that are generated by atmospheric lightning discharges and propagate over L shells of 2-4.5 is considered. Using a test particle model of the whistler-particle interaction, the energy spectra and temporal profile of whistler-induced fluxes as a function of L shell are quantitatively determined for a representative plasmaspheric cold plasma distribution. Results indicate that for higher energy electron precipitation (E greater than 40 keV) there exists an inner magnetospheric region (L between 2 and 3) where the level of whistler-induced precipitation can be expected to be comparatively high. Implications of this finding in terms of observational results are discussed.

Chang, H. C.↗
NASA NTRS2017

Far-UV Spectroscopy of Two Extremely Hot, Helium-Rich White Dwarfs

A large proportion of hot post-asymptotic giant branch stars and white dwarfs (WDs) are hydrogen-deficient. Two distinct evolutionary sequences have been identified. One of them comprises stars of spectral type [WC] and PG1159, and it originates from a late helium-shell flash, creating helium-rich stellar atmospheres with significant admixtures of carbon (up to about 50, mass fraction). The other sequence comprises stars of spectral type O(He) and luminous subdwarf O stars which possibly are descendants of RCrB stars and extreme helium stars. Their carbon abundances are significantly lower (of the order of 1 or less) and it is thought that they originate from binary-star evolution (through merger or common-envelope evolution). Here we investigate two of the three hottest known helium-rich (DO) WDs (PG 1034+001 and PG 0038+199). They are the only ones for which spectra were recorded with the Far Ultraviolet Spectroscopic Explorer and the Hubble Space Telescope, allowing a comprehensive ultraviolet spectral analysis. We find effective temperatures of T(eff) =115000 +/- 5000 K and 125000 +/- 5000 K, respectively, and a surface gravity of log g = 7 +/-0.5. In both stars, nitrogen is strongly oversolar while C and O are significantly subsolar. For all other assessed metals (Ne, Si, P, S, Ar, Fe, and Ni) we find abundances close to solar. We conclude that these WDs are immediate descendants of O(He) stars and, hence, result from close-binary evolution.

Werner, K.↗
NASA NTRS1993

The new Be-type star HD 147196 in the Rho Ophiuchi dark cloud region

The newly discovered hot-emission line star, HD 147196 in the Rho Oph dark cloud region was observed spectroscopically and photometrically and high and low resolution IUE spectra were obtained. The finding of Irvine (1990) that this relatively bright star show its H-alpha-line in emission is confirmed. Previous H-alpha-surveys of the Rho Oph star-forming region did not detect HD 147196 as an H-alpha-emission star, meaning that it must recently be very active and has perhaps transformed itself from a B-type star at shell phase to a Be-phase. The Mg II h + k resonance lines are in absorption and they appear to be interstellar in nature, which means that either the abundance of Mg in the extended atmosphere of the star is low or that the shell is not extended enough to produce emission lines of Mg II. Photometric observations of this B8 V type star do not show any variations during at least the years covered by our monitoring or any excess of NIR radiation in its spectral energy distribution up to the M-passband at 4.8 microns.

The, P. S.↗