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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

Atomistic simulations of nanoindentation on nanoglasses: Effects of grain size and gradient microstructure on the mechanical properties

The use of nanoglass (NG) microstructures has been shown as an effective strategy to improve the ductility of rather brittle metallic glass alloys. To evaluate the effects of grain size and gradient design on the mechanical properties of NGs, we perform molecular dynamics simulations of nanoindentation on Cu 64 Zr 36 NGs. We consider samples with uniform 3 and 7 nm grain sizes as well as gradient microstructures with gradient grain sizes varying from 3 to 7 nm. Here, the results show that the deformation mechanism in NGs with small grain sizes is dominated by the activation and evolution of multiple shear transformation zones. Increasing grain sizes enhances the elastic modulus and hardness at the cost of reduced abrasion resistance. Though the average grain size at the indentation surface plays a crucial role in the deformation behavior of gradient NG models, their strain localization and plastic deformation states are affected by the grain sizes far from the indenter. Desired combinations of mechanical properties can be realized by different NG microstructure designs.

36 MATERIALS SCIENCE↗

Phase I DOE DE-SC0021823 Entitled “Changing the Design Rules of Rubber to Create Lighter Weight, More Fuel Efficient Tires” Final Technical Report 04/08/2022

Molecular Rebar Design, LLC has successfully developed new rubber composites with individualized carbon nanotubes called MOLECULAR REBAR® (MR), improving tire tread compound performance for use with electric vehicles (EVs). Through the iterative nature of the Phase I experimentation, MRD developed a novel carbon nanotube material that disperses well with other typical tire compound fillers and can be chemically functionalized for unique material property benefits. The new MR material is a chemically functionalized, discrete multi-wall carbon nanotube that binds into the rubber compound using silane technology. This Molecular Rebar based tire tread material drastically improves DIN abrasion resistance 25%+ (correlating to improved tire life), reduces tread weight by 6-7%, and reduces rolling resistance 20%+ (correlating to improved energy efficiency), as compared to an in-use, state-of-the-art, silica-silane tread compound. The formulations can be adjusted to maximize energy efficiency, to maximize wear or to have a blend of improvement depending on the tire performance needs of end use customers.

36 MATERIALS SCIENCE↗

Advanced Anti-Fouling Coatings to Improve the Efficiency of Coal Power Plants

As the total cost of carbon to generate energy has become a global concern, operators are increasingly looking at all parts of the generation cycle to find areas where efficiency gains may be found. It has been long identified that fouling of heat exchangers is a persistent cause of up to 2.5% of global CO 2 emissions. Unfortunately, practice has also demonstrated that unless a powerful economic driver exists to encourage preemptive mitigation of fouling, there will always be a strong tendency for operators to minimize any form of intervention due to high costs and challenges in scheduling downtime. The objective of this proposed research effort was to demonstrate how existing power plants could lower their carbon emissions and significantly improve heat transfer efficiency using new surface treatment materials to control fouling in a variety of heat exchange equipment. The surface treatment material which was optimized and deployed in this effort is now known commercially as HeatX. It is a low-surface energy, water- and oil-repellent, abrasion resistant material which can be applied in-situ to a wide variety of previously worn/used/in-service substrates. Once applied, it provides a barrier against corrosion, scale deposit formation, and biofilm adhesion on the circulating water-containing tube-side. Alternatively, if applied to the tube exterior, the non-wetting nature of the surface was demonstrated to promote dropwise condensation, subsequently lowering condenser backpressure and increasing overall plant efficiency. As part of this cooperative effort, the Department of Energy’s support was crucial to de-risk and demonstrate the concept of HeatX, while validating both the performance and economic benefit in multiple pilot field studies. The HeatX material properties were optimized in this effort for full field applicability to heat exchangers and condensers, and Oceanit developed the necessary procedures and protocols to provide enough material to support extended length, multi-year demonstrations in the power generation, desalination, and refining industries, making this technology broadly applicable and ready for commercial transition. Field deployment case studies at thermal power plants have shown that the HeatX treatment can provide economic savings of up to $15,000 per day for an operator based on avoiding maintenance costs and lowering fuel usage. The complete mitigation of fouling effects can increase the efficiency of equipment by up to 7%, in a field where gains of 0.5% are generally seen as operationally significant. The HeatX treatment has also demonstrated exceptional lifetime and compatibility with a wide variety of seawater and hydrocarbon environments, further increasing both the return on investment and the effective emission reduction. Such efficiency improvements correlate to massive carbon savings. For every 1 GW of capacity, operators can see carbon emissions reductions of 300,000 tons of CO 2 per year. When looking at the bigger picture, improved condenser function across the U.S. has the potential to prevent 221.3 million tons of CO 2 emissions, equivalent to the sequestration capacity of 129 million acres of forest. If applied on a global scale, 1.26 billion metric tons of CO 2 could be averted from the atmosphere, the same amount of carbon sequestrated by 1.5 billion acres of forest annually or 262,000 wind turbines operating annually. As businesses across multiple industries take a more active role in focusing on environmental, social, and governance (ESG) solutions as part of their core business operations, HeatX will be an attractive technology for commercial investment.

01 COAL, LIGNITE, AND PEAT↗

Resin Testing and Modeling for Optimal Composite Processing

Polymer composites have properties such as high strength and stiffness, low weight, good thermal and chemical stability, as well as impact and abrasion resistance that make them ideal for high-performance applications. The chemistries of these materials are continuously improving, so determining their properties is vital for successfully producing them and achieving the desired results. Multiple methods can be employed to monitor characteristics such as heat flow, weight, dimension, and modulus as a function of time and temperature. By analyzing this information, models can be developed to predict outcomes of parameters not tested for. In one application, materials proposed for wet filament winding and the production of high pressure vessels can be analyzed to verify they will have the necessary low viscosity for good fiber wetting and long pot life for the extended handling inherent to this process. Such data about a prospective system provides valuable information on how that material could ultimately be processed to yield the desired part.

36 MATERIALS SCIENCE↗

Environmentally Friendly Use of Carbon Ore for Advanced Building Materials for Homes and Commercial Buildings

Through this effort, X-MAT CCC sought to confirm the utility and commercialization potential of carbon-derived building materials (CDBM) technology licensed from our partner, Semplastics. These CDBM products contain at least 52% coal-derived carbon by mass. Including the binders within the resin, the products contain at least 71% carbon by mass overall, meeting a key criterion for DE-FOA-0002185 – Area of Interest (AOI) 5 – Design Research and Development, Validation, and Fabrication of a Prototype Carbon-Based Building. The Phase II project has resulted in a technology demonstrator prototype structure, a detailed design for a carbon-based building, and updated techno-economic analysis (TEA) including detailed market surveys to show the commercial viability of CDBM products. We pursued the following objectives in Phase II: (1) construction of a partial building shell as a technology demonstrator, (2) testing of CDBM products, individually and in assemblies, (3) demonstration of bonding of CDBM and traditional building materials (TBM) in structural applications, (4) production of a detailed design for a carbon-based building, and (5) an update of the TEA that was performed in Phase I. In Phase II, X-MAT CCC and our industry team performed the development and testing needed to improve the maturity of the technology from a Technology Readiness Level (TRL) of 5 to TRL 6. CDBM have been shown by our partner Semplastics to exhibit a number of high-performance characteristics, including high strength (five times the flexure strength of the best commercial brick, and more than twice the compressive strength of construction-grade concrete block), lower density, improved mechanical durability and abrasion resistance, very high temperature stability, and resistance to chemicals, acids, salts, and water. These properties offer significant improvements over conventional building materials. Phase II built upon the work accomplished in Phase I by performing technical and economic research and development to confirm the viability of CDBM as commercial products in various markets. Acknowledgment: This material is based upon work supported by the Department of Energy under Award Number DE-FE0031985.

01 COAL, LIGNITE, AND PEAT↗

OES CO 2 Pipeline FEED Project Design Basis Memorandum

The OES CO₂ Pipeline project will move captured carbon dioxide from two ethanol facilities near Gibson City, Illinois, roughly 7.8 miles southeast to three injection wells outside Anchor, where it will be permanently stored underground. The system is designed to handle up to 4.5 million metric tonnes per year of dense-phase CO₂ at pressures up to 2,500 psig, using 16-inch mainline pipe and 10.750-inch laterals made from API 5L X-60 and X-65 steel. Wall thicknesses vary depending on location, with thinner pipe in open country, heavier wall at road crossings, and the heaviest where the pipe passes under highways or railroads via horizontal directional drill. The pipe gets a fusion-bonded epoxy coating, with an added abrasion-resistant layer wherever it's bored or drilled. Major water crossings will use HDD rather than open trenching. The pipeline will be cathodically protected, equipped with SCADA-compatible pressure and temperature instrumentation, and monitored for leaks using a computational pipeline monitoring system per API RP 1130. Hydrostatic testing will be performed at 1.25 times design pressure, and an ILI caliper run will follow to catch any construction defects. Several items, including fracture toughness requirements, specific NDE methods, and ILI tool selection, are left for the detailed design phase. The whole system falls under 49 CFR Part 195 and ASME B31.4, and Gulf Interstate Engineering prepared this document as the FEED-level design basis under the CarbonSAFE Phase III program.

09 BIOMASS FUELS↗

Investigation of Kevlar fabric based materials for use with inflatable structures

Design, manufacture and testing of laminated and coated composite materials incorporating a structural matrix of Kevlar are reported in detail. The practicality of using Kevlar in aerostat materials is demonstrated and data are provided on practical weaves, lamination and coating particulars, rigidity, strength, weight, elastic coefficients, abrasion resistance, crease effects, peel strength, blocking tendencies, helium permeability, and fabrication techniques. Properties of the Kevlar based materials are compared with conventional, Dacron reinforced counterparts. A comprehensive test and qualification program is discussed and quantitative biaxial tensile and shear test data are provided. The investigation shows that single ply laminates of Kevlar and plastic films offer significant strength to weight improvements, are less permeable than two ply coated materials, but have a lower flex life.

Niccum, R. J.↗

Diamine curing agents for polyurethanes

Three aromatic diamines have properties that make them promising candidates as curing agents for converting isocyanates to polyurethanes with higher adhesive strengths, higher softening temperatures, better toughness, and improved abrasion resistance.

Bell, V. L.↗

Aluminum transfer method for plating plastics

Electroless plating technique produces plate of uniform thickness. Hardness and abrasion resistance can be increased further by heat treatment. Method results in seamless coating over many materials, has low thermal conductivity, and is relatively inexpensive compared to conventional methods.

Goodrich, W. D.↗

Friction and abrasion of elastomeric materials

An abrasion apparatus is described. Experimental measurements are reported for four representative elastomeric materials, including a typical high-quality tire tread material and a possible replacement material for aircraft tire treads based on transpolypentenamer (TPPR). Measurements are carried out at different levels of frictional work input, corresponding to different severities of wear, and at both ambient temperature and at 100 C. Results indicate the marked superiority in abrasion resistance of the material based on TPPR, especially at 100 C, in comparison with the other materials examined.

Gent, A. N.↗

Development of a special purpose spacecraft interior coating, phase 1

Coating formulations were developed consisting of latex blends of fluorocarbon polymers, acrylic resins, stabilizers, modifiers, other additives, and a variety of inorganic pigments. Suitable latex primers were also developed from an acrylic latex base. The formulations dried to touch in about one hour and were fully dry in about twenty-four hours under normal room temperature and humidity conditions. The resulting coatings displayed good optical and mechanical properties, including excellent bonding to (pre-treated) substrates. In addition, the preferred compositions were found to be self-extinguishing when applied to nonflammable substrates and could meet the offgassing requirements specified by NASA for the intended application. Improvements are needed in abrasion resistance and hardness.

Bartoszek, E. J.↗

Heavy-duty sandblast nozzle

Inexpensive sialon (silicon/aluminum/oxygen/nitrogen) nozzle liner resists abrasion and is strong at high temperatures.

Pawlik, E. V.↗

Resilient thermal barrier for high temperatures

Abrasion-resistant thermal barrier, consisting of two layers of woven fabric or braided sleeving with bulk insulation sandwiched between, shows excellent resilience even after compression at temperatures above 980C.

Frye, J. A.↗

Investigation of Kevlar fabric-based materials for use with inflatable structures

Design, manufacture and testing of laminated and coated composite materials incorporating a structural matrix of Kevlar are reported. The practicality of using Kevlar in aerostat materials is demonstrated, and data are provided on practical weaves, lamination and coating particulars, rigidity, strength, weight, elastic coefficients, abrasion resistance, crease effects, peel strength, blocking tendencies, helium permeability, and fabrication techniques. Properties of the Kevlar-based materials are compared with conventional Dacron-reinforced counterparts. A comprehensive test and qualification program is discussed, and considerable quantitative biaxial tensile and shear test data are provided.

Niccum, R. J.↗

Special weave for insulating fabrics

Special weave forms tight fabric for high-alumina-content alumina/boria/silica fibers, without leading to expensive filament fracture during weaving process. Resultant abrasion-resistant material is superior to conventional insulating materials at elevated temperatures.

Frye, J. A.↗